CN108841170A - Automobile instrument panel shell - Google Patents

Automobile instrument panel shell Download PDF

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Publication number
CN108841170A
CN108841170A CN201810604986.1A CN201810604986A CN108841170A CN 108841170 A CN108841170 A CN 108841170A CN 201810604986 A CN201810604986 A CN 201810604986A CN 108841170 A CN108841170 A CN 108841170A
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CN
China
Prior art keywords
shell
engineering plastics
antioxidant
ialn
polyethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810604986.1A
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Chinese (zh)
Inventor
王德京
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuzhou Xin Neng Electrical Appliance Co Ltd
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Xuzhou Xin Neng Electrical Appliance Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Xuzhou Xin Neng Electrical Appliance Co Ltd filed Critical Xuzhou Xin Neng Electrical Appliance Co Ltd
Priority to CN201810604986.1A priority Critical patent/CN108841170A/en
Publication of CN108841170A publication Critical patent/CN108841170A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2251Oxides; Hydroxides of metals of chromium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/28Nitrogen-containing compounds
    • C08K2003/282Binary compounds of nitrogen with aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/06Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of automobile instrument panel shell, including shell, it is characterized in that, shell is made of engineering plastics, iAlN is 0.1-1%, Al2O3 0.3-1%, CrO2 0.1-1%, SiN 0.1-1%, diamond 0.1-5%, polyethanol 0.5-2%, PA635-50%, ABS8-15%, bromide fire retardant 12-20%, the 4-6% of fire retarding synergist containing antimony, compatilizer 2-5%, toughener 3-6%, antioxidant 0.2-0.6%, glass fibre 15-35%, processing aid 0.3-1%, remaining is engineering plastics original powder.2. a kind of modified engineered plastic formula according to claim 1, it is characterised in that:The engineering plastics are prepared by the raw material of following weight percentage:IAlN is 0.5%, Al2O3 0.6%, CrO2 0.5%, SiN 0.5%, diamond 2.5%, polyethanol 1.3%, PA642.5%, ABS11.5%, bromide fire retardant 16%, fire retarding synergist containing antimony 5%, compatilizer 3.5%, toughener 4.5%, antioxidant 0.4%, glass fibre 25%, processing aid 0.6%, further includes 3% toughened master batch.The shell is safer.

