CN108911340A - A kind of method and system using SNCR denitration device processing desulfurization wastewater - Google Patents
A kind of method and system using SNCR denitration device processing desulfurization wastewater Download PDFInfo
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/79—Injecting reactants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2067—Urea
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
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- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
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- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
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- C02F1/72—Treatment of water, waste water, or sewage by oxidation
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- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
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- C02F2209/06—Controlling or monitoring parameters in water treatment pH
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Abstract
The invention discloses a kind of method and system using SNCR denitration device processing desulfurization wastewater, method includes the following steps：The desulfurization wastewater on absorption tower is passed through three headers by the first step；Obtained waste water is passed through and neutralizes in conditioning tank by second step；Obtained waste water is pumped into more medium filter by conveying by third step；4th step will obtain waste water by conveying and be pumped into cartridge filter；It is stand-by to be passed through intermediate water tank by the 5th step for obtained waste water；Waste water in intermediate water tank is sent into SNCR denitration system, mixed with the SNCR process water for being passed through SNCR denitration system by the 6th step；Weak solution obtained in 6th step is entered after spray gun is atomized burner hearth or separator carries out denitration reaction by the 7th step.The present invention has the characteristics that system is simple, utilization rate of equipment and installations is high, wastewater treatment capacity is big, investment operating cost is low.
Description
Technical field
The invention belongs to waste water of heat-engine plant processing technology field, in particular to a kind of method for handling desulfurization wastewater and it is
System.
Background technique
Currently, the requirement of China's wastewater discharge standard is increasingly strict, especially newest promulgation《Water prevention and cure of pollution action meter
It draws》" ten, water ", has even more risen to national strategy level for water environment protection.Also accordingly promulgated that discharge of wastewater is new in each province and city
Standard, and suggest that thermal power plant carries out Treated sewage reusing and wastewater zero discharge comprehensive treatment transformation, water resource and protection are saved to reach
The purpose of environment.The processing of desulfurization wastewater is most important in wastewater zero discharge transformation, while being also difficulty the best part.It is de-
Sulphur waste water is the concentration waste water of wet desulphurization absorption tower, is shown faintly acid (pH value 4-6), and (chemistry needs by heavy metal, suspended matter, COD
Oxygen amount) and the above wastewater discharge standard such as hardness, soluble-salt content be even more to reach 50000mg/L or more, it is necessary to by tight
Lattice processing can be only achieved the standard of reuse or discharge.
Conventional treatment and advanced treating are divided into the processing of desulfurization wastewater at present.Conventional treatment is for heavy metal, suspends
The indexs such as object, COD, hardness such as are neutralized, are flocculated, being clarified, being aoxidized at the processing, these indexs is made to reach discharge standard；And depth
Processing is the processing such as to be concentrated, solidified for soluble-salts such as Cl- and SO42-, achievees the purpose that wastewater zero discharge.To desulfurization
The conventional treatment process of waste water is more mature, realizes and applies in most of power plant, and needs to the advanced treating of desulfurization wastewater
It is selected according to power plant's actual conditions, advanced treatment process is mainly the following：(1) evaporation+crystallization processes, utilize waste water
Be evaporated system and crystallization be evaporated to desulfurization wastewater, treating capacity is big, high-efficient, noresidue waste water, but invest and operating cost compared with
It is high.(2) electrodialysis+Multistage Membranes concentration technology, the techniques such as use is reverse osmosis, positive infiltration and electrodialysis carry out waste water multistage dense
Contracting, can a part of water of reuse, a small amount of waste liquid can be evaporated or sprinkling processing.This process flow is relatively simple, but since desulfurization is useless
Water water quality is poor, and requirement of the technique to pretreatment and film is very high, and investment and operating cost are higher, and application is less.(3) flue evaporates
(or flue duct bypass evaporation) technique, is injected directly into boiler flue or bypass flue for waste water, is evaporated desulfurization using the heat of flue gas
Waste water, cured product are discharged by boiler slag removal or ash disposal system.Flue evaporation technology newly added equipment is less, invests operating cost
It is low, there is more application case in developed country, at home using less.The more flue duct bypass evaporation technology of studies in China at present
It needs to build evaporation drying tower, invests also higher.
SNCR (selective non-catalytic reduction) denitrating technique is using ammonium hydroxide or urea liquid as denitration medicament, from boiler certain bits
It sets and medicament is sprayed into flue, NO_x Reduction by Effective carried out to flue gas in 800-1250 DEG C of temperature range, advantage includes that equipment is simple, medicine
Agent is cheap, investment operating cost is lower but more demanding to flue-gas temperature.The unit quantity for being equipped with SNCR denitration at present accounts for entirely
The 20-30% of portion's denitration unit, the ultra-clean row of NOx is realized in application generally together with SCR (selective catalytic reduction) denitrating technique
It puts.From process flow and system operation, SNCR equipment, which has with flue evaporation technology use in conjunction, handles desulfurization wastewater
Potentiality.
