CN108867148A - A kind of low basis weight decorating printing paper and preparation method thereof - Google Patents

A kind of low basis weight decorating printing paper and preparation method thereof Download PDF

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Publication number
CN108867148A
CN108867148A CN201810888745.4A CN201810888745A CN108867148A CN 108867148 A CN108867148 A CN 108867148A CN 201810888745 A CN201810888745 A CN 201810888745A CN 108867148 A CN108867148 A CN 108867148A
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China
Prior art keywords
parts
pulp
paper
basis weight
printing paper
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CN201810888745.4A
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Chinese (zh)
Inventor
秦启文
秦政
刘成华
韩绪峰
胡中理
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Zaozhuang Tianlong Paper Industry Co Ltd
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Zaozhuang Tianlong Paper Industry Co Ltd
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Priority to CN201810888745.4A priority Critical patent/CN108867148A/en
Publication of CN108867148A publication Critical patent/CN108867148A/en
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/26—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/31—Gums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/38—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing crosslinkable groups
    • D21H17/40—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing crosslinkable groups unsaturated
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/47—Condensation polymers of aldehydes or ketones
    • D21H17/49—Condensation polymers of aldehydes or ketones with compounds containing hydrogen bound to nitrogen
    • D21H17/51—Triazines, e.g. melamine
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：12-26 parts of ppta-pulp fibre, 1-7 parts of ceramic fibre, 35-60 parts of softwood pulp fiber, 0.2-0.8 parts of titanium dioxide, 2-7 parts of modified alta-mud, 4-10 parts of butyronitrile rubber cream, 2-8 parts of saponified rosin size, 1-5 parts of silicone resin, 2-7 parts of melamine resin, 4-15 parts of konjaku flour, 0.5-1.5 parts of aluminium hydroxide.The invention also discloses the preparation methods of the low basis weight decorating printing paper.There is low basis weight decorating printing paper prepared by the present invention good wear-resisting property to effectively increase the wear-resisting property of low basis weight decorating printing paper by the mutual cooperation of titanium dioxide and modified alta-mud, have a vast market foreground.

Description

A kind of low basis weight decorating printing paper and preparation method thereof
Technical field
The present invention relates to pulp technology for making paper, specifically a kind of low basis weight decorating printing paper and preparation method thereof.
Background technique
Paper is a kind of material common in people's work and life, can be divided by purposes：Package paper, printing, Industrial paper, office paper, cultural paper, paper for daily use and speciality paper.And the one kind of decorating printing paper as stationery, usually For the decoration on indoor wall, floor, furniture and ceiling, facing paper side is applied to by adhesive and carries out adhesion, Decoration, fire-retardant, heat preservation, waterproof, effect that is heat-insulated, increasing reflectance can be played.With the continuous development of society, people for The requirement of decorating printing paper is also higher and higher, and low basis weight decorating printing paper also appears in the use of people.But market at present On low basis weight decorating printing paper often wear-resisting property is poor, it is easy to there is scratch, affect whole aesthetic effect.Cause This, the problem of designing a kind of low basis weight decorating printing paper with excellent wear, become urgent need to resolve.
Summary of the invention
The purpose of the present invention is to provide a kind of low basis weight decorating printing paper and preparation method thereof, to solve above-mentioned background skill The problem of being proposed in art.
To achieve the above object, the present invention provides the following technical solutions：
A kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：12-26 parts of ppta-pulp fibre, ceramics are fine Dimension 1-7 parts, 35-60 parts of softwood pulp fiber, 0.2-0.8 parts of titanium dioxide, 2-7 parts of modified alta-mud, 4-10 parts of butyronitrile rubber cream, 2-8 parts of saponified rosin size, 1-5 parts of silicone resin, 2-7 parts of melamine resin, 4-15 parts of konjaku flour, aluminium hydroxide 0.5-1.5 Part；Wherein, the method for preparing modified bentonite be by the sulfuric acid solution that suitable concentration is added in bentonite is 2mol/L, Mechanical stirring 30-40min under conditions of 40-80 DEG C is filtered, vacuum drying, by the powder obtained after vacuum drying in nitrogen High-temperature activation is carried out under atmosphere, is ground to get the modified alta-mud.
