CN108851259A - A kind of latex brassiere and preparation method thereof - Google Patents
A kind of latex brassiere and preparation method thereof Download PDFInfo
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- CN108851259A CN108851259A CN201810780576.2A CN201810780576A CN108851259A CN 108851259 A CN108851259 A CN 108851259A CN 201810780576 A CN201810780576 A CN 201810780576A CN 108851259 A CN108851259 A CN 108851259A
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- latex
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41C—CORSETS; BRASSIERES
- A41C3/00—Brassieres
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41C—CORSETS; BRASSIERES
- A41C5/00—Machines, appliances, or methods for manufacturing corsets or brassieres
- A41C5/005—Machines, appliances, or methods for manufacturing corsets or brassieres by moulding
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N1/00—Electrotherapy; Circuits therefor
- A61N1/44—Applying ionised fluids
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- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Textile Engineering (AREA)
- Radiology & Medical Imaging (AREA)
- Biomedical Technology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Corsets Or Brassieres (AREA)
Abstract
The invention discloses a kind of latex brassieres and preparation method thereof, it is related to brassiere field, the latex brassiere includes the cup being made into integration by lining and connecting band, the lining includes one or more layers emulsion layer, it is provided with bed of cloth on the outside of the emulsion layer, the emulsion layer includes the component of following parts by weight:13-17 parts of natural emulsion;52-60 parts of styrene-butadiene latexes;1-3 parts of promotor;18-27 parts of filler;1-3 parts of vulcanizing agent;1-3 parts of activating agent;3-7 parts of negative ion powder.Negative ion powder is doped in the latex material of excellent spring, and not only comfort is guaranteed, and also has healthcare function.
Description
Technical field
The present invention relates to underwear, in particular to a kind of latex brassiere and preparation method thereof.
Background technique
Latex refers to polymer particles and is dispersed in water the colloid emulsion to be formed, can be divided into natural emulsion, synthetic latex and
Artificial latex.Natural emulsion has excellent elasticity, gas permeability, therefore can be made into the daily necessities such as pillow, mattress as raw material.
Simultaneously latex also have inhibit germ, acarid breed, and without electrostatic, dissipate the advantages of natural frankincense taste, people can be adapted to completely
Body curvature, therefore now latex be also used for as brassiere lining.
Notification number, which discloses one kind for the Chinese patent of CN105029728B, has the function of far infrared and negative ion health
Brassiere and its manufacturing method, including brassiere cup, bra belt and fastener, the brassiere cup by skin contacting adhesive layer, pad and
Decorative surface layer composition, removably device is in the pad accommodating cavity for the pad, and the pad is by Chinese traditional medicine layer, anion day
Right mineral particle layer and active carbon particle layer composition, the Chinese traditional medicine layer, anion natural mineral matter stratum granulosum and active carbon
Granulosa is sewed together after the adjacent overlapping of shell fabric up and down two-by-two, and the anion natural mineral matter particle is placed on the work
In the hollow structure of property charcoal stratum granulosum, the active carbon particle is placed in the hollow structure of the Chinese traditional medicine layer, the Chinese traditional medicine layer,
The width of anion natural mineral matter stratum granulosum and active carbon particle layer ratio is 1.5: 1.5: 1.
Contain anion natural mineral matter particle in the pad of above-mentioned brassiere, can release for human body sucking bear from
Son plays healthcare function.But the quality of anion natural mineral matter particle is harder, wears brassiere and has been easy foreign body sensation, does not relax
It is suitable, and poor air permeability, have much room for improvement.
Summary of the invention
In view of the above technical defects, the first object of the present invention is to provide a kind of latex brassiere, and negative ion powder is doped to
In the latex material of excellent spring, not only comfort is guaranteed, and also has healthcare function.
