CN108892408A - The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch - Google Patents
The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch Download PDFInfo
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- CN108892408A CN108892408A CN201811098040.9A CN201811098040A CN108892408A CN 108892408 A CN108892408 A CN 108892408A CN 201811098040 A CN201811098040 A CN 201811098040A CN 108892408 A CN108892408 A CN 108892408A
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- powder
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- anticoagulant ice
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- miberal
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/60—Agents for protection against chemical, physical or biological attack
- C04B2103/601—Agents for increasing frost resistance
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The invention discloses anticoagulant ice additive of miberal powder in a kind of alternative pitch and preparation method thereof, the raw material including following parts by weight：45-55 parts of calcium chloride, 5-8 parts of phosphoric acid, 8-15 parts of carboxylic acid, 5-10 parts of calc-sinter powder, 8-15 parts of cell quartz powder, 5-8 parts of dolomite powder and 5-8 parts of polyurethane foam powder.Raw material sources of the present invention are extensive, it the use of the complex salt of calcium and magnesium, calcium chloride or sodium chloride is main snow melting material, cell quartz powder is main carriers, polyurethane is hydrophobic insulator, realize the friendly effect of construction, the finished product of preparation can directly substitute the production that miberal powder carries out asphalt, good in -15-0 DEG C of road surface antifreezing effects, and realize the permanence operation of 5-10, the problems such as solving the existing anticoagulant ice technology of storage salt there are constructional difficulties and bad long-term effects.
Description
Technical field
The present invention relates to the anticoagulant ice field of pitch, the anticoagulant ice additive of miberal powder in specifically a kind of alternative pitch.
Background technique
Currently, bituminous pavement occupies absolute leading position, domestic highway and each grade road, bridge in China's road
Bituminous pavement form is all made of in the main roads such as face mats formation, airfield runway, urban road.However, with China's road construction
Development, road builds on a large scale throughout the country, and time, the formation of road snow mantle and dark ice seriously threaten road in winter
Traffic safety, it is so very big that constrain the development of carrier, inconvenience is brought to the production and living of people.Therefore, it solves
Ice problem is coagulated in winter road snowfall, reduces Traffic Accident Loss, improves road efficiency of operation, becomes present grey decision system work
Person needs the direction captured.
Existing winter deicing method is mainly using snow dust is passively removed, after snowfall generation, by manually removing the snow, dispensing
The work that clears the snow is realized in deicing salt and snow removal with machine.The passive common fault except snow dust is that it can not complete Snow removing immediately, when
Effect property is poor, and is difficult to solve the solidifying ice problem in road surface after snow removing.And artificial snow removing, effect is poor, low efficiency；Dispense deicing salt operation
It is extensive, it is big to environmental hazard；Machinery, which clears the snow, to consume energy greatly, can not remove in time to high speed at a distance, road pavement is destroyed very big.
To solve passively to remove the various disadvantages of snow dust, the main side that snow dust is increasingly becoming road deicing snow technology is actively removed
To.Active deicing technology mainly has energy supply type and non-power providing type, and energy supply type mainly passes through the pipeline being laid in advance, takes electricity
Heat, the mode of hydro-thermal carry out deicing or snow melting；Non-power providing type mainly reaches deicing effect using storage salt or elastic road surface.It is passing through
Think after crossing prolonged scientific research and application, in the case where considering cost maintenance, action time and using effect, using storage
Salt technology is more reasonable technology, but there are constructional difficulties and long-term effect are bad for the existing anticoagulant ice technology of storage salt
Problem, this is just that the use of people brings inconvenience.
Summary of the invention
The purpose of the present invention is to provide a kind of anticoagulant ice additives of miberal powder in alternative pitch, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides the following technical solutions：
The anticoagulant ice additive of miberal powder, the raw material including following parts by weight in a kind of alternative pitch：Calcium chloride 45-55
Part, 5-8 parts of phosphoric acid, 8-15 parts of carboxylic acid, 5-10 parts of calc-sinter powder, 8-15 parts of cell quartz powder, dolomite powder 5-8
Part and 5-8 parts of polyurethane foam powder.
As a further solution of the present invention：Calcium chloride is replaced with to the mixture of sodium chloride and calcium chloride, sodium chloride exists
Mass fraction in mixture is 1-100%.
As a further solution of the present invention：The partial size of calcium chloride, calc-sinter powder and polyurethane foam powder is equal
Lower than 0.075mm.
The preparation method of the anticoagulant ice additive of miberal powder in the alternative pitch, specific step is as follows：
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 340-360 degrees Celsius by step 1, then to its
Middle addition calc-sinter powder and dolomite powder keep the temperature and quickly stir 1-1.8 hours；
The product of step 1 is stopped heating and natural cooling, guarantor when naturally cooling to 95-105 degrees Celsius by step 2
Calcium chloride and cell quartz powder are added thereto, persistently stirs evenly and is cooled to room temperature for temperature；
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
As a further solution of the present invention：The speed quickly stirred in step 1 is 750-1080rpm.
