CN108893125A - A kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device - Google Patents

A kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device Download PDF

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Publication number
CN108893125A
CN108893125A CN201811094237.5A CN201811094237A CN108893125A CN 108893125 A CN108893125 A CN 108893125A CN 201811094237 A CN201811094237 A CN 201811094237A CN 108893125 A CN108893125 A CN 108893125A
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CN
China
Prior art keywords
coke oven
tedge
pedestal
heat
recovery device
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Pending
Application number
CN201811094237.5A
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Chinese (zh)
Inventor
宋旭勇
裴立迪
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WUHAN FRONT INDUSTRY EQUIPMENT TECHNOLOGY Co Ltd
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WUHAN FRONT INDUSTRY EQUIPMENT TECHNOLOGY Co Ltd
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Priority to CN201811094237.5A priority Critical patent/CN108893125A/en
Publication of CN108893125A publication Critical patent/CN108893125A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B27/00Arrangements for withdrawal of the distillation gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F27/00Control arrangements or safety devices specially adapted for heat-exchange or heat-transfer apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0075Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for syngas or cracked gas cooling systems
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Coke Industry (AREA)

Abstract

The present invention provides a kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device, innovative point is:The tedge is three-stage, respectively includes cylindrical rising heat exchange of heat pipe, tedge interlude and tedge pedestal;Connecting flange is equipped between the rising heat exchange of heat pipe, tedge interlude and tedge pedestal to be attached.Three-stage tedge long service life of the invention, raw coke oven gas utilization rate of waste heat are high.In the present invention, the setting of tedge interlude mainly opens up various detection mouths, the various states of the convenient raw coke oven gas of observation in time, and the heat of coke oven is mainly carried out heat preservation thermal protection, avoids heat losses too fast by the setting of tedge pedestal, influences waste heat recycling.