To achieve the above object, the present invention provides following technical solutions:
A kind of latex brassiere, including the cup being made into integration by lining and connecting band, the lining includes one or more layers cream
Glue-line, the emulsion layer outside are provided with bed of cloth, and the emulsion layer includes the component of following parts by weight:
13-17 parts of natural emulsion
52-60 parts of styrene-butadiene latexes
1-3 parts of promotor
18-27 parts of filler
1-3 parts of vulcanizing agent
1-3 parts of reinforcing agent
3-7 parts of negative ion powder.
By using above-mentioned technical proposal, negative ion powder can be such that air ionizes, and then generate beneficial to the person
Anion.Anion has good bioactivity, is easy to play its biological effect into human body through human body blood-brain barrier,
Neurasthenia, insomnia can be improved, improved the immunity of the human body.
Negative ion powder is doped in the emulsion layer of excellent spring, can guarantee the comfort for dressing brassiere.Brassiere conduct
Underwear is the necessity that schoolgirl dresses daily, and negative ion powder can generate anion constantly, therefore negative ion powder works
Time is long.Anion neutralizes after encountering the particle with the charges of different polarity and loses electrical property, and the time being present in air only has tens
Second to several minutes, can not be accumulated, human body is needed to absorb in time.Therefore negative ion powder doping brassiere in, relative to be entrained in pillow,
In mattress, effect is maximized.
Brassiere is directly in close contact with human skin, and there are blocking for clothes, therefore environment locating for negative ion powder in outside
Temperature opposite outer environment is higher, and negative ion powder discharges the efficiency of anion and then increases.Chest belongs to the position for being easy perspiration,
Therefore ambient humidity described in negative ion powder is relatively high, and the effect that negative ion powder discharges anion improves.
The present invention is further arranged to:The negative ion powder is tourmaline powder, partial size≤6 μm of the tourmaline powder.
By using above-mentioned technical proposal, tourmaline powder is other than it can generate anion, moreover it is possible to which release has human body
The far infrared of benefit, promotes blood circulation, and keeps metabolism smooth.Tourmaline powder is added in the personal brassiere of women, can be delayed
Solution even cures the cold limbs disease of worried women many years, physiological pain etc..
The present invention is further arranged to:The negative ion powder further includes ceria.
By using above-mentioned technical proposal, the proportion of ceria and tourmaline powder can make the accumulation of negative ion powder surface a large amount of
The energy of air molecule is dissociated, and then is obviously improved the ability that tourmaline powder generates anion.
The present invention is further arranged to:It is 1: 2-1: 3 that the ceria and tourmaline powder match by weight.
By using above-mentioned technical proposal, ceria and tourmaline powder synergy in the ratio range are optimal.
The present invention is further arranged to:The promotor by by weight 1: 1 zinc diethyl dithiocarbamate and
Benzothiazole matches.
By using above-mentioned technical proposal, promotor has preferable effect, improves reaction rate, reduces vulcanization time.
The present invention is further arranged to:The reinforcing agent is matched by by weight 1: 1 zinc oxide and silicate.
By using above-mentioned technical proposal, zinc oxide and silicate can be improved the wearability of emulsion layer, tear resistance.
Simultaneous oxidation zinc can increase the activity of zinc diethyl dithiocarbamate, be allowed to give full play to efficiency, and then shorten vulcanization
Time.
The present invention is further arranged to:The filler is calcium carbonate.
By using above-mentioned technical proposal, calcium carbonate can improve the performance of emulsion layer.
The present invention is further arranged to:The vulcanizing agent is sulphur.
By using above-mentioned technical proposal, the performances such as elasticity, endurance of emulsion layer get a promotion after vulcanization.
The present invention is further arranged to:The component of the emulsion layer further includes 2-6 parts of organosilicons.
By using above-mentioned technical proposal, organosilicon has good hydrophobicity, comfortable pliability, high-low temperature resistant, resistance to
The performances such as aging, moisture-proof, therefore after organosilicon is grafted on the strand of natural emulsion, the defect of natural emulsion can be preferable
It makes up, so that the solvent resistance of emulsion layer, water resistance are promoted.Contain a large amount of silicon oxygen bond isoline type in organosilicon simultaneously
Or the structure of reticular pattern, therefore emulsion layer global density can decline, hole increases, and gas permeability and then increase promote brassiere dress
Comfort.Negative ion powder and air contact area increase so that the burst size of negative ion powder improves, and be convenient for anion with
Air flows and is in personal surrounding.
