CN108844080A - A kind of device of organic silicon slurry slag burning pre-treatment - Google Patents
A kind of device of organic silicon slurry slag burning pre-treatment Download PDFInfo
- Publication number
- CN108844080A CN108844080A CN201810827058.1A CN201810827058A CN108844080A CN 108844080 A CN108844080 A CN 108844080A CN 201810827058 A CN201810827058 A CN 201810827058A CN 108844080 A CN108844080 A CN 108844080A
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- Prior art keywords
- air
- combustion
- combustion chamber
- organic silicon
- air outlet
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
- F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L1/00—Passages or apertures for delivering primary air for combustion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/10—Combustion in two or more stages
- F23G2202/103—Combustion in two or more stages in separate chambers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2203/00—Furnace arrangements
- F23G2203/20—Rotary drum furnace
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Incineration Of Waste (AREA)
Abstract
The invention discloses a kind of devices of organic silicon slurry slag burning pre-treatment, organic silicon slurry slag is sent into middle progress first time combustion reaction in the first combustion chamber of rotary combustion furnace with pipeline pressuring method, steam after the first combustion chambers burn continues into the second combustion chamber being connected with rotary combustion furnace and carries out second of combustion reaction, when being passed through combustion air in the first combustion chamber, carried out by such a way that the first Inner Wall of Combustion Chamber takes opposite air-supply.The present invention can effectively promote the efficiency of combustion of organic silicon slurry slag by the air supply mode of improvement combustion air, and can remove the indoor carbon distribution of burning simultaneously.
Description
Technical field
The present invention relates to organic silicon byproduct synthesized environmental protection process fields, and in particular to a kind of preceding place of organic silicon slurry slag burning
The device of reason.
Background technique
Organic silicon slurry slag refers to a kind of waste residue slurry generated in organic silicon monomer synthesis process, accounts for amount of monomer about 3%, with
The rapidly extension of organic silicon monomer yield, supervene a large amount of organic silicon waste residue slurry, mainly composition be by more height
The silicon powder (partial size is in 2~150um) that boiling object and a small amount of fluidized bed are brought out, copper powder and microelement Fe, Zn, Al, Sn etc..Wherein
70.5~250 DEG C of high-boiling components boiling range, composition be mainly disilane, siloxanes, silicon support alkane, solid content is 20~75%.If
It is exposed in air, easily causes strong acid mist and burning, therefore, it is necessary to carry out harmless treatment to it.Currently, much having
Slurry is emitted on inside pond and is hydrolyzed by Ji Gui manufacturing enterprise, and the hydrogen chloride of discharge is seriously polluted, and a large amount of high-boiling components are not
It can recycle, fish out slag heavy workload, and the cuprous ion in slurry meets open fire and air easily causes to burn due to strong reducing property
And explosion, cause serious security risk.
Combustion method is to handle a kind of method of silicon screenings.Although strong sending and receiving can obtain silane monomer, wide to ingredient requirement
Pine does not need to remove some solid impurities in high-boiling components, can crack all silane.The shortcomings that burning pre-treatment is reaction temperature
Degree is higher, and carbon distribution is serious.Therefore need a kind of device that can reduce the carbon distribution problem in burning pretreatment process.
Summary of the invention
It is an object of that present invention to provide a kind of device of organic silicon slurry slag burning pre-treatment, which can effectively solve the problem that combustion
Burn the serious problem of the carbon distribution of processing organic silicon slurry slag generation.
The present invention is achieved through the following technical solutions:
A kind of device of organic silicon slurry slag burning pre-treatment, including rotary combustion furnace offer in rotary combustion furnace
First combustion chamber, rotary combustion furnace are connected with the second combustion chamber, the second combustion chamber and the first combustion chamber, the second combustion chamber
It is communicated with deduster, the air-supply region of at least two pieces opposite central axis settings is set on the first Inner Wall of Combustion Chamber, is blown at every piece
Multiple air outlets are offered on the corresponding inner wall in region along its length, are also opened along its length on the inner wall of every piece of air-supply region
Equipped with air supply duct, air supply duct is provided with the lower section of air outlet, and is connected to air outlet.
