CN108822903A - A kind of gasoline additive and preparation method thereof - Google Patents
A kind of gasoline additive and preparation method thereof Download PDFInfo
- Publication number
- CN108822903A CN108822903A CN201810633060.5A CN201810633060A CN108822903A CN 108822903 A CN108822903 A CN 108822903A CN 201810633060 A CN201810633060 A CN 201810633060A CN 108822903 A CN108822903 A CN 108822903A
- Authority
- CN
- China
- Prior art keywords
- parts
- gasoline additive
- gasoline
- butyl alcohol
- tert
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003254 gasoline additive Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims abstract description 66
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 9
- FPVHRNMVXIUPGX-UHFFFAOYSA-N CCOC(C(O)(O)O)N Chemical compound CCOC(C(O)(O)O)N FPVHRNMVXIUPGX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 8
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 12
- OBOTXOMQYNJWJJ-UHFFFAOYSA-N 1-bromo-2-methylpropan-2-ol Chemical compound CC(C)(O)CBr OBOTXOMQYNJWJJ-UHFFFAOYSA-N 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 6
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 4
- 229960001124 trientine Drugs 0.000 claims description 4
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 239000003502 gasoline Substances 0.000 abstract description 20
- 230000000694 effects Effects 0.000 abstract description 10
- NNJVILVZKWQKPM-UHFFFAOYSA-N Lidocaine Chemical compound CCN(CC)CC(=O)NC1=C(C)C=CC=C1C NNJVILVZKWQKPM-UHFFFAOYSA-N 0.000 abstract description 8
- PFYXSUNOLOJMDX-UHFFFAOYSA-N bis(2,5-dioxopyrrolidin-1-yl) carbonate Chemical compound O=C1CCC(=O)N1OC(=O)ON1C(=O)CCC1=O PFYXSUNOLOJMDX-UHFFFAOYSA-N 0.000 abstract description 8
- 229960004194 lidocaine Drugs 0.000 abstract description 8
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical group NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- QZKXATFYGSKKFX-UHFFFAOYSA-N CCOC(C(O)(O)O)(N)OCC Chemical compound CCOC(C(O)(O)O)(N)OCC QZKXATFYGSKKFX-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000006079 antiknock agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000003747 fuel oil additive Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/26—Organic compounds containing phosphorus
- C10L1/2608—Organic compounds containing phosphorus containing a phosphorus-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
Abstract
The invention discloses a kind of gasoline additive, the component including following parts by weight：N, 10-20 parts of bis- succinimidyl carbonate of N-, bis- 5-10 parts of (2- ethoxy) amino (trihydroxy methyl) methane, 20-30 parts of ethylene amine tert-butyl alcohol, 3-5 parts of four (lignocaine) hafnium, bis- (2,4,6- tri-tert phenyl) 0.3-0.6 parts of pentaerythritol diphosphites.The invention also discloses the preparation methods of the gasoline additive, include the following steps：Each raw material is sequentially added in reaction kettle according to the ratio, after being stirred at room temperature 2-3 hours, 3-5 hours is stood, obtains gasoline additive.Gasoline additive disclosed by the invention has cheap, and obvious to gasoline performance improvement, vdiverse in function, oil-saving effect is more preferable, the advantages of using safety and environmental protection.
Description
Technical field
The present invention relates to a kind of fuel oil additives more particularly to a kind of gasoline additive and preparation method thereof.
Background technique
With society development and the improvement of people's living standards, the quantity of automobile is more and more, petroleum resources increasingly
Under the background that exhausted, Global Oil reserves increasingly decline, so that China is growing day by day to the demand of gasoline and the stone in China
The utilization rate of oil product, especially motor vehicle gasoline is generally lower, this not only causes the waste of gasoline, while also result in due to
The problem of atmosphere pollution aggravation of the generation of automobile exhaust pollutant.Therefore, motor vehicle exhaust emission pollution is reduced, gasoline is improved and exists
Efficiency of combustion, performance in automobile, energy saving, protection environment is extremely urgent.
