CN108913187A - A kind of method of biomass pyrolytic mink cell focus higher value application - Google Patents
A kind of method of biomass pyrolytic mink cell focus higher value application Download PDFInfo
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- CN108913187A CN108913187A CN201810852119.XA CN201810852119A CN108913187A CN 108913187 A CN108913187 A CN 108913187A CN 201810852119 A CN201810852119 A CN 201810852119A CN 108913187 A CN108913187 A CN 108913187A
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- 239000002028 Biomass Substances 0.000 title claims abstract description 106
- 241000772415 Neovison vison Species 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 37
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 21
- 239000000126 substance Substances 0.000 claims abstract description 16
- 239000003610 charcoal Substances 0.000 claims abstract description 9
- 238000003763 carbonization Methods 0.000 claims abstract description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- 239000002956 ash Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000005864 Sulphur Substances 0.000 claims description 5
- NKTOLZVEWDHZMU-UHFFFAOYSA-N 2,5-xylenol Chemical compound CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 claims description 4
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 240000008042 Zea mays Species 0.000 claims description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 4
- 235000005822 corn Nutrition 0.000 claims description 4
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims description 4
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001555 benzenes Chemical class 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 238000000197 pyrolysis Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- -1 2- metoxyphenol Chemical compound 0.000 claims description 2
- CHWNEIVBYREQRF-UHFFFAOYSA-N 4-Ethyl-2-methoxyphenol Chemical compound CCC1=CC=C(O)C(OC)=C1 CHWNEIVBYREQRF-UHFFFAOYSA-N 0.000 claims description 2
- KSZVOXHGCKKOLL-UHFFFAOYSA-N 4-Ethynyltoluene Chemical compound CC1=CC=C(C#C)C=C1 KSZVOXHGCKKOLL-UHFFFAOYSA-N 0.000 claims description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 241000209140 Triticum Species 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 238000007233 catalytic pyrolysis Methods 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000010907 stover Substances 0.000 claims description 2
- 239000010902 straw Substances 0.000 claims description 2
- 150000008331 benzenesulfonamides Chemical class 0.000 claims 1
- LXXWKCAIQDMAJD-UHFFFAOYSA-N phenol;toluene Chemical compound CC1=CC=CC=C1.OC1=CC=CC=C1 LXXWKCAIQDMAJD-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 19
- 239000006227 byproduct Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 4
- 239000000295 fuel oil Substances 0.000 abstract description 4
- 239000000618 nitrogen fertilizer Substances 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 210000004027 cell Anatomy 0.000 description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000011269 tar Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000011280 coal tar Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000002336 sorption--desorption measurement Methods 0.000 description 3
- 239000012075 bio-oil Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a kind of methods of biomass pyrolytic mink cell focus higher value application, it includes, biomass mink cell focus is placed in biomass charing device and is carbonized, adjustment carbonization temperature range is 450~950 DEG C, obtains biomass light oil, biomass carbon and biogas.The method of present invention offer biomass pyrolytic mink cell focus higher value application; overcome the disadvantages of biomass heavy oil viscosity is big, ash content is high; so that the biomass mink cell focus of forest chemical by-product is turned waste into wealth; utilize biomass charing device next life generation matter light oil, biogas and charcoal; significantly improve the level of resources utilization; it preserves the ecological environment, while production technology of the present invention is simple and convenient to operate very much, and cost and production time is greatly saved.Obtained biomass carbon can be used for the fields such as the fixed nitrogen fertilizer in agricultural, the catalyst carrier in industry, be with a wide range of applications.
Description
Technical field
The invention belongs to forest chemical technical fields, and in particular to a kind of side of biomass pyrolytic mink cell focus higher value application
Method.
Background technique
As increasingly depleted and people the environmental consciousness of conventional fossil fuel constantly enhances, biomass resource is in this year
To get the attention.The main Land use systems form biomass pyrolysis of biomass resource, in biomass pyrolytic or fast pyrogenation
In the process, in addition to generating the lesser bio-oil of density, and the biomass mink cell focus that can not largely efficiently use is produced.This
Kind of biomass pyrolytic heavy oil viscosity is big, poor fluidity, the disadvantages of calorific value is low, combustion quality is poor, can not industrially utilize.Cause
This, there is an urgent need to develop the higher value application methods of Biomass mink cell focus.
Patent CN104130799A " a kind of coal tar catalysis upgrading method ", is to increase catalytic section in coking of coal technique,
Crack heavy tar with Fe-series catalyst or 13X molecular sieve catalytic, with improve coal tar using ingredient, which gives
The Efficient utilization method of coal tar, however the utilization method in relation to biomass mink cell focus is but extremely short of at present.