As a further solution of the present invention：Including below according to the raw material of parts by weight：14-20 parts of ppta-pulp fibre, 3-5 parts of ceramic fibre, 40-50 parts of softwood pulp fiber, 0.4-0.6 parts of titanium dioxide, 4-6 parts of modified alta-mud, butyronitrile rubber cream 7-9 parts, 4-6 parts of saponified rosin size, 2-4 parts of silicone resin, 4-6 parts of melamine resin, 8-14 parts of konjaku flour, aluminium hydroxide 0.7-1.3 parts.
As further scheme of the invention：Including below according to the raw material of parts by weight：16 parts of ppta-pulp fibre, pottery 4 parts of porcelain fiber, 46 parts of softwood pulp fiber, 0.5 part of titanium dioxide, 5 parts of modified alta-mud, butyronitrile rubber newborn 8 parts, saponified rosin size 5 parts, 3 parts of silicone resin, 5 parts of melamine resin, 12 parts of konjaku flour, 1 part of aluminium hydroxide.
As further scheme of the invention：The titanium dioxide, modified alta-mud, konjaku flour and aluminium hydroxide grain Degree is 40-100 mesh.
As further scheme of the invention：The diameter of the ppta-pulp fibre is 15-20 μm, length 5-8mm； The diameter of the ceramic fibre is 35-50 μm, length 6-10mm；The diameter of the softwood pulp fiber is 20-35 μm, length For 20-35mm.
The preparation method of the low basis weight decorating printing paper, steps are as follows：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and the concentration that 5-10 times of volume is then added is 5% sodium dodecyl benzene sulfonate aqueous solution stirs 5-15min under the conditions of 30-40 DEG C, is then filtered to remove liquid, uses clear water It is dried in vacuo after cleaning, obtains mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree be 22-38 ° of SR, control pulping concentration be 3.3%, then jointly be sent into mud pit, be added cellulose biological enzyme with Fiber is discongested in softening, is stirred evenly, is obtained mixture B；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；The high-temperature fusion phase Between disperse 1 minute every 4 minutes progress high speed shears, dispersed by high speed shear, effectively increase the syncretizing effect of material；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns to get.
As further scheme of the invention：Step 5）In, the pulp density manufactured paper with pulp is 0.05%-0.08%, is copied Making pressure is 0.1-0.4Mpa, the quantification of 30-40g/m of body paper2；The pressure 0.2-0.4MPa of the squeezing, time 1-3min；Institute Stating low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer.
Compared with prior art, the beneficial effects of the invention are as follows：
Low basis weight decorating printing paper prepared by the present invention has good wear-resisting property, passes through titanium dioxide and modified alta-mud It cooperates, effectively increases the wear-resisting property of low basis weight decorating printing paper, meanwhile, it effectively prevents rolling up by low temperature drying The case where bent, gauffer and deliming, paper formation degree is high, has a vast market foreground.
Specific embodiment
Technical solution of the present invention is described in more detail With reference to embodiment.
Embodiment 1
A kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：12 parts of ppta-pulp fibre, ceramic fibre 1 Part, 35 parts of softwood pulp fiber, 0.2 part of titanium dioxide, 2 parts of modified alta-mud, butyronitrile rubber newborn 4 parts, 2 parts of saponified rosin size, silicon 1 part of ketone resin, 2 parts of melamine resin, 4 parts of konjaku flour, 0.5 part of aluminium hydroxide；Wherein, the preparation side of the modified alta-mud Method is that the sulfuric acid solution that the concentration of 10 times of volumes is 2mol/L, mechanical stirring under conditions of 60 DEG C will be added in bentonite 35min is filtered, vacuum drying, the powder obtained after vacuum drying is carried out under nitrogen atmosphere with 560 DEG C of temperature condition high Temperature activation, is ground to 80 mesh to get the modified alta-mud；By being modified to bentonite, it is physical to effectively increase its Can, and then be conducive to improve the wearability of low basis weight decorating printing paper；The titanium dioxide, modified alta-mud, konjaku flour and hydrogen The granularity of aluminium oxide is 80 mesh；The diameter of the ppta-pulp fibre is 16 μm, length 6mm；The ceramic fibre it is straight Diameter is 40 μm, length 8mm；The diameter of the softwood pulp fiber is 25 μm, length 25mm.
