CN108911506A - A kind of processing technology of abrasion-resistance glass cup - Google Patents

A kind of processing technology of abrasion-resistance glass cup Download PDF

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Publication number
CN108911506A
CN108911506A CN201811036804.1A CN201811036804A CN108911506A CN 108911506 A CN108911506 A CN 108911506A CN 201811036804 A CN201811036804 A CN 201811036804A CN 108911506 A CN108911506 A CN 108911506A
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abrasion
glass cup
resistance glass
parts
processing technology
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朱梦祎
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00Annealing glass products
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/04Tempering or quenching glass products using gas
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/004Refining agents
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/003General methods for coating; Devices therefor for hollow ware, e.g. containers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of processing technology of abrasion-resistance glass cup, the processing technology includes the following steps:(1) processing of cullet;(2) material mixes:Weigh the raw material of following parts by weight:50~80 parts of powder particles, 45~70 parts of calcites, 30~40 parts of lime stones, 15~20 parts of silica, 5~10 parts of boraxs, 2~6 parts of soda ash, 1~5 portion of salt, 0.1~0.8 part of calcium oxide, 0.01~0.05 part of cobalt powder, 0.6~1.8 part of compound clarifier, above-mentioned raw materials are mixed evenly to obtain mixture;(3) sinter molding;(4) it anneals;(5) Plate making printing;(6) abrasion-resistance glass cup tempering.The processing technology of abrasion-resistance glass cup of the invention can eliminate the interior pressure of abrasion-resistance glass cup body, avoid bursting and the cracking phenomena in later period use in production process, and simplify coating operation process, increase the tightness of film plating layer, the abrasion-resistance glass cup bright color produced, light transmittance is high, long service life.

Description

A kind of processing technology of abrasion-resistance glass cup
Technical field
The present invention relates to abrasion-resistance glass cup technical fields, and in particular to a kind of processing technology of abrasion-resistance glass cup.
Background technique
The manufacture of abrasion-resistance glass cup is typically passed through ingredient, four procedures of melting, molding and annealing.In forming process, It needs for the glass stoste of molten condition to be injected into the molding die with water-cooling system, rapid cooling molding, so that big portion To divide energy deposition in abrasion-resistance glass cup body, forms so-called internal stress, internal stress is excessive, cup body cracking is easily caused, and disappear Except internal stress just needs to anneal to abrasion-resistance glass cup, by the internal stresses release in abrasion-resistance glass cup body.
Current annealing temperature is normally controlled between 300~400 DEG C, in practical annealing process, especially high saturating In the annealing process of lightness abrasion-resistance glass cup, the internal stress in cup body cannot more thoroughly be eliminated, to influence abrasion-resistance glass The quality of cup and use are safe.
Summary of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, a kind of processing technology of abrasion-resistance glass cup is provided, The processing technology can eliminate the interior pressure of abrasion-resistance glass cup body, avoid bursting and the cracking in later period use in production process Phenomenon, and coating operation process is simplified, the tightness of film plating layer is increased, the abrasion-resistance glass cup bright color produced, Light transmittance is high, long service life.
The present invention solves technical problem and adopts the following technical scheme that:
A kind of processing technology of abrasion-resistance glass cup, includes the following steps:
(1) processing of cullet:It chooses to be sent into acid solution without lead white cullet and impregnate 2~3 hours, used after taking-up Giant rinses, and places into 40~50 DEG C of oven dryings 2~3 hours;It is sent into Universalpulverizer after drying to crush, is re-fed into mill Powder machine is ground into 40~60 mesh powder particle a;
(2) material mixes:Weigh the raw material of following parts by weight:50~80 parts of powder particle a, 45~70 parts of calcites, 30 ~40 parts of lime stones, 15~20 parts of silica, 5~10 parts of boraxs, 2~6 parts of soda ash, 1~5 portion of salt, 0.1~0.8 part of oxygen Change calcium, 0.01~0.05 part of cobalt powder, 0.6~1.8 part of compound clarifier, above-mentioned raw materials are mixed evenly to obtain mixture;
(3) sinter molding:It feeds the mixture into high temperature kiln, is fired 6~8 hours at 1200~1300 DEG C, use stone Inker, which is slowly stirred, reaches molten condition;It is re-fed into molding machine, temperature setting is 950~980 DEG C, according to abrasion-resistance glass cup specification Abrasion-resistance glass cup is made;
(4) it anneals:Molding abrasion-resistance glass cup is sent into 650~680 DEG C of annelaing pot, is cooled down 2~3 hours to 180 At~200 DEG C, abrasion-resistance glass cup is taken out, is naturally cooling to room temperature, the abrasion-resistance glass cup after being annealed;
(5) Plate making printing:It is thrown the net using screen cloth, and is arranged to scheduled decorative pattern requirement, stand 16~20 hours after the completion; Ink printing is carried out to abrasion-resistance glass cup again;
(6) abrasion-resistance glass cup tempering:Abrasion-resistance glass cup after printing is sent into 600~700 DEG C of annealing furnace, every 1mm The heating time of thickness is 50~60s, and the temperature adjusting range for heating single is 6~10 DEG C;Quenching after tempering, every 3mm Thickness chilling wind pressure be total wind pressure 85~95%.