Description

A kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device
Technical field
The present invention relates to coke oven equipment technology more particularly to a kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery devices.
Background technique
Currently, the great attention with coke-oven plant to resource recycling, the waste heat recycling of raw coke oven gas is to reduce coke oven energy The waste heat recycling prior art of one of main path of consumption, raw coke oven gas is 650 DEG C~850 DEG C high temperature famine coals for escaping carbonization chamber Gas enters gas collecting tube by rising heat exchange of heat pipe.Water jacket is studded with inside heat exchange of heat pipe because rising, and rises heat exchange of heat pipe inner wall Need absolute waterproofness and integrality.We can not detect the coal gas state inside tedge and rise heat exchange of heat pipe inner wall feelings Condition.
Chinese patent CN107746714A discloses a kind of spiral inner tube coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device, It is characterized in that:Including coke oven coke oven uprising tube evaporator, the rising pipe evaporator includes inner tube, is led to inside said inner tube for raw coke oven gas Road;Said inner tube outer wall be equipped with heat-conducting plate, the heat-conducting plate be helical form boss, the heat-conducting plate from inner tube exterior bottom extremely Inner tube outside top helically arranges, and thermal conductive water pipe is equipped between the heat-conducting plate, and the thermal conductive water pipe is from inner tube exterior bottom It is helically arranged in inner tube outside top between the gap between screw that the heat-conducting plate is formed.The technical solution is according to the coke oven Raw coke oven gas amount determines the rising pipe evaporator quantity of series operation in tedge, realizes that the waste heat of raw coke oven gas amount and the device recycles The matching of ability.But the technical solution cost is relatively high, and existing tedge has following two:1, tedge Physical life is short.2, raw coke oven gas heat utilization ratio is low.
Chinese patent CN102977901A discloses a kind of Riser waste heat recovery device for coke oven, on the tube wall of tedge It is provided with coiling heat exchanger tube.The method of tedge augmentation of heat transfer is that fin is arranged in the heat convection section in heat exchange tedge Increase heat convection area, to increase the waste heat of recycling raw coke oven gas.The technical solution, which discloses, can effectively recycle raw coke oven gas Waste heat, it is energy saving, have very important significance to energy-saving and emission-reduction.But the technical solution is based on the basis of tedge Increase coiling heat exchanger tube, setting certainly exists connectivity problem between the two, while also resulting in tedge manufacturing cost and increasing Add, service life is not grown.
Summary of the invention
To overcome manufacturing cost existing in the prior art increasing, service life is not grown, and raw coke oven gas heat utilization ratio is low The problem of, the present invention provides a kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery devices.
The technical solution adopted by the present invention is:A kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device, innovative point are: The tedge is three-stage, respectively includes cylindrical rising heat exchange of heat pipe, tedge interlude and tedge pedestal;It is described Connecting flange is equipped between rising heat exchange of heat pipe, tedge interlude and tedge pedestal to be attached.
In some embodiments, the length ratio for rising heat exchange of heat pipe, tedge middle section and tedge pedestal is 6:2:2。
In some embodiments, the junction of the connecting flange is provided with ceramic fibre gasket;Gasket and company It is sealed between acting flange using silicon carbide, cement, flux and curing agent.
In some embodiments, the tedge middle section is equipped with pressure detecting mouth, temperature detection mouth and observation panel;It is described Pressure detecting mouth is apart from tedge pedestal 315mm;Angle between the pressure detecting mouth and tedge pedestal is 45 °.
In some embodiments, temperature detection mouth distance rises tube body pedestal 315mm;The temperature detection mouth and rising Angle between tube bottom seat is 75 °.
In some embodiments, the observation panel is apart from tedge pedestal 270mm.
In some embodiments, the tedge base inner wall is mounted with refractory brick, tedge pedestal refractory brick surface Coated with composite coating;The composite coating is composed of white fused alumina, mullite, wearable silicon nitride curing agent.
In some embodiments, the curing agent is any one of silicon phosphate, sodium base or lithium base curing agent.
In some embodiments, the tedge pedestal is provided with slanting baffle;The tilt angle of the slanting baffle is 45 ° Angle.
In some embodiments, the overall length 617mm of the tedge pedestal.
Compared with prior art, the beneficial effects of the invention are as follows:
(1) three-stage tedge long service life of the invention, raw coke oven gas utilization rate of waste heat are high.In the present invention, rise The setting of pipe interlude mainly opens up various detection mouths, and convenient observation in time rises the various states of heat exchange of heat pipe, tedge The heat of coke oven is mainly carried out heat preservation thermal protection by the setting of pedestal, avoids heat losses too fast, influences waste heat recycling.
(2) equal length in tedge middle section and tedge pedestal of the present invention, and be 1/3 with the length for rising heat exchange of heat pipe Relationship, primary concern is that, tedge pedestal can satisfy tedge interlude and rise heat exchange of heat pipe load-bearing need It asks, in addition, tedge interlude and tedge pedestal keep identical length, can be conducive to rise while load-bearing range Pipe interlude can not accurately see the monitoring for rising heat exchange of heat pipe if tedge interlude is excessively high or excessively low The heat exchange situation for examining heat exchanger is unfavorable for waste heat recycling and plays optimum efficiency.
(3) in the present invention, angle and temperature detection mouth between pressure detecting mouth and tedge pedestal are set With the angle between tedge pedestal, purpose be provided to preferably to guarantee pressure detecting mouth 5 and temperature detection mouth smoothly into Row detection data, the data that the above three detection mouth being arranged through the invention is fed back adjust and rise liquid in heat exchange of heat pipe Body flow makes rising heat exchange of heat pipe reach optimum Working.
