CN108892902A - A kind of ball valve High-strength fluorine rubber - Google Patents

A kind of ball valve High-strength fluorine rubber Download PDF

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Publication number
CN108892902A
CN108892902A CN201810540255.5A CN201810540255A CN108892902A CN 108892902 A CN108892902 A CN 108892902A CN 201810540255 A CN201810540255 A CN 201810540255A CN 108892902 A CN108892902 A CN 108892902A
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China
Prior art keywords
parts
stearate
oxide
ball valve
silica
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CN201810540255.5A
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Chinese (zh)
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张培
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Individual
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Individual
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Priority to CN201810540255.5A priority Critical patent/CN108892902A/en
Publication of CN108892902A publication Critical patent/CN108892902A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18Homopolymers or copolymers or tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of ball valve High-strength fluorine rubbers, belong to ball valve sealing technical field, which is characterized in that its parts by weight group becomes:20-40 parts of tetrapropanate fluorine rubber, middle medium thermal carbon blacks 80-120 parts, 30-60 parts of iso-cyanuric acid triallyl ester, 20-50 parts of benzoic anhydride polyester polyol, 10-30 parts of diethylenetriamine, 6-12 parts of modified graphene oxide, 2-8 parts of vulcanization aid, 3-9 parts of titanium dioxide, 2-6 parts of aluminum stearate, 4-8 parts of aluminium hydroxide, 2-5 parts of aluminium triphosphate, 1-6 parts of zinc stearate, 2-8 parts of zinc oxide, 5-15 parts of antimony oxide, 2-6 parts of triallyl isocyanurate, 3-9 parts of toluene di-isocyanate(TDI), 1-5 parts of glass fibre, 2-6 parts of silica flour, -4 parts of silica 1, 2-5 parts of pentaerythritol stearate, 3-6 parts of diphenyl silanediol.The beneficial effects of the invention are as follows:Significantly improve mechanical property.

