CN108865476A - A kind of sapphire dewaxing cleaning agent and preparation method thereof - Google Patents
A kind of sapphire dewaxing cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN108865476A CN108865476A CN201810940819.4A CN201810940819A CN108865476A CN 108865476 A CN108865476 A CN 108865476A CN 201810940819 A CN201810940819 A CN 201810940819A CN 108865476 A CN108865476 A CN 108865476A
- Authority
- CN
- China
- Prior art keywords
- agent
- sapphire
- cleaning agent
- sodium
- dewaxing cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229910052594 sapphire Inorganic materials 0.000 title claims abstract description 48
- 239000010980 sapphire Substances 0.000 title claims abstract description 47
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 12
- 230000007797 corrosion Effects 0.000 claims abstract description 10
- 238000005260 corrosion Methods 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 10
- 150000007529 inorganic bases Chemical class 0.000 claims abstract description 10
- 230000000740 bleeding effect Effects 0.000 claims abstract description 9
- 239000008139 complexing agent Substances 0.000 claims abstract description 9
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- 150000007530 organic bases Chemical class 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims description 10
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- -1 Polysiloxanes Polymers 0.000 claims description 5
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000000176 sodium gluconate Substances 0.000 claims description 4
- 235000012207 sodium gluconate Nutrition 0.000 claims description 4
- 229940005574 sodium gluconate Drugs 0.000 claims description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 4
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 229920006243 acrylic copolymer Polymers 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 229960001484 edetic acid Drugs 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 230000000149 penetrating effect Effects 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 claims description 2
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 claims description 2
- CEGDSRUGKSIHHO-UHFFFAOYSA-N 1,2-diaminoethane-1,1,2,2-tetrol Chemical compound NC(O)(O)C(N)(O)O CEGDSRUGKSIHHO-UHFFFAOYSA-N 0.000 claims 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 229940031098 ethanolamine Drugs 0.000 claims 1
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 claims 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims 1
- 229910001948 sodium oxide Inorganic materials 0.000 claims 1
- 239000001433 sodium tartrate Substances 0.000 claims 1
- 229960002167 sodium tartrate Drugs 0.000 claims 1
- 235000011004 sodium tartrates Nutrition 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 9
- 230000008676 import Effects 0.000 abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010437 gem Substances 0.000 description 2
- 229910001751 gemstone Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C11D2111/14—
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- C11D2111/44—
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- C11D2111/46—
Abstract
The present invention provides a kind of sapphire dewaxing cleaning agents, are made of following raw material by mass percentage：2~10wt% of inorganic base, 3~6wt% of organic base, 2~6wt% of complexing agent, 3~5wt% of corrosion inhibiter, 8~10wt% of nonionic surfactant, 3~5wt% of bleeding agent, 2~4wt% of dispersing agent, 0.2~0.8wt% of defoaming agent, surplus are water.Sapphire dewaxing cleaning agent of the invention quickly can thoroughly remove wax, and sapphire surface dirt residual is few, and service life is long, environment friendly and pollution-free, and application method is simple, can replace import dewaxing cleaning agent, be saved greatly cost.
Description
Technical field
The invention belongs to sapphire material manufacture field, in particular to a kind of sapphire dewaxing cleaning agent and its preparation side
Method.
Background technique
Sapphire group becomes aluminium oxide (α-Al2O3), it is by three oxygen atoms and two aluminium atoms with covalent bond pattern knot
It closes, crystal structure is hexagonal lattice structure.It is infrared in from black light since to penetrate band very wide for sapphire optics
Line all has good translucency, in addition also has the characteristics that the high velocity of sound, high temperature resistant, anticorrosive, high rigidity, fusing point are high, therefore
It is widely applied in the optical elements such as infrared facility, high-intensitive radium-shine eyeglass, photomask materials and various electronic instrument accessories.
Its surface can adhere to waxing and is processed by shot blasting with being fixed on polishing disk in sapphire polishing processing, polish
After its surface must be cleaned, the bur on surface is cleaned up, otherwise will affect sapphire subsequent applications performance.
The cleaning agent for carrying out wax cleaning to sapphire at present mainly has solvent type, half aqua type and three kinds of aqueous cleaning agent.Wherein, preceding
Two class waste liquor contamination environment are serious and are harmful to the human body, therefore handle difficult and at high cost；And most of at present water base go wax clear
Lotion, there are cleanings to be not thorough, has the problems such as organic matter or Baiban Granules object remain, and relies on import substantially, therefore cost
It is high.
Summary of the invention
In view of the above drawbacks of the prior art, the purpose of the present invention is to provide one kind go wax thoroughly, without hickie residual,
At low cost, environment-friendly type water base dewaxing cleaning agent.
