CN108889575A - A kind of alternate surface construction method of Metal Substrate hydrophobe striped - Google Patents
A kind of alternate surface construction method of Metal Substrate hydrophobe striped Download PDFInfo
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- CN108889575A CN108889575A CN201810741540.3A CN201810741540A CN108889575A CN 108889575 A CN108889575 A CN 108889575A CN 201810741540 A CN201810741540 A CN 201810741540A CN 108889575 A CN108889575 A CN 108889575A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/002—Pretreatement
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/32—Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/007—After-treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
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- Other Surface Treatments For Metallic Materials (AREA)
Abstract
The invention discloses belong to non-silicon micromachined surface construction method alternate with a kind of Metal Substrate hydrophobe striped of micro-nano functional material preparation technical field.This method winds around wire in substrate, and sintering forms one under weight pressure, after gained sintered body immerses hydrophobic nanoparticles suspension, hydrophobic nanoparticles are deposited on the region without wire covering in substrate, and super-hydrophobic striped is formed after high temperature post bake；Wire is peeled off from the substrate, the region exposed forms hydrophilic striped；The alternate striated surface spacing of Metal Substrate hydrophobe striped of building, width can pass through wire diameter, the regulation of weight pressure size respectively, and method is simple, easy to operate, has broad application prospects.
Description
Technical field
The invention belongs to non-silicon micromachined and micro-nano functional material preparation technical field, in particular to a kind of Metal Substrate is close and distant
The alternate surface construction method of water bar line.
Background technique
Surface present in nature based on uniform wellability surface, such as：Super-hydrophobic purple leaf Lu Li grass surface with
And super-hydrophobic lotus leaf surface etc.；Part of the surface then shows the alternate binary imbibition characteristic of hydrophobe, to realize specific function,
Such as：Bajiao banana leaf surface just constitutes quick collection and disengaging, it can be achieved that liquid by hydrophobe striped is alternate.Bionical close and distant water bar
The also gradually concern by fields such as cellular biochemical detection, fuel cell water management, condensation heat transfer reinforcings of the alternate surface of line.Only
2017, the Natural Science Fund In The Light established project about hydrophobe surface condensation heat transfer research in 2018 is as high as 6.Therefore, close
Hydrophobic alternate surface construction method also becomes the key technology that these fields attract attention.Currently, the alternate surface of hydrophobe striped
Construction method is often processed by MEMS, is suitable for the nonmetallic surfaces such as glass, monocrystalline silicon, PDMS, and frequently with laser, plasma
The advanced equipments of high grade and precision such as body, synchrotron radiation, processing cost is expensive, is suitable only for laboratory and develops on a small scale.And it is realized in Metal Substrate
Structural parameters are controllable, it is cheap, can the construction method on the compound alternate surface of hydrophobe striped of large-scale application, micro-nano then extremely have
Limit.
Summary of the invention
The purpose of the present invention is to provide a kind of alternate surface construction method of Metal Substrate hydrophobe striped, specific technical solutions
It is as follows：
A kind of alternate surface construction method of Metal Substrate hydrophobe striped includes the following steps：
(1) substrate is guaranteed into surfacing through sanding and polishing, wire, substrate pass sequentially through acetone, alcohol, deionization
Water cleaning, is dried with nitrogen spare, to degrease and oxide, guarantees surface cleaning；Wire one end is welded in substrate,
Wire is wound around in substrate in the same direction；
(2) substrate for being wound with wire is melted into temperature in wire material, substrate material under weight action of compressive stress
Degree and sintering 2-4 hours in softening temperature overlapping interval, restore to room temperature after annealing, obtain the sintered body of wire and substrate；
(3) sintered body obtained by step (2) is immersed into hydrophobic nanoparticles suspension, hydrophobic nanoparticles deposit in substrate
The region not covered by wire, and keep hydrophobic nanoparticles fixed by high temperature post bake, form super-hydrophobic striped；It is wherein hydrophobic
Hydrophobic nanoparticles are polytetrafluorethylenano nano particle, perfluor nanometer silane particle or polyurethane nano in nano particle suspension
Particle, solvent is volatile organic solvent such as ethyl alcohol, convenient for rapid evaporation after nanoparticle deposition；The temperature of high temperature post bake is thin
Water nano particle fusing point
60%~80%；
(4) wire is peeled off from the substrate, exposes the region of wire covering, forms hydrophilic striped；Hydrophilic striped
With super-hydrophobic striped interphase distribution, it is built into the alternate surface of Metal Substrate hydrophobe striped.