Addition gasoline additive is to make up quality problems existing for gasoline itself and motor vehicle machine-building pole in the oil
Limit is existing insufficient, so that chill effect, gap effect can be overcome to petrol engine by reaching, removes intake valve, EFI mouth
Carbon distribution, improve efficiency of combustion, performance, it is energy saving, protect the effective ways of environment.The leaded of Universal efficient, iron are golden at present
Belong to class additive such as gasoline anti-knock agent lead tetraethide etc., although combustibility can be improved, octane number is improved, because of lead sheet
The Particulate Pollution that the toxicity of body and other metal based compounds can generate, seriously affects environment, and it is to engine cylinder
There is also harm with exhaust system.Other kinds of gasoline additive also more or less exists inconvenient for use in the prior art, section
Oily effect is undesirable, and environmental pollution is serious, has a single function, and when being applied in automobile, causes swelling to corrode automobile fuel pump, causes
Phenomena such as engine scuffing increases, and reduces service life of aeroengine is more serious, is unfavorable for the technology to the long term maintenance of automobile
Problem.
Therefore, it is obvious that a kind of pair of gasoline performance improvement is needed in the market, vdiverse in function, the better gasoline addition of oil-saving effect
Agent.
Summary of the invention
In order to overcome the defects of the prior art, the present invention provides a kind of gasoline additive and preparation method thereof, the preparation
Method and process is simple, it is cheap, be suitable for industrial applications；Overcome by the gasoline additive that the preparation method is prepared
Conventional gasoline additive is more or less existing inconvenient for use, and oil-saving effect is undesirable, environmental pollution is serious, has a single function,
When being applied in automobile, causes swelling to corrode automobile fuel pump, engine scuffing is caused to increase, reduce service life of aeroengine etc.
The technical issues of phenomenon is more serious, is unfavorable for the long term maintenance to automobile.It is bright to gasoline performance improvement with cheap
Aobvious, vdiverse in function, oil-saving effect is more preferable, the advantages of using safety and environmental protection.
To achieve the above object of the invention, the technical solution adopted by the present invention is that, a kind of gasoline additive, including following weight
The component of part：10-20 parts of bis- succinimidyl carbonate of N, N-, bis- (2- ethoxy) amino (trihydroxy methyl) methane 5-10
Part, 20-30 parts of ethylene amine tert-butyl alcohol, 3-5 parts of four (lignocaine) hafnium, bis- (2,4,6- tri-tert phenyl) pentaerythrites
0.3-0.6 parts of diphosphites.
Preferably, the preparation method of the ethylene amine tert-butyl alcohol, includes the following steps：Ethylene amine substance is dissolved in
Solution is formed in organic solvent, then bromo- tert-butyl alcohol is added thereto, reaction 6-8 hours is stirred at room temperature, back spin is evaporated off
Organic solvent is removed, ethylene amine tert-butyl alcohol is obtained.
Preferably, the mass ratio of the ethylene amine substance, organic solvent, bromo- tert-butyl alcohol is 1:(7-10):(2.5-
3.5)。
Preferably, the ethylene amine substance is selected from pentaethylene hexamine, tetraethylenepentamine, triethylene tetramine, divinyl three
One or more of amine.
Preferably, the organic solvent is selected from one or more of isopropanol, acetone, ether, methylene chloride.
Preferably, the preparation method of the gasoline additive, includes the following steps：Each raw material is sequentially added instead according to the ratio
It answers in kettle, after being stirred at room temperature 2-3 hours, stands 3-5 hours, obtain gasoline additive.
Generated beneficial effect is by adopting the above technical scheme：
1) gasoline additive provided by the invention, simple process, it is cheap, be suitable for industrial applications.
