CN1088624A - The high-temp plastic Ni 3 Al alloy that contains rare earth element - Google Patents

The high-temp plastic Ni 3 Al alloy that contains rare earth element Download PDF

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Publication number
CN1088624A
CN1088624A CN 92113863 CN92113863A CN1088624A CN 1088624 A CN1088624 A CN 1088624A CN 92113863 CN92113863 CN 92113863 CN 92113863 A CN92113863 A CN 92113863A CN 1088624 A CN1088624 A CN 1088624A
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CN
China
Prior art keywords
alloy
rare earth
earth element
temp plastic
contains rare
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 92113863
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Chinese (zh)
Inventor
郭建亭
孙超
李辉
王淑荷
谭明晖
赖万慧
殷为民
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Institute of Metal Research of CAS
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Institute of Metal Research of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Metal Research of CAS filed Critical Institute of Metal Research of CAS
Priority to CN 92113863 priority Critical patent/CN1088624A/en
Publication of CN1088624A publication Critical patent/CN1088624A/en
Pending legal-status Critical Current

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Abstract

The invention provides a kind of high-temp plastic Ni 3The Al alloy is characterized in that the following Ni 70~79 of alloying constituent, and Al 19~27, and B 0.8~2.0, rare earth element 0.05~0.3.Alloy provided by the present invention can make Ni 3Al improves 50~100% at the high-temp plastic of hot processing temperature.

Description

The high-temp plastic Ni 3 Al alloy that contains rare earth element
The present invention relates to intermetallic Ni-Al compound, particularly Ni 3 Al alloy.
It is good that intermetallic compound has a fusing point height, light specific gravity, hot strength, series of advantages such as antioxidant property excellence, but they often are highly brittle, and plasticity approaches zero, thereby can't practical application.Found the boron micro-alloyed Nl that makes from 1979 3Since the A malleableize, the research of intermetallic compound has entered a new stage.At present, generally believe that boron is malleableize Nl 3The key element of Al, Nl 3Add 0.1~0.5at%B among the Al, its temperature-room type plasticity can obviously improve, and reach about 35%, yet high-temp plastic is very poor, and high-temperature and durable is around in zero, Nl 3The characteristics of Al mainly are suitable for doing high-temperature structural material, and enduring quality is so poor, can not satisfy the needs on the engineering.
The object of the present invention is to provide a kind of Ni 3 Al alloy, have high-temp plastic preferably.
Main contents of the present invention have provided a kind of alloy, contain following elemental composition (below the atomic percent all with)
Nl Al B rare earth element
71-79 19-28 0.6-2.0 0.05~0.3
Rare earth element can be Y, Ce, mishmetal etc., can also add Zr and Cr, to increase plasticity and intensity.Proportioning components is as follows:
NI Al B Zr Cr rare earth element
71-74 19-22 0.1~2.0 0.5-2.0 6-8 0.05~0.3
Metallographicobservation finds that rare earth element can crystal grain thinning, and they are at intermetallic compound Nl 5Also gather partially at crystal boundary as in steel alloy, tending among the Al, not only changed Nl 5The Chemical Composition of Al crystal boundary forms the atomic arrangement that has also changed crystal boundary, thereby grain boundary dislocation is changed, and has promptly increased the mobility of grain boundary dislocation, improves the consistency of crystal boundary slippage.Both comprehensive actions have reduced boundary stress concentrates, thereby has improved Nl 3High-temp plastic.Experimental result shows, after the adding proper amount of rare-earth, can make Nl 3Al improves 50~100% at the high-temp plastic of hot processing temperature (1100 ℃).Be described in detail the present invention below by embodiment.
Embodiment 1
Composition Nl, 75.4; Al, 24.4; B, 0.1; Y, 0.1
1100 ℃ of tensile properties
σ b(MPa),360;σ 0.2(MPa)330;δ(%)2.1;
Embodiment 2
Composition Nl, 75.35; Al, 24.5; B, 0.1; Ce, 0.05
1100 ℃ of tensile properties:
σ b(MPa),350;σ 0.2(MPa),335;δ(%),1.0;
Embodiment 3
Composition Ni, 75.4; Al, 24.2; B, 0.1; Mishmetal, 0.3
1100 ℃ are drawn performance:
σ b(MPa),390;σ 0.2(MPa),320;δ(%),2.0;

Claims (2)

1, a kind of high-temp plastic Ni 3 Al alloy that contains rare earth element is characterized in that alloy ingredient is as follows, and percentage composition is (atomic percent, below all with):
Ni Al B rare earth element
71~79 19~27 0.8~2.0 0.05~0.3
Rare ten elements can be Y, Ce, mishmetal etc.
2, by the described alloy of claim 1, it is characterized in that also containing Z and Cr, proportioning components is as follows:
NI Al B Zr Cr rare earth element
71-74 19-22 0.1~2.0 0.5-2.0 6-8 0.05~0.3
CN 92113863 1992-12-25 1992-12-25 The high-temp plastic Ni 3 Al alloy that contains rare earth element Pending CN1088624A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 92113863 CN1088624A (en) 1992-12-25 1992-12-25 The high-temp plastic Ni 3 Al alloy that contains rare earth element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 92113863 CN1088624A (en) 1992-12-25 1992-12-25 The high-temp plastic Ni 3 Al alloy that contains rare earth element

Publications (1)

Publication Number Publication Date
CN1088624A true CN1088624A (en) 1994-06-29

Family

ID=4946627

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 92113863 Pending CN1088624A (en) 1992-12-25 1992-12-25 The high-temp plastic Ni 3 Al alloy that contains rare earth element

Country Status (1)

Country Link
CN (1) CN1088624A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101979693A (en) * 2010-11-16 2011-02-23 谭丽霞 Nano-crystalline NiAl-Al2O3-Y composite material and preparation method thereof
US20130217568A1 (en) * 2012-02-20 2013-08-22 Saudi Basic Industries Corporation Oxidative dehydrogenation of olefins catalyst and methods of making and using the same
US9731280B2 (en) 2012-11-21 2017-08-15 Shanghai Huayi Acrylic Acid Co. Ltd. Ferrite catalyst and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101979693A (en) * 2010-11-16 2011-02-23 谭丽霞 Nano-crystalline NiAl-Al2O3-Y composite material and preparation method thereof
US20130217568A1 (en) * 2012-02-20 2013-08-22 Saudi Basic Industries Corporation Oxidative dehydrogenation of olefins catalyst and methods of making and using the same
US9731280B2 (en) 2012-11-21 2017-08-15 Shanghai Huayi Acrylic Acid Co. Ltd. Ferrite catalyst and preparation method thereof

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