To separate from substrate convenient for wire, selected wire, substrate material are not exactly the same, and wire is proof gold
Belong to, substrate is the alloy containing corresponding metal；Wire is alloy, and substrate is the corresponding pure metal of component any one in alloy；Gold
Category silk should have overlapping with the melt temperature of substrate material with softening temperature section.
Preferably, pure metal material is copper, aluminium, iron or titanium, and corresponding alloy material is tin bronze, almag, stainless
Steel or Ti-Ni alloy.
Beneficial effects of the present invention are：
(1) present invention is selected using cheap wire as mask plate in conjunction with high temperature sintering technique and hydrophobic nanoparticles
The alternate surface of Metal Substrate hydrophobe striped of selecting property sedimentation process preparation, surface texture parameters include fringe spacing, width of fringe,
Microscopic appearance, thickness, roughness and contact angle of super-hydrophobic striped etc. are controllable；
(2) present invention is using nanoparticle deposition and fixation is formed on the substrate super-hydrophobic striped, this no chemical reaction,
Only by gravity sedimentation, the Physical Processing mode of intermolecular force fixation, so that super-hydrophobic striped choice of material is not by substrate material
The influence of matter, construction method of the present invention is to substrate material also without particular/special requirement；
(3) from mathematical topologies, hydrophilic region and super-hydrophobic region on close and distant water surface prepared by the present invention
All it is non-interconnected, in practical application, this characteristic is different in the presence of essence from the super-hydrophobic region of connection, is such as applied to strengthen
When surface condensation conducts heat, it will be super thin using hydrophilic striped that non-interconnected hydrophilic region and super-hydrophobic region, which are by surface energy differential,
On water bar line condensing droplet pull into thin liquid film realize it is heat conduction reinforced；
(4) construction method provided by the invention has expanded non-silicon micro-processing method, not only structural parameters it is controllable and cheap, can
Large scale preparation helps to promote the alternate surface of hydrophobe striped in fields such as fuel cell water management, condensation heat transfer reinforcings
Practical application.
Detailed description of the invention
Fig. 1-a is that wire winds substrate schematic diagram；
Fig. 1-b is A-A sectional view in Fig. 1-a；
Fig. 2 is to be sintered schematic diagram after wire winds substrate；
Fig. 3 is schematic diagram in the substrate immersion hydrophobic nanoparticles suspension for be wound with wire；
Fig. 4-a is the stripping metal silk schematic diagram from the substrate for be deposited with hydrophobic nanoparticles；
Fig. 4-b is B-B sectional view in Fig. 4-a；
Fig. 5 is C portion partial enlarged view in Fig. 4-b；
Fig. 6 is the microstructure SEM image on the alternate surface of hydrophobe striped of building；
Label declaration：1- wire, 2- substrate, 3- sintering furnace, 4- graphite plate, 5- weight, 6- extraction valve, 7- nitrogen valve,
8- hydrophobic nanoparticles suspension, 9- hydrophobic nanoparticles, the super-hydrophobic striped of 10-, the hydrophilic striped of 11-, 12- hydrophobe striped phase
Between surface, the gap 13-.
Specific embodiment
The present invention provides a kind of alternate surface construction methods of Metal Substrate hydrophobe striped, With reference to embodiment
The present invention is described further.
Fig. 1-Fig. 4 is the alternate surface construction method process flow chart of Metal Substrate hydrophobe striped, is included the following steps：
(1) substrate 2 is guaranteed into surfacing through sanding and polishing, wire 1, substrate 2 pass sequentially through acetone, alcohol, go
Ionized water cleaning, is dried with nitrogen spare, to degrease and oxide, guarantees surface cleaning；1 one end of wire is welded on base
On bottom 2, wire 1 is wound around in substrate 2 in the same direction, specifically as shown in Fig. 1-a, Fig. 1-b is that A-A is section
Figure.
(2) substrate 2 for being wound with wire 1 is placed in sintering furnace 3, on wire 1 top surface be sequentially placed graphite plate 4,
Weight 5 is first turned on extraction valve 6 for burner hearth and is evacuated to vacuum state after sintering furnace 3 is closed, then open nitrogen valve 7 and be filled with nitrogen
As protective gas, sintering furnace 3 is warming up to the melt temperature and softening temperature overlapping interval of 1 two kinds of materials of substrate 2 and wire
Interior a certain sintering temperature, and held for some time, and after annealing, are restored to room temperature, i.e. substrate 2 and wire 1 is sintered to one
A entirety, it is specific as shown in Figure 2；Wire 1 winds and is sintered behind 2 surface of substrate, and wire 1 contacts hair by line with substrate 2
Exhibition is striped covering and welding with one fixed width.