Summary of the invention
The purpose of this section is to summarize some aspects of the embodiment of the present invention and briefly introduce some preferable implementations
Example.It may do a little simplified or be omitted to avoid our department is made in this section and the description of the application and the title of the invention
Point, the purpose of abstract of description and denomination of invention it is fuzzy, and this simplification or omit and cannot be used for limiting the scope of the invention.
In view of above-mentioned technological deficiency, the present invention is proposed.
Therefore, the present invention overcomes the deficiencies in the prior art, provides a kind of high-valued benefit of biomass pyrolytic mink cell focus
Method.
In order to solve the above technical problems, the present invention provides following technical solutions：A kind of biomass pyrolytic mink cell focus high level
Change the method utilized comprising,
Biomass mink cell focus is placed in biomass charing device and is carbonized, adjustment carbonization temperature range is 450~950
DEG C, obtain biomass light oil, biomass carbon and biogas.
A kind of preferred embodiment of method as biomass pyrolytic mink cell focus higher value application of the present invention：The life
The source of substance mink cell focus includes produced by the slow pyrolysis, fast pyrogenation, catalytic pyrolysis of biomass material.
A kind of preferred embodiment of method as biomass pyrolytic mink cell focus higher value application of the present invention：The life
Substance mink cell focus, in terms of mass fraction, content of ashes 3~20%, moisture content 0.1~10%, volatile matter content 1~
20%, total sulphur content 0.01~2%, 8~100KJ/g of low heat valve.
A kind of preferred embodiment of method as biomass pyrolytic mink cell focus higher value application of the present invention：The charcoal
Change, temperature range is 450~650 DEG C.
A kind of preferred embodiment of method as biomass pyrolytic mink cell focus higher value application of the present invention：Described
Biomass light oil, component include naphthalene, phenol and phenol derivatives, acetic acid, methanol, ethyl alcohol, hydroxypropanone-, furfural, benzene and
Benzene derivative.
A kind of preferred embodiment of method as biomass pyrolytic mink cell focus higher value application of the present invention：The life
Substance gas, component include water, hydrogen, methane, carbon monoxide, carbon dioxide.
A kind of preferred embodiment of method as biomass pyrolytic mink cell focus higher value application of the present invention：The life
Raw material of substance includes wheat stalk, corn stover, rice straw, corn ear, sawdust.
A kind of preferred embodiment of method as biomass pyrolytic mink cell focus higher value application of the present invention：The benzene
Amphyl includes 2- methoxyl group -4- methylphenol, 2,5- xylenol, 2- metoxyphenol, 2- methylphenol, 3- methyl
Phenol, 4- ethyl -2- metoxyphenol, 4- ethyl -3- metoxyphenol, 4- ethyl -phenol, 1- acetenyl -4- methylbenzene.
A kind of preferred embodiment of method as biomass pyrolytic mink cell focus higher value application of the present invention：The benzene
Derivative includes toluene, dimethylbenzene, 1- acetenyl -4- toluene
Beneficial effects of the present invention：Biomass mink cell focus is mainly used for directly burning at present, but calorific value is low, charcoal particulate emission
Greatly, environment is polluted, the techniques such as catalytic hydrogenation upgrading are also not used to, the present invention provides biomass pyrolytic mink cell focus higher value application
Method, the disadvantages of biomass heavy oil viscosity is big, ash content is high is overcome, so that the biomass mink cell focus of forest chemical by-product becomes
Waste be changed into values, using biomass charing device next life generation matter light oil, biogas and charcoal, significantly improves resource benefit
It with efficiency, preserves the ecological environment, while production technology of the present invention is simple and convenient to operate very much, and cost and production is greatly saved
Time.Obtained biomass carbon can be used for the fields such as the fixed nitrogen fertilizer in agricultural, the catalyst carrier in industry, have wide
General application prospect.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment
Attached drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for this
For the those of ordinary skill of field, without any creative labor, it can also be obtained according to these attached drawings other
Attached drawing.Wherein：
Fig. 1 is biomass charing device schematic diagram of the present invention.
Fig. 2 is the field emission scanning electron microscope figure of biomass carbon prepared by the present invention.
Fig. 3 is nitrogen adsorption-desorption curve of biomass carbon prepared by the present invention.
Specific embodiment
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, right combined with specific embodiments below
A specific embodiment of the invention is described in detail.
In the following description, numerous specific details are set forth in order to facilitate a full understanding of the present invention, but the present invention can be with
Implemented using other than the one described here other way, those skilled in the art can be without prejudice to intension of the present invention
In the case of do similar popularization, therefore the present invention is not limited by the specific embodiments disclosed below.