In the present embodiment, the preparation method of the low basis weight decorating printing paper, steps are as follows：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and the concentration that 6 times of volumes are then added is 5% Sodium dodecyl benzene sulfonate aqueous solution, stir 10min under the conditions of 35 DEG C, liquid be then filtered to remove, after being cleaned with clear water Vacuum drying, obtains mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree is 30 ° of SR, and controlling pulping concentration is 3.3%, is then sent into mud pit jointly, and 0.04 ‰ cellulose life is added Object enzyme discongests fiber to soften, and stirs evenly, and obtains mixture B；Pass through pulping, defibrination and the phase interworking for adding cellulose biological enzyme It closes, effectively increases beating results；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；The high-temperature fusion phase Between disperse 1 minute every 4 minutes progress high speed shears, dispersed by high speed shear, effectively increase the syncretizing effect of material；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；Wherein, the pulp density manufactured paper with pulp is 0.06%, and pressure of manufacturing paper with pulp is 0.3Mpa, the quantification of 35g/m of body paper2；The squeezing Pressure 0.3MPa, time 2min；The low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer；By low The case where temperature drying effectively prevents curling, gauffer and deliming, paper formation degree is high；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns are to get low basis weight decorating printing paper；It is logical The mutual cooperation for crossing titanium dioxide and modified alta-mud effectively increases the wear-resisting property of low basis weight decorating printing paper.
Embodiment 2
A kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：26 parts of ppta-pulp fibre, ceramic fibre 7 Part, 60 parts of softwood pulp fiber, 0.8 part of titanium dioxide, 7 parts of modified alta-mud, butyronitrile rubber newborn 10 parts, 8 parts of saponified rosin size, silicon 5 parts of ketone resin, 7 parts of melamine resin, 15 parts of konjaku flour, 1.5 parts of aluminium hydroxide；Wherein, the preparation of the modified alta-mud Method is that the sulfuric acid solution that the concentration of 10 times of volumes is 2mol/L, mechanical stirring under conditions of 60 DEG C will be added in bentonite 35min is filtered, vacuum drying, the powder obtained after vacuum drying is carried out under nitrogen atmosphere with 560 DEG C of temperature condition high Temperature activation, is ground to 80 mesh to get the modified alta-mud；By being modified to bentonite, it is physical to effectively increase its Can, and then be conducive to improve the wearability of low basis weight decorating printing paper；The titanium dioxide, modified alta-mud, konjaku flour and hydrogen The granularity of aluminium oxide is 80 mesh；The diameter of the ppta-pulp fibre is 16 μm, length 6mm；The ceramic fibre it is straight Diameter is 40 μm, length 8mm；The diameter of the softwood pulp fiber is 25 μm, length 25mm.
In the present embodiment, the preparation method of the low basis weight decorating printing paper, steps are as follows：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and the concentration that 6 times of volumes are then added is 5% Sodium dodecyl benzene sulfonate aqueous solution, stir 10min under the conditions of 35 DEG C, liquid be then filtered to remove, after being cleaned with clear water Vacuum drying, obtains mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree is 30 ° of SR, and controlling pulping concentration is 3.3%, is then sent into mud pit jointly, and 0.04 ‰ cellulose life is added Object enzyme discongests fiber to soften, and stirs evenly, and obtains mixture B；Pass through pulping, defibrination and the phase interworking for adding cellulose biological enzyme It closes, effectively increases beating results；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；The high-temperature fusion phase Between disperse 1 minute every 4 minutes progress high speed shears, dispersed by high speed shear, effectively increase the syncretizing effect of material；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；Wherein, the pulp density manufactured paper with pulp is 0.06%, and pressure of manufacturing paper with pulp is 0.3Mpa, the quantification of 35g/m of body paper2；The squeezing Pressure 0.3MPa, time 2min；The low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer；By low The case where temperature drying effectively prevents curling, gauffer and deliming, paper formation degree is high；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns are to get low basis weight decorating printing paper；It is logical The mutual cooperation for crossing titanium dioxide and modified alta-mud effectively increases the wear-resisting property of low basis weight decorating printing paper.