The second object of the present invention is to provide a kind of preparation method of latex brassiere.
A kind of preparation method of latex brassiere, includes the following steps:
The preparation of S1 emulsion layer:
A. 13-17 parts of natural emulsions, 1-2 parts of coupling agent A-171 are added in reaction kettle, are mixed slowly 20 minutes, then persistently rise
Simultaneously mixing speed is continuously improved up to 55 DEG C in temperature, and 2-6 parts of organosilicons are then added dropwise, react 5 hours, cooling stand-by;
It B. is 1: 2- by weight by above-mentioned modified natural emulsion, 52-60 parts of styrene-butadiene latexes, 3-7 parts
Negative ion powder made of 1: 3 ceria and tourmaline powder configuration is added to agitator tank, stirs evenly;
C. again by 1-3 parts of sulphur, 1-3 parts by weight 1: 1 of zinc diethyl dithiocarbamate and benzothiazole match and
At promotor, reinforcing agent, 18-27 parts of calcium carbonate add made of 1-3 parts by weight 1: 1 of zinc oxide and silicate proportion
Enter, is stirred continuously 2-4 hours;
D. material is then injected into mold, is heated to 80-90 DEG C, vulcanization formed to obtain emulsion layer after 30 minutes;
The preparation of S2 brassiere:Multilayer emulsion layer and the two layers of cloth bed of material are hot pressed into lining, finally cut sizing.
Through the above technical solutions, the brassiere with healthcare function and wearing comfort can be obtained.
In conclusion the invention has the advantages that:
1. negative ion powder is entrained in the mode in emulsion layer, it can guarantee the comfort for dressing brassiere and there is healthcare function, have
Beneficial health;
2. the combination of tourmaline powder and ceria can significantly improve anion concentration, enhance health-care effect;
3. modification of the organosilicon to natural emulsion strand, it can be improved the performance of emulsion layer various aspects, and gas permeability mentions
Height additionally aids the generation of anion.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the brassiere of embodiment six;
Fig. 2 is the schematic cross-sectional view of lining in embodiment six;
Fig. 3 is the examining report first page that microbiological analysis inspection center of Guangdong Province carries out anion concentration analysis to emulsion layer;
Fig. 4 is the examining report second page that microbiological analysis inspection center of Guangdong Province carries out anion concentration analysis to emulsion layer;
Fig. 5 is the examining report third page that microbiological analysis inspection center of Guangdong Province carries out anion concentration analysis to emulsion layer;
Fig. 6 is examining report page four that microbiological analysis inspection center of Guangdong Province carries out anion concentration analysis to emulsion layer.
Description of symbols:1, cup;2, connecting band;3, lining;31, emulsion layer;32, bed of cloth.
Specific embodiment
Below in conjunction with attached drawing, invention is further described in detail.
Embodiment one:
A kind of preparation method of latex brassiere is as follows:
The preparation of S1 emulsion layer:
A. 13 parts of natural emulsions, 1 part of coupling agent A-171 are added in reaction kettle, are mixed slowly 20 minutes, then persistently overheating is not
The disconnected mixing speed that improves then is added dropwise 2 parts of organosilicons, reacts 5 hours up to 55 DEG C, cooling stand-by;
B. by above-mentioned modified natural emulsion, 52 parts of styrene-butadiene latexes, 3 parts by weight be 1: 2 dioxy
Change negative ion powder made of cerium and tourmaline powder configuration to be added to agitator tank, stir evenly;
It C. again will be made of 1 part of sulphur, 1 part by weight 1: 1 of zinc diethyl dithiocarbamate and benzothiazole proportion
Reinforcing agent made of promotor, 1 part by weight 1: 1 of zinc oxide and silicate proportion, 18 parts of calcium carbonate are added, and are stirred continuously
2-4 hours;
D. material is then injected into mold, is heated to 80 DEG C, vulcanization formed to obtain emulsion layer after 30 minutes;
The preparation of S2 brassiere:One or more layers emulsion layer and the two layers of cloth bed of material are hot pressed into lining, finally cut sizing.