Wherein, using density, big, stable structure metal material, the effect of graphite plate 4 are isolating metal silk 1 to weight 5
With weight 5, both to prevent the adhesion under high temperature sintering；Nitrogen is filled with for preventing substrate 2 and wire 1 during the sintering process
It aoxidizes.
(3) step (2) resulting part is immersed in hydrophobic nanoparticles suspension 8, nano particle suspension 8 passes through two
The gap 13 that wire 1 and substrate 2 are formed is penetrated into and arrives at 2 surface of substrate (Fig. 5), and hydrophobic nanoparticles 9 are covered wire 1
Under film and gravity, the region not covered by wire 1 on 2 surface of substrate is deposited to, and local melting by high temperature post bake,
It anchors in substrate 2, forms the super-hydrophobic striped 10 with certain nanometer coarse structure；It is specific as shown in Figure 3；
Wherein, super-hydrophobic striped 10 is made of hydrophobic nanoparticles 9, and the microscopic appearance of super-hydrophobic striped includes contact angle etc.
It can include spherical, ellipsoid, dendritic, polyhedron by the shape of hydrophobic nanoparticles, hydrophobic nanoparticles partial size etc. regulates and controls, slightly
Rugosity can be regulated and controled by hydrophobic nanoparticles turbid liquid concentration, and thickness is regulated and controled by sedimentation time.
(4) wire 1 to be removed from substrate 2, the region that the wire 1 exposed covers forms hydrophilic striped 11, with
Super-hydrophobic 10 interphase distribution of striped is built into the alternate surface 12 of Metal Substrate hydrophobe striped；Specifically as depicted in fig. 4-a, Fig. 4-b is
B-B is sectional view；Fig. 5 is C portion partial enlarged view in Fig. 4-b.
Wherein, the fringe spacing on the alternate surface 12 of diameter control Metal Substrate hydrophobe striped of wire 1, the pressure of weight 5 are answered
Power controls the width of fringe of hydrophilic striped 11 on the alternate surface 12 of Metal Substrate hydrophobe striped.
Fig. 6 is the microstructure SEM image on the alternate surface of hydrophobe striped constructed by the above method, due to wire
The non-depositing hydrophobic nano particle 9 in region of 1 covering, therefore hydrophilic striped on the alternate surface 12 of hydrophobe striped shown in Fig. 6 (a)
11 Facing materials are identical as 2 material of substrate, and super-hydrophobic striped 10 is then due to depositing and being fixed with the dewatering nano of hydrophobic material
Grain 9 and have certain roughness；Shown in hydrophilic 11 microstructure of striped such as Fig. 6 (b), as can be seen from the figure degree of roughness is not
Greatly；Shown in super-hydrophobic 10 microstructure of striped such as Fig. 6 (c), particle is hydrophobic nanoparticles 9 in Fig. 6 (c).
Embodiment 1
Substrate uses almag, and wire uses fine aluminium, by 50mm*50mm square, the almag table of thickness 10mm
Face is polished, is polished, and then degreases together with 100 μm of diameter of fine aluminium silk and oxide：Successively with acetone, alcohol,
Deionized water cleaning, is dried with nitrogen rear spare.
Clean aluminium wire is tightly wound around in the clean almag substrate of polishing, and is put into atmosphere sintering furnace.?
The stainless steel ingot weight that 5kg is placed on compact arranged aluminium wire applies compression, by graphite plate between aluminium wire and stainless steel ingot weight
Isolation is to prevent the two adhesion under high temperature sintering.Burner hearth is filled with 40kPa nitrogen after vacuumizing, be warming up to 550 DEG C, heat preservation 4h is simultaneously
Room temperature is cooled to by tap water.
Aluminium wire is integrally formed after high temperature sintering with almag substrate, is immersed into using ethyl alcohol as solvent, quality
In the polytetrafluorethylenano nano particle suspension liquid of score 50%, polytetrafluorethylenano nano grain diameter 800nm, nanoparticle deposition
It takes out, is then put into 125 DEG C of baking oven after 5min, taken out after post bake 2h.During being somebody's turn to do, polytetrafluorethylenano nano particle passes through
Almag substrate surface is arrived at and is deposited in gap between aluminium wire, forms super-hydrophobic striped, 5 μm of super-hydrophobic striation thickness, table
152 ° of face contact angle.