In conclusion the advanced treatment process of most of desulfurization wastewater is required to higher investment and operating cost,
Investment payback time is longer, and investment cost performance is low.Therefore, research and develop that a kind for the treatment of effeciency is high, investment cost is few, maintenance is simple
Novel desulphurization waste water treatment system and technique will be a very important projects.
Summary of the invention
It is an object of the invention to provide a kind of method and systems using SNCR denitration device processing desulfurization wastewater, solve
The treatment process of desulfurization wastewater is required to higher investment and operating cost at present, and the investment payback time is longer, and investment cost performance is low
The problem of.
To achieve the goals above, technical solution of the present invention is specific as follows：
A kind of system using SNCR denitration device processing desulfurization wastewater, including three headers, neutralization conditioning tank, multimedium mistake
Filter, cartridge filter, intermediate water tank and SNCR denitration system；The desulfurization wastewater outlet of the entrance connection desulfurizing tower of three headers,
The outlet connection of three headers neutralizes the entrance of conditioning tank；The outlet of conditioning tank is by connecting multimedium mistake with the first transfer pipeline
The entrance of filter, the outlet of more medium filter pass through the entrance of the piping connection cartridge filter of the second delivery pump of band, security personnel
The entrance of the outlet connection intermediate water tank of filter；The outlet of intermediate water tank passes through the piping connection SNCR denitration system with metering pump
The waterwater entrance of system, SNCR denitration system are additionally provided with SNCR technique water inlet.
Further, pH meter is additionally provided in conditioning tank.
Further, conditioning tank connection lime milk dosing device and oxidant doser.
Further, intermediate water tank is equipped with SDI instrument and conductance table.
Further, the wastewater outlet of SNCR denitration system connects spray gun；Spray gun protrude into for denitration reaction burner hearth or
In separator.
Further, the waste water in intermediate water tank is pumped into the dilution module of SNCR denitration system by metering, and is passed through
The SNCR process water of SNCR denitration system mixes, and urea liquid or ammonium hydroxide will be diluted to the weak solution of 5-10%, through spray gun mist
Enter burner hearth after change or separator carries out denitration reaction；Aqueous solution is evaporated completely while denitration reaction carries out, salt therein
Crystallization, crystalline particle are discharged or enter back-end ductwork by dreg removing system, captured by cleaner.
A method of desulfurization wastewater being handled using SNCR denitration device, is included the following steps：
The desulfurization wastewater on absorption tower is passed through three headers by the first step, and three headers take off heavy metal, suspended matter, hard impurity
It removes；
Waste water obtained in the first step is passed through and neutralizes in conditioning tank by second step, and stone then is added into neutralization conditioning tank
Grey cream adjusts the pH value of waste water to 7.0-8.0, and adding oxidant reduces COD；
Obtained waste water in second step is pumped into more medium filter by conveying, passes through multimedium mistake by third step
Suspended matter, particle, the colloid generated in filter removal waste water；
4th step will obtain waste water by conveying and be pumped into cartridge filter, removed by cartridge filter in third step
Suspended matter, particle, the colloid generated in waste water；
It is stand-by to be passed through intermediate water tank by the 5th step for waste water obtained in 4th step；
Waste water in intermediate water tank is pumped into SNCR denitration system by metering, into SNCR denitration system by the 6th step
Dilution module, mixed with the SNCR process water for being passed through SNCR denitration system, by the urea liquid or ammonia in SNCR denitration system
Water is diluted to the weak solution of concentration 5-10%；
Weak solution obtained in 6th step, is entered burner hearth by the 7th step after spray gun is atomized or separator progress denitration is anti-
It answers, aqueous solution is evaporated completely while denitration reaction carries out, and wastewater treatment is completed in salt crystallization therein.
Further, the more medium filter uses quartz sand and active carbon.
Further, filter core of security filter diameter≤0.5 μm.
Further, in the 7th step, weak solution enters burner hearth after spray gun is atomized or separator carries out denitration reaction,
For coal-powder boiler, point is sprayed into 1200 DEG C of fire box temperature of region, point selection hearth region or separation are sprayed into for CFB boiler
Device entrance.
