CN108892408A - The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch - Google Patents

The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch Download PDF

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Publication number
CN108892408A
CN108892408A CN201811098040.9A CN201811098040A CN108892408A CN 108892408 A CN108892408 A CN 108892408A CN 201811098040 A CN201811098040 A CN 201811098040A CN 108892408 A CN108892408 A CN 108892408A
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China
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powder
parts
anticoagulant ice
preparation
miberal
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CN201811098040.9A
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盖波
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/601Agents for increasing frost resistance

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

The invention discloses anticoagulant ice additive of miberal powder in a kind of alternative pitch and preparation method thereof, the raw material including following parts by weight:45-55 parts of calcium chloride, 5-8 parts of phosphoric acid, 8-15 parts of carboxylic acid, 5-10 parts of calc-sinter powder, 8-15 parts of cell quartz powder, 5-8 parts of dolomite powder and 5-8 parts of polyurethane foam powder.Raw material sources of the present invention are extensive, it the use of the complex salt of calcium and magnesium, calcium chloride or sodium chloride is main snow melting material, cell quartz powder is main carriers, polyurethane is hydrophobic insulator, realize the friendly effect of construction, the finished product of preparation can directly substitute the production that miberal powder carries out asphalt, good in -15-0 DEG C of road surface antifreezing effects, and realize the permanence operation of 5-10, the problems such as solving the existing anticoagulant ice technology of storage salt there are constructional difficulties and bad long-term effects.

