CN108840602A - A kind of volcanic association object plate, profile and production method - Google Patents
A kind of volcanic association object plate, profile and production method Download PDFInfo
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- CN108840602A CN108840602A CN201810604074.4A CN201810604074A CN108840602A CN 108840602 A CN108840602 A CN 108840602A CN 201810604074 A CN201810604074 A CN 201810604074A CN 108840602 A CN108840602 A CN 108840602A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/127—Urea formaldehyde condensation polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Cultivation Of Plants (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The present invention relates to a kind of volcanic association object plates, profile, are made from the following raw materials in parts by weight：Volcanic rock 100-110, graphene 10-15, potassium permanganate 2-5, urea-formaldehyde resin adhesive 30-50, ardealite 1-2, stalk 1-2, dregs of a decoction 0.1-0.2.Using volcanic rock as basic raw material, graphene is added, while making full use of trade waste and agriculture and forestry organic waste material, products obtained therefrom is light, has excellent performance.
Description
Technical field
The present invention relates to building, house ornamentation field, i.e., a kind of volcanic association object plate, profile and production methods.
Background technique
With the continuous improvement of China's economic strength gradually increased with scientific and technological level, government adopts in terms of building field
With advanced power-saving technology, the energy saving pay attention to day by day of energy-saving material and approval.In the prior art, it builds, is organic in house ornamentation
Plate, profile are gradually going up because of scarcity of resources, price, and future will can not meet the market demand.At present in construction and decoration,
The material of indoor paving ground or dado decoration generally uses wooden, stone matter or porcelain, and effect and performance are each has something to recommend him, and installation is also
It is simplified and traditional different.
CN201610246103.5 discloses a kind of volcanic association object plate, profile, is made of the raw material of following weight ratio：
The dregs of a decoction：Volcanic rock：Stalk：Polyvinyl chloride=15-25：25-35：25-35：15-25.Volcanic association object plate, profile production
Method, its step are as follows：Raw material dried, crushed, is sieved, in proportion ingredient, stir evenly, be glued, mating formation, hot pressing and squeezing
Up to plate, profile after cured.
CN200710066440.7 discloses a kind of volcano honeycomb stone stuck bamboo sheet elastic plate of temperature controllable, including honeycomb stone
Plate, bamboo chip and rubber sheet gasket, volcano honeycomb stone board bottom level are provided at least 1 thermal trough, the round floor bonding in addition to thermal trough
There is rubber sheet gasket, slabstone face layer is bonded with bamboo chip；Thermal trough can be longitudinal slot, transverse groove or shaped groove, thermally conductive channel section
For arc or rectangular；Rubber sheet gasket is with a thickness of 0.2~2cm；In use, first setting up keel on ground to be laid or metope
Item, the good water pipe of device in advance under keel shoe, injects hot water or cold water into water pipe as needed, through heat transmitting heat dissipation or
Heat absorption, then by the thermal trough of slabstone, entire floor, metope is made all to play heat dissipation or heat-absorbing action, there is temperature adjustment function, due to
Add with rubber sheet gasket, greatly strengthen the elasticity of plate, it is one kind that it is not only beautiful and can save a large amount of timber, which to do superficial layer using bamboo,
Good interior decoration plate.
CN201410044667.1 discloses a kind of inorganic mineral lumber, profile, and the raw material including following weight ratio is made：
Diatomite：Shell powder：Pine needle meal=35-45：20-30：30-40；Or boron mud：Shell powder：Pine needle meal=30-40：25-35：
30-40；Or calcium carbonate：Shell powder：Pine needle meal=20-30：35-40：35-40；Or diatomite：Shell powder：Straw powder=30-
35：20-30：40-45；Or boron mud：Shell powder：Straw powder=30-40：20-25：40-45；Or calcium carbonate：Shell powder：Straw powder
=20-30：30-35：40-45.