Three different feeding amount sections are divided into along the air supply direction of air-supply region, the first feeding amount section is first intensive
Blow zones, the second feeding amount section are the second evacuation blow zones, and third feeding amount section is the intensive blow zones of third, and first is intensive
The air outlet number of blow zones is greater than the air outlet number of the second evacuation blow zones, and the air outlet number of the intensive blow zones of third is big
Air outlet number in the second evacuation blow zones.The indoor organic silicon slurry slag of the first burning is generally sent to need more in first combustion
More heats and combustion air are so that it starts to burn, therefore should apply more combustion-supporting skies in the first feeding amount section
Gas.Below then because in contrast therefore combustion air that flameholding needs will lack, finally comburant is carried out sufficient
After-flame work, therefore be also required to increase air output in third feeding amount section.Air supply direction to be from the first entry of combustion chamber
The initial position of feeding.
Multiple air outlets are that dislocation is oppositely arranged.Dislocation is oppositely arranged the convection current that can make full use of relative atmospheric, will be right
The particulate matter that will adhere to or just be attached on inner wall that burning on the inner wall of face obtains is blown away.
Layer of titanium dioxide layer is coated on the inner wall of first combustion chamber.Titanium dioxide layer be for smooth, smooth coating,
It can aid in the generation for reducing carbon distribution.
Air outlet is loudspeaker diffused air outlet.Loudspeaker diffused air outlet is advantageous in that:When combustion air is from outlet air
After mouthful coming out, air-flow can against inner wall flowing from two sides, on the one hand can be abundant with the organic silicon slurry slag that may be close to inner wall
It mixes and makes organic silicon slurry slag full combustion, the type of flow being on the other hand close to can take away that will adhere to after burning
Grain object, plays the role of being substantially reduced the first Inner Wall of Combustion Chamber carbon distribution.
The present apparatus is helped by realizing to be passed through in the first combustion chamber in such a way that the first Inner Wall of Combustion Chamber takes opposite air-supply
Fire air.
The prior art is to be provided with air outlet at some point of combustion furnace, and this mode is for ordinary comburant
It can satisfy the sufficient condition of burning.However when handling organic silicon slurry slag, inventor's discovery is due to organic silicon slurry slag
It is made of high-boiling components and fine silicon powder, copper powder etc. that flying spot is more than 70 degrees Celsius, is a kind of liquid-solid mixture with mobility,
Such liquid-solid mixture is not easy to be sufficiently mixed with the combustion air by an air outlet in combustion, along with its combustion
It is very high to burn the temperature that reaction needs, therefore forms carbon distribution on the easy insufficient and easy wall in the combustion chamber that burns, goes down for a long time
The heat transfer efficiency of combustion chamber can be reduced, so that burning energy consumption is increasing.First burnup room is passed through combustion air by the present invention
Mode is modified to the opposite mode blown, and on the one hand the air with respect to air-supply can carry out the liquid-solid mixture of organic silicon slurry slag
Stirring promotes the contact area of organic silicon slurry slag and air, on the other hand can carry out air-flow purification to the inner wall of combustion chamber, prevent
Only burning particles are attached on the first Inner Wall of Combustion Chamber.
Compared with prior art, the present invention having the following advantages and benefits:
The present invention realizes the air supply mode of new combustion air by the improvement to furnace interior structure, can be effective
The efficiency of combustion of organic silicon slurry slag is promoted, and the indoor carbon distribution of burning can be removed simultaneously.
Detailed description of the invention
Attached drawing described herein is used to provide to further understand the embodiment of the present invention, constitutes one of the application
Point, do not constitute the restriction to the embodiment of the present invention.In the accompanying drawings:
Fig. 1 is the first chamber structure schematic diagram of the invention.