Embodiment 3
A kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：19 parts of ppta-pulp fibre, ceramic fibre 4 Part, 47.5 parts of softwood pulp fiber, 0.5 part of titanium dioxide, 4.5 parts of modified alta-mud, butyronitrile rubber newborn 7 parts, saponified rosin size 5 Part, 3 parts of silicone resin, 4.5 parts of melamine resin, 9.5 parts of konjaku flour, 1 part of aluminium hydroxide；Wherein, the modified alta-mud Preparation method be that the sulfuric acid solution that the concentration of 10 times of volumes is 2mol/L will be added in bentonite, it is mechanical under conditions of 60 DEG C Stir 35min, filter, vacuum drying, by the powder obtained after vacuum drying under nitrogen atmosphere with 560 DEG C of temperature condition into Row high-temperature activation is ground to 80 mesh to get the modified alta-mud；By being modified to bentonite, its object is effectively increased Rationality energy, and then be conducive to improve the wearability of low basis weight decorating printing paper；The titanium dioxide, modified alta-mud, konjaku flour Granularity with aluminium hydroxide is 80 mesh；The diameter of the ppta-pulp fibre is 16 μm, length 6mm；The ceramic fibre Diameter be 40 μm, length 8mm；The diameter of the softwood pulp fiber is 25 μm, length 25mm.
In the present embodiment, the preparation method of the low basis weight decorating printing paper, steps are as follows：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and the concentration that 6 times of volumes are then added is 5% Sodium dodecyl benzene sulfonate aqueous solution, stir 10min under the conditions of 35 DEG C, liquid be then filtered to remove, after being cleaned with clear water Vacuum drying, obtains mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree is 30 ° of SR, and controlling pulping concentration is 3.3%, is then sent into mud pit jointly, and 0.04 ‰ cellulose life is added Object enzyme discongests fiber to soften, and stirs evenly, and obtains mixture B；Pass through pulping, defibrination and the phase interworking for adding cellulose biological enzyme It closes, effectively increases beating results；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；The high-temperature fusion phase Between disperse 1 minute every 4 minutes progress high speed shears, dispersed by high speed shear, effectively increase the syncretizing effect of material；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；Wherein, the pulp density manufactured paper with pulp is 0.06%, and pressure of manufacturing paper with pulp is 0.3Mpa, the quantification of 35g/m of body paper2；The squeezing Pressure 0.3MPa, time 2min；The low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer；By low The case where temperature drying effectively prevents curling, gauffer and deliming, paper formation degree is high；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns are to get low basis weight decorating printing paper；It is logical The mutual cooperation for crossing titanium dioxide and modified alta-mud effectively increases the wear-resisting property of low basis weight decorating printing paper.
Embodiment 4
A kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：14 parts of ppta-pulp fibre, ceramic fibre 3 Part, 40 parts of softwood pulp fiber, 0.4 part of titanium dioxide, 4 parts of modified alta-mud, butyronitrile rubber newborn 7 parts, 4 parts of saponified rosin size, silicon 2 parts of ketone resin, 4 parts of melamine resin, 8 parts of konjaku flour, 0.7 part of aluminium hydroxide；Wherein, the preparation side of the modified alta-mud Method is that the sulfuric acid solution that the concentration of 10 times of volumes is 2mol/L, mechanical stirring under conditions of 60 DEG C will be added in bentonite 35min is filtered, vacuum drying, the powder obtained after vacuum drying is carried out under nitrogen atmosphere with 560 DEG C of temperature condition high Temperature activation, is ground to 80 mesh to get the modified alta-mud；By being modified to bentonite, it is physical to effectively increase its Can, and then be conducive to improve the wearability of low basis weight decorating printing paper；The titanium dioxide, modified alta-mud, konjaku flour and hydrogen The granularity of aluminium oxide is 80 mesh；The diameter of the ppta-pulp fibre is 16 μm, length 6mm；The ceramic fibre it is straight Diameter is 40 μm, length 8mm；The diameter of the softwood pulp fiber is 25 μm, length 25mm.