CN200610048831.1 discloses a kind of volcanic rock bound wooden plate, takes the length, of same size of machine-shaping
Volcano honeycomb slabstone and solid wood board, solid wood board 60 degree boiling 24 hours, be warming up to 80 degree of boiling 76~100 hours again, then
It cools to 40 degree of taking-ups to dry in the shade 3~15 days, uniformly be applied on the corresponding bonding plane of stand-by volcano honeycomb slabstone and solid wood board respectively
Cloth adhesive latex is aligned bonding after standing 3~6 minutes, through cold pressing treatment, 70~80kg/m of pressure2It is lower to be kept for 24 hours, it is natural
Its fastening adhesion of at least 7 angels is stood at 15~35 DEG C of temperature, the volcanic rock bound wooden plate provided maintains both stone wood
Advantage overcomes its disadvantage, is formed with the non-toxic adhesive glue bond without formaldehyde through cold pressing treatment.With it is elastic, moisture-proof, fire prevention,
Sound insulation, it is heat-insulated, heat preservation, it is indeformable, easy for installation, can save a large amount of keel strip and glued laminated board, can directly with mixed mud glue
It connects.
CN200610065286.7 discloses a kind of stone plastic composite materials and the composite plate made of the material, component
And weight proportion is：Mountain flour 40, Corvic 30, Plant Powder 30.The mountain flour, Corvic and crops powder
Fineness is 300-800 mesh respectively.The mountain flour is at least one of powdered whiting and precipitated calcium carbonate mountain flour.The plant
Powder is at least one of straw powder, cotton stem powder and weedtree powder.
CN200510018195.3, which is disclosed, utilizes the materials such as the production wood-based plate of solid slag caused by saponin producing process
Method.It is characterized in that waste saponin residue is uniformly mixed with certain proportion adhesive and curing agent, in certain temperature and pressure item
Under part, for a period of time, shaping substrate or base-material is made in hot pressing.After overcuring and corner arrange, then in its surface sprayed coating
The processing such as layer, or decorative cover is pasted, the materials such as the wood-based plate of extensive use are made.
CN201510414284.3 discloses a kind of sound-absorbing sound insulation ecology high density fiberboard, by the raw material system of following parts by weight
It prepares into：Sodium hydroxide q.s. that agricultural crop straw 42-45, concentration are 2%, silane coupling agent kh450 2-2.5, concentration are
95% ethyl alcohol 66-70, wood leftover material 30-32, Aqueous Polyurethane Adhesives 7-8, emulsified wax 1.5-2, appropriate amount of water, zeolite
Molecular sieve 4-6, graphene 2.5-3.5, cordate houttuynia 5-7, flax complete stool 3-4, epoxidized soybean oil 1-2.By the basis of traditional handicraft
On surface treatment appropriate has been carried out to ingredients such as agricultural crop straw, the wood leftover materials used, a large amount of forest can be saved
Resource, and containing zeolite molecular sieve etc. in inorganic agent, porous ingredient is generated with natural plant fibre cooperation, increases sound-absorbing
Soundproof effect.
CN201610590339.0 discloses a kind of high-strength carbon fiber wood composite fiberboard, by the raw material of following parts by weight
It is made：The chopped carbon fiber of wood-fibred 100-110, urea-formaldehyde resin adhesive 10-11, nano nickel 10-11, appropriate dehydrated alcohol, 5-8mm
Tie up 33-35, acetone 1.7-1.9, isocyanate resin adhesive 3.3-3.5, ammonium chloride 5.6-5.9, nano-titanium dioxide 2.5-3,
Carboxylated graphene 2.2-2.5, cobalt oxide 1.5-1.8, sodium borohydride 2-2.3.
CN201510413745.5 discloses a kind of heat-resisting rubber powder of waste tire modified bamboo fiber plate, by following parts by weight
Raw material is made：Bamboo fibre 162-164,0.2% sodium hydroxide solution be appropriate, soybean protein isolate 16.2-16.7, preservative 1.5-
1.6, rubber powder of waste tire 7-8, carboxylated graphene 2-3, polyaminoester emulsion 2-3, cashew nut shell oil 0.5-0.7, micron order bamboo
Powdered carbon 1-2.Bamboo fibre plate is modified using rubber powder of waste tire, and the surface exhibits of plate go out good hydrophobicity；Pass through
Using carboxylated graphene, polyaminoester emulsion, micron order bamboo charcoal powder, so that plate has good heat resistance, high toughness.