To achieve the above object, sapphire dewaxing cleaning agent of the invention is made of following raw material by mass percentage：Nothing
Machine 2~10wt% of alkali, 3~6wt% of organic base, 2~6wt% of complexing agent, 3~5wt% of corrosion inhibiter, nonionic surfactant 8
~10wt%, 3~5wt% of bleeding agent, 2~4wt% of dispersing agent, 0.2~0.8wt% of defoaming agent, surplus are water.
Further, the signified inorganic base of the present invention not only includes containing inorganic base hydroxy, and further including after hydrolyzing is in
The inorganic salts of alkalinity.Inorganic base is selected from one of potassium hydroxide, sodium hydroxide, sodium carbonate, sodium bicarbonate or a variety of.Wherein,
Although sodium carbonate, sodium bicarbonate belong to after hydrolysis in alkaline inorganic salts, but be also classified as inorganic base in the present invention.
Further, organic base is in monoethanolamine, diethanol amine, triethanolamine, triethylene diamine, tetrahydroxy second two
One of amine, tetramethylammonium hydroxide are a variety of.
Further, complexing agent is selected from sodium gluconate, ethylenediamine tetra-acetic acid, the sodium salt of ethylenediamine tetra-acetic acid, tartaric acid
One of sodium, sodium nitrilo triacetate, five sodium of diethylene triamine pentacetic acid (DTPA) are a variety of.
Further, corrosion inhibiter is metasilicate pentahydrate sodium or waterglass.Corrosion inhibiter plays inhibition protection, reduces to matrix
Surface damage.
Further, nonionic surfactant is selected from heterogeneous C10~C13 fatty alcohol polyoxyethylene ether, fatty acid methyl
The condensation product of ester and ethylene oxide is one or two kinds of.Nonionic surfactant has potent emulsifiability, to wax dirt emulsifying power
Power is strong, and removal speed is fast.
Further, bleeding agent is one or two kinds of in penetrating agent JFC, fast penetrant T.Bleeding agent penetration is strong,
Be conducive to remove dirt from matrix surface, reduce surface smut residual.
Further, dispersing agent is a kind of in sodium carboxymethylcellulose, Sodium Polyacrylate, maleic acrylic copolymer
Or two kinds.Dispersing agent is conducive to wax dirt dispersing and dissolving into solution, reduces surface particles object residual.
Further, defoaming agent in organic silicon defoamer, polyether antifoam agent, Polyether Modified Polysiloxanes Defoaming Agent one
Kind.
Further, water is deionized water or pure water.
The preparation method of sapphire dewaxing cleaning agent of the invention, includes the following steps：
(1) various raw materials are weighed respectively by above-mentioned mass percent；
(2) reaction vessel is added water to, inorganic base, organic base are added, stirring is cooled to 40~50 DEG C to after being completely dissolved,
Then complexing agent and corrosion inhibiter are added again, continue stirring to forming complete clear transparent solutions；
(3) nonionic surfactant, bleeding agent, dispersing agent are successively added, clear solution is stirred to clarify, adds and disappear
Infusion stirs evenly to get sapphire dewaxing cleaning agent is arrived.
Further, above-mentioned mixing time is preferably 1~2 hour.
The application method of sapphire dewaxing cleaning agent of the invention, includes the following steps：
(1) it after sapphire dewaxing cleaning agent being diluted 20 times, is added in ultrasonic cleaner, temperature is set as 65~75
DEG C, the time is set as 300~500s, takes the sapphire sheet of sticky wax after processing to be put into and starts to clean in ultrasonic cleaner；
(2) by the sapphire sheet taking-up pure water rinsed clean after cleaning, drying.
Beneficial effects of the present invention at least show in the following areas：
(1) multiple component effects of sapphire dewaxing cleaning agent of the invention mutually cooperate with, and reach and quickly thoroughly remove wax, blue
The advantages that gemstone surface dirt residual is few, and service life is long.
(2) sapphire dewaxing cleaning agent of the invention is water base, environment friendly and pollution-free, can replace import dewaxing cleaning agent, greatly
The earth has saved cost.
(3) sapphire dewaxing cleaning agent of the invention using simple, it can be achieved that ultrasonic step cleans, spent after cleaning from
Sub- water is rinsed well, is dried.
Specific embodiment
It elaborates below to the embodiment of the present invention, following embodiments is under the premise of the technical scheme of the present invention
Implemented, the detailed implementation method and specific operation process are given, but protection scope of the present invention be not limited to it is following
Embodiment.
Embodiment 1
In a preferred embodiment, sapphire dewaxing cleaning agent of the invention is by mass percentage by following raw material group
At：Inorganic base 4wt%, organic base 3wt%, complexing agent 2wt%, corrosion inhibiter 3wt%, nonionic surfactant 8wt%, infiltration
Agent 5wt%, dispersing agent 2wt%, defoaming agent 0.4wt%, deionized water 72.6wt%.