Preferably, step (1) acid solution be concentration 15~20% hydrofluoric acid solution and 5~10% nitric acid solution According to volume ratio 3:1 is formulated.
Preferably, the compound clarifier is that compound rare-earth factory cerium slag forms in clarifying agent.
Preferably, the volumetric injection of step (3) molding machine is 40~100cm3, and injection pressure is 10~20MPa.
Preferably, the specification of step (5) screen cloth is 100~200 mesh, and tension is 100~150N.
Preferably, the thickness control of ink layer is in 1~3mm when step (5) ink prints.
Preferably, quenching is carried out again after standing 30~40min after step (6) the tempering processing.
Preferably, total wind pressure of step (6) quenching is maintained at 20~35MPa.
Compared with prior art, the present invention has following beneficial effect:
(1) processing technology of abrasion-resistance glass cup of the invention, the main processing including cullet, sinter into material mixing Type, annealing, Plate making printing, abrasion-resistance glass cup tempering, which can eliminate the interior pressure of abrasion-resistance glass cup body, avoid In production process burst with the cracking phenomena in later period use, and simplify coating operation process, increase film plating layer Tightness, the abrasion-resistance glass cup bright color produced, light transmittance is high, long service life.
(2) in abrasion-resistance glass cup raw material of the invention, having chosen cullet turns waste into wealth, and there are also common calcites, stone Lime stone, silica, low in cost, the compound clarifier for being added to cerium slag is not only added to wear-resisting and tensile resistance, also increases The transparency of glass is added;650~680 DEG C of annealing temperature eliminates the internal stress and heat resistance of abrasion-resistance glass cup body, mentions High quality;The printing plated film of decorative pattern fits closely, beautiful succinct, improves the user satisfaction of user;According to thickness of glass Tempering processing and quenching ensure that the quality stability and technology stability of abrasion-resistance glass cup, be suitble to large-scale production.
Specific embodiment
Invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1.
A kind of processing technology of abrasion-resistance glass cup, includes the following steps:
(1) processing of cullet:It chooses to be sent into acid solution without lead white cullet and impregnate 2.5 hours, used after taking-up Giant rinses, and places into 40~50 DEG C of oven dryings 2~3 hours;It is sent into Universalpulverizer after drying to crush, is re-fed into mill Powder machine is ground into 40~60 mesh powder particle a;Acid solution be concentration 15% hydrofluoric acid solution and 6% nitric acid solution according to Volume ratio 3:1 is formulated.
(2) material mixes:Weigh the raw material of following parts by weight:56 parts of powder particle a, 48 parts of calcites, 35 parts of lime stones, 16 parts of silica, 8 parts of boraxs, 3 parts of soda ash, 2 portions of salt, 0.5 part of calcium oxide, 0.02 part of cobalt powder, 0.9 part of compound clarifier, Above-mentioned raw materials are mixed evenly to obtain mixture;Compound clarifier is that compound rare-earth factory cerium slag forms in clarifying agent.
(3) sinter molding:It feeds the mixture into high temperature kiln, is fired 6.6 hours at 1230 DEG C, it is slow using graphite rod Stirring reaches molten condition;It is re-fed into molding machine, temperature setting is 960 DEG C, and abrasion-resistance glass is made according to abrasion-resistance glass cup specification Cup;Wherein, the volumetric injection of molding machine is 40~100cm3, and injection pressure is 10~20MPa.
(4) it anneals:Molding abrasion-resistance glass cup is sent into 650~680 DEG C of annelaing pot, is cooled down 2~3 hours to 180 At~200 DEG C, abrasion-resistance glass cup is taken out, is naturally cooling to room temperature, the abrasion-resistance glass cup after being annealed.