Compared with prior art, the beneficial effects of the invention are as follows：Raw material sources of the present invention are extensive, use the network of calcium and magnesium
Salt, calcium chloride or sodium chloride are main snow melting material, and cell quartz powder is main carriers, and polyurethane is hydrophobic insulator, are realized
The friendly effect of construction, the finished product of preparation can directly substitute the production that miberal powder carries out asphalt, anti-on -15-0 DEG C of road surfaces
It is good to freeze effect, and realizes the permanence operation of 5-10, solve the existing anticoagulant ice technology of storage salt there are constructional difficulties with
The problems such as long-term effect is bad.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment 1
The anticoagulant ice additive of miberal powder, the raw material including following parts by weight in a kind of alternative pitch：45 parts of calcium chloride, phosphorus
5 parts of acid, 8 parts of carboxylic acid, 5 parts of calc-sinter powder, 8 parts of cell quartz powder, 5 parts of dolomite powder and polyurethane foam powder
5 parts.The partial size of calcium chloride, calc-sinter powder and polyurethane foam powder is below 0.075mm.
The preparation method of the anticoagulant ice additive of miberal powder in the alternative pitch, specific step is as follows：
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 340 degrees Celsius by step 1, then adds thereto
Enter calc-sinter powder and dolomite powder, keep the temperature and quickly stirs 1.5 hours；
Step 2, product stopping heating and natural cooling by step 1, heat preservation when naturally cooling to 95 degrees Celsius, to
Calcium chloride and cell quartz powder is wherein added, persistently stirs evenly and is cooled to room temperature；
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
Embodiment 2
The anticoagulant ice additive of miberal powder, the raw material including following parts by weight in a kind of alternative pitch：52 parts of sodium chloride, phosphorus
6.8 parts of acid, 13 parts of carboxylic acid, 7.5 parts of calc-sinter powder, 12.4 parts of cell quartz powder, 6.6 parts of dolomite powder and poly- ammonia
7.2 parts of ester foaming powder.The partial size of sodium chloride, calc-sinter powder and polyurethane foam powder is below 0.075mm.
The preparation method of the anticoagulant ice additive of miberal powder in the alternative pitch, specific step is as follows：
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 350 degrees Celsius by step 1, then adds thereto
Enter calc-sinter powder and dolomite powder, keep the temperature and is quickly stirred 1 hour with the revolving speed of 960rpm；
Step 2, product stopping heating and natural cooling by step 1, heat preservation when naturally cooling to 100 degrees Celsius,
Calcium chloride and cell quartz powder are added thereto, persistently stirs evenly and is cooled to room temperature；
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
Embodiment 3
The anticoagulant ice additive of miberal powder, the raw material including following parts by weight in a kind of alternative pitch：55 parts of calcium chloride, phosphorus
8 parts of acid, 15 parts of carboxylic acid, 10 parts of calc-sinter powder, 15 parts of cell quartz powder, 8 parts of dolomite powder and polyurethane foam
8 parts of powder.The partial size of calcium chloride, calc-sinter powder and polyurethane foam powder is below 0.075mm.
The preparation method of the anticoagulant ice additive of miberal powder in the alternative pitch, specific step is as follows：
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 360 degrees Celsius by step 1, then adds thereto
Enter calc-sinter powder and dolomite powder, keep the temperature and is quickly stirred 1.8 hours with the revolving speed of 1050rpm；
Step 2, product stopping heating and natural cooling by step 1, heat preservation when naturally cooling to 105 degrees Celsius,
Calcium chloride and cell quartz powder are added thereto, persistently stirs evenly and is cooled to room temperature；
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
The product of embodiment 1-3 is individually examined, checking procedure is as follows：Step 1 takes out finished product in cone with soupspoon
Heap shape heap is depressed in surface, with soupspoon ground from conial vertex, and taper heap is made to be pressed into smooth inner concave；
Step 2 takes deionized water to be dripped water droplet by concave surface minimum point with 0.5ml dropper；
Step 3 records the time that anticoagulant ice material is not penetrated into stop of the water droplet in concave surface.
It measures, residence time of its water droplet of the product of embodiment 1-3 in concave surface is all larger than 10 minutes, meets use condition.
Aggregate is mixed and stirred 30 seconds in advance, add pitch and mix and stir 90 seconds, obtain asphalt, embodiment 1 is then added
Product or miberal powder and asphalt mix and stir 60 seconds, then carry out forming experiment, experiment condition reference《Highway engineering pitch and drip
Green mixture Experimental Procedures》The specific requirement of (JTG E20-2011) carries out, and experimental result is shown in Table 2.It will be mixed with 2 product of embodiment
Asphalt carry out the experiment of corrosion of carbon steel rate, it is saturated solution that corrosion of carbon steel rate, which tests solution used, is shown in Table 1.
