CN108827044A - Two circuit heat-exchange systems and heat-exchange method for biomass fluidized bed gasification furnace - Google Patents

Two circuit heat-exchange systems and heat-exchange method for biomass fluidized bed gasification furnace Download PDF

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Publication number
CN108827044A
CN108827044A CN201810802906.3A CN201810802906A CN108827044A CN 108827044 A CN108827044 A CN 108827044A CN 201810802906 A CN201810802906 A CN 201810802906A CN 108827044 A CN108827044 A CN 108827044A
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China
Prior art keywords
heat
oil
conduction oil
fluidized bed
exchange
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Pending
Application number
CN201810802906.3A
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Chinese (zh)
Inventor
孙向文
王君峰
姜雪
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Harbin Boiler Co Ltd
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Harbin Boiler Co Ltd
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Priority to CN201810802906.3A priority Critical patent/CN108827044A/en
Publication of CN108827044A publication Critical patent/CN108827044A/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F23/00Features relating to the use of intermediate heat-exchange materials, e.g. selection of compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0916Biomass

Abstract

Two circuit heat-exchange systems and heat-exchange method for biomass fluidized bed gasification furnace.The gasification burning temperature of output is 700 ~ 800 DEG C, conveying equipment type selecting is relatively difficult, it cannot achieve the conveying of high-temperature gasification combustion gas, gasification burning temperature starts that tar is precipitated when being lower than 350 DEG C, can be bonded in exchanger tube wall after precipitation or even can block heat exchanger causes equipment to be stopped transport, and cannot thoroughly solve the problems, such as that tar is precipitated by soot blower.The present invention forms:Heat-exchanging loop and store loop, the heat-exchanging loop include oil gas heat exchanger(4)With oil water heat exchange device(5), the conduction oil outlet of the oil gas heat exchanger is connected to the heat conducting oil inlet of the oil water heat exchange device, the heat conducting oil inlet and conduction oil expansion drum of the oil gas heat exchanger(2)Conduction oil outlet pass through heat conduction oil circulating pump(3)Connection.The present invention is used for the two circuit heat-exchange systems and heat-exchange method of biomass fluidized bed gasification furnace.