Secondly, " one embodiment " or " embodiment " referred to herein, which refers to, may be included at least one realization side of the invention
A particular feature, structure, or characteristic in formula." in one embodiment " that different places occur in the present specification not refers both to
The same embodiment, nor the individual or selective embodiment mutually exclusive with other embodiments.
Embodiment 1：
For the biomass mink cell focus used in the present embodiment for the by-product tar of forest chemical, indices are as follows：Ash content
Content 7.81%, moisture content 0.20%, volatile matter content 8.01%, total sulphur content 0.03%, low heat valve 30.9KJ/g.
Above-mentioned biomass mink cell focus 220.00g is weighed, is placed in biomass charing device, is carbonized at 550 DEG C, is made
Obtain biomass light oil 22.72g, biomass carbon 91.02g and biogas condensate liquid 42.18g, biomass light oil, biomass carbon
Yield with biogas is respectively 10%, 41% and 19%.
The measurement of nitrogen adsorption-desorption curve is carried out to gained biomass carbon.II is presented in the adsorption curve of the biomass carbon
H3 type is presented in type, lag loop, which does not show any absorption limitation in higher relative pressure region.Above-mentioned knot
Fruit shows that the cellular structure of biomass carbon prepared through the invention is mainly macropore, is calculated by BET method, obtains its ratio
Surface area is 20.3m2/g。
The composition of biomass light oil is as shown in table 1.
The composition of 1 biomass light oil of table
Embodiment 2：
For the biomass mink cell focus used in the present embodiment for the by-product tar of forest chemical, indices are as follows：Ash content
Content 7.81%, moisture content 0.20%, volatile matter content 8.01%, total sulphur content 0.03%, low heat valve 30.9KJ/g.
Above-mentioned biomass mink cell focus 220.00g is weighed, is placed in biomass charing device, is carbonized at 450 DEG C, is made
Obtain biomass light oil 22.72g, biomass carbon 91.02g and biogas condensate liquid 42.18g, biomass light oil, biomass carbon
Yield with biogas is respectively 15%, 46% and 15%.
Embodiment 3：
For the biomass mink cell focus used in the present embodiment for the by-product tar of forest chemical, indices are as follows：Ash content
Content 7.81%, moisture content 0.20%, volatile matter content 8.01%, total sulphur content 0.03%, low heat valve 30.9KJ/g.
Above-mentioned biomass mink cell focus 220.00g is weighed, is placed in biomass charing device, is carbonized at 650 DEG C, is made
Obtain biomass light oil 22.72g, biomass carbon 91.02g and biogas condensate liquid 42.18g, biomass light oil, biomass carbon
Yield with biogas is respectively 20%, 35% and 25%.
The iodine number range of biomass carbon prepared by the present invention is 400~1300, and specific surface area range is 10~1500m2/
g.The group of biogas prepared by the present invention is divided into water, hydrogen, methane, carbon monoxide, carbon dioxide.
Fig. 1 is biomass charing device schematic diagram of the present invention.The biomass charing device that the present invention uses includes following four
A unit：High temperature carbonization unit, condensing unit, water-oil separating unit, Fraction collection unit, the present invention is first by biomass mink cell focus
It is added to biomass carbonated unit, is heated, after reacting, condensing, discovery can be collected into biomass light oil, generated
Gas is biogas.Fig. 2 is the field emission scanning electron microscope figure of biomass carbon prepared by the present invention.Fig. 3 is prepared by the present invention
Nitrogen adsorption-desorption curve of biomass carbon.
It is noted that the present invention uses biomass charing device to re-use biomass mink cell focus for the first time,
Meanwhile present invention firstly discovers that：Bio oil can generate biomass carbon, biological light oil after the charing of the method for the present invention,
And the research of the invention finds that the carbonization temperature pair of biomass charing device of the present invention and products therefrom component have apparent shadow
It ringing, the present invention carbonizes at 650 DEG C, obtained biomass light oil and biogas yield highest, and at 450 DEG C
The biomass carbon yield highest arrived, the present invention can regulate and control light oil, substance charcoal and biogas by regulation carbonization temperature
Yield.