Compared with the existing technology, the invention has the advantages that：
(1) desulfurization wastewater is sprayed into burner hearth using SNCR system and is evaporated crystallization by the present invention, and system is simple, wastewater treatment capacity
Greatly, by-product (sodium salt etc.) follows bottom ash or flying dust to be discharged, without individually processing.
(2) present invention only need to increase a small amount of new equipment, cooperate original SNCR system to complete desulfurization wastewater processing, compared with tradition
Evaporator be evaporated or the method for film concentration, equipment investment significantly reduces, and operation and maintenance amount is accordingly reduced.
(3) desulfurization wastewater after processing greatly reduces the consumption of process water as SNCR thinned water, is power plant
Great lot of water resources is saved.
Detailed description of the invention
Fig. 1 is a kind of schematic diagram for the system that desulfurization wastewater is handled using SNCR denitration device of the present invention.
Wherein, 1. 3 header, in 2. and conditioning tank, 3. more medium filters, 4. cartridge filters, 5. intermediate water tanks,
6.SNCR denitrating system.
Specific embodiment
Refering to Figure 1, a kind of system using SNCR denitration device processing desulfurization wastewater of the present invention, including three headers
1, conditioning tank 2, more medium filter 3, cartridge filter 4, intermediate water tank 5 and SNCR denitration system 6 are neutralized.Three headers 1 enter
The desulfurization wastewater outlet of mouth connection desulfurizing tower 101, the outlet connection of three headers 1 neutralize the entrance of conditioning tank 2, the connection of conditioning tank 2
Lime milk dosing device 102 and oxidant doser 103；PH meter 104 is additionally provided in conditioning tank 2；The outlet of conditioning tank 2 is by having
The outlet of the entrance of first delivery pump, 105 piping connection more medium filter 3, more medium filter 3 passes through the second delivery pump of band
The entrance of 106 piping connection cartridge filter 4, the entrance of the outlet connection intermediate water tank 5 of cartridge filter 4；Intermediate water tank 5
It is equipped with SDI instrument 107 and conductance table 108.The outlet of intermediate water tank 5 passes through the piping connection SNCR denitration system with metering pump 109
The waterwater entrance of system 6, SNCR denitration system 6 are additionally provided with SNCR technique water inlet, and the waste water in intermediate water tank 5 passes through metering pumping
The dilution module for entering SNCR denitration system 6 is mixed with the SNCR process water for being passed through SNCR denitration system 6, will urea liquid or
Ammonium hydroxide is diluted to the weak solution of 5-10%, and burner hearth is entered after spray gun is atomized or separator carries out denitration reaction；Denitration reaction into
Aqueous solution is evaporated completely while row, salt (main component is sodium chloride and sodium sulphate) knot in the form of short grained therein
Crystalline substance, biggish particle are discharged by dreg removing system, and lesser particle enters back-end ductwork, are captured by cleaner.
Embodiment 1
As shown in Figure 1, a kind of method using SNCR denitration device processing desulfurization wastewater, includes the following steps：
The desulfurization wastewater on absorption tower is passed through three headers 1 by the first step, and three headers 1 are by heavy metal, suspended matter, hard impurity
Removing；
Waste water obtained in the first step is passed through and neutralizes in conditioning tank 2 by second step, is then added into neutralization conditioning tank 2
Milk of lime adjusts the pH value of waste water to 7.0, and adding oxidant reduces COD；
Obtained waste water in second step is pumped into more medium filter 3 by conveying, passes through multimedium mistake by third step
Filter 3 removes suspended matter, particle, the colloid generated in waste water；
4th step will obtain waste water by conveying and be pumped into cartridge filter 4, gone by cartridge filter 4 in third step
Except the suspended matter, particle, colloid generated in waste water；
It is stand-by to be passed through intermediate water tank 5 by the 5th step for waste water obtained in 4th step；
Waste water in intermediate water tank 5 is pumped into SNCR denitration system 6 by metering, into SNCR denitration system by the 6th step
The dilution module of system 6, mixes with the SNCR process water for being passed through SNCR denitration system 6, by the urea liquid in SNCR denitration system 6
Or ammonium hydroxide is diluted to the weak solution of concentration 5%；
Weak solution obtained in 6th step is entered burner hearth after spray gun is atomized and carries out denitration reaction by the 7th step, and denitration is anti-
Aqueous solution is evaporated completely while should carrying out, and salt therein is crystallized in the form of short grained, completes wastewater treatment.