Description

Two circuit heat-exchange systems and heat-exchange method for biomass fluidized bed gasification furnace
Technical field:
The present invention relates to a kind of gasification furnace heat-exchange systems, and in particular to a kind of two circuits for biomass fluidized bed gasification furnace are changed Hot systems and heat-exchange method.
Background technique:
As the requirement of Environmental protection is continuously improved, the importance of the renewable energy such as biomass is gradually increased, country The multinomial file of successively issue, energetically biological support matter generation technology application.
China's biomass energy is at present mainly based on agriculture and forestry organic waste material, and agricultural wastes are mainly agricultural crop straw, mainly Based on corn, wheat, paddy stalk, calorific value is annual for the stalk amount of resource utilization in 3000-3500kcal/kg About 400,000,000 tons, amount of storage is huge.
Biomass Energy Utilization mode there are several types of:1, pure fired biomass generation technology(Direct combustion power generation);2, biomass Mix burning generation technology;3, boiler and biomass coupled electricity-generation technology.
Wherein boiler has following advantage compared to other two kinds with biomass coupled electricity-generation technology:It is measurable to mix burning amount, energy Enjoy national preferential policy;Can be by large-sized unit high parameter advantage, generating efficiency is high;It can be real by large-sized unit environment-friendly advantage Now minimum discharge.Therefore, biomass coupled electricity-generation technology will be greatly developed and be promoted in the near future.
Biomass fuel gasifies in gasification furnace generates biological fuel gas, and biological fuel gas is defeated after cyclone dedusting Out.Since the gasification burning temperature of output is higher, about 700 ~ 800 DEG C, conveying equipment type selecting is relatively difficult, or even cannot achieve The conveying of high-temperature gasification combustion gas.In order to guarantee the service condition of upstream device, contain in the gasification burning generated after gasification of biomass There is a small amount of tar, starts to be precipitated when gasification burning temperature is lower than 350 DEG C.Tar can be bonded in exchanger tube wall after being precipitated, And can constantly in conjunction with the flying dust in gasification burning, not only can heat exchanger heat transfer influential effect, or even heat exchanger can be blocked and led It causes equipment to stop transport, cannot thoroughly solve the problems, such as that tar is precipitated by soot blower.
Summary of the invention:
Present invention aim to address the odd gasification burning temperature height of existing gasification furnace cannot achieve conveying, and temperature is too low to be caused The problem of tar is precipitated, provide it is a kind of by control heat conducting oil inlet temperature control gasification burning outlet temperature for biomass The two circuit heat-exchange systems and heat-exchange method of fluidized-bed gasification furnace.
Above-mentioned purpose is realized by following technical scheme:
A kind of two circuit heat-exchange systems for biomass fluidized bed gasification furnace, composition include:Heat-exchanging loop and store loop, The heat-exchanging loop includes oil gas heat exchanger and oil water heat exchange device, the conduction oil outlet of the oil gas heat exchanger and described The heat conducting oil inlet of oil water heat exchange device is connected to, the heat conducting oil inlet of the oil gas heat exchanger and the conduction oil of conduction oil expansion drum Outlet is connected by heat conduction oil circulating pump.
The two circuit heat-exchange systems for biomass fluidized bed gasification furnace, the store loop includes conduction oil Storage tank, the thermally conductive oil tank pass through piping connection with the oil gas heat exchanger and the conduction oil expansion drum respectively.
The two circuit heat-exchange systems for biomass fluidized bed gasification furnace, the conduction oil expansion drum it is thermally conductive Oil-in and discharge pump pass through piping connection.
The two circuit heat-exchange systems for biomass fluidized bed gasification furnace, the conduction oil of the oil water heat exchange device Outlet is connected to the entrance of the heat conduction oil circulating pump.
The two circuit heat-exchange systems for biomass fluidized bed gasification furnace, the cooling water of the oil water heat exchange device Entrance is connected to water supply system.
A kind of heat-exchange method of the two circuit heat-exchange systems for biomass fluidized bed gasification furnace, this method include following step Suddenly:Conduction oil is introduced into conduction oil expansion drum by conduction oil by discharge pump, is entered after boosting using heat conduction oil circulating pump Oil gas heat exchanger, the temperature for entering the conduction oil of oil gas heat exchanger is 210 DEG C or more, the high-temperature heat-conductive generated after heating It after oil is cooling in oil water heat exchange device, returns in the oil supply pipe of Heat-transfer Oil Pump, realizes recycling for conduction oil, oil gas heat exchange The temperature of flue gas is maintained at 350 DEG C in device, and thermally conductive oil tank is also provided in system, thermally conductive in system when system shutdown Oily all put into thermally conductive oil tank stores.
Beneficial effect:
1. the present invention is by control heat conducting oil inlet temperature at 210 DEG C or more, the temperature for controlling gasification burning arbitrary intervals is high In 350 DEG C, and there is certain nargin, it is entirely avoided tar has ensured oil gas heat exchange the problem of heating surface surface is precipitated The operation reliably and with long-term of device, substantially increases the availability of biomass fluidized bed gasification furnace equipment, to biomass fluid bed gasification The development of furnace technology is of great significance.
Oil gas heat exchanger is arranged in the present invention, for reducing the temperature of gasification burning, so that the outlet temperature of gasification burning exists 350 DEG C or more, conveying equipment type selecting is facilitated, realizes the conveying of high-temperature gasification combustion gas, while preventing the precipitation of gasification burning.
Oil water heat exchange device is arranged in the present invention, reduces for the temperature to conduction oil, and the thermally conductive oil temperature after reduction is high In 210 DEG C, guarantee the inlet temperature of conduction oil, to realize recycling for conduction oil.
Store loop is arranged in the present invention, and when system shutdown, the conduction oil in system, which is all put into thermally conductive oil tank, to be stored up It deposits, guarantees the safe operation of system.
The present invention uses conduction oil, because conduction oil still may be at liquid, the list of conduction oil at a higher temperature It mutually exchanges heat, keeps the stability that heat-exchange system is simple, runs high.
Detailed description of the invention:
Attached drawing 1 is structural schematic diagram of the invention;
In figure:1, discharge pump;2, conduction oil expansion drum;3, heat conduction oil circulating pump;4, oil gas heat exchanger;5, oil water heat exchange device;6, Water supply system;7, thermally conductive oil tank.
Specific embodiment:
Embodiment 1:
A kind of two circuit heat-exchange systems for biomass fluidized bed gasification furnace, composition include:Heat-exchanging loop and store loop, The heat-exchanging loop includes oil gas heat exchanger 4 and oil water heat exchange device 5, the conduction oil outlet of the oil gas heat exchanger with it is described Oil water heat exchange device heat conducting oil inlet connection, the heat conducting oil inlet of the oil gas heat exchanger and leading for conduction oil expansion drum 2 Hot oil outlet is connected by heat conduction oil circulating pump 3.
The entrance temperature control control in oil gas heat exchanger of conduction oil is at 210 DEG C or more, the outside wall surface temperature of oil gas heat exchanger It is maintained at 350 DEG C or more;
In system operation, the temperature that conduction oil enters oil gas heat exchanger is 210-320 DEG C, and outlet oil temperature is 260-370 DEG C, The flow of middle conduction oil is 100-500m3/h。
The inlet temperature of gasification burning is 800 DEG C, and outlet temperature is 450 DEG C, and the flow of gasification burning is 34500Nm3/h。
In system operation, conduction oil enters that the temperature of oil water heat exchange device is 260-370 DEG C, outlet oil temperature is 210-320 DEG C, the flow of conduction oil is 100 ~ 500m3/h;
The inlet water temperature of cooling water be 50 DEG C, exit water temperature I 150 DEG C(Water temperature is identical when working with oxygen-eliminating device), flow 45t/ h。
Embodiment 2:
According to the two circuit heat-exchange systems described in embodiment 1 for biomass fluidized bed gasification furnace, the store loop packet Thermally conductive oil tank 7 is included, the thermally conductive oil tank passes through with the oil gas heat exchanger and the conduction oil expansion drum respectively Piping connection.
Embodiment 3:
Two circuit heat-exchange systems of biomass fluidized bed gasification furnace are used for according to embodiment 1 or 2, the conduction oil to be swollen The heat conducting oil inlet and discharge pump 1 of swell pass through piping connection.
Embodiment 4:
Two circuit heat-exchange systems of biomass fluidized bed gasification furnace, the grease are used for according to embodiment 1 or 2 or 3 The conduction oil outlet of heat exchanger is connected to the entrance of the heat conduction oil circulating pump.
Embodiment 5:
Two circuit heat-exchange systems of biomass fluidized bed gasification furnace, the oil are used for according to embodiment 1 or 2 or 3 or 4 The cooling water inlet of water- to-water heat exchanger is connected to water supply system 6.
Embodiment 6:
A kind of heat-exchange method of the two circuit heat-exchange systems for biomass fluidized bed gasification furnace, this method comprises the following steps: Conduction oil is introduced into conduction oil expansion drum by conduction oil by discharge pump, enters oil gas after boosting using heat conduction oil circulating pump Heat exchanger, the temperature for entering the conduction oil of oil gas heat exchanger is 210 DEG C or more, and the high temperature heat conductive oil generated after heating exists In oil water heat exchange device after cooling, returns in the oil supply pipe of Heat-transfer Oil Pump, recycling for conduction oil is realized, in oil gas heat exchanger The temperature of flue gas is maintained at 350 DEG C, and thermally conductive oil tank is also provided in system, and when system shutdown, the conduction oil in system is complete Portion puts into thermally conductive oil tank and stores, and is that still may be at liquid at a higher temperature because of conduction oil using conduction oil, The single-phase heat exchange of conduction oil keeps the stability that heat-exchange system is simple, runs high.