Biomass mink cell focus is mainly used for directly burning at present, but calorific value is low, and charcoal particulate emission is big, pollute environment, also without
Method provides the method for biomass pyrolytic mink cell focus higher value application, overcomes life for the techniques such as catalytic hydrogenation upgrading, the present invention
The disadvantages of substance heavy oil viscosity is big, ash content is high utilizes biology so that the biomass mink cell focus of forest chemical by-product is turned waste into wealth
Matter carbonizing apparatus next life generation matter light oil, biogas and charcoal, significantly improve the level of resources utilization, protecting ecology
Environment, while production technology of the present invention is simple and convenient to operate very much, and cost and production time is greatly saved.Obtained life
Substance charcoal can be used for the fields such as the fixed nitrogen fertilizer in agricultural, the catalyst carrier in industry, be with a wide range of applications.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to preferable
Embodiment describes the invention in detail, those skilled in the art should understand that, it can be to technology of the invention
Scheme is modified or replaced equivalently, and without departing from the spirit and scope of the technical solution of the present invention, should all be covered in this hair
In bright scope of the claims.
Claims (9)
1. a kind of method of biomass pyrolytic mink cell focus higher value application, it is characterised in that：Including,
Biomass mink cell focus is placed in biomass charing device and is carbonized, adjustment carbonization temperature range is 450~950 DEG C,
Obtain biomass light oil, biomass carbon and biogas.
2. the method for biomass pyrolytic mink cell focus higher value application as described in claim 1, it is characterised in that：The biomass
The source of mink cell focus includes produced by the slow pyrolysis, fast pyrogenation, catalytic pyrolysis of biomass material.
3. the method for biomass pyrolytic mink cell focus higher value application as claimed in claim 1 or 2, it is characterised in that：The life
Substance mink cell focus, in terms of mass fraction, content of ashes 3~20%, moisture content 0.1~10%, volatile matter content 1~
20%, total sulphur content 0.01~2%, 8~100KJ/g of low heat valve.
4. the method for biomass pyrolytic mink cell focus higher value application as claimed in claim 1 or 2, it is characterised in that：The charcoal
Change, temperature range is 450~650 DEG C.
5. the method for biomass pyrolytic mink cell focus higher value application as claimed in claim 1 or 2, it is characterised in that：Described
Biomass light oil, component include naphthalene, phenol and phenol derivatives, acetic acid, methanol, ethyl alcohol, hydroxypropanone-, furfural, benzene and
Benzene derivative.
6. the method for biomass pyrolytic mink cell focus higher value application as claimed in claim 1 or 2, it is characterised in that：The life
Substance gas, component include water, hydrogen, methane, carbon monoxide, carbon dioxide.
7. the method for biomass pyrolytic mink cell focus higher value application as claimed in claim 2, it is characterised in that：The biomass
Raw material includes wheat stalk, corn stover, rice straw, corn ear, sawdust.
8. the method for biomass pyrolytic mink cell focus higher value application as claimed in claim 5, it is characterised in that：The phenol spreads out
Biology includes 2- methoxyl group -4- methylphenol, 2,5- xylenol, 2- metoxyphenol, 2- methylphenol, 3- methylbenzene
Phenol, 4- ethyl -2- metoxyphenol, 4- ethyl -3- metoxyphenol, 4- ethyl -phenol, 1- acetenyl -4- methylbenzene.
9. the method for biomass pyrolytic mink cell focus higher value application as claimed in claim 5, it is characterised in that：The benzenesulfonamide derivative
Object includes toluene, dimethylbenzene, 1- acetenyl -4- toluene.
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| CN108913187B CN108913187B (en) | 2020-12-01 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110286106A (en) * | 2019-06-13 | 2019-09-27 | 中国石油集团渤海钻探工程有限公司 | 3-D quantitative fluorescence index for oiliness calculation method |
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| CN108410485A (en) * | 2018-04-13 | 2018-08-17 | 北京三聚绿能科技有限公司 | A kind of method of biomass pyrolysis |
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2018
- 2018-07-30 CN CN201810852119.XA patent/CN108913187B/en not_active Expired - Fee Related
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| CN101602953A (en) * | 2009-07-22 | 2009-12-16 | 丁赤民 | The purification system of straw quick thermal cracking products |
| CN102070408A (en) * | 2010-12-10 | 2011-05-25 | 华北电力大学 | Method for preparing light phenol organic mixture through catalytic pyrolysis of biomass |
| CN102838453A (en) * | 2012-08-28 | 2012-12-26 | 华北电力大学 | Method to prepare phenolic organic mixture preparation by means of catalytic pyrolysis of biomass through coke |
| CN108410485A (en) * | 2018-04-13 | 2018-08-17 | 北京三聚绿能科技有限公司 | A kind of method of biomass pyrolysis |
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| CN110286106A (en) * | 2019-06-13 | 2019-09-27 | 中国石油集团渤海钻探工程有限公司 | 3-D quantitative fluorescence index for oiliness calculation method |
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