New material high performance, multifunction, greenization development trend are complied with, characteristic resources new material sustainable development is pushed
Forward position material layout is reinforced in exhibition, is guiding with strategic emerging industries and key project construction demand, optimizes new material industrialization
And application environment, reinforce new material Standard System Construction, it is horizontal to improve new material application.
Prediction layout forward position new material research and development.Break through graphene industrial application technology, expand nano material photoelectron,
The fields such as new energy, biological medicine application range forms the innovation achievement that a batch has drive property extensively.
Bulk solid waste and comprehensive utilization of tailing are pushed energetically.Push metallurgical slag, residue of chemical industry, red mud, ardealite etc.
Industrial waste comprehensive utilization is promoted a collection of advanced and applicable technology and equipment, is reinforced to strategic dilute in industrial solid castoff
The recycling of noble metal.
Reinforce agriculture and forestry organic waste material to recycle.It is basic to realize that feces of livestock and poultry, residual film, agricultural crop straw, forestry three remain object etc.
Agriculture and forestry organic waste material resource utilization.
Existing plate-making method, method and prepared material respectively have its not perfect place, and such as there is raw material varieties
It is single, the problems such as manufacturing method is coarse, and plate property is insufficient.
Summary of the invention
The present invention provides a kind of volcanic association object plates, profile to add graphite using volcanic rock as basic raw material
Alkene, while trade waste and agriculture and forestry organic waste material are made full use of, products obtained therefrom is light, has excellent performance.
The technical scheme is that：A kind of volcanic association object plate, is made from the following raw materials in parts by weight：Volcanic rock
100-110, graphene 10-15, potassium permanganate 2-5, urea-formaldehyde resin adhesive 30-50, ardealite 1-2, stalk 1-2, the dregs of a decoction
0.1-0.2。
The preparation method of volcanic association object plate of the invention, includes the following steps：
1) graphene and potassium permanganate being mixed, suitable quantity of water, wet ball grinding 1-2h is added, room temperature dries, it is denoted as product A,
It is spare；
2) by stalk, the direct ball mill grinding of the dregs of a decoction, ball milling 1-2h is denoted as product B, spare；
3) volcanic rock, ardealite are mixed, wet ball grinding 2-3h, is added obtained by the resulting product A of step 1) and step 2)
Product B, ball milling 2-3h；
4) the resulting product of step 3) is uniformly mixed, compression forming with urea-formaldehyde resin adhesive, cures, plate is made.
Further, the wet ball grinding time of step 1) is 1.5h, room temperature flash-off time 1-3h；
Further, the Ball-milling Time of step 2) is 1.5h；
Further, the wet ball grinding time of step 3) is 2.5h；The Ball-milling Time is 2.5h；
Further, the compression forming of step 4), pressure 3-5MPa, time 1-2h；
Further, the curing of step 4), time 1-3d.
Wherein, in the wet ball grinding of graphene and potassium permanganate, the surface of graphene generates a large amount of hydroxyl, carboxyl-functional
Group, these oxygen-containing functional groups have fabulous hydrophily and polarity, and stalk contains a large amount of cellulose, can with containing hydroxyl,
The graphene of carboxyl fully interacts, and effectively improves the performance of gained volcanic association object plate.
Volcanic rock surface is uniformly covered with stomata, material environmental protection, and the air hole structure of volcanic rock not only makes final product matter
Gently, while this air hole structure enables graphene to combine closely with it, more effectively improves volcanic association object plate
Elastic property.
The part methylol and hydroxyl retained in Lauxite has stronger affinity (for example forming hydrogen bond), effectively
With the graphene containing hydroxyl, carboxyl, and with stalk stronger active force is formed, guarantee the property of volcanic association object plate
Energy.