2) gasoline additive provided by the invention, it is more or less existing inconvenient for use to overcome conventional gasoline additive,
Oil-saving effect is undesirable, and environmental pollution is serious, has a single function, and when being applied in automobile, causes swelling to corrode automobile fuel pump, leads
Phenomena such as causing engine scuffing to increase, reducing service life of aeroengine is more serious, is unfavorable for the skill to the long term maintenance of automobile
Art problem.With cheap, obvious to gasoline performance improvement, vdiverse in function, oil-saving effect is more preferable, uses the excellent of safety and environmental protection
Point.
3) gasoline additive provided by the invention, each component cooperate, and mutually cooperate with, can significantly improve the pungent of gasoline
Alkane value improves gasoline antiknock performance, improves combustibility of the gasoline in gasoline engine, improves the thermal efficiency, reduce oil consumption, improves function
Rate reduces discharge of poisonous waste amount, extends the service life of gasoline engine, can effectively improve gasoline quality, and oil-saving effect is obvious,
So that the deposits such as its carbon distribution, colloid for playing the role of extremely strong removing and inhibition automotive oil system, improve the clear of automobile
Net property, anti-corrosive properties, lubrication friction, wear-resistant antirust, anti-corrosive keep gas supply system unobstructed, can effectively improve and promote gasoline combustion
Burning situation.
Specific embodiment
In order to make those skilled in the art more fully understand technical solution of the present invention, and make features described above of the invention,
Purpose and advantage are more clear understandable, and the present invention will be further explained with reference to the examples below.Embodiment is only used for
It is bright the present invention rather than limit the scope of the invention.
Present invention raw material as used in the following examples is from upper Haiquan sunrise foreign trade Co., Ltd.
Embodiment 1
A kind of gasoline additive, the component including following parts by weight：It is 10 parts of bis- succinimidyl carbonate of N, N-, double
5 parts of (2- ethoxy) amino (trihydroxy methyl) methane, 20 parts of ethylene amine tert-butyl alcohol, four 3 parts of (lignocaine) hafniums, it is bis- (2,
4,6- tri-tert phenyl) 0.3 part of pentaerythritol diphosphites.
The preparation method of the ethylene amine tert-butyl alcohol, includes the following steps：Pentaethylene hexamine 10g is dissolved in isopropanol
Solution is formed in 70g, then bromo- tert-butyl alcohol 25g is added thereto, reaction 6 hours is stirred at room temperature, back spin is evaporated off different
Propyl alcohol obtains ethylene amine tert-butyl alcohol.
The preparation method of the gasoline additive, includes the following steps：Each raw material is sequentially added in reaction kettle according to the ratio,
After being stirred at room temperature 2 hours, 3 hours are stood, gasoline additive is obtained.
Embodiment 2
A kind of gasoline additive, the component including following parts by weight：It is 12 parts of bis- succinimidyl carbonate of N, N-, double
It is 6 parts of (2- ethoxy) amino (trihydroxy methyl) methane, 22 parts of ethylene amine tert-butyl alcohol, four 3.5 parts of (lignocaine) hafniums, double
0.4 part of pentaerythritol diphosphites of (2,4,6- tri-tert phenyl).
The preparation method of the ethylene amine tert-butyl alcohol, includes the following steps：Tetraethylenepentamine 10g is dissolved in acetone
Solution is formed in 80g, then bromo- tert-butyl alcohol 28g is added thereto, reaction 6.5 hours is stirred at room temperature, back spin is evaporated off
Acetone obtains ethylene amine tert-butyl alcohol.
The preparation method of the gasoline additive, includes the following steps：Each raw material is sequentially added in reaction kettle according to the ratio,
After being stirred at room temperature 2.3 hours, 4 hours are stood, gasoline additive is obtained.
Embodiment 3
A kind of gasoline additive, the component including following parts by weight：It is 15 parts of bis- succinimidyl carbonate of N, N-, double
8 parts of (2- ethoxy) amino (trihydroxy methyl) methane, 25 parts of ethylene amine tert-butyl alcohol, four 4 parts of (lignocaine) hafniums, it is bis- (2,
4,6- tri-tert phenyl) 0.45 part of pentaerythritol diphosphites.