(5) Plate making printing:It is thrown the net using screen cloth, and is arranged to scheduled decorative pattern requirement, stand 16~20 hours after the completion; Ink printing is carried out to abrasion-resistance glass cup again;Wherein, the specification of screen cloth is 100~200 mesh, and tension is 100~150N, ink print The thickness control of ink layer is in 1~3mm when brush.
(6) abrasion-resistance glass cup tempering:Abrasion-resistance glass cup after printing is sent into 600~700 DEG C of annealing furnace, every 1mm The heating time of thickness is 50~60s, and the temperature adjusting range for heating single is 6~10 DEG C;It is anxious that 30~40min is stood after tempering Cold treatment, the thickness chilling wind pressure of every 3mm are the 85~95% of total wind pressure, and total wind pressure is maintained at 20~35Mpa.
Embodiment 2.
A kind of processing technology of abrasion-resistance glass cup, includes the following steps:
(1) processing of cullet:It chooses to be sent into acid solution without lead white cullet and impregnate 2.5 hours, used after taking-up Giant rinses, and places into 40~50 DEG C of oven dryings 2~3 hours;It is sent into Universalpulverizer after drying to crush, is re-fed into mill Powder machine is ground into 40~60 mesh powder particle a;Acid solution be concentration 17% hydrofluoric acid solution and 8% nitric acid solution according to Volume ratio 3:1 is formulated.
(2) material mixes:Weigh the raw material of following parts by weight:72 parts of powder particle a, 52 parts of calcites, 38 parts of lime stones, 15 parts of silica, 7 parts of boraxs, 2 parts of soda ash, 3 portions of salt, 0.5 part of calcium oxide, 0.03 part of cobalt powder, 1 part of compound clarifier, will Above-mentioned raw materials are mixed evenly to obtain mixture;Compound clarifier is that compound rare-earth factory cerium slag forms in clarifying agent.
(3) sinter molding:It feeds the mixture into high temperature kiln, fires 7 hours at 1250 DEG C, slowly stirred using graphite rod It mixes and reaches molten condition;It is re-fed into molding machine, temperature setting is 970 DEG C, and abrasion-resistance glass cup is made according to abrasion-resistance glass cup specification; Wherein, the volumetric injection of molding machine is 40~100cm3, and injection pressure is 10~20MPa.
(4) it anneals:Molding abrasion-resistance glass cup is sent into 650~680 DEG C of annelaing pot, is cooled down 2~3 hours to 180 At~200 DEG C, abrasion-resistance glass cup is taken out, is naturally cooling to room temperature, the abrasion-resistance glass cup after being annealed.
(5) Plate making printing:It is thrown the net using screen cloth, and is arranged to scheduled decorative pattern requirement, stand 16~20 hours after the completion; Ink printing is carried out to abrasion-resistance glass cup again;Wherein, the specification of screen cloth is 100~200 mesh, and tension is 100~150N, ink print The thickness control of ink layer is in 1~3mm when brush.
(6) abrasion-resistance glass cup tempering:Abrasion-resistance glass cup after printing is sent into 600~700 DEG C of annealing furnace, every 1mm The heating time of thickness is 50~60s, and the temperature adjusting range for heating single is 6~10 DEG C;It is anxious that 30~40min is stood after tempering Cold treatment, the thickness chilling wind pressure of every 3mm are the 85~95% of total wind pressure, and total wind pressure is maintained at 20~35Mpa.
Embodiment 3.
A kind of processing technology of abrasion-resistance glass cup, includes the following steps:
(1) processing of cullet:It chooses to be sent into acid solution without lead white cullet and impregnate 2.6 hours, used after taking-up Giant rinses, and places into 40~50 DEG C of oven dryings 2~3 hours;It is sent into Universalpulverizer after drying to crush, is re-fed into mill Powder machine is ground into 40~60 mesh powder particle a;Acid solution be concentration 17% hydrofluoric acid solution and 9% nitric acid solution according to Volume ratio 3:1 is formulated.
(2) material mixes:Weigh the raw material of following parts by weight:70 parts of powder particle a, 50 parts of calcites, 35 parts of lime stones, 20 parts of silica, 9 parts of boraxs, 5 parts of soda ash, 4 portions of salt, 0.6 part of calcium oxide, 0.02 part of cobalt powder, 1.5 parts of compound clarifiers, Above-mentioned raw materials are mixed evenly to obtain mixture;Compound clarifier is that compound rare-earth factory cerium slag forms in clarifying agent.