(4) in the present invention, the setting distance of temperature detection mouth is with the setting of pressure detecting mouth apart from identical, main consideration , can be tested by pressure detecting mouth at the identical temperature of same distance, or under the uniform pressure of same distance It is detected by temperature detection mouth, a variable can be stablized, the data fluctuations for being unlikely to detection are excessive, guarantee the true of detection data Reality and credibility.In short, in the present invention, setting detection mouth and observation panel are convenient for observing the pressure and temperature of coal gas in tedge Degree, can quickly know the state of coal gas in tedge, reach best effort effect, improve heat exchange efficiency.
(5) composite coating that the present invention is arranged can satisfy rushing for the big calorimetric of coke oven generation using rear 7 surface of refractory brick It hits, in addition, high temperature resistant degree reaches 2.5-2.8 times of 7 high temperature resistant temperature of prior art refractory brick.In addition, the present invention is reduced not Carry out the ingredient of stone, while improving the ingredient of some white fused aluminas and wearable silicon nitride curing agent, because the source of mullite is compared It is rare, it is possible to reduce cost, while three's group is shaped to composite coating, guarantees that coating plays outstanding heat resistant and wear resistant performance, And composite coating and refractory brick have good consistency, have and produce widened value.
(6) in this embodiment of the invention, the tedge pedestal 3 is provided with slanting baffle 71;The slanting baffle 71 Tilt angle be 45° angle.The setting effect of slanting baffle 71 is mainly when refractory brick 7 sinks, and refractory brick 7 is along under slanting baffle Heavy, 71 stress of slanting baffle becomes smaller, and while extending the service life of slanting baffle 71, extends the service life of tedge pedestal 3, into And increase the service life of entire tedge.Tests prove that device can be increased using waste-heat recovery device of the invention Service life at least 1 year or more.
Detailed description of the invention
Fig. 1 is coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device overall structure diagram of the present invention;
Fig. 2 is the top view of Fig. 1 of the present invention;
Fig. 3 is the structural schematic diagram of tedge pedestal of the present invention;
Fig. 4 is the waste-heat recovery device top view of present invention setting detection mouth;
Fig. 5 is the side view of present invention setting pressure detecting mouth;
Fig. 6 is the side view of present invention setting temperature detection mouth.
Specific embodiment
Below in conjunction with drawings and examples, the present invention will be described in further detail.It should be appreciated that described herein Specific examples are only used to explain the present invention, is not intended to limit the present invention.
The invention discloses a kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device, innovative point is:Such as Fig. 1,2 institutes Show:The tedge is three-stage, respectively includes cylindrical rising heat exchange of heat pipe 1, tedge interlude 2 and tedge pedestal 3;Connecting flange is equipped between the rising heat exchange of heat pipe 1, tedge interlude 2 and tedge pedestal 3 to be attached.This hair Bright three-stage tedge long service life, raw coke oven gas utilization rate of waste heat are high.In the present invention, the setting of tedge interlude 2 Various detection mouths are mainly opened up, convenient observation in time rises the various states of heat exchange of heat pipe 1, the setting master of tedge pedestal 3 If the heat of coke oven is carried out heat preservation thermal protection, avoid heat losses too fast, influences waste heat recycling.
As it is further preferred that in this embodiment of the invention, the rising heat exchange of heat pipe 1, tedge middle section 2 Length ratio with tedge pedestal 3 is 6:2:2.In the present invention, the mentality of designing important as one, tedge middle section 2 With the equal length of tedge pedestal 3, and with rise heat exchange of heat pipe 1 length be 1/3 relationship, primary concern is that, on Riser pedestal 3 can satisfy tedge interlude 2 and rise the load bearing demand of heat exchange of heat pipe 1, in addition, tedge interlude 2 Identical length is kept with tedge pedestal 3, tedge interlude 2 can be conducive to while load-bearing range and tedge is changed The monitoring of hot device 1 can not accurately observe the heat exchange feelings of heat exchanger if tedge interlude 2 is excessively high or excessively low Condition is unfavorable for waste heat recycling and plays optimum efficiency.As a preferred embodiment of the present invention, the tedge pedestal 3 Total length is set as 617mm, which is conducive to have the function of that good heat saves and waste heat recycles while load-bearing.
In the present invention, in order to increase rise heat exchange of heat pipe 1 and tedge interlude 2 and tedge interlude 2 with it is upper The seal degree of connecting flange between riser pedestal 3, the junction of the connecting flange are provided with ceramic fibre gasket (figure In be not shown);The sealing performance for further increasing gasket, in this embodiment of the invention, the gasket with connect It is sealed between flange using sealant, the sealant is made of silicon carbide, cement, flux and curing agent.The flux For potassium hydroxide or borate, the curing agent is p-hydroxybenzenyl sulfonate.
