CN108863263A - It is a kind of can accumulation of heat black matrix cement material and preparation method - Google Patents

It is a kind of can accumulation of heat black matrix cement material and preparation method Download PDF

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Publication number
CN108863263A
CN108863263A CN201810766961.1A CN201810766961A CN108863263A CN 108863263 A CN108863263 A CN 108863263A CN 201810766961 A CN201810766961 A CN 201810766961A CN 108863263 A CN108863263 A CN 108863263A
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parts
accumulation
black matrix
heat
cement material
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CN201810766961.1A
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黄鑫
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Tongcheng Jing Rui Architectural Decoration Engineering Co Ltd
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Tongcheng Jing Rui Architectural Decoration Engineering Co Ltd
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Publication of CN108863263A publication Critical patent/CN108863263A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention belongs to cement material technical fields, provide it is a kind of can accumulation of heat black matrix cement material and preparation method, use levigate Portland clinker for major ingredient, while additional black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary material.Wherein, black colorant main function is absorptivity of the material after enhancing this cement solidification to sunlight, and silicon powder main function is the transmitting to heat of the block after enhancing originally thes cement solidifies.

Description

It is a kind of can accumulation of heat black matrix cement material and preparation method
Technical field
The invention belongs to cement material technical fields, and in particular, to it is a kind of can accumulation of heat black matrix cement material and preparation Method.
Background technique
Heat-storing material:Exactly a kind of new chemical material that can be stored thermal energy and discharge thermal energy, it stores rank in heat Section, peak time extra thermal energy storage is got up, in service stage, is released the thermal energy of storage by heat-storing material, For heating, heat supply etc..So storage and release process circulation, realizes the incoordination of thermal energy over time and space, reaches The efficient of the energy utilizes and energy-efficient purpose.Sensible heat accumulation of heat not only uses principle simple, lower cost for material, and has fine Feasibility.
In the prior art, the most common sensible heat heat storage medium mainly has solid concrete, Castable ceramics, and liquid has mineral Oil and fused salt etc..The accumulation of heat of oils heat storage medium, heat release are convenient and efficient, but long-term behaviour is unstable, and inflammable, use cost It is higher;Composed of lava heat storage medium specific heat is higher, and chemical property is stablized, but most of fused salt fusing point is higher, when night, system was long Between suspend mode or need additionally to heat to keep its liquid phase state during shutting down, liquid-phase fused salts are local-crystalized sometimes, and it is existing chromatography occur As influencing heat exchanger effectiveness.Concrete and Castable ceramics are a kind of preferable sensible heat heat storage mediums, and specific heat capacity is higher, unit Heat storage is at low cost, builds maintenance and is easy.To sensible heat heat storage medium, the substance for selecting specific heat capacity big is to improve heat storage capacity A kind of feasible method.
Black matrix cement is that fence-Boltzmann law of making a mistake according to this proposes, i.e., as the coefficient of blackness of material improves, Radiation and absorbability all enhance therewith.For black matrix cement compared with common portland cement, absorption on daytime thermal characteristics are stronger, night It distributes that heat is bigger evening, there is excellent heat storage performance.Black matrix cement is used for work by the especially biggish area of day and night temperature Journey takes good hot memory technology and system to design, can be effectively reduced building energy consumption, improves building energy conservation heat insulation effect Rate saves the investment of mass energy resource and thermal insulation material.
Therefore, the present invention provide it is a kind of can accumulation of heat black matrix cement material and preparation method.
Summary of the invention
For the defects in the prior art, the object of the present invention is to provide it is a kind of can accumulation of heat black matrix cement material and preparation Method.
There is provided according to an aspect of the present invention it is a kind of can accumulation of heat black matrix cement material, it is described can accumulation of heat black matrix cement Material includes the component of following parts by weight:Levigate Portland clinker 65-94 parts, 1-5 parts of black colorant, silicon powder 4-11 Part, 3-16 parts of polypropylene fibre, 3-8 parts of sodium dehydroacetate, 3-7 parts of calcium formate, 2-8 parts of glass fiber felt, hydroxypropyl methyl cellulose 11-17 parts, 13-17 parts of auxiliary material.
Preferably, it is described can accumulation of heat black matrix cement material include following parts by weight component:Levigate portland cement 65-74 parts of clinker, 1-4 parts of black colorant, 7-11 parts of silicon powder, 3-11 parts of polypropylene fibre, 3-5 parts of sodium dehydroacetate, formic acid 3-6 parts of calcium, 2-4 parts of glass fiber felt, 11-15 parts of hydroxypropyl methyl cellulose, 13-14 parts of auxiliary material.