Styrene-butadiene latexes, that is, styrene-butadiene latex;Organosilicon, that is, organic silicon emulsion is bought from Laiyang Sheng Bang organosilicon section
Skill Co., Ltd;The partial size of tourmaline powder is 2 μm;The partial size of ceria is 35nm.
Embodiment two:
The preparation of S1 emulsion layer:
A. 17 parts of natural emulsions, 2 parts of coupling agent A-171 are added in reaction kettle, are mixed slowly 20 minutes, then persistently overheating is not
The disconnected mixing speed that improves then is added dropwise 6 parts of organosilicons, reacts 5 hours up to 55 DEG C, cooling stand-by;
B. by above-mentioned modified natural emulsion, 60 parts of styrene-butadiene latexes, 7 parts by weight be 1: 3 dioxy
Change negative ion powder made of cerium and tourmaline powder configuration to be added to agitator tank, stir evenly;
It C. again will be made of 3 parts of sulphur, 3 parts by weight 1: 1 of zinc diethyl dithiocarbamate and benzothiazole proportion
Reinforcing agent made of promotor, 3 parts by weight 1: 1 of zinc oxide and silicate proportion, 27 parts of calcium carbonate are added, and are stirred continuously
4 hours;
D. material is then injected into mold, is heated to 90 DEG C, vulcanization formed to obtain emulsion layer after 30 minutes;
The preparation of S2 brassiere:One or more layers emulsion layer and the two layers of cloth bed of material are hot pressed into lining, finally cut sizing.
Styrene-butadiene latexes, that is, styrene-butadiene latex;Organosilicon, that is, organic silicon emulsion is bought from Laiyang Sheng Bang organosilicon section
Skill Co., Ltd;The partial size of tourmaline powder is 2 μm;The partial size of ceria is 35nm.
Embodiment three:
The preparation of S1 emulsion layer:
A. 15 parts of natural emulsions, 1.5 parts of coupling agent A-171 are added in reaction kettle, are mixed slowly 20 minutes, then persistently overheating is simultaneously
Mixing speed is continuously improved up to 55 DEG C, 4 parts of organosilicons are then added dropwise, reacts 5 hours, it is cooling stand-by;
B. by above-mentioned modified natural emulsion, 56 parts of styrene-butadiene latexes, 5 parts by weight be 1: 2.5 two
Negative ion powder made of cerium oxide and tourmaline powder configuration is added to agitator tank, stirs evenly;
It C. again will be made of 2 parts of sulphur, 2 parts by weight 1: 1 of zinc diethyl dithiocarbamate and benzothiazole proportion
Reinforcing agent made of promotor, 2 parts by weight 1: 1 of zinc oxide and silicate proportion, 23 parts of calcium carbonate are added, and are stirred continuously
3 hours;
D. material is then injected into mold, is heated to 85 DEG C, vulcanization formed to obtain emulsion layer after 30 minutes;
The preparation of S2 brassiere:One or more layers emulsion layer and the two layers of cloth bed of material are hot pressed into lining, finally cut sizing.
Styrene-butadiene latexes, that is, styrene-butadiene latex;Organosilicon, that is, organic silicon emulsion is bought from Laiyang Sheng Bang organosilicon section
Skill Co., Ltd;The partial size of tourmaline powder is 2 μm;The partial size of ceria is 35nm.
Example IV:
Unlike embodiment three, negative ion powder is all made of tourmaline powder.
Embodiment five:
Unlike embodiment three, latex layer component does not include A in the preparation of organosilicon and coupling agent A-171, S1 emulsion layer
Step without.
