CN108906011A - A kind of adsorbent recycling system and technique - Google Patents

A kind of adsorbent recycling system and technique Download PDF

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Publication number
CN108906011A
CN108906011A CN201810967806.6A CN201810967806A CN108906011A CN 108906011 A CN108906011 A CN 108906011A CN 201810967806 A CN201810967806 A CN 201810967806A CN 108906011 A CN108906011 A CN 108906011A
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CN
China
Prior art keywords
vacuum
adsorbent
vacuum pump
catalytic combustion
valve
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Pending
Application number
CN201810967806.6A
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Chinese (zh)
Inventor
陆景鹏
陆标
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Suzhou Jun Green Environmental Technology Service Co Ltd
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Suzhou Jun Green Environmental Technology Service Co Ltd
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Priority to CN201810967806.6A priority Critical patent/CN108906011A/en
Publication of CN108906011A publication Critical patent/CN108906011A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3491Regenerating or reactivating by pressure treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3483Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/07Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material

Abstract

The invention discloses a kind of adsorbent recycling systems, bellows, a catalysis combustion air fan and a catalytic combustion burner are mixed including a vacuum desorption tower, a vacuum pump, a dedusting, pass sequentially through pipeline connection, adsorbent is placed in the vacuum desorption tower, in the case where the vacuum desorption tower, the vacuum pump, the dedusting mix the collective effect of bellows, the catalysis combustion air fan and the catalytic combustion burner, the organic matter for being adsorbed on adsorbent surface pair parses and ultimately generates CO2And H2O is simultaneously discharged, and removal process is safe and efficient, and does not generate secondary pollution.The invention also discloses a kind of adsorbents to recycle technique, using the adsorbent recycling system, by controlling the working condition of the vacuum desorption tower, the vacuum pump, the catalysis combustion air fan and the catalytic combustion burner, the safe and efficient recycling of adsorbent is realized.

Description

A kind of adsorbent recycling system and technique
Technical field
The present invention relates to adsorbent recovery technology field, more precisely it is related to a kind of adsorbent recycling system and work Skill.
Background technique
With the continuous development of China's economy and the depth adjustment of the industrial structure, clean manufacturing, which has become, a kind of gos deep into people The idea of development of the heart.We have seen that in recent years, China is in the regulation and investment power for continuing to increase environment especially industrial waste gas Degree, and achieve significant achievement.It is more that technics comparing may be selected in waste gas pollution control and treatment, but due to by investment operating cost, production status Etc. composite factors influence, Some Enterprises selection locates the tail gas that generates in production process using absorption method.Absorption method processing is useless The advantages that gas has cost of investment low, and simple process is mature, and engineering construction is easy, but after adsorbent uses certain time limit, just Adsorption saturation can be reached and lose adsorption capacity.In order to make equipment have lasting adsorption capacity, enterprise can install in situ de- Applying equipment, or the adsorbent more renewed.
Since generally desorption apparatus and process is complicated in situ for Vehicles Collected from Market, program is cumbersome, and cost of investment is high, so many enterprises There is no installation desorption equipment in situ, and especially some relatively small enterprises of disposal of pollutants, adsorbent desorption cycles are longer, former Position desorption capacity utilization is lower, and investment adsorbent in-situ desorption equipment will cause certain waste.At this point, enterprise can select by Adsorbent after adsorption saturation transfers to the enterprise with related qualification to unify collection processing as danger wastes, and processing mode is more Directly to burn, the serious waste of resource will cause.In addition, manufacturing enterprise also needs to undertake high active carbon purchase, dangerous waste The management cost and economic cost of temporary and dangerous waste disposition.What is more, the yield of the waste and old active carbon in some areas is much Greater than the disposing capacity of this area, the waste and old active carbon that many enterprises generate nowhere is disposed, and is thus brought additionally to enterprise Dangerous waste administrative burden.
There are many existing adsorbent recovery technologies, such as condensation technology is desorbed in steam, but can generate in removal process Waste water causes secondary pollution;Hot-air desorption-combustion technology safety in removal process is poor, is easy to appear active carbon certainly Fire phenomenon;Hot nitrogen desorption-condensation/catalytic combustion technology operating cost is higher, and be desorbed efficiency it is not ideal enough, desorption rate compared with Slowly.To sum up, this field needs a kind of new adsorbent recovery and utilization technology, to realize that safe and efficient adsorbent recycles.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of adsorbent recycling system, including a vacuum desorption tower, One vacuum pump, a dedusting mix bellows, a catalysis combustion air fan and a catalytic combustion burner, pass sequentially through pipeline connection, adsorbent It is placed in the vacuum desorption tower, mixes bellows, catalysis burning in the vacuum desorption tower, the vacuum pump, the dedusting Under the collective effect of blower and the catalytic combustion burner, the organic matter for being adsorbed on adsorbent surface pair is parsed and is ultimately generated CO2And H2O is simultaneously discharged.