Description

The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch
Technical field
The present invention relates to the anticoagulant ice field of pitch, the anticoagulant ice additive of miberal powder in specifically a kind of alternative pitch.
Background technique
Currently, bituminous pavement occupies absolute leading position, domestic highway and each grade road, bridge in China's road Bituminous pavement form is all made of in the main roads such as face mats formation, airfield runway, urban road.However, with China's road construction Development, road builds on a large scale throughout the country, and time, the formation of road snow mantle and dark ice seriously threaten road in winter Traffic safety, it is so very big that constrain the development of carrier, inconvenience is brought to the production and living of people.Therefore, it solves Ice problem is coagulated in winter road snowfall, reduces Traffic Accident Loss, improves road efficiency of operation, becomes present grey decision system work Person needs the direction captured.
Existing winter deicing method is mainly using snow dust is passively removed, after snowfall generation, by manually removing the snow, dispensing The work that clears the snow is realized in deicing salt and snow removal with machine.The passive common fault except snow dust is that it can not complete Snow removing immediately, when Effect property is poor, and is difficult to solve the solidifying ice problem in road surface after snow removing.And artificial snow removing, effect is poor, low efficiency;Dispense deicing salt operation It is extensive, it is big to environmental hazard;Machinery, which clears the snow, to consume energy greatly, can not remove in time to high speed at a distance, road pavement is destroyed very big.
To solve passively to remove the various disadvantages of snow dust, the main side that snow dust is increasingly becoming road deicing snow technology is actively removed To.Active deicing technology mainly has energy supply type and non-power providing type, and energy supply type mainly passes through the pipeline being laid in advance, takes electricity Heat, the mode of hydro-thermal carry out deicing or snow melting;Non-power providing type mainly reaches deicing effect using storage salt or elastic road surface.It is passing through Think after crossing prolonged scientific research and application, in the case where considering cost maintenance, action time and using effect, using storage Salt technology is more reasonable technology, but there are constructional difficulties and long-term effect are bad for the existing anticoagulant ice technology of storage salt Problem, this is just that the use of people brings inconvenience.
Summary of the invention
The purpose of the present invention is to provide a kind of anticoagulant ice additives of miberal powder in alternative pitch, to solve above-mentioned background The problem of being proposed in technology.
To achieve the above object, the present invention provides the following technical solutions:
The anticoagulant ice additive of miberal powder, the raw material including following parts by weight in a kind of alternative pitch:Calcium chloride 45-55 Part, 5-8 parts of phosphoric acid, 8-15 parts of carboxylic acid, 5-10 parts of calc-sinter powder, 8-15 parts of cell quartz powder, dolomite powder 5-8 Part and 5-8 parts of polyurethane foam powder.
As a further solution of the present invention:Calcium chloride is replaced with to the mixture of sodium chloride and calcium chloride, sodium chloride exists Mass fraction in mixture is 1-100%.
As a further solution of the present invention:The partial size of calcium chloride, calc-sinter powder and polyurethane foam powder is equal Lower than 0.075mm.
The preparation method of the anticoagulant ice additive of miberal powder in the alternative pitch, specific step is as follows:
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 340-360 degrees Celsius by step 1, then to its Middle addition calc-sinter powder and dolomite powder keep the temperature and quickly stir 1-1.8 hours;
The product of step 1 is stopped heating and natural cooling, guarantor when naturally cooling to 95-105 degrees Celsius by step 2 Calcium chloride and cell quartz powder are added thereto, persistently stirs evenly and is cooled to room temperature for temperature;
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
As a further solution of the present invention:The speed quickly stirred in step 1 is 750-1080rpm.
Compared with prior art, the beneficial effects of the invention are as follows:Raw material sources of the present invention are extensive, use the network of calcium and magnesium Salt, calcium chloride or sodium chloride are main snow melting material, and cell quartz powder is main carriers, and polyurethane is hydrophobic insulator, are realized The friendly effect of construction, the finished product of preparation can directly substitute the production that miberal powder carries out asphalt, anti-on -15-0 DEG C of road surfaces It is good to freeze effect, and realizes the permanence operation of 5-10, solve the existing anticoagulant ice technology of storage salt there are constructional difficulties with The problems such as long-term effect is bad.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment 1
The anticoagulant ice additive of miberal powder, the raw material including following parts by weight in a kind of alternative pitch:45 parts of calcium chloride, phosphorus 5 parts of acid, 8 parts of carboxylic acid, 5 parts of calc-sinter powder, 8 parts of cell quartz powder, 5 parts of dolomite powder and polyurethane foam powder 5 parts.The partial size of calcium chloride, calc-sinter powder and polyurethane foam powder is below 0.075mm.
The preparation method of the anticoagulant ice additive of miberal powder in the alternative pitch, specific step is as follows:
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 340 degrees Celsius by step 1, then adds thereto Enter calc-sinter powder and dolomite powder, keep the temperature and quickly stirs 1.5 hours;
Step 2, product stopping heating and natural cooling by step 1, heat preservation when naturally cooling to 95 degrees Celsius, to Calcium chloride and cell quartz powder is wherein added, persistently stirs evenly and is cooled to room temperature;
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
Embodiment 2
The anticoagulant ice additive of miberal powder, the raw material including following parts by weight in a kind of alternative pitch:52 parts of sodium chloride, phosphorus 6.8 parts of acid, 13 parts of carboxylic acid, 7.5 parts of calc-sinter powder, 12.4 parts of cell quartz powder, 6.6 parts of dolomite powder and poly- ammonia 7.2 parts of ester foaming powder.The partial size of sodium chloride, calc-sinter powder and polyurethane foam powder is below 0.075mm.
The preparation method of the anticoagulant ice additive of miberal powder in the alternative pitch, specific step is as follows:
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 350 degrees Celsius by step 1, then adds thereto Enter calc-sinter powder and dolomite powder, keep the temperature and is quickly stirred 1 hour with the revolving speed of 960rpm;
Step 2, product stopping heating and natural cooling by step 1, heat preservation when naturally cooling to 100 degrees Celsius, Calcium chloride and cell quartz powder are added thereto, persistently stirs evenly and is cooled to room temperature;
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
Embodiment 3
The anticoagulant ice additive of miberal powder, the raw material including following parts by weight in a kind of alternative pitch:55 parts of calcium chloride, phosphorus 8 parts of acid, 15 parts of carboxylic acid, 10 parts of calc-sinter powder, 15 parts of cell quartz powder, 8 parts of dolomite powder and polyurethane foam 8 parts of powder.The partial size of calcium chloride, calc-sinter powder and polyurethane foam powder is below 0.075mm.
The preparation method of the anticoagulant ice additive of miberal powder in the alternative pitch, specific step is as follows:
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 360 degrees Celsius by step 1, then adds thereto Enter calc-sinter powder and dolomite powder, keep the temperature and is quickly stirred 1.8 hours with the revolving speed of 1050rpm;
Step 2, product stopping heating and natural cooling by step 1, heat preservation when naturally cooling to 105 degrees Celsius, Calcium chloride and cell quartz powder are added thereto, persistently stirs evenly and is cooled to room temperature;
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
The product of embodiment 1-3 is individually examined, checking procedure is as follows:Step 1 takes out finished product in cone with soupspoon Heap shape heap is depressed in surface, with soupspoon ground from conial vertex, and taper heap is made to be pressed into smooth inner concave;
Step 2 takes deionized water to be dripped water droplet by concave surface minimum point with 0.5ml dropper;
Step 3 records the time that anticoagulant ice material is not penetrated into stop of the water droplet in concave surface.
It measures, residence time of its water droplet of the product of embodiment 1-3 in concave surface is all larger than 10 minutes, meets use condition.
Aggregate is mixed and stirred 30 seconds in advance, add pitch and mix and stir 90 seconds, obtain asphalt, embodiment 1 is then added Product or miberal powder and asphalt mix and stir 60 seconds, then carry out forming experiment, experiment condition reference《Highway engineering pitch and drip Green mixture Experimental Procedures》The specific requirement of (JTG E20-2011) carries out, and experimental result is shown in Table 2.It will be mixed with 2 product of embodiment Asphalt carry out the experiment of corrosion of carbon steel rate, it is saturated solution that corrosion of carbon steel rate, which tests solution used, is shown in Table 1.
Table 1
Table 2
Table 1 shows that the corrosion of carbon steel rate of product of the invention meets《Deicing salt》(DB11/T161-2012) requirement.
When table 2 shows the present invention for asphalt, the stability of finished product, flow valuve, track dynamic stability, freeze thawing are split The indexs such as experiment retained strength ratio, residual stability, low-temperature bending experiment failure strain, infiltration index are split to meet《Highway drip Green pavement construction technical specification》The specific requirement of (JTG F40-2004), and product of the invention and asphalt cooperate Deicing is easier relative to existing asphalt at -5 DEG C when use.
The present invention is reacted by phosphoric acid and carboxylic acid with dolomite and limestone, generates the complex salt containing calcium and magnesium, and surplus Under the action of remaining phosphoric acid and carboxylic acid, complex salt, calcium chloride or the sodium chloride of calcium and magnesium and the interfacial adhesion of cell quartz powder are realized, and Then feature mixing material similar with miberal powder, the mixing material are prepared into whole progress water proof processing by polyurethane foam Miberal powder can be directly substituted on the basis of existing mature bituminous mixture technique and participates in mixture production, and is not influencing road While the basic property of face, antifreeze function is played for a long time, it can be achieved that the road surface within -15-0 DEG C is antifreeze, realizes 5-10's Permanence operation.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (5)