Ardealite is rationally utilized as trade waste, by it, significantly reduces the production of volcanic association object plate
Cost, the calcium constituent in ardealite can combine closely with the cellulose in stalk, the dregs of a decoction, improve volcanic association object plate
Performance.
Beneficial effects of the present invention：
1, cost of the invention is low, makes full use of trade waste ardealite and agriculture and forestry organic waste material stalk, the dregs of a decoction.
2, graphene of the invention obtains a large amount of hydroxyl in surface, carboxyl after potassium permanganate oxidation, makes it in volcanic rock
The effect that graphene is given full play in composition plate makes it combine closely with other raw materials.
3, volcanic rock of the invention provides a large amount of stomata, has both guaranteed the light of product, while this stomata becomes graphite
The aggregation place of alkene, stalk, is tightly combined.
4, the carboxymethyl of Lauxite of the invention, hydroxyl, can with graphene, volcanic rock, stalk, the dregs of a decoction, formed compared with
Strong active force, performance are more excellent.
5, volcanic association object plate of the invention is light, function admirable.
Specific embodiment
Embodiment 1
A kind of volcanic association object plate, is made from the following raw materials in parts by weight：Volcanic rock 100, graphene 10, permanganic acid
Potassium 2, urea-formaldehyde resin adhesive 30, ardealite 1, stalk 1, the dregs of a decoction 0.1.
It includes the following steps：
1) graphene and potassium permanganate being mixed, suitable quantity of water, wet ball grinding 1h is added, room temperature dries 1h, is denoted as product A,
It is spare；
2) by stalk, the direct ball mill grinding of the dregs of a decoction, ball milling 1h is denoted as product B, spare；
3) volcanic rock, ardealite are mixed, wet ball grinding 2h, the resulting product A of step 1) is added and step 2) is resulting
Product B, ball milling 2h；
4) the resulting product of step 3) is uniformly mixed with urea-formaldehyde resin adhesive, compression forming, pressure 3MPa, the time
For 1h, 1d is cured, plate is made.
Embodiment 2
A kind of volcanic association object plate, is made from the following raw materials in parts by weight：Volcanic rock 110, graphene 15, permanganic acid
Potassium 5, urea-formaldehyde resin adhesive 50, ardealite 2, stalk 2, the dregs of a decoction 0.2.
It includes the following steps：
1) graphene and potassium permanganate being mixed, suitable quantity of water, wet ball grinding 2h is added, room temperature dries 3h, is denoted as product A,
It is spare；
2) by stalk, the direct ball mill grinding of the dregs of a decoction, ball milling 2h is denoted as product B, spare；
3) volcanic rock, ardealite are mixed, wet ball grinding 3h, the resulting product A of step 1) is added and step 2) is resulting
Product B, ball milling 3h；
4) the resulting product of step 3) is uniformly mixed with urea-formaldehyde resin adhesive, compression forming, pressure 5MPa, the time
For 2h, 3d is cured, plate is made.
Embodiment 3
A kind of volcanic association object plate, is made from the following raw materials in parts by weight：Volcanic rock 104, graphene 12, permanganic acid
Potassium 3, urea-formaldehyde resin adhesive 35, ardealite 1, stalk 1, the dregs of a decoction 0.15.
It includes the following steps：
1) graphene and potassium permanganate are mixed, suitable quantity of water, wet ball grinding 1.2h is added, room temperature dries 1.3h, is denoted as production
Object A, it is spare；
2) by stalk, the direct ball mill grinding of the dregs of a decoction, ball milling 1.2h is denoted as product B, spare；
3) volcanic rock, ardealite are mixed, wet ball grinding 2.3h, is added obtained by the resulting product A of step 1) and step 2)
Product B, ball milling 2.3h；
4) the resulting product of step 3) is uniformly mixed with urea-formaldehyde resin adhesive, compression forming, pressure 3.5MPa, when
Between be 1.2h, cure 1.3d, plate is made.