It is another object of the present invention to provide a kind of adsorbents to recycle technique, recycles benefit using the adsorbent With system, pass through the control vacuum desorption tower, the vacuum pump, the catalysis combustion air fan and the catalytic combustion burner Working condition realizes the safe and efficient recycling of adsorbent.
In order to achieve the above object, the present invention provides a kind of adsorbent recycling system, including a vacuum desorption tower, one Vacuum pump, a dedusting mix bellows, a catalysis combustion air fan, a catalytic combustion burner and an exhaust tube, the vacuum desorption tower top Portion has a feed inlet, and bottom has a discharge port, and the vacuum desorption top of tower has an exhaust outlet, and the vacuum pump has One vacuum pump air inlet and a vacuum pump air outlet, the exhaust outlet is connect by pipeline with the vacuum pump air inlet, described Dedusting mixes bellows, and there is a dedusting to mix bellows air inlet and the mixed bellows air outlet of a dedusting, and the vacuum pump air outlet passes through pipeline It mixes bellows air inlet with the dedusting to connect, the catalysis combustion air fan has a catalysis combustion air fan air inlet and a catalysis combustion Fan outlet is burnt, the dedusting mixes bellows air outlet and connect by pipeline with the catalysis combustion air fan air inlet, described to urge Changing combustion furnace has a catalytic combustion burner air inlet and a catalytic combustion burner air outlet, and the catalytic combustion burner air inlet passes through pipe Road is connect with the catalysis combustion air fan air outlet, and the catalytic combustion burner air outlet is connect by pipeline with the exhaust tube.
Preferably, a heat exchanger is installed inside the vacuum desorption tower, the heat exchanger have a heat transferring medium import and The outlet of one heat transferring medium, the heat transferring medium import are connect by pipeline with the catalytic combustion burner air outlet, and the heat exchange is situated between Matter outlet is connect by pipeline with the exhaust tube.
Preferably, including a valve member, the valve member include one first valve, a third valve, one the 4th valve Door and one vacuum valve is let out, first valve is arranged on the pipeline that the feed inlet is connect with the vacuum pump air inlet, The third valve is arranged on the pipeline between the catalytic combustion burner air outlet and the exhaust tube, and the 4th valve is set It sets on the pipeline between the heat transferring medium import and the catalytic combustion burner air outlet, it is described to let out vacuum valve and the vacuum Desorption column combines setting.
Preferably, the heat exchanger uses one of tubular heat exchanger, coil exchanger, plate heat exchanger.
Preferably, including a dilution fresh inlet, the dedusting mix bellows air inlet and pass through pipeline and the dilution fresh air Import connection.
Preferably, setting temperature controller and pressure controller inside the vacuum desorption tower.
Preferably, the dedusting mixes inner bellows and is provided with dust-extraction unit and concentration buffer device.
Preferably, the vacuum pump is using in scroll vacuum pump, screw vacuum pump, Roots vaccum pump, slide-valve vacuum pump One kind.
Preferably, the catalytic combustion burner is using one in direct-combustion furnace, regenerative combustion furnace, heat accumulating type catalytic combustion furnace Kind.
The present invention also provides a kind of adsorbents to recycle technique, using the adsorbent recycling system, including step Suddenly:
(A) discharge port is closed, adsorbent is loaded from the feed inlet to the vacuum desorption tower, described in closing Feed inlet;
(B) start the catalytic combustion burner;
(C) start the vacuum pump, increase the vacuum pump working frequency, control the catalysis combustion air fan frequency and keep The catalytic combustion burner temperature is stablized;
(D) control valve component controls the vacuum desorption tower internal temperature and is stepped up, and keeps the vacuum desorption Tower internal temperature stablizes a period of time;
(E) control valve component, and successively close the vacuum pump, the catalysis combustion air fan and catalysis burning Furnace opens discharge port, removes adsorbent.