The preparation method of the ethylene amine tert-butyl alcohol, includes the following steps：Triethylene tetramine 10g is dissolved in ether
Solution is formed in 85g, then bromo- tert-butyl alcohol 30g is added thereto, reaction 7.2 hours is stirred at room temperature, back spin is evaporated off
Ether obtains ethylene amine tert-butyl alcohol.
The preparation method of the gasoline additive, includes the following steps：Each raw material is sequentially added in reaction kettle according to the ratio,
After being stirred at room temperature 2.6 hours, 4.2 hours are stood, gasoline additive is obtained.
Embodiment 4
A kind of gasoline additive, the component including following parts by weight：It is 18 parts of bis- succinimidyl carbonate of N, N-, double
It is 8 parts of (2- ethoxy) amino (trihydroxy methyl) methane, 28 parts of ethylene amine tert-butyl alcohol, four 4.5 parts of (lignocaine) hafniums, double
0.5 part of pentaerythritol diphosphites of (2,4,6- tri-tert phenyl).
The preparation method of the ethylene amine tert-butyl alcohol, includes the following steps：Diethylenetriamine 10g is dissolved in dichloromethane
Solution is formed in alkane 95g, then bromo- tert-butyl alcohol 33g is added thereto, reaction 7.5 hours is stirred at room temperature, back spin is evaporated off
Methylene chloride is removed, ethylene amine tert-butyl alcohol is obtained.
The preparation method of the gasoline additive, includes the following steps：Each raw material is sequentially added in reaction kettle according to the ratio,
After being stirred at room temperature 2.8 hours, 4.5 hours are stood, gasoline additive is obtained.
Embodiment 5
A kind of gasoline additive, the component including following parts by weight：It is 20 parts of bis- succinimidyl carbonate of N, N-, double
10 parts of (2- ethoxy) amino (trihydroxy methyl) methane, 30 parts of ethylene amine tert-butyl alcohol, four 5 parts of (lignocaine) hafniums, it is bis- (2,
4,6- tri-tert phenyl) 0.6 part of pentaerythritol diphosphites.
The preparation method of the ethylene amine tert-butyl alcohol, includes the following steps：Triethylene tetramine 10g is dissolved in isopropanol
Solution is formed in 100g, then bromo- tert-butyl alcohol 35g is added thereto, reaction 8 hours is stirred at room temperature, back spin is evaporated off different
Propyl alcohol obtains ethylene amine tert-butyl alcohol.
The preparation method of the gasoline additive, includes the following steps：Each raw material is sequentially added in reaction kettle according to the ratio,
After being stirred at room temperature 3 hours, 5 hours are stood, gasoline additive is obtained.
Comparative example 1
This example provides a kind of gasoline additive, and preparation method and formula are similar to Example 1, the difference is that without addition N,
Bis- succinimidyl carbonate of N-.
Comparative example 2
This example provides a kind of gasoline additive, and preparation method and formula are similar to Example 1, the difference is that double without addition
(2- ethoxy) amino (trihydroxy methyl) methane.
Comparative example 3
This example provides a kind of gasoline additive, and preparation method and formula are similar to Example 1, the difference is that without addition second
Eneamines tert-butyl alcohol.
Comparative example 4
This example provides a kind of gasoline additive, and preparation method and formula are similar to Example 1, the difference is that without addition four
(lignocaine) hafnium.
Comparative example 5
This example provides a kind of gasoline additive, and preparation method and formula are the same as 103540372 B of Chinese invention patent CN
Embodiment 1.
Gasoline additive obtained by above-described embodiment 1-5 and comparative example 1-5 is added in No. 93 gasoline, adding proportion is
0.3% (volume ratio), is tested, and test result and test method are shown in Table 1.