In the present embodiment, the preparation method of the low basis weight decorating printing paper, steps are as follows：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and the concentration that 6 times of volumes are then added is 5% Sodium dodecyl benzene sulfonate aqueous solution, stir 10min under the conditions of 35 DEG C, liquid be then filtered to remove, after being cleaned with clear water Vacuum drying, obtains mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree is 30 ° of SR, and controlling pulping concentration is 3.3%, is then sent into mud pit jointly, and 0.04 ‰ cellulose life is added Object enzyme discongests fiber to soften, and stirs evenly, and obtains mixture B；Pass through pulping, defibrination and the phase interworking for adding cellulose biological enzyme It closes, effectively increases beating results；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；The high-temperature fusion phase Between disperse 1 minute every 4 minutes progress high speed shears, dispersed by high speed shear, effectively increase the syncretizing effect of material；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；Wherein, the pulp density manufactured paper with pulp is 0.06%, and pressure of manufacturing paper with pulp is 0.3Mpa, the quantification of 35g/m of body paper2；The squeezing Pressure 0.3MPa, time 2min；The low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer；By low The case where temperature drying effectively prevents curling, gauffer and deliming, paper formation degree is high；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns are to get low basis weight decorating printing paper；It is logical The mutual cooperation for crossing titanium dioxide and modified alta-mud effectively increases the wear-resisting property of low basis weight decorating printing paper.
Embodiment 5
A kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：20 parts of ppta-pulp fibre, ceramic fibre 5 Part, 50 parts of softwood pulp fiber, 0.6 part of titanium dioxide, 6 parts of modified alta-mud, butyronitrile rubber newborn 9 parts, 6 parts of saponified rosin size, silicon 4 parts of ketone resin, 6 parts of melamine resin, 14 parts of konjaku flour, 1.3 parts of aluminium hydroxide；Wherein, the preparation of the modified alta-mud Method is that the sulfuric acid solution that the concentration of 10 times of volumes is 2mol/L, mechanical stirring under conditions of 60 DEG C will be added in bentonite 35min is filtered, vacuum drying, the powder obtained after vacuum drying is carried out under nitrogen atmosphere with 560 DEG C of temperature condition high Temperature activation, is ground to 80 mesh to get the modified alta-mud；By being modified to bentonite, it is physical to effectively increase its Can, and then be conducive to improve the wearability of low basis weight decorating printing paper；The titanium dioxide, modified alta-mud, konjaku flour and hydrogen The granularity of aluminium oxide is 80 mesh；The diameter of the ppta-pulp fibre is 16 μm, length 6mm；The ceramic fibre it is straight Diameter is 40 μm, length 8mm；The diameter of the softwood pulp fiber is 25 μm, length 25mm.
In the present embodiment, the preparation method of the low basis weight decorating printing paper, steps are as follows：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and the concentration that 6 times of volumes are then added is 5% Sodium dodecyl benzene sulfonate aqueous solution, stir 10min under the conditions of 35 DEG C, liquid be then filtered to remove, after being cleaned with clear water Vacuum drying, obtains mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree is 30 ° of SR, and controlling pulping concentration is 3.3%, is then sent into mud pit jointly, and 0.04 ‰ cellulose life is added Object enzyme discongests fiber to soften, and stirs evenly, and obtains mixture B；Pass through pulping, defibrination and the phase interworking for adding cellulose biological enzyme It closes, effectively increases beating results；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；The high-temperature fusion phase Between disperse 1 minute every 4 minutes progress high speed shears, dispersed by high speed shear, effectively increase the syncretizing effect of material；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；Wherein, the pulp density manufactured paper with pulp is 0.06%, and pressure of manufacturing paper with pulp is 0.3Mpa, the quantification of 35g/m of body paper2；The squeezing Pressure 0.3MPa, time 2min；The low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer；By low The case where temperature drying effectively prevents curling, gauffer and deliming, paper formation degree is high；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns are to get low basis weight decorating printing paper；It is logical The mutual cooperation for crossing titanium dioxide and modified alta-mud effectively increases the wear-resisting property of low basis weight decorating printing paper.