Compared with prior art, the advantages of a kind of adsorbent recycling system and technique disclosed by the invention, is:Institute Stating adsorbent recycling system can be under super low energy consumption, efficiently, the suction by adsorption saturation during waste gas pollution control and treatment of high speed Attached medium is desorbed, and realizes the regeneration and recycling of adsorbent, and operating cost is low, and high-efficient, desorption rate is desorbed Fastly, secondary pollution will not be generated;The adsorbent recycles technique and uses the adsorbent recycling system, easy to operate Convenient, error rate is low.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with It obtains other drawings based on these drawings.
It is as shown in Figure 1 a kind of structural schematic diagram of adsorbent recycling system of the invention.
It is illustrated in figure 2 the flow chart that a kind of adsorbent of the invention recycles technique.
Specific embodiment
As shown in Figure 1, a kind of adsorbent recycling system of the present invention include a vacuum desorption tower 10, a vacuum pump 20, One dedusting mix bellows 30, one be catalyzed combustion air fan 40, a catalytic combustion burner 50, one dilution fresh inlet 60, an exhaust tube 70 with An and valve member 80.There is a feed inlet 11, bottom has a discharge port 12, and adsorbent is logical at the top of the vacuum desorption tower 10 It crosses the feed inlet 11 to be placed in inside the vacuum desorption tower 10, through the discharge port 12 inside the vacuum desorption tower 10 It takes out.The vacuum pump 20 has a vacuum pump air inlet and a vacuum pump air outlet, and 10 top of vacuum desorption tower also has There is an exhaust outlet 14, the exhaust outlet 14 is connect by pipeline with the vacuum pump air inlet;The dedusting, which mixes bellows 30, to be had One dedusting mixes bellows air inlet and a dedusting mixes bellows air outlet, and the vacuum pump air outlet mixes wind by pipeline and the dedusting The connection of case air inlet;The dedusting mixes bellows air inlet and connect simultaneously with the dilution fresh inlet 60;The catalysis burning wind Machine 40 has a catalysis combustion air fan air inlet and a catalysis combustion air fan air outlet, and the dedusting mixes bellows air outlet and passes through pipe Road is connect with the catalysis combustion air fan air inlet;There is the catalytic combustion burner 50 a catalytic combustion burner air inlet 51 and one to urge Change combustion furnace air outlet 52, the catalytic combustion burner air inlet 51 is connect by pipeline with the catalysis combustion air fan air outlet, The catalytic combustion burner air outlet 52 is connect by pipeline with the exhaust tube 70.Preferably, inside the vacuum desorption tower 10 Temperature controller and pressure controller are set, for guaranteeing that the temperature, pressure inside the vacuum desorption tower 10 is stablized;It is described to remove Dirt mixes bellows 30 and is internally provided with dust-extraction unit and concentration buffer device;The vacuum pump 20 can use scroll vacuum pump, spiral shell One of bar vacuum pump, Roots vaccum pump, slide-valve vacuum pump;The catalytic combustion burner 50 can use direct-combustion furnace, accumulation of heat One of formula combustion furnace, heat accumulating type catalytic combustion furnace.It is worth noting that, the adsorbent recycling system can be to useless The adsorbents such as active carbon, molecular sieve, natural zeolite, the macromolecule resin of the adsorption saturation during gas disposal carry out recycling benefit With.
Further, a heat exchanger 13 is installed, the heat exchanger 13 has a heat exchange inside the vacuum desorption tower 10 Medium entrance 131 and a heat transferring medium air outlet 132, the heat transferring medium import 131 pass through pipeline and the catalytic combustion burner Air outlet 52 connects, and the heat transferring medium air outlet 132 is connect by pipeline with the exhaust tube 70.Preferably, the heat exchange Device 13 can use one of tubular heat exchanger, coil exchanger, plate heat exchanger.The catalytic combustion burner 50 burns The a part containing hot exhaust gas generated afterwards directly passes through the exhaust tube 70 and is discharged, and a part passes through the heat transferring medium import 131 Into the heat exchanger 13, the adsorbent in the vacuum desorption tower 10 is heated, to realize residual heat recovery, is reduced The energy consumption of the adsorbent recycling system, while improving recovery efficiency.For needing to recycle adsorbent difference, control Temperature is 20 DEG C to 100 DEG C when being desorbed inside the vacuum desorption tower 10.