Wherein, it neutralizes and PH meter is installed in the outlet of conditioning tank 2, neutralize conditioning tank 2 by PH and count measurement solution acid alkalinity
Value；SDI instrument and conductance table are provided on intermediate water tank 5；In 7th step to crystal salt in, big particle is arranged by dreg removing system
Out, small particle enters back-end ductwork, is captured by cleaner；More medium filter 3 uses quartz sand and active carbon；It protects
Pacify 0.5 μm of 4 filter core diameter of filter；In 7th step, weak solution enters burner hearth after spray gun is atomized and carries out denitration reaction, for coal
Powder furnace sprays into point in 1200 DEG C of fire box temperature of region and improves denitration efficiency to reach preferably mixing purpose.
Embodiment 2
As shown in Figure 1, a kind of method using SNCR denitration device processing desulfurization wastewater, includes the following steps：
The desulfurization wastewater on absorption tower is passed through three headers 1 by the first step, and three headers 1 are by heavy metal, suspended matter, hard impurity
Removing；
Waste water obtained in the first step is passed through and neutralizes in conditioning tank 2 by second step, is then added into neutralization conditioning tank 2
Milk of lime adjusts the pH value of waste water to 8.0, and adding oxidant reduces COD；
Obtained waste water in second step is pumped into more medium filter 3 by conveying, passes through multimedium mistake by third step
Filter 3 removes suspended matter, particle, the colloid generated in waste water；
4th step will obtain waste water by conveying and be pumped into cartridge filter 4, gone by cartridge filter 4 in third step
Except the suspended matter, particle, colloid generated in waste water；
It is stand-by to be passed through intermediate water tank 5 by the 5th step for waste water obtained in 4th step；
Waste water in intermediate water tank 5 is pumped into SNCR denitration system 6 by metering, into SNCR denitration system by the 6th step
The dilution module of system 6, mixes with the SNCR process water for being passed through SNCR denitration system 6, by the urea liquid in SNCR denitration system 6
Or ammonium hydroxide is diluted to the weak solution of concentration 10%；
Weak solution obtained in 6th step is entered separator after spray gun is atomized and carries out denitration reaction, denitration by the 7th step
Aqueous solution is evaporated completely while reaction carries out, and salt therein is crystallized in the form of short grained, completes wastewater treatment.
Wherein, it neutralizes and PH meter is installed in the outlet of conditioning tank 2, neutralize conditioning tank 2 by PH and count measurement solution acid alkalinity
Value；SDI instrument and conductance table are provided on intermediate water tank 5；In 7th step to crystal salt in, big particle is arranged by dreg removing system
Out, small particle enters back-end ductwork, is captured by cleaner；More medium filter 3 uses quartz sand and active carbon；It protects
Pacify 0.4 μm of 4 filter core diameter of filter；In 7th step, weak solution enters separator after spray gun is atomized and carries out denitration reaction, for
CFB boiler sprays into point selection hearth region or separator inlet, to reach preferably mixing purpose, improves denitration efficiency.
Claims (10)
1. a kind of system using SNCR denitration device processing desulfurization wastewater, which is characterized in that including three headers (1), neutralize and adjust
Save pond (2), more medium filter (3), cartridge filter (4), intermediate water tank (5) and SNCR denitration system (6)；Three headers (1)
Entrance connection desulfurizing tower (101) desulfurization wastewater outlet, three headers (1) outlet connection neutralize conditioning tank (2) entrance；It adjusts
The outlet for saving pond (2) passes through the entrance with the first conveying (105) piping connection more medium filter (3), more medium filter
(3) outlet passes through the entrance of the piping connection cartridge filter (4) of the second delivery pump of band (106), and cartridge filter (4) goes out
The entrance of mouth connection intermediate water tank (5)；The outlet of intermediate water tank (5) passes through the piping connection SNCR denitration with metering pump (109)
The waterwater entrance of system (6), SNCR denitration system (6) are additionally provided with SNCR technique water inlet.
2. a kind of system using SNCR denitration device processing desulfurization wastewater according to claim 1, which is characterized in that adjust
PH meter (104) are additionally provided in section pond (2).
3. a kind of system using SNCR denitration device processing desulfurization wastewater according to claim 1, which is characterized in that adjust
Save pond (2) connection lime milk dosing device (102) and oxidant doser (103).
4. a kind of system using SNCR denitration device processing desulfurization wastewater according to claim 1, which is characterized in that in
Between water tank (5) be equipped with SDI instrument (107) and conductance table (108).
5. a kind of system using SNCR denitration device processing desulfurization wastewater according to claim 1, which is characterized in that
The wastewater outlet of SNCR denitration system (6) connects spray gun；Spray gun protrudes into burner hearth or separator for denitration reaction.