Preferably, it is described can accumulation of heat black matrix cement material include following parts by weight component:Levigate portland cement 68 parts of clinker, 3 parts of black colorant, 9 parts of silicon powder, 5 parts of polypropylene fibre, 4 parts of sodium dehydroacetate, 5 parts of calcium formate, glass fiber felt 3 Part, 13 parts of hydroxypropyl methyl cellulose, 13 parts of auxiliary material.
Preferably, the auxiliary material is the mixture of gypsum, flyash.
Preferably, the chemical composition of the levigate Portland clinker is:SiO 2For 12-21%, Fe2O 3For 4- 5%, Al2O 3For 5-8%, CaO 61-67%, surplus MgO.
Preferably, the glass fiber felt is alkali-resistant glass fibre short-cut original silk silk felt.
It is a kind of can accumulation of heat black matrix cement material preparation method, the preparation method specifically comprises the following steps:
(1)Levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, dehydroacetic acid are weighed according to the weight ratio Sodium, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary material;
(2)By levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass Felt, hydroxypropyl methyl cellulose, auxiliary material are put into ball mill, and ball mill mill tube revolving speed is 48-55r/min, above-mentioned original Material in ball mill residence time 30-35min, be subsequently added into suitable water and stir evenly, obtain can accumulation of heat black matrix cement Material.
Preferably, described(2)The additional amount of water is 0.5-2.3 times of raw material total amount.
Compared with prior art, the present invention has following beneficial effect:
Compared with prior art, the present invention the present invention has following features and beneficial effect:
1, one kind provided by the invention can accumulation of heat black matrix cement material, use levigate Portland clinker for major ingredient, simultaneously Additional black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary Material.Wherein, black colorant main function is absorptivity of the material after enhancing this cement solidification to sunlight, and silicon powder is mainly made With the transmitting to heat to enhance the block after originally theing cement solidifies.
2, one kind provided by the invention can accumulation of heat black matrix cement material, using black matrix water made from formula of the invention Mud can be made into heat storage performance and the good cement material of heating conduction by natural curing;Black matrix cement material color obtained Blackness is high, and blackbody coefficient is high, and heat storage coefficient is big, is heat storage performance, heat radiation, thermal diffusion cement material of good performance.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention Rather than it limits the scope of the invention.
Embodiment 1
One kind provided in this embodiment can accumulation of heat black matrix cement material, it is described can the black matrix cement material of accumulation of heat include following weight Measure the component of number:94 parts of levigate Portland clinker, 1 part of black colorant, 11 parts of silicon powder, 3 parts of polypropylene fibre, dehydrogenation 8 parts of sodium acetate, 3 parts of calcium formate, 8 parts of glass fiber felt, 11 parts of hydroxypropyl methyl cellulose, 17 parts of auxiliary material.
Preferably, the auxiliary material is the mixture of gypsum, flyash.
Preferably, the chemical composition of the levigate Portland clinker is:SiO 2For 21%, Fe2O 3For 4%, Al2O 3For 8%, CaO 61%, surplus MgO.
Preferably, the glass fiber felt is alkali-resistant glass fibre short-cut original silk silk felt.
It is a kind of can accumulation of heat black matrix cement material preparation method, the preparation method specifically comprises the following steps:
(1)Levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, dehydroacetic acid are weighed according to the weight ratio Sodium, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary material;
(2)By levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass Felt, hydroxypropyl methyl cellulose, auxiliary material are put into ball mill, and ball mill mill tube revolving speed is 48-55r/min, above-mentioned original Material in ball mill residence time 30-35min, be subsequently added into suitable water and stir evenly, obtain can accumulation of heat black matrix cement Material.
Preferably, described(2)The additional amount of water is 2.3 times of raw material total amount.
Embodiment 2
One kind provided in this embodiment can accumulation of heat black matrix cement material, it is described can the black matrix cement material of accumulation of heat include following weight Measure the component of number:65 parts of levigate Portland clinker, 5 parts of black colorant, 4 parts of silicon powder, 16 parts of polypropylene fibre, dehydrogenation 3 parts of sodium acetate, 7 parts of calcium formate, 2 parts of glass fiber felt, 17 parts of hydroxypropyl methyl cellulose, 13 parts of auxiliary material.
Preferably, the auxiliary material is the mixture of gypsum, flyash.
Preferably, the chemical composition of the levigate Portland clinker is:SiO 2For 12%, Fe2O 3For 5%, Al2O 3For 5%, CaO 67%, surplus MgO.
Preferably, the glass fiber felt is alkali-resistant glass fibre short-cut original silk silk felt.
It is a kind of can accumulation of heat black matrix cement material preparation method, the preparation method specifically comprises the following steps:
(1)Levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, dehydroacetic acid are weighed according to the weight ratio Sodium, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary material;