The valve member 80 includes one first valve 81, one second valve 82, a third valve 83 and one the 4th valve Door 84, first valve 81 is arranged on the pipeline that the feed inlet 11 is connect with the vacuum pump 20, second valve 82 are disposed proximate on the pipeline of the dilution fresh inlet 60, and the third valve 83 is arranged in the catalytic combustion burner outlet air On pipeline between mouthfuls 52 and the exhaust tube 70, the 4th valve 84 setting the heat transferring medium import 131 with it is described On pipeline between catalytic combustion burner air outlet 52.The valve member 80 further includes letting out vacuum valve, it is described let out vacuum valve with The vacuum desorption tower 10 combines setting, can control gas inside the vacuum desorption tower 10 by letting out vacuum valve described in adjusting Pressure.
Low energy consumption for the adsorbent recycling system, and desorption is high-efficient, and rate is fast, will not generate secondary pollution, and pacify Full property is preferable.
As shown in Fig. 2, the adsorbent, which recycles technique, uses the adsorbent recycling system, including step:
(A) discharge port is closed, adsorbent is loaded from the feed inlet to the vacuum desorption tower, described in closing Feed inlet;
(B) start the catalytic combustion burner;
(C) start the vacuum pump, increase the vacuum pump working frequency, control the catalysis combustion air fan frequency and keep The catalytic combustion burner temperature is stablized;
(D) control valve component controls the vacuum desorption tower internal temperature and is stepped up, and keeps the vacuum desorption Tower internal temperature stablizes a period of time;
(E) control valve component, and successively close the vacuum pump, the catalysis combustion air fan and catalysis burning Furnace opens discharge port, removes adsorbent.
After wherein step (C) starts the vacuum pump 20,10 air pressure inside of vacuum desorption tower is reduced, and is adsorbed on absorption The organic matter on agent surface, which gradually parses and drains into the dedusting by the vacuum pump 20, mixes bellows 30, and burns in the catalysis Bellows 30 are mixed by the dedusting under the action of blower 40 and the catalysis combustion air fan 40 enters the catalytic combustion burner 50 and fires It burns, generates CO2And H2O, and a part containing hot exhaust gas after burning directly passes through the exhaust tube 70 discharge, another part into Enter the heat exchanger 13, accelerates the desorption process of 10 internal adsorbent of vacuum desorption tower.
Specifically, the work using the adsorbent recycling system to adsorption saturation in ethyl acetate waste gas treatment process The step of property charcoal is recycled be:
(A) systems inspection complete and confirm it is errorless after, the discharge port is closed, then by ethyl acetate waste gas treatment process The active carbon of middle adsorption saturation is loaded from mouth is loaded to vacuum desorption tower, after the completion of filling, closes the feed inlet;
(B) start the catalytic combustion burner;
(C) start the vacuum pump, increase the vacuum pump working frequency to 50Hz, control the catalysis combustion air fan frequency Rate keeps the catalytic combustion burner temperature to stablize;
(D) control valve component controls the air inlet of vacuum desorption tower internal exchanger, is stepped up temperature in desorption column To 40 DEG C, temperature stablizes 2h;
(E) it opens and lets out vacuum valve, after 10s, be again switched off and let out vacuum valve, after 10min, successively close the vacuum pump, institute Catalysis combustion air fan and the catalytic combustion burner are stated, is again turned on and lets out vacuum valve, to the vacuum desorption tower internal pressure and outside Atmospheric pressure balance in boundary's when temperature is lower than 40 DEG C, opens discharge port, the active carbon being transferred out of in vacuum desorption tower.
Using the adsorbent recycling system to the active carbon of adsorption saturation in toluene, xylene waste gas treatment process The step of being recycled be:
(A) systems inspection complete and confirm it is errorless after, close the discharge port, then by toluene, xylene waste gas processing The active carbon of adsorption saturation is loaded from mouth is loaded to vacuum desorption tower in the process, after the completion of filling, closes the feed inlet;
(B) start the catalytic combustion burner;
(C) start the vacuum pump, increase the vacuum pump working frequency to 50Hz, control the catalysis combustion air fan frequency Rate keeps the catalytic combustion burner temperature to stablize;
(D) control valve component controls the air inlet of vacuum desorption tower internal exchanger, is stepped up temperature in desorption column To 50 DEG C, temperature stablizes 3h;
(E) it opens and lets out vacuum valve, after 10s, be again switched off and let out vacuum valve, after 10min, successively close the vacuum pump, institute Catalysis combustion air fan and the catalytic combustion burner are stated, is again turned on and lets out vacuum valve, to the vacuum desorption tower internal pressure and outside Atmospheric pressure balance in boundary's when temperature is lower than 40 DEG C, opens discharge port, the active carbon being transferred out of in vacuum desorption tower.