Description

Automobile instrument panel shell
Technical field
The present invention relates to automobile instrument fields, and in particular to the production of the shell of instrument board.
Background technique
Existing automobile instrument panel using engineering plastics as shell, when colliding, instrument board fragmentation will cause compared with Big danger, improving shell toughness is effective ways.
Summary of the invention
The purpose of the present invention is to provide a kind of automobile instrument panel shell with higher toughness.
To achieve the goals above, the present invention includes a kind of automobile instrument panel shell, including shell, which is characterized in that shell Body is made of engineering plastics, iAlN 0.1-1%, Al2O3 0.3-1%, CrO2 0.1-1%, SiN 0.1-1%, artificial Diamond is 0.1-5%, polyethanol 0.5-2%, PA635-50%, ABS8-15%, bromide fire retardant 12-20%, contains antimony resistance Combustion synergist 4-6%, compatilizer 2-5%, toughener 3-6%, antioxidant 0.2-0.6%, glass fibre 15-35%, processing help Agent 0.3-1%, remaining is engineering plastics original powder.2. a kind of modified engineered plastic formula according to claim 1, feature It is:The engineering plastics are prepared by the raw material of following weight percentage:IAlN is 0.5%, Al2O3 0.6%, CrO2 are 0.5%, SiN 0.5%, diamond 2.5%, polyethanol 1.3%, PA642.5%, ABS11.5%, bromine system are fire-retardant Agent 16%, compatilizer 3.5%, toughener 4.5%, antioxidant 0.4%, glass fibre 25%, adds fire retarding synergist containing antimony 5% Work auxiliary agent 0.6% further includes 3% toughened master batch,
The toughened master batch is prepared by following methods:
A, using polypropylene, ethylene propylene diene rubber and butadiene-styrene elastomer as base stock, using dimethylbenzene as solvent;Described poly- third The additional amount of alkene, ethylene propylene diene rubber and butadiene-styrene elastomer is respectively 180~190kg, 70~90kg and 17~18kg, described molten The additional amount of agent dimethylbenzene is 3200~3300L;
B, solvent xylene is weighed according to various materials additional amount ratio described in step a, puts into reaction kettle, and add Enter weighed base stock polypropylene, ethylene propylene diene rubber and butadiene-styrene elastomer, be then stirred, heat, when temperature reaches At 120 DEG C~130 DEG C, be added under conditions of keeping temperature-resistant 24~26kg of bridging agent styrene and acrylic acid 32~ 35kg, stirring are allowed to be uniformly dispersed, and 3~4kg of initiator benzoyl peroxide is then added, and it is small to react 2~3 at this temperature When, 2~2.5kg of antioxidant is added at the end of reaction and is uniformly mixing to obtain reaction mass;
C, kettle is extracted in the reaction mass injection obtained step b, and addition accounts for 2.5~3 times of reaction mass weight of distilled water, Solvent xylene is extracted, brilliant liquid mixture is obtained;
D, the brilliant liquid mixture that step c is obtained is separated, and obtains crystal;
E, the obtained crystal of step d is dried, it is dry female to get product toughening less than 0.5% to crystal moisture content Material
Remaining is engineering plastics original powder.
The beneficial effects of the present invention are can effectively improve shell toughness, and then improve the safety of shell.
Specific embodiment
A kind of automobile instrument panel shell, including shell, which is characterized in that shell is made of engineering plastics, iAlN 0.1- 1%, Al2O3 0.3-1%, CrO2 0.1-1%, SiN 0.1-1%, diamond 0.1-5%, polyethanol are 0.5-2%, PA635-50%, ABS8-15%, bromide fire retardant 12-20%, the 4-6% of fire retarding synergist containing antimony, compatilizer 2- 5%, toughener 3-6%, antioxidant 0.2-0.6%, glass fibre 15-35%, processing aid 0.3-1%, remaining is engineering plastic Expect original powder.2. a kind of modified engineered plastic formula according to claim 1, it is characterised in that:The engineering plastics are by following The raw material of weight percent is prepared:IAlN is 0.5%, Al2O3 0.6%, CrO2 0.5%, SiN 0.5%, artificial Diamond is 2.5%, polyethanol 1.3%, PA642.5%, ABS11.5%, bromide fire retardant 16%, fire retarding synergist containing antimony 5%, compatilizer 3.5%, toughener 4.5%, antioxidant 0.4%, glass fibre 25%, processing aid 0.6%, further include 3% Toughened master batch,
The toughened master batch is prepared by following methods:
A, using polypropylene, ethylene propylene diene rubber and butadiene-styrene elastomer as base stock, using dimethylbenzene as solvent;Described poly- third The additional amount of alkene, ethylene propylene diene rubber and butadiene-styrene elastomer is respectively 180~190kg, 70~90kg and 17~18kg, described molten The additional amount of agent dimethylbenzene is 3200~3300L;
B, solvent xylene is weighed according to various materials additional amount ratio described in step a, puts into reaction kettle, and add Enter weighed base stock polypropylene, ethylene propylene diene rubber and butadiene-styrene elastomer, be then stirred, heat, when temperature reaches At 120 DEG C~130 DEG C, be added under conditions of keeping temperature-resistant 24~26kg of bridging agent styrene and acrylic acid 32~ 35kg, stirring are allowed to be uniformly dispersed, and 3~4kg of initiator benzoyl peroxide is then added, and it is small to react 2~3 at this temperature When, 2~2.5kg of antioxidant is added at the end of reaction and is uniformly mixing to obtain reaction mass;
C, kettle is extracted in the reaction mass injection obtained step b, and addition accounts for 2.5~3 times of reaction mass weight of distilled water, Solvent xylene is extracted, brilliant liquid mixture is obtained;
D, the brilliant liquid mixture that step c is obtained is separated, and obtains crystal;
E, the obtained crystal of step d is dried, it is dry female to get product toughening less than 0.5% to crystal moisture content Material
Remaining is engineering plastics original powder.
The foregoing is merely the preferred embodiment of the present invention, are not intended to restrict the invention, for those skilled in the art For member, the invention may be variously modified and varied.All any modifications in spirit of that invention and principle, made are equal Replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (2)