1. the anticoagulant ice additive of miberal powder in a kind of alternative pitch, which is characterized in that the raw material including following parts by weight:Chlorination - 55 parts of Ca45,5-8 parts of phosphoric acid, 8-15 parts of carboxylic acid, 5-10 parts of calc-sinter powder, 8-15 parts of cell quartz powder, dolomite 5-8 parts and 5-8 parts of polyurethane foam powder of powder.
2. the anticoagulant ice additive of miberal powder in alternative pitch according to claim 1, which is characterized in that the calcium chloride The mixture of sodium chloride and calcium chloride is replaced with, the mass fraction of sodium chloride in the mixture is 1-100%.
3. the anticoagulant ice additive of miberal powder in alternative pitch according to claim 1, which is characterized in that the chlorination The partial size of calcium, calc-sinter powder and polyurethane foam powder is below 0.075mm.
4. the preparation method of the anticoagulant ice additive of miberal powder in a kind of alternative pitch a method according to any one of claims 1-3, It is characterized in that, specific step is as follows:
Phosphoric acid is uniformly mixed with carboxylic acid in dry environments and is heated to 340-360 degrees Celsius by step 1, then adds thereto Enter calc-sinter powder and dolomite powder, keep the temperature and quickly stirs 1-1.8 hours;
Step 2, product stopping heating and natural cooling by step 1, heat preservation when naturally cooling to 95-105 degrees Celsius, to Calcium chloride and cell quartz powder is wherein added, persistently stirs evenly and is cooled to room temperature;
Step 3, by polyurethane foam powder be added step 2 product in and high-speed stirred uniformly to get arrive finished product.
5. the preparation method of the anticoagulant ice additive of miberal powder in alternative pitch according to claim 4, which is characterized in that The speed quickly stirred in the step 1 is 750-1080rpm.
CN201811098040.9A 2018-09-20 2018-09-20 The anticoagulant ice additive and preparation method thereof of miberal powder in a kind of alternative pitch Pending CN108892408A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111675506A (en) * 2020-05-29 2020-09-18 山东高速集团有限公司创新研究中心 Anti-freezing agent and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774592A (en) * 2015-04-10 2015-07-15 常州履信新材料科技有限公司 Slow-release antifreezing material for asphalt pavements and preparation method thereof
CN105384393A (en) * 2015-11-30 2016-03-09 盖波 Freeze-resisting asphalt mixture and preparation method thereof
CN105623607A (en) * 2016-02-26 2016-06-01 盖波 Snow melting slip proofing agent and preparing method thereof
CN105838326A (en) * 2016-04-28 2016-08-10 北京联合大学 Ecological rehabilitation promoting snow-melting agent and preparation method thereof
CN107603563A (en) * 2017-09-29 2018-01-19 徐州得铸生物科技有限公司 A kind of new municipal administration environment protection snow-dissolved agent
CN108410189A (en) * 2018-02-01 2018-08-17 北京欧美中科学技术研究院 A kind of pitch modified form material with anti-freezing cold-resistant function