1 embodiment of table and comparative example gasoline additive the performance test results
As can be seen from the above table, gasoline additive disclosed by the embodiments of the present invention reduces tail gas to octane number is improved
Discharge, increase rate of economizing gasoline is more effective, this is the result of various components synergistic effects.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and what is described in the above embodiment and the description is only the present invention
Principle, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these variation and
Improvement is both fallen in the range of claimed invention.The present invention claims protection scope by appended claims and its
Equivalent defines.
Claims (6)
1. a kind of gasoline additive, which is characterized in that the component including following parts by weight：Bis- succinimidyl carbonate of N, N-
10-20 parts, bis- 5-10 parts of (2- ethoxy) amino (trihydroxy methyl) methane, 20-30 parts of ethylene amine tert-butyl alcohol, four (diethyls
Amino) 3-5 parts of hafnium, 0.3-0.6 parts of pentaerythritol diphosphites of bis- (2,4,6- tri-tert phenyl).
2. gasoline additive according to claim 1, which is characterized in that the ethylene amine uncle
The preparation method of butyl alcohol, includes the following steps：Ethylene amine substance is dissolved in organic solvent and forms solution, then to its
It is middle that bromo- tert-butyl alcohol is added, reaction 6-8 hours is stirred at room temperature, organic solvent is evaporated off in back spin, obtains ethylene amine uncle
Butyl alcohol.
3. gasoline additive according to claim 2, which is characterized in that the ethylene amine substance, organic solvent, bromo-
The mass ratio of tert-butyl alcohol is 1:(7-10):(2.5-3.5).
4. gasoline additive according to claim 2, which is characterized in that the ethylene amine substance is selected from five ethylene six
One or more of amine, tetraethylenepentamine, triethylene tetramine, diethylenetriamine.
5. gasoline additive according to claim 2, which is characterized in that the organic solvent choosing
From one or more of isopropanol, acetone, ether, methylene chloride.
6. a kind of preparation method of any one of -5 gasoline additives according to claim 1, feature exist
In including the following steps：Each raw material is sequentially added in reaction kettle according to the ratio, after being stirred at room temperature 2-3 hours, stands 3-5
Hour, obtain gasoline additive.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010726704.2A CN111892962A (en) | 2018-06-20 | 2018-06-20 | Preparation method of environment-friendly gasoline additive for improving combustion performance of gasoline |
| CN201810633060.5A CN108822903B (en) | 2018-06-20 | 2018-06-20 | Gasoline additive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810633060.5A CN108822903B (en) | 2018-06-20 | 2018-06-20 | Gasoline additive and preparation method thereof |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010726704.2A Division CN111892962A (en) | 2018-06-20 | 2018-06-20 | Preparation method of environment-friendly gasoline additive for improving combustion performance of gasoline |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108822903A true CN108822903A (en) | 2018-11-16 |
| CN108822903B CN108822903B (en) | 2021-05-28 |
Family
ID=64142565
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810633060.5A Active CN108822903B (en) | 2018-06-20 | 2018-06-20 | Gasoline additive and preparation method thereof |
| CN202010726704.2A Withdrawn CN111892962A (en) | 2018-06-20 | 2018-06-20 | Preparation method of environment-friendly gasoline additive for improving combustion performance of gasoline |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010726704.2A Withdrawn CN111892962A (en) | 2018-06-20 | 2018-06-20 | Preparation method of environment-friendly gasoline additive for improving combustion performance of gasoline |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN108822903B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1201303A1 (en) * | 1999-03-29 | 2002-05-02 | Nippon Steel Chemical Co., Ltd. | Cationic exchange resin |