1. a kind of automobile instrument panel shell, including shell, which is characterized in that shell is made of engineering plastics, iAlN 0.1- 1%, Al2O3 0.3-1%, CrO2 0.1-1%, SiN 0.1-1%, diamond 0.1-5%, polyethanol are 0.5-2%, PA635-50%, ABS8-15%, bromide fire retardant 12-20%, the 4-6% of fire retarding synergist containing antimony, compatilizer 2- 5%, toughener 3-6%, antioxidant 0.2-0.6%, glass fibre 15-35%, processing aid 0.3-1%, remaining is engineering plastic Expect original powder, further includes 3% toughened master batch.
2. a kind of modified engineered plastic formula according to claim 1, it is characterised in that:The engineering plastics are by following weight The raw material of percentage is prepared:IAlN is 0.5%, Al2O3 0.6%, CrO2 0.5%, SiN 0.5%, artificial diamond Stone is 2.5%, polyethanol 1.3%, PA642.5%, ABS11.5%, bromide fire retardant 16%, fire retarding synergist containing antimony 5%, Compatilizer 3.5%, toughener 4.5%, antioxidant 0.4%, glass fibre 25%, processing aid 0.6% further include 3% increasing Tough masterbatch,
The toughened master batch is prepared by following methods:
A, using polypropylene, ethylene propylene diene rubber and butadiene-styrene elastomer as base stock, using dimethylbenzene as solvent;The polypropylene, The additional amount of ethylene propylene diene rubber and butadiene-styrene elastomer is respectively 180~190kg, 70~90kg and 17~18kg, the solvent The additional amount of dimethylbenzene is 3200~3300L;
B, solvent xylene is weighed according to various materials additional amount ratio described in step a, puts into reaction kettle, and title is added Base stock polypropylene, ethylene propylene diene rubber and the butadiene-styrene elastomer taken, is then stirred, heats, when temperature reaches 120 DEG C At~130 DEG C, 24~26kg of bridging agent styrene and 32~35kg of acrylic acid, stirring are added under conditions of keeping temperature-resistant It is allowed to be uniformly dispersed, 3~4kg of initiator benzoyl peroxide is then added, react 2~3 hours at this temperature, reaction terminates When be added 2~2.5kg of antioxidant be uniformly mixing to obtain reaction mass;
C, kettle is extracted in the reaction mass injection obtained step b, and addition accounts for 2.5~3 times of reaction mass weight of distilled water, will be molten Agent dimethylbenzene extracts, and obtains brilliant liquid mixture;
D, the brilliant liquid mixture that step c is obtained is separated, and obtains crystal;
E, the obtained crystal of step d is dried, drying is to crystal moisture content less than 0.5% to get product toughened master batch
Remaining is engineering plastics original powder.
CN201810604986.1A 2018-06-12 2018-06-12 Automobile instrument panel shell Withdrawn CN108841170A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810604986.1A CN108841170A (en) 2018-06-12 2018-06-12 Automobile instrument panel shell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810604986.1A CN108841170A (en) 2018-06-12 2018-06-12 Automobile instrument panel shell

Publications (1)

Publication Number Publication Date
CN108841170A true CN108841170A (en) 2018-11-20

Family

ID=64210953

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810604986.1A Withdrawn CN108841170A (en) 2018-06-12 2018-06-12 Automobile instrument panel shell

Country Status (1)

Country Link
CN (1) CN108841170A (en)

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Application publication date: 20181120

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