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774592A (en) * 2015-04-10 2015-07-15 常州履信新材料科技有限公司 Slow-release antifreezing material for asphalt pavements and preparation method thereof
CN105384393A (en) * 2015-11-30 2016-03-09 盖波 Freeze-resisting asphalt mixture and preparation method thereof
CN105623607A (en) * 2016-02-26 2016-06-01 盖波 Snow melting slip proofing agent and preparing method thereof
CN105838326A (en) * 2016-04-28 2016-08-10 北京联合大学 Ecological rehabilitation promoting snow-melting agent and preparation method thereof
CN107603563A (en) * 2017-09-29 2018-01-19 徐州得铸生物科技有限公司 A kind of new municipal administration environment protection snow-dissolved agent
CN108410189A (en) * 2018-02-01 2018-08-17 北京欧美中科学技术研究院 A kind of pitch modified form material with anti-freezing cold-resistant function

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
邹艳琴等: "《道路建筑材料》", 31 August 2008, 西北大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111675506A (en) * 2020-05-29 2020-09-18 山东高速集团有限公司创新研究中心 Anti-freezing agent and preparation method thereof
CN111675506B (en) * 2020-05-29 2022-07-29 山东高速集团有限公司创新研究中心 Anti-freezing agent and preparation method thereof

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Application publication date: 20181127