As it can be seen that the heterogeneity of the adsorbent handled as needed, can specifically adjust the adsorbent and recycle work Design parameter in skill, to realize effective recycle.The adsorbent recycling technological operation is simple and convenient, is not easy out Mistake, and flexible adjustment, it is applied widely.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest scope of cause.

Claims (10)

1. a kind of adsorbent recycling system, which is characterized in that mix wind including a vacuum desorption tower, a vacuum pump, a dedusting Case, a catalysis combustion air fan, a catalytic combustion burner and an exhaust tube, the vacuum desorption top of tower have a feed inlet, bottom Portion have a discharge port, the vacuum desorption top of tower have an exhaust outlet, the vacuum pump have a vacuum pump air inlet and One vacuum pump air outlet, the exhaust outlet are connect by pipeline with the vacuum pump air inlet, and the dedusting, which mixes bellows, has one Dedusting mixes bellows air inlet and a dedusting mixes bellows air outlet, and the vacuum pump air outlet mixes bellows by pipeline and the dedusting Air inlet connection, the catalysis combustion air fan have a catalysis combustion air fan air inlet and a catalysis combustion air fan air outlet, institute It states the mixed bellows air outlet of dedusting to connect by pipeline with the catalysis combustion air fan air inlet, the catalytic combustion burner has one to urge Change combustion furnace air inlet and a catalytic combustion burner air outlet, the catalytic combustion burner air inlet is burnt by pipeline and the catalysis Fan outlet connection, the catalytic combustion burner air outlet are connect by pipeline with the exhaust tube.
2. adsorbent recycling system as described in claim 1, which is characterized in that installation one inside the vacuum desorption tower There is a heat transferring medium import and a heat transferring medium to export for heat exchanger, the heat exchanger, and the heat transferring medium import passes through pipeline It is connect with the catalytic combustion burner air outlet, the heat transferring medium outlet is connect by pipeline with the exhaust tube.
3. adsorbent recycling system as claimed in claim 2, which is characterized in that including a valve member, the valve Component lets out vacuum valve including one first valve, a third valve, one the 4th valve and one, and first valve is arranged described On the pipeline that feed inlet is connect with the vacuum pump air inlet, third valve setting the catalytic combustion burner air outlet with On pipeline between the exhaust tube, the 4th valve is arranged in the heat transferring medium import and the catalytic combustion burner outlet air On pipeline between mouthful, the vacuum valve of letting out is arranged in conjunction with the vacuum desorption tower.
4. adsorbent recycling system as claimed in claim 2, which is characterized in that the heat exchanger is exchanged heat using shell and tube One of device, coil exchanger, plate heat exchanger.
5. adsorbent recycling system as described in claim 1, which is characterized in that described including a dilution fresh inlet Dedusting mixes bellows air inlet and is connect by pipeline with the dilution fresh inlet.
6. adsorbent recycling system as described in claim 1, which is characterized in that setting temperature inside the vacuum desorption tower Spend controller and pressure controller.
7. adsorbent recycling system as described in claim 1, which is characterized in that the dedusting mixes inner bellows and is provided with Dust-extraction unit and concentration buffer device.
8. adsorbent recycling system as described in claim 1, which is characterized in that the vacuum pump uses swirl vacuum One of pump, screw vacuum pump, Roots vaccum pump, slide-valve vacuum pump.
9. adsorbent recycling system as described in claim 1, which is characterized in that the catalytic combustion burner uses direct combustion One of furnace, regenerative combustion furnace, heat accumulating type catalytic combustion furnace.
10. a kind of adsorbent recycles technique, which is characterized in that recycled using adsorbent as claimed in claim 3 System, including step:
(A) discharge port is closed, adsorbent is loaded from the feed inlet to the vacuum desorption tower, the charging is closed Mouthful;
(B) start the catalytic combustion burner;
(C) start the vacuum pump, increase the vacuum pump working frequency, control described in the catalysis combustion air fan frequency holding Catalytic combustion burner temperature is stablized;
(D) control valve component controls the vacuum desorption tower internal temperature and is stepped up, and keeps in the vacuum desorption tower Portion's temperature stablizes a period of time;
(E) control valve component, and the vacuum pump, the catalysis combustion air fan and the catalytic combustion burner are successively closed, it beats It starts discharging material mouth, removes adsorbent.
CN201810967806.6A 2018-08-23 2018-08-23 A kind of adsorbent recycling system and technique Pending CN108906011A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
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Application publication date: 20181130