Embodiment 6
A kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：17 parts of ppta-pulp fibre, ceramic fibre 4 Part, 45 parts of softwood pulp fiber, 0.5 part of titanium dioxide, 5 parts of modified alta-mud, butyronitrile rubber newborn 8 parts, 5 parts of saponified rosin size, silicon 3 parts of ketone resin, 5 parts of melamine resin, 11 parts of konjaku flour, 1 part of aluminium hydroxide；Wherein, the preparation side of the modified alta-mud Method is that the sulfuric acid solution that the concentration of 10 times of volumes is 2mol/L, mechanical stirring under conditions of 60 DEG C will be added in bentonite 35min is filtered, vacuum drying, the powder obtained after vacuum drying is carried out under nitrogen atmosphere with 560 DEG C of temperature condition high Temperature activation, is ground to 80 mesh to get the modified alta-mud；By being modified to bentonite, it is physical to effectively increase its Can, and then be conducive to improve the wearability of low basis weight decorating printing paper；The titanium dioxide, modified alta-mud, konjaku flour and hydrogen The granularity of aluminium oxide is 80 mesh；The diameter of the ppta-pulp fibre is 16 μm, length 6mm；The ceramic fibre it is straight Diameter is 40 μm, length 8mm；The diameter of the softwood pulp fiber is 25 μm, length 25mm.
In the present embodiment, the preparation method of the low basis weight decorating printing paper, steps are as follows：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and the concentration that 6 times of volumes are then added is 5% Sodium dodecyl benzene sulfonate aqueous solution, stir 10min under the conditions of 35 DEG C, liquid be then filtered to remove, after being cleaned with clear water Vacuum drying, obtains mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree is 30 ° of SR, and controlling pulping concentration is 3.3%, is then sent into mud pit jointly, and 0.04 ‰ cellulose life is added Object enzyme discongests fiber to soften, and stirs evenly, and obtains mixture B；Pass through pulping, defibrination and the phase interworking for adding cellulose biological enzyme It closes, effectively increases beating results；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；The high-temperature fusion phase Between disperse 1 minute every 4 minutes progress high speed shears, dispersed by high speed shear, effectively increase the syncretizing effect of material；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；Wherein, the pulp density manufactured paper with pulp is 0.06%, and pressure of manufacturing paper with pulp is 0.3Mpa, the quantification of 35g/m of body paper2；The squeezing Pressure 0.3MPa, time 2min；The low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer；By low The case where temperature drying effectively prevents curling, gauffer and deliming, paper formation degree is high；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns are to get low basis weight decorating printing paper；It is logical The mutual cooperation for crossing titanium dioxide and modified alta-mud effectively increases the wear-resisting property of low basis weight decorating printing paper.
Embodiment 7
A kind of low basis weight decorating printing paper, including below according to the raw material of parts by weight：16 parts of ppta-pulp fibre, ceramic fibre 4 Part, 46 parts of softwood pulp fiber, 0.5 part of titanium dioxide, 5 parts of modified alta-mud, butyronitrile rubber newborn 8 parts, 5 parts of saponified rosin size, silicon 3 parts of ketone resin, 5 parts of melamine resin, 12 parts of konjaku flour, 1 part of aluminium hydroxide；Wherein, the preparation side of the modified alta-mud Method is that the sulfuric acid solution that the concentration of 10 times of volumes is 2mol/L, mechanical stirring under conditions of 60 DEG C will be added in bentonite 35min is filtered, vacuum drying, the powder obtained after vacuum drying is carried out under nitrogen atmosphere with 560 DEG C of temperature condition high Temperature activation, is ground to 80 mesh to get the modified alta-mud；By being modified to bentonite, it is physical to effectively increase its Can, and then be conducive to improve the wearability of low basis weight decorating printing paper；The titanium dioxide, modified alta-mud, konjaku flour and hydrogen The granularity of aluminium oxide is 80 mesh；The diameter of the ppta-pulp fibre is 16 μm, length 6mm；The ceramic fibre it is straight Diameter is 40 μm, length 8mm；The diameter of the softwood pulp fiber is 25 μm, length 25mm.