(2)By levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass Felt, hydroxypropyl methyl cellulose, auxiliary material are put into ball mill, and ball mill mill tube revolving speed is 48r/min, above-mentioned raw materials exist Residence time 35min in ball mill is subsequently added into suitable water and stirs evenly, obtain can accumulation of heat black matrix cement material.
Preferably, described(2)The additional amount of water is 0.5 times of raw material total amount.
Embodiment 3
One kind provided in this embodiment can accumulation of heat black matrix cement material, it is described can the black matrix cement material of accumulation of heat include following weight Measure the component of number:74 parts of levigate Portland clinker, 1 part of black colorant, 11 parts of silicon powder, 3 parts of polypropylene fibre, dehydrogenation 5 parts of sodium acetate, 3 parts of calcium formate, 4 parts of glass fiber felt, 11 parts of hydroxypropyl methyl cellulose, 14 parts of auxiliary material.
Preferably, the auxiliary material is the mixture of gypsum, flyash.
Preferably, the chemical composition of the levigate Portland clinker is:SiO 2For 21%, Fe2O 3For 5%, Al2O 3For 8%, CaO 67%, surplus MgO.
Preferably, the glass fiber felt is alkali-resistant glass fibre short-cut original silk silk felt.
It is a kind of can accumulation of heat black matrix cement material preparation method, the preparation method specifically comprises the following steps:
(1)Levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, dehydroacetic acid are weighed according to the weight ratio Sodium, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary material;
(2)By levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass Felt, hydroxypropyl methyl cellulose, auxiliary material are put into ball mill, and ball mill mill tube revolving speed is 48-55r/min, above-mentioned original Material in ball mill residence time 30-35min, be subsequently added into suitable water and stir evenly, obtain can accumulation of heat black matrix cement Material.
Preferably, described(2)The additional amount of water is 2.3 times of raw material total amount.
Embodiment 4
One kind provided in this embodiment can accumulation of heat black matrix cement material, it is described can the black matrix cement material of accumulation of heat include following weight Measure the component of number:65 parts of levigate Portland clinker, 4 parts of black colorant, 7 parts of silicon powder, 11 parts of polypropylene fibre, dehydrogenation 3 parts of sodium acetate, 6 parts of calcium formate, 2 parts of glass fiber felt, 15 parts of hydroxypropyl methyl cellulose, 13 parts of auxiliary material.
Preferably, the auxiliary material is the mixture of gypsum, flyash.
Preferably, the chemical composition of the levigate Portland clinker is:SiO 2For 12%, Fe2O 3For 4%, Al2O 3For 5%, CaO 61%, surplus MgO.
Preferably, the glass fiber felt is alkali-resistant glass fibre short-cut original silk silk felt.
It is a kind of can accumulation of heat black matrix cement material preparation method, the preparation method specifically comprises the following steps:
(1)Levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, dehydroacetic acid are weighed according to the weight ratio Sodium, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary material;
(2)By levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass Felt, hydroxypropyl methyl cellulose, auxiliary material are put into ball mill, and ball mill mill tube revolving speed is 48-55r/min, above-mentioned original Material in ball mill residence time 30-35min, be subsequently added into suitable water and stir evenly, obtain can accumulation of heat black matrix cement Material.
Preferably, described(2)The additional amount of water is 0.5 times of raw material total amount.
Embodiment 5
One kind provided in this embodiment can accumulation of heat black matrix cement material, it is described can the black matrix cement material of accumulation of heat include following weight Measure the component of number:68 parts of levigate Portland clinker, 3 parts of black colorant, 9 parts of silicon powder, 5 parts of polypropylene fibre, dehydrogenation 4 parts of sodium acetate, 5 parts of calcium formate, 3 parts of glass fiber felt, 13 parts of hydroxypropyl methyl cellulose, 13 parts of auxiliary material.
Preferably, the auxiliary material is the mixture of gypsum, flyash.
Preferably, the chemical composition of the levigate Portland clinker is:SiO 2For 15%, Fe2O 3For 5%, Al2O 3For 6%, CaO 66%, surplus MgO.
Preferably, the glass fiber felt is alkali-resistant glass fibre short-cut original silk silk felt.
It is a kind of can accumulation of heat black matrix cement material preparation method, the preparation method specifically comprises the following steps:
(1)Levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, dehydroacetic acid are weighed according to the weight ratio Sodium, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary material;
(2)By levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass Felt, hydroxypropyl methyl cellulose, auxiliary material are put into ball mill, and ball mill mill tube revolving speed is 48-55r/min, above-mentioned original Material in ball mill residence time 30-35min, be subsequently added into suitable water and stir evenly, obtain can accumulation of heat black matrix cement Material.
Preferably, described(2)The additional amount of water is 1.3 times of raw material total amount.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited to above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring substantive content of the invention.