| CN101125659A (en) * | 2006-05-30 | 2008-02-20 | 气体产品与化学公司 | Diethylsilane as a silicon source in the deposition of metal silicate films |
| CN102153685A (en) * | 2011-01-10 | 2011-08-17 | 合肥工业大学 | Method for preparing polyvinylamine |
| CN104774320A (en) * | 2015-03-27 | 2015-07-15 | 中国昆仑工程公司 | Composite catalyst and polytrimethylene terephthalate preparation method |
-
2018
- 2018-06-20 CN CN201810633060.5A patent/CN108822903B/en active Active
- 2018-06-20 CN CN202010726704.2A patent/CN111892962A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1201303A1 (en) * | 1999-03-29 | 2002-05-02 | Nippon Steel Chemical Co., Ltd. | Cationic exchange resin |
| CN101125659A (en) * | 2006-05-30 | 2008-02-20 | 气体产品与化学公司 | Diethylsilane as a silicon source in the deposition of metal silicate films |
| CN102153685A (en) * | 2011-01-10 | 2011-08-17 | 合肥工业大学 | Method for preparing polyvinylamine |
| CN104774320A (en) * | 2015-03-27 | 2015-07-15 | 中国昆仑工程公司 | Composite catalyst and polytrimethylene terephthalate preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108822903B (en) | 2021-05-28 |
| CN111892962A (en) | 2020-11-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100562560C (en) | A kind of gasoline cleaning agent that can remarkably reducing deposit of gasoline engine combustion chamber | |
| CN108329956B (en) | Environment-friendly gasoline additive and preparation method thereof | |
| CN103695050B (en) | Vehicle methanol gasoline composite additive | |
| CN104263429A (en) | Alcohol-based vehicle fuel | |
| CN113862050A (en) | Multifunctional fuel oil additive and preparation method thereof | |
| CN106281507A (en) | alcohol-based fuel additive | |
| CN109312244B (en) | Fuel antiknock agent, process for producing the same, and fuel composition | |
| CN1277908C (en) | Additive for environmental protection and saving petrol of fuel, and preparation method thereof | |
| CN111394141A (en) | Environment-friendly energy-saving automobile detergent and preparation method thereof | |
| CN108822903A (en) | A kind of gasoline additive and preparation method thereof | |
| CN109294639A (en) | A kind of fuel power elevator and preparation method thereof | |
| CN109294640B (en) | Diesel oil additive and preparation method thereof | |
| CN107880956A (en) | A kind of nano fuel additive agent and preparation method thereof | |
| CN107868683A (en) | Save gasoline additive | |
| CN1374377A (en) | Fuel oil additive | |
| CN109181797B (en) | Efficient gasoline detergent and preparation method thereof | |
| CN112852509A (en) | Gasoline additive, composition thereof and gasoline composition | |
| CN112574790A (en) | Gasoline cleaning synergist and preparation method thereof | |
| CN102559304A (en) | Multifunctional bio-diesel composite additive for vehicles and preparation method thereof | |
| CN110093194B (en) | Antiknock agent | |
| CN106221835A (en) | Diesel fueled combustion enhancement additive | |
| CN108517230B (en) | Environment-friendly gasoline cleaning combustion improver and preparation method thereof | |
| CN1063216C (en) | Liquid fuel additive | |
| TWI572707B (en) | Composition of gasoline octane booster and gasoline octane booster | |
| CN109536217A (en) | A kind of methanol gasoline and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20211112 Address after: 471000 room 212, building 1, No. 007, Sanshan Road, Luoyang area, China (Henan) pilot Free Trade Zone, Luoyang City, Henan Province Patentee after: Runnuo Biotechnology (Henan) Co.,Ltd. Address before: 410217 4-1-49, floor 4, building C5, golden entrepreneurship Park, Wangcheng economic and Technological Development Zone, Changsha, Hunan Patentee before: HUNAN CHENLI NEW MATERIAL Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231220 Address after: Room 101, 1st Floor, No. 8 Huaxia Road, Luoyang Area (High tech), China (Henan) Pilot Free Trade Zone, Luoyang City, Henan Province, 471000 Patentee after: Saide Energy Technology (Henan) Co.,Ltd. Address before: 471000 room 212, building 1, No. 007, Sanshan Road, Luoyang area, China (Henan) pilot Free Trade Zone, Luoyang City, Henan Province Patentee before: Runnuo Biotechnology (Henan) Co.,Ltd. |