In the present embodiment, the preparation method of the low basis weight decorating printing paper, steps are as follows：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and the concentration that 6 times of volumes are then added is 5% Sodium dodecyl benzene sulfonate aqueous solution, stir 10min under the conditions of 35 DEG C, liquid be then filtered to remove, after being cleaned with clear water Vacuum drying, obtains mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree is 30 ° of SR, and controlling pulping concentration is 3.3%, is then sent into mud pit jointly, and 0.04 ‰ cellulose life is added Object enzyme discongests fiber to soften, and stirs evenly, and obtains mixture B；Pass through pulping, defibrination and the phase interworking for adding cellulose biological enzyme It closes, effectively increases beating results；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；The high-temperature fusion phase Between disperse 1 minute every 4 minutes progress high speed shears, dispersed by high speed shear, effectively increase the syncretizing effect of material；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；Wherein, the pulp density manufactured paper with pulp is 0.06%, and pressure of manufacturing paper with pulp is 0.3Mpa, the quantification of 35g/m of body paper2；The squeezing Pressure 0.3MPa, time 2min；The low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer；By low The case where temperature drying effectively prevents curling, gauffer and deliming, paper formation degree is high；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns are to get low basis weight decorating printing paper；It is logical The mutual cooperation for crossing titanium dioxide and modified alta-mud effectively increases the wear-resisting property of low basis weight decorating printing paper.
Low basis weight decorating printing paper prepared by the present invention has good wear-resisting property, passes through titanium dioxide and bentone The mutual cooperation of soil, effectively increases the wear-resisting property of low basis weight decorating printing paper, meanwhile, it is effectively prevented by low temperature drying The case where curling, gauffer and deliming, paper formation degree is high, has a vast market foreground.
Better embodiment of the invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party Formula within the knowledge of one of ordinary skill in the art can also be without departing from the purpose of the present invention Various changes can be made.There is no necessity and possibility to exhaust all the enbodiments.And it thus amplifies out apparent Variation or variation be still in the protection scope of this invention.

Claims (9)

1. a kind of low basis weight decorating printing paper, which is characterized in that including below according to the raw material of parts by weight：Ppta-pulp fibre 12-26 parts, 1-7 parts of ceramic fibre, 35-60 parts of softwood pulp fiber, 0.2-0.8 parts of titanium dioxide, 2-7 parts of modified alta-mud, 4-10 parts of butyronitrile rubber cream, 2-8 parts of saponified rosin size, 1-5 parts of silicone resin, 2-7 parts of melamine resin, 4-15 parts of konjaku flour, 0.5-1.5 parts of aluminium hydroxide；Wherein, the method for preparing modified bentonite is molten suitable sulfuric acid will to be added in bentonite Liquid, mechanical stirring 30-40min under conditions of 40-80 DEG C are filtered, vacuum drying, by the powder obtained after vacuum drying in nitrogen Atmosphere encloses lower carry out high-temperature activation, grinds to get the modified alta-mud.
2. low basis weight decorating printing paper according to claim 1, which is characterized in that including below according to the original of parts by weight Material：14-20 parts of ppta-pulp fibre, 40-50 parts of softwood pulp fiber, 0.4-0.6 parts of titanium dioxide, changes 3-5 parts of ceramic fibre 4-6 parts of bentonite of property, 7-9 parts of butyronitrile rubber cream, 4-6 parts of saponified rosin size, 2-4 parts of silicone resin, 4-6 parts of melamine resin, 8-14 parts of konjaku flour, 0.7-1.3 parts of aluminium hydroxide.
3. low basis weight decorating printing paper according to claim 2, which is characterized in that including below according to the original of parts by weight Material：16 parts of ppta-pulp fibre, 4 parts of ceramic fibre, 46 parts of softwood pulp fiber, 0.5 part of titanium dioxide, 5 parts of modified alta-mud, Butyronitrile rubber cream 8 parts, 5 parts of saponified rosin size, 3 parts of silicone resin, 5 parts of melamine resin, 12 parts of konjaku flour, 1 part of aluminium hydroxide.
4. low basis weight decorating printing paper according to claim 1 or 2 or 3, which is characterized in that the titanium dioxide, modification The granularity of bentonite, konjaku flour and aluminium hydroxide is 40-100 mesh.
5. low basis weight decorating printing paper according to claim 4, which is characterized in that the diameter of the ppta-pulp fibre is 15-20 μm, length 5-8mm；The diameter of the ceramic fibre is 35-50 μm, length 6-10mm；The softwood pulp fiber Diameter be 20-35 μm, length 20-35mm.