Fig. 2 is present invention process structural schematic diagram.
Label and corresponding parts title in attached drawing:
The first combustion chamber 1-, 101- air supply duct, 102- air outlet, the second combustion chamber 2-, 3- grey leakage port, 4- deduster.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer, below with reference to embodiment and attached drawing, to this
Invention is described in further detail, and exemplary embodiment of the invention and its explanation for explaining only the invention, are not made
For limitation of the invention.
Embodiment 1
A kind of device of organic silicon slurry slag burning pre-treatment, including rotary combustion furnace offer in rotary combustion furnace
First combustion chamber 1, rotary combustion furnace are connected with the second combustion chamber 2, and the second combustion chamber 2 is connected to the first combustion chamber 1, the second combustion
It burns room 2 and is communicated with deduster 4, the air-supply region of at least two pieces opposite central axis settings is set on 1 inner wall of the first combustion chamber, every
Multiple air outlets 102 are offered on the corresponding inner wall of block air-supply region along its length, along length on the inner wall of every piece of air-supply region
Degree direction is also provided with air supply duct 101, and air supply duct 101 is provided with the lower section of air outlet 102, and connects with air outlet 102
It is logical.
Embodiment 2
Three different feeding amount sections are divided into along the air supply direction of air-supply region, the first feeding amount section is first intensive
Blow zones, the second feeding amount section are the second evacuation blow zones, and third feeding amount section is the intensive blow zones of third, and first is intensive
102 numbers of air outlet of blow zones are greater than 102 numbers of air outlet of the second evacuation blow zones, the air outlet of the intensive blow zones of third
102 numbers are greater than 102 numbers of air outlet of the second evacuation blow zones.
Embodiment 3
Multiple air outlets 102 are that dislocation is oppositely arranged.Dislocation is oppositely arranged the convection current that can make full use of relative atmospheric, will
The particulate matter that will adhere to or just be attached on inner wall that burning on facing interior wall obtains is blown away.
Layer of titanium dioxide layer is coated on the inner wall of first combustion chamber 1.Titanium dioxide layer is for smooth, smooth painting
Layer can aid in the generation for reducing carbon distribution.
Air outlet 102 is loudspeaker diffused air outlet 102.
When the present invention is handled before the burning for carrying out organic silicon slurry slag, specifically by organic silicon slurry slag with pipeline pressuring method
It is sent into middle progress first time combustion reaction in the first combustion chamber 1 of rotary combustion furnace, the steam after the burning of the first combustion chamber 1
It continues into the second combustion chamber 2 being connected with rotary combustion furnace and carries out second of combustion reaction, lead in the first combustion chamber 1
When entering combustion air, carried out by such a way that 1 inner wall of the first combustion chamber takes opposite air-supply.
As shown in Figure 1 and Figure 2, rotary burning stove heating is worked as into temperature so that the temperature of the first combustion chamber 1 slowly increases
When rising to 400-500 DEG C, the pressurization of organic silicon slurry slag nitrogen is entered in the first combustion chamber 1 by pipeline, when temperature arrives
When up to 600 DEG C, it is passed through combustion oxygen from air taking port, organic silicon slurry slag full combustion simultaneously constantly moves in revolution to bottom, combustion
It burns the grey object generated to enter in grey leakage port 3, the flue gas for generation of burning enters the second combustion chamber 2, rises in the second combustion chamber 2
Temperature carries out second of combustion reaction to 1050 DEG C or more, enters back into 4 ash disposal of deduster.
In the present invention, combustion oxygen is come out by air supply duct 101 from the air taking port of air-supply region, with organic silicon slurry slag
The first combustion chamber 1 will be assembled or be just gathered in the particulate matter for being sufficiently mixed, and generating after organic silicon slurry slag full combustion
It when on inner wall, is sent away, realizes the purpose for removing carbon remover.