Description

A kind of ball valve High-strength fluorine rubber
Technical field
The present invention relates to ball valve sealing technical fields, more particularly to a kind of ball valve High-strength fluorine rubber.
Background technique
Rubber seal is that a kind of general basic element rubber seal in sealing device is answered extensively in sealing technique A kind of rubber product.Since it is very small with elasticity modulus, the advantages of elongation is high, air permeation resistance and it is generally applicable In being mounted on various mechanical equipments.It is severe due to use environment, it is influenced if any low temperature etc., thus, damage sealing element.
Poor mechanical property in the prior art is unable to satisfy demand in actual use, therefore needs to design a kind of high-tensile strength The rubber seal of performance is learned to solve the problems of the prior art.
Summary of the invention
In order to solve the above technical problems, one technical scheme adopted by the invention is that:A kind of high-intensitive fluorine of ball valve is provided Rubber.
The purpose of the present invention is achieved through the following technical solutions:A kind of ball valve High-strength fluorine rubber, feature It is, parts by weight group becomes:20-40 parts of tetrapropanate fluorine rubber, medium thermal carbon blacks 80-120 parts middle, the different trimerization of triallyl 30-60 parts of cyanate, 20-50 parts of benzoic anhydride polyester polyol, 10-30 parts of diethylenetriamine, 6-12 parts of modified graphene oxide, sulphur Change auxiliary agent 2-8 parts, 3-9 parts of titanium dioxide, 2-6 parts of aluminum stearate, 4-8 parts of aluminium hydroxide, 2-5 parts of aluminium triphosphate, stearic acid 1-6 parts of zinc, 2-8 parts of zinc oxide, 5-15 parts of antimony oxide, 2-6 parts of triallyl isocyanurate, toluene di-isocyanate(TDI) 3- 9 parts, 1-5 parts of glass fibre, 2-6 parts of silica flour, -4 parts of silica 1,2-5 parts of pentaerythritol stearate, diphenyl silicon two 3-6 parts of alcohol.
Preferably, parts by weight group becomes:20 parts of tetrapropanate fluorine rubber, 80 parts of middle medium thermal carbon blacks, triallyl are different 30 parts of cyanurate, 20 parts of benzoic anhydride polyester polyol, 10 parts of diethylenetriamine, 6 parts of modified graphene oxide, vulcanization aid 2 Part, 3 parts of titanium dioxide, 2 parts of aluminum stearate, 4 parts of aluminium hydroxide, 2 parts of aluminium triphosphate, 1 part of zinc stearate, 2 parts of zinc oxide, three Aoxidize 5 parts of two antimony, 2 parts of triallyl isocyanurate, 3 parts of toluene di-isocyanate(TDI), 1 part of glass fibre, 2 parts of silica flour, two 1 part of silica, 2 parts of pentaerythritol stearate, 3 parts of diphenyl silanediol.
Preferably, parts by weight group becomes:40 parts of tetrapropanate fluorine rubber, 120 parts of middle medium thermal carbon blacks, triallyl are different 60 parts of cyanurate, 50 parts of benzoic anhydride polyester polyol, 30 parts of diethylenetriamine, 12 parts of modified graphene oxide, vulcanization aid 8 Part, 9 parts of titanium dioxide, 6 parts of aluminum stearate, 8 parts of aluminium hydroxide, 5 parts of aluminium triphosphate, 6 parts of zinc stearate, 8 parts of zinc oxide, three Aoxidize 15 parts of two antimony, 6 parts of triallyl isocyanurate, 9 parts of toluene di-isocyanate(TDI), 5 parts of glass fibre, 6 parts of silica flour, two 4 parts of silica, 5 parts of pentaerythritol stearate, 6 parts of diphenyl silanediol.
The beneficial effects of the invention are as follows:Titanium dioxide effectively enhances the characteristics such as wear-resisting, the anti-corrosion and intensity of rubber;Glass fibers Dimension further promotes the mechanical property of rubber;Silica flour adjusts the hardness of silicon rubber, improves the processing performance of sizing material;Silica As reinforcing agent, mechanical strength is improved;Diphenyl silanediol improves the process industrial art performance of rubber as constitution controller;? Under the common mating reaction of each component, the mechanical strength of rubber produced by the present invention is remarkably reinforced, and the great market competitiveness and is pushed away Wide use value.
Specific embodiment
The present invention will be further described below, but protection scope of the present invention be not limited to it is as described below.
Embodiment 1
A kind of ball valve High-strength fluorine rubber, parts by weight group become:20 parts of tetrapropanate fluorine rubber, middle medium thermal carbon blacks 80 Part, 30 parts of iso-cyanuric acid triallyl ester, 20 parts of benzoic anhydride polyester polyol, 10 parts of diethylenetriamine, modified graphene oxide 6 Part, 2 parts of vulcanization aid, 3 parts of titanium dioxide, 2 parts of aluminum stearate, 4 parts of aluminium hydroxide, 2 parts of aluminium triphosphate, 1 part of zinc stearate, 2 parts of zinc oxide, 5 parts of antimony oxide, 2 parts of triallyl isocyanurate, 3 parts of toluene di-isocyanate(TDI), 1 part of glass fibre, 2 parts of silica flour, silica 1 part, 2 parts of pentaerythritol stearate, 3 parts of diphenyl silanediol.
Embodiment 2
A kind of ball valve High-strength fluorine rubber, parts by weight group become:40 parts of tetrapropanate fluorine rubber, middle medium thermal carbon blacks 120 Part, 60 parts of iso-cyanuric acid triallyl ester, 50 parts of benzoic anhydride polyester polyol, 30 parts of diethylenetriamine, modified graphene oxide 12 parts, 8 parts of vulcanization aid, 9 parts of titanium dioxide, 6 parts of aluminum stearate, 8 parts of aluminium hydroxide, 5 parts of aluminium triphosphate, zinc stearate 6 Part, 8 parts of zinc oxide, 15 parts of antimony oxide, 6 parts of triallyl isocyanurate, 9 parts of toluene di-isocyanate(TDI), glass fibre 5 Part, 6 parts of silica flour, 4 parts of silica, 5 parts of pentaerythritol stearate, 6 parts of diphenyl silanediol.
Embodiment 3
A kind of ball valve High-strength fluorine rubber, which is characterized in that its parts by weight group becomes:30 parts of tetrapropanate fluorine rubber, middle particle heat It splits 100 parts of method carbon black, 40 parts of iso-cyanuric acid triallyl ester, 35 parts of benzoic anhydride polyester polyol, 20 parts of diethylenetriamine, be modified 9 parts of graphene oxide, 5 parts of vulcanization aid, 6 parts of titanium dioxide, 4 parts of aluminum stearate, 6 parts of aluminium hydroxide, aluminium triphosphate 3.5 Part, 3.5 parts of zinc stearate, 5 parts of zinc oxide, 10 parts of antimony oxide, 4 parts of triallyl isocyanurate, toluene diisocynate 6 parts of ester, 3 parts of glass fibre, 4 parts of silica flour, 2.5 parts of silica, 3.5 parts of pentaerythritol stearate, diphenyl silanediol 4.5 part.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, there can be various modifications and variations in the spirit and principles in the present invention, these equivalent variation or replacement etc., It is all included in the scope of protection of the present invention.