(3) sinter molding:It feeds the mixture into high temperature kiln, is fired 7.5 hours at 1280 DEG C, it is slow using graphite rod Stirring reaches molten condition;It is re-fed into molding machine, temperature setting is 960 DEG C, and abrasion-resistance glass is made according to abrasion-resistance glass cup specification Cup;Wherein, the volumetric injection of molding machine is 40~100cm3, and injection pressure is 10~20MPa.
(4) it anneals:Molding abrasion-resistance glass cup is sent into 650~680 DEG C of annelaing pot, is cooled down 2~3 hours to 180 At~200 DEG C, abrasion-resistance glass cup is taken out, is naturally cooling to room temperature, the abrasion-resistance glass cup after being annealed.
(5) Plate making printing:It is thrown the net using screen cloth, and is arranged to scheduled decorative pattern requirement, stand 16~20 hours after the completion; Ink printing is carried out to abrasion-resistance glass cup again;Wherein, the specification of screen cloth is 100~200 mesh, and tension is 100~150N, ink print The thickness control of ink layer is in 1~3mm when brush.
(6) abrasion-resistance glass cup tempering:Abrasion-resistance glass cup after printing is sent into 600~700 DEG C of annealing furnace, every 1mm The heating time of thickness is 50~60s, and the temperature adjusting range for heating single is 6~10 DEG C;It is anxious that 30~40min is stood after tempering Cold treatment, the thickness chilling wind pressure of every 3mm are the 85~95% of total wind pressure, and total wind pressure is maintained at 20~35Mpa.
Embodiment 4.
A kind of processing technology of abrasion-resistance glass cup, includes the following steps:
(1) processing of cullet:It chooses to be sent into acid solution without lead white cullet and impregnate 3 hours, height is used after taking-up It presses hydraulic giant to rinse, places into 40~50 DEG C of oven dryings 2~3 hours;It is sent into Universalpulverizer after drying to crush, is re-fed into milling Machine is ground into 40~60 mesh powder particle a;Acid solution be concentration 15% hydrofluoric acid solution and 5% nitric acid solution according to body Product ratio 3:1 is formulated.
(2) material mixes:Weigh the raw material of following parts by weight:80 parts of powder particle a, 60 parts of calcites, 40 parts of lime stones, 20 parts of silica, 10 parts of boraxs, 6 parts of soda ash, 5 portions of salt, 0.8 part of calcium oxide, 0.05 part of cobalt powder, 1.6 parts of compound clarifiers, Above-mentioned raw materials are mixed evenly to obtain mixture;Compound clarifier is that compound rare-earth factory cerium slag forms in clarifying agent.
(3) sinter molding:It feeds the mixture into high temperature kiln, fires 6 hours at 1300 DEG C, slowly stirred using graphite rod It mixes and reaches molten condition;It is re-fed into molding machine, temperature setting is 980 DEG C, and abrasion-resistance glass cup is made according to abrasion-resistance glass cup specification; Wherein, the volumetric injection of molding machine is 40~100cm3, and injection pressure is 10~20MPa.
(4) it anneals:Molding abrasion-resistance glass cup is sent into 650~680 DEG C of annelaing pot, is cooled down 2~3 hours to 180 At~200 DEG C, abrasion-resistance glass cup is taken out, is naturally cooling to room temperature, the abrasion-resistance glass cup after being annealed;
(5) Plate making printing:It is thrown the net using screen cloth, and is arranged to scheduled decorative pattern requirement, stand 16~20 hours after the completion; Ink printing is carried out to abrasion-resistance glass cup again;Wherein, the specification of screen cloth is 100~200 mesh, and tension is 100~150N, ink print The thickness control of ink layer is in 1~3mm when brush.
(6) abrasion-resistance glass cup tempering:Abrasion-resistance glass cup after printing is sent into 600~700 DEG C of annealing furnace, every 1mm The heating time of thickness is 50~60s, and the temperature adjusting range for heating single is 6~10 DEG C;It is anxious that 30~40min is stood after tempering Cold treatment, the thickness chilling wind pressure of every 3mm are the 85~95% of total wind pressure, and total wind pressure is maintained at 20~35Mpa.