Wherein, inorganic base is sodium hydroxide, and organic base is monoethanolamine, and complexing agent is sodium gluconate, and corrosion inhibiter is water
Glass；Nonionic surfactant is C10~C12 fatty alcohol polyoxyethylene ether of BASF, bleeding agent JFC, dispersing agent are
Sodium Polyacrylate, defoaming agent are organic silicon defoamer.
The preparation method of the sapphire dewaxing cleaning agent of the present embodiment includes the following steps：
(1) various raw materials are accurately weighed respectively by above-mentioned mass percent；
(2) reaction kettle is added in deionized water, adds sodium hydroxide, monoethanolamine, stirred 1~2 hour and extremely dissolve completely,
Be cooled to 40~50 DEG C, then add sodium gluconate and waterglass again, continue stirring 1~2 hour it is molten to complete clear
Liquid；
(3) C10~C12 fatty alcohol polyoxyethylene ether, JFC, Sodium Polyacrylate are successively added and stirs 1~2 hour to clarification
Clear solution adds organic silicon defoamer, stirs evenly to get the sapphire dewaxing cleaning agent of the present embodiment is arrived.
Embodiment 2~8
The raw material components of the sapphire dewaxing cleaning agent of embodiment 2~8 are different from embodiment 1, but preparation method and implementation
Example 1 is identical.As shown in the table, surplus is to go to the raw material components (unit wt%) of the sapphire dewaxing cleaning agent of embodiment 2~8
Ionized water or pure water.
The application method of the sapphire dewaxing cleaning agent of Examples 1 to 8 includes the following steps：
(1) it after sapphire dewaxing cleaning agent being diluted 20 times, being added in ultrasonic cleaner, temperature is set as 70 DEG C, when
Between be set as 400s, take the sapphire sheet of sticky wax after processing to be put into cleaning in ultrasonic cleaner；
(2) it by sapphire sheet taking-up pure water rinsed clean and is dried after cleaning.
Sapphire sheet after drying is observed under the microscope, and remained on surface particulate matter is detected using surface particles instrument
Number, experimental data are as follows.Comparative example is the DEVEL product of Japanese daily use chemicals Seiko, the indigo plant of application method and above-described embodiment 1~8
Jewel dewaxing cleaning agent application method is consistent.
By above data as it can be seen that using the sapphire surface after the sapphire dewaxing cleaning agent cleaning of Examples 1 to 8 without wax
Mark residual, remained on surface particulate count is 4000 hereinafter, qualification rate reaches 99% or more, significantly better than Japanese daily use chemicals essence
The DEVEL product of work.As it can be seen that sapphire dewaxing cleaning agent of the invention not only can replace imported product completely, and can take
Obtain better cleaning effect.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that the ordinary skill of this field is without wound
The property made labour, which according to the present invention can conceive, makes many modifications and variations.Therefore, all technician in the art
Pass through logic analysis, reasoning or the limited available technology of test on the basis of existing technology under this invention's idea
Scheme, all should be within the scope of protection determined by the claims.
Claims (10)
1. a kind of sapphire dewaxing cleaning agent, which is characterized in that the sapphire dewaxing cleaning agent is by mass percentage by following
Raw material composition：2~10wt% of inorganic base, 3~6wt% of organic base, 2~6wt% of complexing agent, 3~5wt% of corrosion inhibiter, nonionic
8~10wt% of surfactant, 3~5wt% of bleeding agent, 2~4wt% of dispersing agent, 0.2~0.8wt% of defoaming agent, surplus are
Water.
2. sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the inorganic base is selected from potassium hydroxide, hydrogen
One of sodium oxide molybdena, sodium carbonate, sodium bicarbonate are a variety of.
3. sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the organic base is selected from monoethanolamine, two
In ethanol amine, triethanolamine, one of triethylene diamine, THED tetrahydroxy ethylene diamine, tetramethylammonium hydroxide or a variety of.
4. sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the complexing agent be selected from sodium gluconate,
Ethylenediamine tetra-acetic acid, sodium ethylene diamine tetracetate, sodium tartrate, sodium nitrilo triacetate, one in five sodium of diethylene triamine pentacetic acid (DTPA)
Kind is a variety of.
5. sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the corrosion inhibiter be metasilicate pentahydrate sodium or
Person's waterglass.
6. sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the nonionic surfactant is selected from different
One or both of configuration C10~C13 fatty alcohol polyoxyethylene ether, fatty acid methyl ester and condensation product of ethylene oxide.
7. sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the bleeding agent is selected from penetrating agent JFC, fast
It is one or two kinds of in fast penetrant t.
8. sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the dispersing agent is selected from carboxymethyl cellulose
It is sodium, Sodium Polyacrylate, one or two kinds of in maleic acrylic copolymer.
9. sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the defoaming agent is defoamed selected from organosilicon
One of agent, polyether antifoam agent, Polyether Modified Polysiloxanes Defoaming Agent.
10. the preparation method of sapphire dewaxing cleaning agent as described in claim 1, which is characterized in that the preparation method packet
Include following steps：
(1) various raw materials are weighed respectively by the mass percent；
(2) reaction vessel is added in the water, adds the inorganic base, the organic base, stirring is cooled to after being completely dissolved
40~50 DEG C, the complexing agent and the corrosion inhibiter are then added again, continue stirring to forming complete clear transparent solutions；
(3) nonionic surfactant, the bleeding agent, the dispersing agent, stirring to formation clear are successively added
Solution adds the defoaming agent, stirs evenly to get the sapphire dewaxing cleaning agent is arrived.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110628532A (en) * | 2019-09-12 | 2019-12-31 | 江苏吉星新材料有限公司 | Sapphire cleaning agent and preparation method thereof |
| CN110777013A (en) * | 2019-11-07 | 2020-02-11 | 蓝思科技（长沙）有限公司 | Cleaning agent and preparation method and cleaning process thereof |
| CN111088119A (en) * | 2019-12-18 | 2020-05-01 | 太湖达名欣盖板制造有限公司 | Touch control type glass cleaning agent |
| CN111909797A (en) * | 2020-09-01 | 2020-11-10 | 中科孚迪科技发展有限公司 | Cleaning agent for hard and brittle material wafer |
| CN111979055A (en) * | 2020-09-01 | 2020-11-24 | 中科孚迪科技发展有限公司 | Preparation method of cleaning agent for hard and brittle material wafer |
| CN114106934A (en) * | 2021-12-01 | 2022-03-01 | 福建省佑达环保材料有限公司 | Sapphire wafer cleaning agent and preparation method thereof |
| CN115852381A (en) * | 2022-10-19 | 2023-03-28 | 广州市联诺化工科技有限公司 | High-pressure spray cleaning agent for automatic line spraying and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140902A (en) * | 2013-03-27 | 2014-11-12 | 东友精细化工有限公司 | Cleaning solution composition for sapphire wafer |
| CN104178367A (en) * | 2013-05-27 | 2014-12-03 | 天津西美半导体材料有限公司 | Dewaxing cleaning agent for sapphire substrate |
| CN106868519A (en) * | 2017-03-07 | 2017-06-20 | 马鞍山拓锐金属表面技术有限公司 | Aqua type metal cleaner and preparation method thereof |
-
2018
- 2018-08-17 CN CN201810940819.4A patent/CN108865476A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140902A (en) * | 2013-03-27 | 2014-11-12 | 东友精细化工有限公司 | Cleaning solution composition for sapphire wafer |
| CN104178367A (en) * | 2013-05-27 | 2014-12-03 | 天津西美半导体材料有限公司 | Dewaxing cleaning agent for sapphire substrate |
| CN106868519A (en) * | 2017-03-07 | 2017-06-20 | 马鞍山拓锐金属表面技术有限公司 | Aqua type metal cleaner and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110628532A (en) * | 2019-09-12 | 2019-12-31 | 江苏吉星新材料有限公司 | Sapphire cleaning agent and preparation method thereof |
| CN110777013A (en) * | 2019-11-07 | 2020-02-11 | 蓝思科技（长沙）有限公司 | Cleaning agent and preparation method and cleaning process thereof |
| CN111088119A (en) * | 2019-12-18 | 2020-05-01 | 太湖达名欣盖板制造有限公司 | Touch control type glass cleaning agent |
| CN111909797A (en) * | 2020-09-01 | 2020-11-10 | 中科孚迪科技发展有限公司 | Cleaning agent for hard and brittle material wafer |
| CN111979055A (en) * | 2020-09-01 | 2020-11-24 | 中科孚迪科技发展有限公司 | Preparation method of cleaning agent for hard and brittle material wafer |
| CN114106934A (en) * | 2021-12-01 | 2022-03-01 | 福建省佑达环保材料有限公司 | Sapphire wafer cleaning agent and preparation method thereof |
| CN114106934B (en) * | 2021-12-01 | 2023-10-31 | 福建省佑达环保材料有限公司 | Sapphire wafer cleaning agent and preparation method thereof |
| CN115852381A (en) * | 2022-10-19 | 2023-03-28 | 广州市联诺化工科技有限公司 | High-pressure spray cleaning agent for automatic line spraying and preparation method thereof |
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