Embodiment six:
A kind of latex brassiere, as shown in Figure 1 and Figure 2, including two cups 1 being made into integration by lining 3 and for connecting two
The connecting band 2 of cup 1.Lining 3 includes two layers of emulsion layer 31, is provided with bed of cloth 32 on the outside of emulsion layer 31.
Comparative example one:
Unlike embodiment three, the component of emulsion layer does not include negative ion powder.
If Fig. 3 to Fig. 6 is the detection that microbiological analysis inspection center in Guangdong Province's carries out anion concentration analysis to emulsion layer
Report.
The test of the anion concentration of each embodiment and comparative example one:
The method recorded using GB/T 18809-2002, contains the anion at brassiere using DLY-7 type air ion measuring instrument
Amount measures, and measurement result is as shown in table 1.
Table 1
It can be obtained according to table 1:Ceria, which generates anion to tourmaline powder, has facilitation;The addition of organosilicon facilitates sky
Gas anion concentration increases.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (10)
1. a kind of latex brassiere, including the cup (1) being made into integration by lining (3) and connecting band (2), lining (3) packet
One or more layers emulsion layer (31) is included, is provided with bed of cloth (32) on the outside of the emulsion layer (31), it is characterised in that:The latex
Layer (31) includes the component of following parts by weight:
13-17 parts of natural emulsion
52-60 parts of styrene-butadiene latexes
1-3 parts of promotor
18-27 parts of filler
1-3 parts of vulcanizing agent
1-3 parts of reinforcing agent
3-7 parts of negative ion powder.
2. a kind of latex brassiere according to claim 1, it is characterised in that:The negative ion powder is tourmaline powder, described
Partial size≤6 μm of tourmaline powder.
3. a kind of latex brassiere according to claim 2, it is characterised in that:The negative ion powder further includes ceria.
4. a kind of latex brassiere according to claim 3, it is characterised in that:The ceria and tourmaline powder are by weight
Part meter proportion is 1:2-1:3.
5. a kind of latex brassiere according to claim 1, it is characterised in that:The promotor is by by weight 1:The two of 1
Zinc diethyl dithiocarbamate and benzothiazole match.
6. a kind of latex brassiere according to claim 5, it is characterised in that:The reinforcing agent is by by weight 1:1 oxygen
Change zinc and silicate matches.
7. a kind of latex brassiere according to claim 1, it is characterised in that:The filler is calcium carbonate.
8. a kind of latex brassiere according to claim 1, it is characterised in that:The vulcanizing agent is sulphur.
9. a kind of latex brassiere according to claim 1, it is characterised in that:The component of the emulsion layer further includes 2-6 parts
Organosilicon, 1-2 parts of coupling agent A-171.
10. a kind of preparation method of latex brassiere, it is characterised in that:Include the following steps to be made:
The preparation of S1 emulsion layer:
A. 13-17 parts of natural emulsions, 1-2 parts of coupling agent A-171 are added in reaction kettle, are mixed slowly 20 minutes, then persistently rise
Simultaneously mixing speed is continuously improved up to 55 DEG C in temperature, and 2-6 parts of organosilicons are then added dropwise, react 5 hours, cooling stand-by;
It B. is 1 by weight by above-mentioned modified natural emulsion, 52-60 parts of styrene-butadiene latexes, 3-7 parts:2-
1:Negative ion powder made of 3 ceria and tourmaline powder configuration is added to agitator tank, stirs evenly;
C. again by 1-3 parts of sulphur, 1-3 parts by weight 1:1 zinc diethyl dithiocarbamate and benzothiazole proportion and
At promotor, 1-3 parts by weight 1:Reinforcing agent made of 1 zinc oxide and silicate proportion, 18-27 parts of calcium carbonate add
Enter, is stirred continuously 2-4 hours;
D. material is then injected into mold, is heated to 80-90 DEG C, vulcanization formed to obtain emulsion layer after 30 minutes;
The preparation of S2 brassiere:One or more layers emulsion layer and the two layers of cloth bed of material are hot pressed into lining, finally cut sizing.
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