Embodiment 4
A kind of volcanic association object plate, is made from the following raw materials in parts by weight：Volcanic rock 110, graphene 15, permanganic acid
Potassium 2, urea-formaldehyde resin adhesive 30, ardealite 2, stalk 2, the dregs of a decoction 0.2.
It includes the following steps：
1) graphene and potassium permanganate being mixed, suitable quantity of water, wet ball grinding 2h is added, room temperature dries 2h, is denoted as product A,
It is spare；
2) by stalk, the direct ball mill grinding of the dregs of a decoction, ball milling 2h is denoted as product B, spare；
3) volcanic rock, ardealite are mixed, wet ball grinding 3h, the resulting product A of step 1) is added and step 2) is resulting
Product B, ball milling 2h；
4) the resulting product of step 3) is uniformly mixed with urea-formaldehyde resin adhesive, compression forming, pressure 4MPa, the time
For 2h, 3d is cured, plate is made.
Embodiment 1 (i.e. comparative example 1) foundation of four kinds of plates and CN201610246103.5 in above-described embodiment《People
Make plate and face artificial board physicochemical property test method》The partial properties index of (GBT 17657-1999) measurement see the table below.
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 |
| Density g/cm3 | 0.65 | 0.60 | 0.61 | 0.55 | 0.85 |
| Static bending strength MPa | 26 | 28 | 26 | 30 | 20-21 |
| Elasticity modulus MPa | 2420 | 2350 | 2450 | 2400 | 2000-2235Mpa |
| Plate face supine human body N | 1800 | 1900 | 1850 | 1800 | 1500 |
It can be seen that volcanic association object plate property of the invention is excellent, density is lower than 0.70g/cm3, static bending strength is higher than
25MPa, elasticity modulus are higher than 2300MPa, and plate face supine human body is higher than 1700N.
Claims (7)
1. a kind of volcanic association object plate and preparation method thereof, is made from the following raw materials in parts by weight：Volcanic rock 100-110,
Graphene 10-15, potassium permanganate 2-5, urea-formaldehyde resin adhesive 30-50, ardealite 1-2, stalk 1-2, dregs of a decoction 0.1-0.2.
2. plate according to claim 1 and preparation method thereof, includes the following steps：
1) graphene and potassium permanganate are mixed, suitable quantity of water, wet ball grinding 1-2h is added, room temperature dries, and is denoted as product A, spare；
2) by stalk, the direct ball mill grinding of the dregs of a decoction, ball milling 1-2h is denoted as product B, spare；
3) volcanic rock, ardealite are mixed, wet ball grinding 2-3h, the resulting product A of step 1) and the resulting production of step 2) is added
Object B, ball milling 2-3h；
4) the resulting product of step 3) is uniformly mixed, compression forming with urea-formaldehyde resin adhesive, cures, plate is made.
3. the wet ball grinding time of plate according to claim 1 and preparation method thereof, step 1) is 1.5h, room temperature dries
Time 1-3h.
4. plate according to claim 1 and preparation method thereof, the Ball-milling Time of step 2) is 1.5h.
5. plate according to claim 1 and preparation method thereof, the wet ball grinding time of step 3) is 2.5h；The ball milling
Time is 2.5h.
6. plate according to claim 1 and preparation method thereof, the compression forming of step 4), pressure 3-5MPa,
Time is 1-2h.
7. plate according to claim 1 and preparation method thereof, the curing of step 4), time 1-3d.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810604074.4A CN108840602B (en) | 2018-06-13 | 2018-06-13 | volcanic rock composition plate, section bar and manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810604074.4A CN108840602B (en) | 2018-06-13 | 2018-06-13 | volcanic rock composition plate, section bar and manufacturing method |
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| Publication Number | Publication Date |
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| CN108840602A true CN108840602A (en) | 2018-11-20 |
| CN108840602B CN108840602B (en) | 2020-01-31 |
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| US20150345132A1 (en) * | 2014-05-30 | 2015-12-03 | Guang Zhou Zong Bao Xian Wei Zhi Pin Co., Ltd. | Fiber reinforcement fire-proof thermal insulation plate and preparation process thereof |
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