Sintering makes almag substrate closely be combined into one with aluminium wire, and the basal region under aluminium wire covering avoids
The deposition and fixation of polytetrafluorethylenano nano particle.Therefore, the item after aluminium wire is separated from almag substrate, under aluminium wire covering
Hydrophily is still presented in line shape basal region, that is, forms hydrophilic striped.15 ° of hydrophilic striated surface contact angle；It is received by polytetrafluoroethylene (PTFE)
The super-hydrophobic striped and the hydrophilic striped of almag micron interphase distribution in substrate that rice grain deposition generates, finally construct parent
The alternate surface of hydrophobic striped.The fringe spacing on the alternate surface of hydrophobe striped is 100 μm, 40 μm of the width of hydrophilic striped.
Claims (7)
1. a kind of alternate surface construction method of Metal Substrate hydrophobe striped, which is characterized in that the described method comprises the following steps：
(1) wire is wound around in substrate, and be sintered into one；
(2) sintered body obtained by step (1) is immersed into hydrophobic nanoparticles suspension, hydrophobic nanoparticles be deposited in substrate not by
The region of wire covering, and it is fixed through high temperature post bake；
(3) wire is separated from substrate and obtains the alternate surface of Metal Substrate hydrophobe striped；
The wire is pure metal, and substrate is the alloy containing corresponding metal；Wire is alloy, and substrate is any one in alloy
The corresponding pure metal of component.
2. the method according to claim 1, wherein wire, substrate pretreatment are sanding and polishing, cleaning.
3. the method according to claim 1, wherein the wire, the melt temperature of substrate material and softening
Temperature range overlapping.
4. corresponding to metal the method according to claim 1, wherein the pure metal is copper, aluminium, iron or titanium
Alloy is tin bronze, almag, stainless steel or Ti-Ni alloy.
5. the method according to claim 1, wherein being wound with the substrate of wire in the step (1) in weight
Under object action of compressive stress, in being sintered 2-4 hours in wire material, substrate material melt temperature and softening temperature overlapping interval.
6. the method according to claim 1, wherein hydrophobic in the step (2) hydrophobic nanoparticles suspension
Nano particle is polytetrafluorethylenano nano particle, perfluor nanometer silane particle or polyurethane nano particle, and solvent has to be volatile
Solvent.
7. the method according to claim 1, wherein the temperature of the step (2) high temperature post bake is dewatering nano
The 60%~80% of particle fusing point.
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| CN201810741540.3A CN108889575B (en) | 2018-07-06 | 2018-07-06 | Metal-based hydrophilic and hydrophobic stripe alternate surface construction method |
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| CN201810741540.3A CN108889575B (en) | 2018-07-06 | 2018-07-06 | Metal-based hydrophilic and hydrophobic stripe alternate surface construction method |
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| CN108889575B CN108889575B (en) | 2021-02-02 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114133612A (en) * | 2021-11-25 | 2022-03-04 | 河南大学 | Bionic super-spreading surface and preparation method thereof |
| CN114769848A (en) * | 2022-03-01 | 2022-07-22 | 山东大学 | Processing method and application of striped hydrophilic-hydrophobic heterogeneous surface |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046152A (en) * | 2014-06-23 | 2014-09-17 | 清华大学 | Superhydrophobic paint, superhydrophobic coating and preparation method thereof |
-
2018
- 2018-07-06 CN CN201810741540.3A patent/CN108889575B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046152A (en) * | 2014-06-23 | 2014-09-17 | 清华大学 | Superhydrophobic paint, superhydrophobic coating and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| MOHAMMAD ALWAZZAN ET AL: "Condensation on hybrid-patterned copper tubes (II): Visualization study of droplet dynamics", 《INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER》 * |
| 谢剑: "《管内及表面冷凝相分布调控实验研究》", 《管内及表面冷凝相分布调控实验研究》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114133612A (en) * | 2021-11-25 | 2022-03-04 | 河南大学 | Bionic super-spreading surface and preparation method thereof |
| CN114133612B (en) * | 2021-11-25 | 2022-12-20 | 河南大学 | Bionic super-spreading surface and preparation method thereof |
| CN114769848A (en) * | 2022-03-01 | 2022-07-22 | 山东大学 | Processing method and application of striped hydrophilic-hydrophobic heterogeneous surface |
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