Claims (3)

1. a kind of ball valve High-strength fluorine rubber, which is characterized in that its parts by weight group becomes:20-40 parts of tetrapropanate fluorine rubber, middle grain Sub- thermal crack black 80-120 parts, 30-60 parts of iso-cyanuric acid triallyl ester, 20-50 parts of benzoic anhydride polyester polyol, divinyl 10-30 parts of triamine, 6-12 parts of modified graphene oxide, 2-8 parts of vulcanization aid, 3-9 parts of titanium dioxide, 2-6 parts of aluminum stearate, hydrogen 4-8 parts of aluminium oxide, 2-5 parts of aluminium triphosphate, 1-6 parts of zinc stearate, 2-8 parts of zinc oxide, 5-15 parts of antimony oxide, three allyls 2-6 parts of base chlorinated isocyanurates, 3-9 parts of toluene di-isocyanate(TDI), 1-5 parts of glass fibre, 2-6 parts of silica flour, silica 1-4 Part, 2-5 parts of pentaerythritol stearate, 3-6 parts of diphenyl silanediol.
2. a kind of ball valve High-strength fluorine rubber according to claim 1, which is characterized in that its parts by weight group becomes:Four Third 20 parts of fluorubber, 80 parts of middle medium thermal carbon blacks, 30 parts of iso-cyanuric acid triallyl ester, benzoic anhydride polyester polyol 20 Part, 10 parts of diethylenetriamine, 6 parts of modified graphene oxide, 2 parts of vulcanization aid, 3 parts of titanium dioxide, 2 parts of aluminum stearate, hydrogen-oxygen Change 4 parts of aluminium, 2 parts of aluminium triphosphate, 1 part of zinc stearate, 2 parts of zinc oxide, 5 parts of antimony oxide, triallyl isocyanurate 2 Part, 3 parts of toluene di-isocyanate(TDI), 1 part of glass fibre, 2 parts of silica flour, silica 1 part, 2 parts of pentaerythritol stearate, two 3 parts of diphenyl silanediol.
3. a kind of ball valve High-strength fluorine rubber according to claim 1, which is characterized in that its parts by weight group becomes:Four Third 40 parts of fluorubber, 120 parts of middle medium thermal carbon blacks, 60 parts of iso-cyanuric acid triallyl ester, benzoic anhydride polyester polyol 50 Part, 30 parts of diethylenetriamine, 12 parts of modified graphene oxide, 8 parts of vulcanization aid, 9 parts of titanium dioxide, 6 parts of aluminum stearate, hydrogen-oxygen Change 8 parts of aluminium, 5 parts of aluminium triphosphate, 6 parts of zinc stearate, 8 parts of zinc oxide, 15 parts of antimony oxide, triallyl isocyanurate 6 parts, 9 parts of toluene di-isocyanate(TDI), 5 parts of glass fibre, 6 parts of silica flour, 4 parts of silica, 5 parts of pentaerythritol stearate, 6 parts of diphenyl silanediol.
CN201810540255.5A 2018-05-30 2018-05-30 A kind of ball valve High-strength fluorine rubber Withdrawn CN108892902A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810540255.5A CN108892902A (en) 2018-05-30 2018-05-30 A kind of ball valve High-strength fluorine rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810540255.5A CN108892902A (en) 2018-05-30 2018-05-30 A kind of ball valve High-strength fluorine rubber

Publications (1)

Publication Number Publication Date
CN108892902A true CN108892902A (en) 2018-11-27

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CN201810540255.5A Withdrawn CN108892902A (en) 2018-05-30 2018-05-30 A kind of ball valve High-strength fluorine rubber

Country Status (1)

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CN (1) CN108892902A (en)

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Application publication date: 20181127

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