The processing technology of abrasion-resistance glass cup of the invention, the main processing including cullet, material mixing, sinter molding, Annealing, Plate making printing, abrasion-resistance glass cup tempering, which can eliminate the interior pressure of abrasion-resistance glass cup body, avoid giving birth to During production burst with the cracking phenomena in later period use, and simplify coating operation process, increase the tight of film plating layer Density, the abrasion-resistance glass cup bright color produced, light transmittance is high, long service life.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications It should be regarded as protection scope of the present invention.

Claims (8)

1. a kind of processing technology of abrasion-resistance glass cup, which is characterized in that include the following steps:
(1) processing of cullet:It chooses to be sent into acid solution without lead white cullet and impregnate 2~3 hours, high pressure is used after taking-up Hydraulic giant rinses, and places into 40~50 DEG C of oven dryings 2~3 hours;It is sent into Universalpulverizer after drying to crush, is re-fed into flour mill It is ground into 40~60 mesh powder particle a;
(2) material mixes:Weigh the raw material of following parts by weight:50~80 parts of powder particle a, 45~70 parts of calcites, 30~40 Part lime stone, 15~20 parts of silica, 5~10 parts of boraxs, 2~6 parts of soda ash, 1~5 portion of salt, 0.1~0.8 part of calcium oxide, 0.01~0.05 part of cobalt powder, 0.6~1.8 part of compound clarifier, above-mentioned raw materials are mixed evenly to obtain mixture;
(3) sinter molding:It feeds the mixture into high temperature kiln, is fired 6~8 hours at 1200~1300 DEG C, use graphite rod It is slowly stirred and reaches molten condition;It is re-fed into molding machine, temperature setting is 950~980 DEG C, is made according to abrasion-resistance glass cup specification Abrasion-resistance glass cup;
(4) it anneals:Molding abrasion-resistance glass cup is sent into 650~680 DEG C of annelaing pot, is cooled down 2~3 hours to 180~200 DEG C when, take out abrasion-resistance glass cup, be naturally cooling to room temperature, the abrasion-resistance glass cup after being annealed;
(5) Plate making printing:It is thrown the net using screen cloth, and is arranged to scheduled decorative pattern requirement, stand 16~20 hours after the completion;It is right again Abrasion-resistance glass cup carries out ink printing;
(6) abrasion-resistance glass cup tempering:Abrasion-resistance glass cup after printing is sent into 600~700 DEG C of annealing furnace, every 1mm thickness Heating time be 50~60s, heat single temperature adjusting range be 6~10 DEG C;Quenching after tempering, the thickness of every 3mm Spend 85~95% that chilling wind pressure is total wind pressure.
2. the processing technology of abrasion-resistance glass cup according to claim 1, which is characterized in that step (1) acid solution is The hydrofluoric acid solution of concentration 15~20% and 5~10% nitric acid solution according to volume ratio 3:1 is formulated.
3. the processing technology of abrasion-resistance glass cup according to claim 1, which is characterized in that the compound clarifier is clear Qing Jizhong compound rare-earth factory cerium slag forms.
4. the processing technology of abrasion-resistance glass cup according to claim 1, which is characterized in that step (3) molding machine Volumetric injection is 40~100cm3, and injection pressure is 10~20MPa.
5. the processing technology of abrasion-resistance glass cup according to claim 1, which is characterized in that the rule of step (5) screen cloth Lattice are 100~200 mesh, and tension is 100~150N.
6. the processing technology of abrasion-resistance glass cup according to claim 1, which is characterized in that step (5) the ink printing When ink layer thickness control in 1~3mm.
7. the processing technology of abrasion-resistance glass cup according to claim 1, which is characterized in that step (6) the tempering processing Quenching is carried out again after standing 30~40min afterwards.
8. the processing technology of abrasion-resistance glass cup according to claim 1, which is characterized in that step (6) quenching Total wind pressure be maintained at 20~35MPa.
CN201811036804.1A 2018-09-06 2018-09-06 A kind of processing technology of abrasion-resistance glass cup Pending CN108911506A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109694204A (en) * 2019-02-13 2019-04-30 安徽金冠玻璃有限责任公司 A kind of processing technology of abrasion-resistance glass cup
CN112723720A (en) * 2020-11-19 2021-04-30 晶研一材料科技(宜兴)有限公司 Die-casting forming process of microcrystalline ceramic glass

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109694204A (en) * 2019-02-13 2019-04-30 安徽金冠玻璃有限责任公司 A kind of processing technology of abrasion-resistance glass cup
CN112723720A (en) * 2020-11-19 2021-04-30 晶研一材料科技(宜兴)有限公司 Die-casting forming process of microcrystalline ceramic glass

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