Claims (6)

1. a kind of two circuit heat-exchange systems for biomass fluidized bed gasification furnace, composition include:It heat-exchanging loop and stores back Road, it is characterized in that:The heat-exchanging loop includes oil gas heat exchanger and oil water heat exchange device, the conduction oil of the oil gas heat exchanger Outlet is connected to the heat conducting oil inlet of the oil water heat exchange device, and the heat conducting oil inlet and conduction oil of the oil gas heat exchanger are swollen The conduction oil outlet of swell is connected by heat conduction oil circulating pump.
2. the two circuit heat-exchange systems according to claim 1 for biomass fluidized bed gasification furnace, it is characterized in that:It is described Store loop include thermally conductive oil tank, the thermally conductive oil tank respectively with the oil gas heat exchanger and the conduction oil Expansion drum passes through piping connection.
3. the two circuit heat-exchange systems according to claim 1 or 2 for biomass fluidized bed gasification furnace, it is characterized in that: The heat conducting oil inlet and discharge pump of the conduction oil expansion drum pass through piping connection.
4. the two circuit heat-exchange systems according to claim 1 or 2 or 3 for biomass fluidized bed gasification furnace, feature It is:The conduction oil outlet of the oil water heat exchange device is connected to the entrance of the heat conduction oil circulating pump.
5. the two circuit heat-exchange systems according to claim 1 or 2 or 3 or 4 for biomass fluidized bed gasification furnace, special Sign is:The cooling water inlet of the oil water heat exchange device is connected to water supply system.
6. the heat-exchange method described in a kind of claim 1-5 for two circuit heat-exchange systems of biomass fluidized bed gasification furnace, It is characterized in that:This method comprises the following steps:Conduction oil is introduced into conduction oil expansion drum by conduction oil by discharge pump, using Oil gas heat exchanger is entered after heat conduction oil circulating pump boosting, the temperature for entering the conduction oil of oil gas heat exchanger is 210 DEG C or more, It after the high temperature heat conductive oil generated after heating is cooling in oil water heat exchange device, returns in the oil supply pipe of Heat-transfer Oil Pump, realizes Conduction oil recycles, and the temperature of flue gas is maintained at 350 DEG C in oil gas heat exchanger, and thermally conductive oil tank is also provided in system, When system shutdown, the conduction oil in system, which is all put into thermally conductive oil tank, to be stored.
CN201810802906.3A 2018-07-20 2018-07-20 Two circuit heat-exchange systems and heat-exchange method for biomass fluidized bed gasification furnace Pending CN108827044A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112611238A (en) * 2020-12-17 2021-04-06 哈尔滨锅炉厂有限责任公司 Three-loop heat exchange system for biomass fluidized bed gasifier

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102243021A (en) * 2010-05-10 2011-11-16 中国石油天然气股份有限公司 Heat conducting oil smoke residual heat recovery method
CN203741285U (en) * 2014-03-24 2014-07-30 国电长源湖北生物质气化科技有限公司 Biomass hot fuel gas cooling system
CN105605776A (en) * 2016-03-03 2016-05-25 杭州锅炉集团股份有限公司 Heat transfer oil heat-exchanging energy-saving system
CN205774357U (en) * 2016-06-21 2016-12-07 中国华电科工集团有限公司 Biological fuel gas bootstrap system
CN107325847A (en) * 2017-08-04 2017-11-07 浙江大学 A kind of cooling of gas of high temperature pyrolysis and gasification containing tar and exhaust heat recovering method and device
CN208635619U (en) * 2018-07-20 2019-03-22 哈尔滨锅炉厂有限责任公司 The two circuit heat-exchange systems for biomass fluidized bed gasification furnace

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102243021A (en) * 2010-05-10 2011-11-16 中国石油天然气股份有限公司 Heat conducting oil smoke residual heat recovery method
CN203741285U (en) * 2014-03-24 2014-07-30 国电长源湖北生物质气化科技有限公司 Biomass hot fuel gas cooling system
CN105605776A (en) * 2016-03-03 2016-05-25 杭州锅炉集团股份有限公司 Heat transfer oil heat-exchanging energy-saving system
CN205774357U (en) * 2016-06-21 2016-12-07 中国华电科工集团有限公司 Biological fuel gas bootstrap system
CN107325847A (en) * 2017-08-04 2017-11-07 浙江大学 A kind of cooling of gas of high temperature pyrolysis and gasification containing tar and exhaust heat recovering method and device
CN208635619U (en) * 2018-07-20 2019-03-22 哈尔滨锅炉厂有限责任公司 The two circuit heat-exchange systems for biomass fluidized bed gasification furnace

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112611238A (en) * 2020-12-17 2021-04-06 哈尔滨锅炉厂有限责任公司 Three-loop heat exchange system for biomass fluidized bed gasifier

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