Table 1
Table 2
Table 1 shows that the corrosion of carbon steel rate of product of the invention meets《Deicing salt》(DB11/T161-2012) requirement.
When table 2 shows the present invention for asphalt, the stability of finished product, flow valuve, track dynamic stability, freeze thawing are split
The indexs such as experiment retained strength ratio, residual stability, low-temperature bending experiment failure strain, infiltration index are split to meet《Highway drip
Green pavement construction technical specification》The specific requirement of (JTG F40-2004), and product of the invention and asphalt cooperate
Deicing is easier relative to existing asphalt at -5 DEG C when use.
The present invention is reacted by phosphoric acid and carboxylic acid with dolomite and limestone, generates the complex salt containing calcium and magnesium, and surplus
Under the action of remaining phosphoric acid and carboxylic acid, complex salt, calcium chloride or the sodium chloride of calcium and magnesium and the interfacial adhesion of cell quartz powder are realized, and
Then feature mixing material similar with miberal powder, the mixing material are prepared into whole progress water proof processing by polyurethane foam
Miberal powder can be directly substituted on the basis of existing mature bituminous mixture technique and participates in mixture production, and is not influencing road
While the basic property of face, antifreeze function is played for a long time, it can be achieved that the road surface within -15-0 DEG C is antifreeze, realizes 5-10's
Permanence operation.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (5)
1. the anticoagulant ice additive of miberal powder in a kind of alternative pitch, which is characterized in that the raw material including following parts by weight：Chlorination
- 55 parts of Ca45,5-8 parts of phosphoric acid, 8-15 parts of carboxylic acid, 5-10 parts of calc-sinter powder, 8-15 parts of cell quartz powder, dolomite
5-8 parts and 5-8 parts of polyurethane foam powder of powder.
2. the anticoagulant ice additive of miberal powder in alternative pitch according to claim 1, which is characterized in that the calcium chloride
The mixture of sodium chloride and calcium chloride is replaced with, the mass fraction of sodium chloride in the mixture is 1-100%.
3. the anticoagulant ice additive of miberal powder in alternative pitch according to claim 1, which is characterized in that the chlorination
The partial size of calcium, calc-sinter powder and polyurethane foam powder is below 0.075mm.
4. the preparation method of the anticoagulant ice additive of miberal powder in a kind of alternative pitch a method according to any one of claims 1-3,
It is characterized in that, specific step is as follows：
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 340-360 degrees Celsius by step 1, then adds thereto
Enter calc-sinter powder and dolomite powder, keep the temperature and quickly stirs 1-1.8 hours；
Step 2, product stopping heating and natural cooling by step 1, heat preservation when naturally cooling to 95-105 degrees Celsius, to
Calcium chloride and cell quartz powder is wherein added, persistently stirs evenly and is cooled to room temperature；
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
5. the preparation method of the anticoagulant ice additive of miberal powder in alternative pitch according to claim 4, which is characterized in that
The speed quickly stirred in the step 1 is 750-1080rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811098040.9A CN108892408A (en) | 2018-09-20 | 2018-09-20 | The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811098040.9A CN108892408A (en) | 2018-09-20 | 2018-09-20 | The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch |
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| Publication Number | Publication Date |
|---|---|
| CN108892408A true CN108892408A (en) | 2018-11-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811098040.9A Pending CN108892408A (en) | 2018-09-20 | 2018-09-20 | The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111675506A (en) * | 2020-05-29 | 2020-09-18 | 山东高速集团有限公司创新研究中心 | Anti-freezing agent and preparation method thereof |
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| CN104774592A (en) * | 2015-04-10 | 2015-07-15 | 常州履信新材料科技有限公司 | Slow-release antifreezing material for asphalt pavements and preparation method thereof |
| CN105384393A (en) * | 2015-11-30 | 2016-03-09 | 盖波 | Freeze-resisting asphalt mixture and preparation method thereof |
| CN105623607A (en) * | 2016-02-26 | 2016-06-01 | 盖波 | Snow melting slip proofing agent and preparing method thereof |
| CN105838326A (en) * | 2016-04-28 | 2016-08-10 | 北京联合大学 | Ecological rehabilitation promoting snow-melting agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111675506A (en) * | 2020-05-29 | 2020-09-18 | 山东高速集团有限公司创新研究中心 | Anti-freezing agent and preparation method thereof |
| CN111675506B (en) * | 2020-05-29 | 2022-07-29 | 山东高速集团有限公司创新研究中心 | Anti-freezing agent and preparation method thereof |
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Application publication date: 20181127 |