Claims (8)

1. one kind can accumulation of heat black matrix cement material, it is characterised in that:It is described can the black matrix cement material of accumulation of heat include following weight Measure the component of number:Levigate Portland clinker 65-94 parts, 1-5 parts of black colorant, 4-11 parts of silicon powder, polypropylene fibre 3-16 parts, 3-8 parts of sodium dehydroacetate, 3-7 parts of calcium formate, 2-8 parts of glass fiber felt, 11-17 parts of hydroxypropyl methyl cellulose, auxiliary material 13-17 parts of material.
2. it is according to claim 1 can accumulation of heat black matrix cement material, it is characterised in that:It is described can accumulation of heat black matrix cement Material includes the component of following parts by weight:Levigate Portland clinker 65-74 parts, 1-4 parts of black colorant, silicon powder 7-11 Part, 3-11 parts of polypropylene fibre, 3-5 parts of sodium dehydroacetate, 3-6 parts of calcium formate, 2-4 parts of glass fiber felt, hydroxypropyl methyl cellulose 11-15 parts, 13-14 parts of auxiliary material.
3. it is according to claim 1 can accumulation of heat black matrix cement material, it is characterised in that:It is described can accumulation of heat black matrix cement Material includes the component of following parts by weight:68 parts of levigate Portland clinker, 3 parts of black colorant, 9 parts of silicon powder, poly- third 5 parts of alkene fiber, 4 parts of sodium dehydroacetate, 5 parts of calcium formate, 3 parts of glass fiber felt, 13 parts of hydroxypropyl methyl cellulose, auxiliary material 13 Part.
4. it is according to claim 1 can accumulation of heat black matrix cement material, it is characterised in that:The auxiliary material be gypsum, The mixture of flyash.
5. it is according to claim 1 can accumulation of heat black matrix cement material, it is characterised in that:The levigate portland cement is ripe The chemical composition of material is:SiO 2For 12-21%, Fe2O 3For 4-5%, Al2O 3For 5-8%, CaO 61-67%, surplus is MgO。
6. it is according to claim 1 can accumulation of heat black matrix cement material, it is characterised in that:The glass fiber felt is alkali-proof glass Fiber short-cut original silk silk felt.
7. one kind according to claim 1-6 can accumulation of heat black matrix cement material preparation method, feature exists In:The preparation method specifically comprises the following steps:
(1)Levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, dehydroacetic acid are weighed according to the weight ratio Sodium, calcium formate, glass fiber felt, hydroxypropyl methyl cellulose, auxiliary material;
(2)By levigate Portland clinker, black colorant, silicon powder, polypropylene fibre, sodium dehydroacetate, calcium formate, glass Felt, hydroxypropyl methyl cellulose, auxiliary material are put into ball mill, and ball mill mill tube revolving speed is 48-55r/min, above-mentioned original Material in ball mill residence time 30-35min, be subsequently added into suitable water and stir evenly, obtain can accumulation of heat black matrix cement Material.
8. it is according to claim 7 can accumulation of heat black matrix cement material, it is characterised in that:It is described(2)The additional amount of water is 0.5-2.3 times of raw material total amount.
CN201810766961.1A 2018-07-13 2018-07-13 It is a kind of can accumulation of heat black matrix cement material and preparation method Withdrawn CN108863263A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115838268A (en) * 2022-12-14 2023-03-24 燕新控股集团有限公司 Heat-storage heat-preservation modified cement and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115838268A (en) * 2022-12-14 2023-03-24 燕新控股集团有限公司 Heat-storage heat-preservation modified cement and preparation method thereof

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Application publication date: 20181123