6. a kind of system using SNCR denitration device processing desulfurization wastewater according to claim 1, which is characterized in that in
Between waste water in water tank (5) the dilution module of SNCR denitration system (6) is pumped by metering, and be passed through SNCR denitration system
(6) SNCR process water mixing, will be diluted to urea liquid or ammonium hydroxide the weak solution of 5-10%, furnace is entered after spray gun is atomized
Thorax or separator carry out denitration reaction；Aqueous solution is evaporated completely while denitration reaction carries out, salt crystallization therein, crystallization
Grain is discharged or enters back-end ductwork by dreg removing system, is captured by cleaner.
7. a kind of method using SNCR denitration device processing desulfurization wastewater, which is characterized in that include the following steps：
The desulfurization wastewater on absorption tower is passed through three headers (1) by the first step, and three headers (1) are by heavy metal, suspended matter, hard impurity
Removing；
Waste water obtained in the first step is passed through and neutralizes in conditioning tank (2) by second step, and then to neutralizing, conditioning tank (2) are middle to be added
Milk of lime adjusts the pH value of waste water to 7.0-8.0, and adding oxidant reduces COD；
Obtained waste water in second step is pumped into more medium filter (3) by conveying, passes through multi-medium filtering by third step
Suspended matter, particle, the colloid generated in device (3) removal waste water；
4th step will obtain waste water by conveying and be pumped into cartridge filter (4), gone by cartridge filter (4) in third step
Except the suspended matter, particle, colloid generated in waste water；
It is stand-by to be passed through intermediate water tank (5) by the 5th step for waste water obtained in 4th step；
Waste water in intermediate water tank (5) is pumped into SNCR denitration system (6) by metering, into SNCR denitration system by the 6th step
The dilution module of system (6), mixes with the SNCR process water for being passed through SNCR denitration system (6), by the urine in SNCR denitration system (6)
Plain solution or ammonium hydroxide are diluted to the weak solution of concentration 5-10%；
Weak solution obtained in 6th step is entered after spray gun is atomized burner hearth or separator carries out denitration reaction, taken off by the 7th step
Aqueous solution is evaporated completely while nitre reaction carries out, and wastewater treatment is completed in salt crystallization therein.
8. a kind of method using SNCR denitration device processing desulfurization wastewater according to claim 1, it is characterised in that：Institute
More medium filter (3) are stated using quartz sand and active carbon.
9. a kind of method using SNCR denitration device processing desulfurization wastewater according to claim 1, it is characterised in that：Institute
State cartridge filter (4) filter core diameter≤0.5 μm.
10. a kind of method using SNCR denitration device processing desulfurization wastewater according to claim 1, it is characterised in that：
In 7th step, weak solution enters burner hearth after spray gun is atomized or separator carries out denitration reaction, for coal-powder boiler, sprays into point
Point selection hearth region or separator inlet are sprayed into for CFB boiler in 1200 DEG C of region of fire box temperature.
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| CN201810954372.6A CN108911340A (en) | 2018-08-21 | 2018-08-21 | A kind of method and system using SNCR denitration device processing desulfurization wastewater |
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| CN201810954372.6A CN108911340A (en) | 2018-08-21 | 2018-08-21 | A kind of method and system using SNCR denitration device processing desulfurization wastewater |
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| CN (1) | CN108911340A (en) |
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| CN105157044A (en) * | 2015-09-30 | 2015-12-16 | 华南理工大学 | Leachate back-spraying denitration device and method for garbage incinerator |
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| CN206783441U (en) * | 2017-05-11 | 2017-12-22 | 扬州绿都环境工程设备有限公司 | Desulphurization denitration wastewater treatment equipment |
| CN208747847U (en) * | 2018-08-21 | 2019-04-16 | 中国华能集团清洁能源技术研究院有限公司 | A kind of system using SNCR denitration device processing desulfurization wastewater |
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| CN105157044A (en) * | 2015-09-30 | 2015-12-16 | 华南理工大学 | Leachate back-spraying denitration device and method for garbage incinerator |
| CN105481157A (en) * | 2015-12-18 | 2016-04-13 | 王辛平 | Method for zero emission treatment of desulfurization waste water based on flue gas waste heat evaporation |
| CN105540977A (en) * | 2016-01-14 | 2016-05-04 | 中电环保股份有限公司 | Desulfurized waste water treatment method and system |
| CN105967420A (en) * | 2016-06-17 | 2016-09-28 | 国网河南省电力公司电力科学研究院 | Synergistic gas-liquid-solid pollutant treatment system based on power plant wastewater zero-discharge technology |
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| CN208747847U (en) * | 2018-08-21 | 2019-04-16 | 中国华能集团清洁能源技术研究院有限公司 | A kind of system using SNCR denitration device processing desulfurization wastewater |
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