Specifically, in this embodiment of the invention, as shown in Fig. 1,4,5,6:The tedge interlude 2 is equipped with pressure Power detection mouth 5, temperature detection mouth 6 and observation panel 4;Wherein, pressure detecting mouth 5 is examined for rising gas pressure in heat exchange of heat pipe 1 It surveys, distance 315mm of the pressure detecting mouth 5 apart from tedge pedestal 3;Between the pressure detecting mouth 5 and tedge pedestal 3 Angle be 45 °.Wherein, temperature detection mouth 6 rises gas temperature detection in heat exchange of heat pipe 1 for detecting.Temperature detection mouth 6 away from From 3 distance 315mm of tedge pedestal;Angle between the temperature detection mouth 6 and tedge pedestal 3 is 75 °.The setting Observation panel 4 be used for observe rising heat exchange of heat pipe 1 interior change.In the present invention, setting pressure detecting mouth 5 and tedge bottom The angle between angle and temperature detection mouth 6 and tedge pedestal 3 between seat 3, purpose are provided to preferably protect Card pressure detecting mouth 5 and temperature detection mouth 6 smoothly carry out detection data, and the above three detection mouth being arranged through the invention is anti- The data come are fed back to, adjusts and rises fluid flow in heat exchange of heat pipe 1, rising heat exchange of heat pipe 1 is made to reach optimum Working.As It is further preferred that in the present invention, distance 270mm of the observation panel 4 apart from tedge pedestal 3.In this reality of the invention Apply in mode, the setting distance of temperature detection mouth 6 and the setting of pressure detecting mouth 5 apart from identical, primary concern is that, identical It can be tested by pressure detecting mouth 5 at the identical temperature of distance, or be examined under the uniform pressure of same distance by temperature Survey mouth 6 detect, a variable can be stablized, be unlikely to detection data fluctuations it is excessive, guarantee detection data authenticity and can Letter property.In short, in the present invention, setting detection mouth and observation panel 4, can be with convenient for the pressure and temperature of coal gas in observation tedge The state for quickly knowing coal gas in tedge reaches best effort effect, improves heat exchange efficiency.
As it is further preferred that in this embodiment of the invention, as shown in Figure 3:3 inner wall of tedge pedestal Refractory brick 7 is also mounted, the purpose of setting refractory brick 7 is to maintain the heat-resisting quantity of inner wall, as shown in Figure 3:In order to further mention The performance of the corrosion-and high-temp-resistant of high tedge pedestal 3, in the present invention, 7 surface of refractory brick of tedge pedestal 3 are coated with multiple Close coating;The composite coating is composed of white fused alumina, mullite, wearable silicon nitride curing agent.As further preferred , composite coating is to be followed successively by 3 by ratio between white fused alumina, mullite, wearable silicon nitride curing agent:0.5:2 are composed. For the composite coating that the present invention is arranged, the impact of the big calorimetric of coke oven generation can satisfy using rear 7 surface of refractory brick, this Outside, high temperature resistant degree reaches 2.5-2.8 times of 7 high temperature resistant temperature of prior art refractory brick.In addition, the present invention reduces mullite Ingredient, while improving the ingredient of some white fused aluminas and wearable silicon nitride curing agent can because the source of mullite is than sparser To reduce cost, while three's group is shaped to composite coating, guarantees that coating plays outstanding heat resistant and wear resistant performance, and compound painting Layer and refractory brick have good consistency, have and produce widened value.As it is further preferred that in this reality of the invention It applies in mode, the wearable silicon nitride curing agent is any one of silicon phosphate, sodium base or lithium base curing agent.
As it is further preferred that the tedge pedestal 3 is provided with slanting baffle in this embodiment of the invention 71;The tilt angle of the slanting baffle 71 is 45° angle.The setting effect of slanting baffle 71 is mainly the fire resisting when refractory brick 7 sinks Brick 7 sinks along slanting baffle, and 71 stress of slanting baffle becomes smaller, and while extending the service life of slanting baffle 71, extends tedge bottom The service life of seat 3, and then increase the service life of entire tedge.Tests prove that recycling dress using waste heat of the invention Set service life at least 1 year or more for can increasing device.
By above-mentioned change, three-stage of the present invention has following performance compared with the two-period form of the prior art:
Comparison project Three-stage Two-period form
Equipment life 8 years 5 years
Heat exchange efficiency 36% 25%
By above-mentioned change, there is following performance compared with without using the product using the product:
Comparison project It uses It is not used
Gas pressure data Pressure detecting It can not achieve
Gas temperature data Temperature detection It can not achieve
Rise inside pipe wall observation Inner wall observation It can not achieve
In the description of the present invention, it is to be understood that, term " coaxial ", " bottom ", " one end ", " top ", " middle part ", The orientation or positional relationship of the instructions such as " other end ", "upper", " side ", " top ", "inner", " front ", " center ", " both ends " is It is based on the orientation or positional relationship shown in the drawings, is merely for convenience of description of the present invention and simplification of the description, rather than instruction or dark Show that signified device or element must have a particular orientation, be constructed and operated in a specific orientation, therefore should not be understood as pair Limitation of the invention.
In the present invention unless specifically defined or limited otherwise, term " installation ", " setting ", " connection ", " fixation ", Terms such as " being screwed on " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integral;It can be with It is mechanical connection, is also possible to be electrically connected;It can be directly connected, two can also be can be indirectly connected through an intermediary The interaction relationship of connection or two elements inside a element, unless otherwise restricted clearly, for the common of this field For technical staff, the specific meanings of the above terms in the present invention can be understood according to specific conditions.
The preferred embodiment of the present invention has shown and described in above description, as previously described, it should be understood that the present invention is not office Be limited to form disclosed herein, should not be regarded as an exclusion of other examples, and can be used for various other combinations, modification and Environment, and can be changed within that scope of the inventive concept describe herein by the above teachings or related fields of technology or knowledge It is dynamic.And changes and modifications made by those skilled in the art do not depart from the spirit and scope of the present invention, then it all should be appended by the present invention In scope of protection of the claims.