Above-described specific embodiment has carried out further the purpose of the present invention, technical scheme and beneficial effects
It is described in detail, it should be understood that being not intended to limit the present invention the foregoing is merely a specific embodiment of the invention
Protection scope, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include
Within protection scope of the present invention.
Claims (5)
1. a kind of device of organic silicon slurry slag burning pre-treatment, including rotary combustion furnace, the is offered in rotary combustion furnace
One combustion chamber (1), rotary combustion furnace are connected with the second combustion chamber (2), and the second combustion chamber (2) are connected to the first combustion chamber (1),
Second combustion chamber (2) is communicated with deduster (4), which is characterized in that be arranged on the first combustion chamber (1) inner wall at least two pieces relatively in
The air-supply region of mandrel setting, offers multiple air outlets (102) along its length on the corresponding inner wall of every piece of air-supply region,
It is also provided with along its length on the inner wall of every piece of air-supply region air supply duct (101), air supply duct (101) is provided with air outlet
(102) lower section, and be connected to air outlet (102).
2. the device of organic silicon slurry slag burning pre-treatment according to claim 1, which is characterized in that along sending for air-supply region
Wind direction is divided into three different feeding amount sections, and the first feeding amount section is the first intensive blow zones, the second feeding amount section
For the second evacuation blow zones, third feeding amount section is the intensive blow zones of third, and the air outlet (102) of the first intensive blow zones is a
Number is greater than air outlet (102) number of the second evacuation blow zones, and air outlet (102) number of the intensive blow zones of third is greater than second
Evacuate air outlet (102) number of blow zones.
3. the device of organic silicon slurry slag burning pre-treatment according to claim 1, which is characterized in that multiple air outlets
(102) it is oppositely arranged for dislocation.
4. the device of organic silicon slurry slag burning pre-treatment according to claim 1, which is characterized in that the first combustion chamber (1)
Inner wall on be coated with layer of titanium dioxide layer.
5. the device of organic silicon slurry slag burning pre-treatment according to claim 1-4, which is characterized in that air outlet
It (102) is loudspeaker diffused air outlet.
Priority Applications (1)
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CN201810827058.1A CN108844080A (en) | 2018-07-25 | 2018-07-25 | A kind of device of organic silicon slurry slag burning pre-treatment |
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CN201810827058.1A CN108844080A (en) | 2018-07-25 | 2018-07-25 | A kind of device of organic silicon slurry slag burning pre-treatment |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1026323A (en) * | 1996-07-08 | 1998-01-27 | Handa Techno:Kk | Rotary kiln |
CN2674299Y (en) * | 2003-08-01 | 2005-01-26 | 北京钠锘环境工程有限责任公司 | Rotary kiln incinerator for toxic harmful dangerous waste |
CN201621706U (en) * | 2009-11-16 | 2010-11-03 | 史金麟 | Three-section rotary combustion furnace |
CN202002118U (en) * | 2011-03-18 | 2011-10-05 | 江苏宏图洁环保工程设备有限公司 | Incinerator special for organic silicone waste slag slurry |
JP2017146085A (en) * | 2016-02-20 | 2017-08-24 | 株式会社エム・アイ・エス | Combustor |
-
2018
- 2018-07-25 CN CN201810827058.1A patent/CN108844080A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1026323A (en) * | 1996-07-08 | 1998-01-27 | Handa Techno:Kk | Rotary kiln |
CN2674299Y (en) * | 2003-08-01 | 2005-01-26 | 北京钠锘环境工程有限责任公司 | Rotary kiln incinerator for toxic harmful dangerous waste |
CN201621706U (en) * | 2009-11-16 | 2010-11-03 | 史金麟 | Three-section rotary combustion furnace |
CN202002118U (en) * | 2011-03-18 | 2011-10-05 | 江苏宏图洁环保工程设备有限公司 | Incinerator special for organic silicone waste slag slurry |
JP2017146085A (en) * | 2016-02-20 | 2017-08-24 | 株式会社エム・アイ・エス | Combustor |
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Application publication date: 20181120 |
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