6. a kind of preparation method of low basis weight decorating printing paper a method as claimed in any one of claims 1 to 5, which is characterized in that step is such as Under：
1）Ceramic fibre is weighed according to parts by weight and ppta-pulp fibre is uniformly mixed, and neopelex water is then added Solution stirs 5-15min, is then filtered to remove liquid, is dried in vacuo after being cleaned with clear water, obtain mixture A；
2）Weigh softwood pulp fiber and step 1）Obtained in mixture A, carried out at pulping and defibrination in pulper respectively Reason to beating degree is 22-38 ° of SR, and control pulping concentration is 3.3%, is then sent into mud pit jointly, cellulose biological enzyme is added, It stirs evenly, obtains mixture B；
3）By step 2）Obtained in titanium dioxide, konjaku flour and butyronitrile rubber cream are added in mixture B, be stirred dispersion, shape It is spare at the uniform paper pulp C of material dispersion；
4）Saponified rosin size, silicone resin, melamine resin, modified alta-mud and aluminium hydroxide are weighed according to parts by weight, into Row mechanical stirring is uniform, is then sent into boiler jointly and carries out high-temperature fusion 30 minutes, obtains glue D, spare；
5）By step 3）Obtained in paper pulp C be sent into paper machine and manufacture paper with pulp, then by press dewatering and low temperature drying, obtain former Paper E；
6）Glue D made from step 4) is coated on step 5）Obtained in body paper E two sides, then by hot press 52 DEG C, carry out hot pressing under 17MPa, then rolled by nipper, then printed patterns to get.
7. the preparation method of low basis weight decorating printing paper according to claim 6, which is characterized in that step 5）In, it is described The pulp density manufactured paper with pulp is 0.05%-0.08%, and pressure of manufacturing paper with pulp is 0.1-0.4Mpa, the quantification of 30-40g/m of body paper2。
8. the preparation method of low basis weight decorating printing paper according to claim 7, which is characterized in that step 5）In, it is described The pressure 0.2-0.4MPa of squeezing, time 1-3min.
9. the preparation method of low basis weight decorating printing paper according to claim 8, which is characterized in that step 5）In, it is described Low temperature drying is that low temperature drying is carried out at 30 DEG C by low temp dryer.
CN201810888745.4A 2018-08-07 2018-08-07 A kind of low basis weight decorating printing paper and preparation method thereof Pending CN108867148A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110273323A (en) * 2019-06-19 2019-09-24 浙江夏王纸业有限公司 A kind of p-aramid fiber enhancing flame-proof abrasion-resistant type decorating base paper and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN101805589A (en) * 2010-02-09 2010-08-18 陕西科技大学 Raw paper of high-performance environment-friendly paper based friction material and manufacturing method of friction plate
CN101817535A (en) * 2009-05-25 2010-09-01 甘肃银光聚银化工有限公司 Method for preparing modified bentonite
CN102878232A (en) * 2012-09-29 2013-01-16 杭州克尔菲利科技有限公司 Ceramic-fiber-paper-based friction plate and production method thereof
CN106368070A (en) * 2016-11-14 2017-02-01 张日龙 Light basis weight decoration printing paper and preparation method thereof
CN108014753A (en) * 2017-11-02 2018-05-11 铜陵博锋实业有限公司 A kind of preparation method of porous modified alta-mud granule adsorbent

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Publication number Priority date Publication date Assignee Title
CN101817535A (en) * 2009-05-25 2010-09-01 甘肃银光聚银化工有限公司 Method for preparing modified bentonite
CN101805589A (en) * 2010-02-09 2010-08-18 陕西科技大学 Raw paper of high-performance environment-friendly paper based friction material and manufacturing method of friction plate
CN102878232A (en) * 2012-09-29 2013-01-16 杭州克尔菲利科技有限公司 Ceramic-fiber-paper-based friction plate and production method thereof
CN106368070A (en) * 2016-11-14 2017-02-01 张日龙 Light basis weight decoration printing paper and preparation method thereof
CN108014753A (en) * 2017-11-02 2018-05-11 铜陵博锋实业有限公司 A kind of preparation method of porous modified alta-mud granule adsorbent

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110273323A (en) * 2019-06-19 2019-09-24 浙江夏王纸业有限公司 A kind of p-aramid fiber enhancing flame-proof abrasion-resistant type decorating base paper and preparation method thereof

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Application publication date: 20181123