Claims (10)

1. a kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device, it is characterised in that:The tedge is three-stage, is respectively included Cylindrical rising heat exchange of heat pipe (1), tedge interlude (2) and tedge pedestal (3);The rising heat exchange of heat pipe (1), on Connecting flange is equipped between riser interlude (2) and tedge pedestal (3) to be attached.
2. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 1, it is characterised in that:The tedge changes The length ratio of hot device (1), tedge middle section (2) and tedge pedestal (3) is 6:2:2.
3. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 1 or 2, it is characterised in that:The connection The junction of flange is provided with ceramic fibre gasket;It is sealed between ceramic fibre gasket and connecting flange using sealant; The sealant includes silicon carbide, cement, flux and curing agent.
4. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 1, it is characterised in that:In the tedge Between section (2) be equipped with pressure detecting mouth (5), temperature detection mouth (6) and observation panel (4);The pressure detecting mouth (5) is apart from tedge The distance of pedestal (3) is 315mm;Angle between the pressure detecting mouth (5) and tedge pedestal (3) is 45 °.
5. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 4, it is characterised in that:Temperature detection mouth (6) distance apart from tedge pedestal (3) is 315mm;Angle between the temperature detection mouth (6) and tedge pedestal (3) It is 75 °.
6. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 5, it is characterised in that:The observation panel (4) distance apart from tedge pedestal (3) is 270mm.
7. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 1, it is characterised in that:The tedge bottom Seat (3) inner wall is mounted with refractory brick (7) that tedge pedestal (3) refractory brick (7) surface is coated with composite coating;The compound painting Layer is composed of white fused alumina, mullite, wearable silicon nitride curing agent.
8. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 7, it is characterised in that:The wear-resisting carbonization Silicon curing agent is any one of silicon phosphate, sodium base or lithium base curing agent.
9. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 1, it is characterised in that:The tedge bottom Seat (3) is provided with slanting baffle (71);The tilt angle of the slanting baffle (71) is 45° angle.
10. coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device according to claim 1, it is characterised in that:The tedge The overall length 617mm of pedestal (3).
CN201811094237.5A 2018-09-19 2018-09-19 A kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device Pending CN108893125A (en)

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CN104673331A (en) * 2015-02-25 2015-06-03 鞍山拜尔自控有限公司 Heat exchange and heat energy recovery method employing coke oven ascension pipe and heat exchange and heat energy recovery device employing coke oven ascension pipe
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CN106079489A (en) * 2016-07-29 2016-11-09 启明新材料股份有限公司 A kind of membrane production equipment of afterheat recovery type
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CN106995705A (en) * 2017-03-16 2017-08-01 常州江南冶金科技有限公司 Coke oven coke oven uprising tube base
CN108330234A (en) * 2018-02-26 2018-07-27 西安交通大学 A kind of dry-type centrifugal granulation and waste heat recovery experimental provision
CN208733015U (en) * 2018-09-19 2019-04-12 武汉方特工业设备技术有限公司 A kind of coke oven coke oven uprising tube raw coke oven gas waste-heat recovery device

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