CN108822682A - A kind of aqueous epoxide resin paint and preparation method thereof - Google Patents
A kind of aqueous epoxide resin paint and preparation method thereof Download PDFInfo
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- CN108822682A CN108822682A CN201810530516.5A CN201810530516A CN108822682A CN 108822682 A CN108822682 A CN 108822682A CN 201810530516 A CN201810530516 A CN 201810530516A CN 108822682 A CN108822682 A CN 108822682A
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- epoxide resin
- resin paint
- aqueous epoxide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous epoxide resin paint, the weight proportion of the aqueous epoxide resin paint each component is liquid-state epoxy resin 20-30 parts, 10-15 parts of styrene-acrylic emulsion, 10-15 parts of silica solution, 5-10 parts of salicylic acid, 5-10 parts of benzoic acid, 4-6 parts of water-compatible amino resin, 4-6 parts of rare earth aluminate, 4-6 parts of surfactant, 2-3 parts of levelling agent, 2-3 parts of curing agent, 1-2 parts of defoaming agent, 1-2 parts of Graphene powder, 1-2 parts of titanium dioxide, 1-2 parts of dispersing agent, 1-2 parts of pigment.Coating of the invention is using lotion as medium, only need a small amount of cosolvent, greatly reduce the content of volatile organic compounds, environmental pollution is small, improve the environmental-protecting performance of aqueous epoxide resin paint, make aqueous epoxide resin paint that there is good adhesive force, improves the scour & wear resistance energy of aqueous epoxide resin paint, preparation process is simple, easy to implement.
Description
Technical field
The present invention relates to coating processing technique field, specifically a kind of aqueous epoxide resin paint and preparation method thereof.
Background technique
Traditional epoxy resin must use organic solvent in use, therefore contain organic volatile in its system
Object can not only cause environment seriously to pollute, and also have a great threat to human health, such as application No. is
201710206124.9 a kind of aqueous epoxide resin paint of patent disclosure, which solve existing aqueous epoxide resin paint
It is at high cost, but there is that environmental-protecting performance is not high, coating quality is not high, preparation process is cumbersome, labor intensity of operating staff is big
The problem of.
Summary of the invention
The purpose of the present invention is overcome environmental-protecting performance existing for existing aqueous epoxide resin paint is high, coating quality not
The problem high, preparation process is cumbersome, labor intensity of operating staff is big, provides that a kind of preparation cost is low, capability and performance is good, environmentally friendly
Performance is good, preparation process is easy to grasp, the small aqueous epoxide resin paint of labor intensity of operating staff and preparation method thereof.
The technical solution adopted by the present invention to solve the technical problems is：
A kind of aqueous epoxide resin paint, the weight proportion of the aqueous epoxide resin paint each component are liquid-state epoxy resin
20-30 parts, 10-15 parts of styrene-acrylic emulsion, 10-15 parts of silica solution, 5-10 parts of salicylic acid, 5-10 parts of benzoic acid, water-compatible amino resin
4-6 parts, 4-6 parts of rare earth aluminate, 4-6 parts of surfactant, 2-3 parts of levelling agent, 2-3 parts of curing agent, 1-2 parts of defoaming agent, stone
1-2 parts of black alkene powder, 1-2 parts of titanium dioxide, 1-2 parts of dispersing agent, 1-2 parts of pigment.
The surfactant is neopelex, cetyl trimethylammonium bromide, stearic acid or fat
Any one or more mixing in acid glyceride.
The levelling agent is polyacrylic acid, carboxymethyl cellulose, acrylate, Lauxite, butadiene-styrene rubber, pyrophosphoric acid four
Any one or more mixing in sodium.
The curing agent is any one in di-2-ethylhexylphosphine oxide hexamethylene alkanamine, isophorone diamine or diethyl amino propylamine
Or a variety of mixing.
The defoaming agent is polyether siloxane copolymer lotion, polyethylene wax, n-butanol, tributyl phosphate, hydroxide
Magnesium, phosphate, organic silicon defoamer, amide, dimethyl silicone polymer, any one or more mixing in polyether-silicone.
The dispersing agent is modified polyacrylate solution, modified siloxane, polymeric carboxylic, sodium tripolyphosphate, third
Olefin(e) acid, sodium sulfite, ethyl acetate, any one or more mixing in calgon.
The preparation method includes the following steps：
A. raw material is subjected to title choosing according to parts by weight formula, and solid material is subjected to pulverization process respectively, smash it through 220-
The sieve of 270 mesh is screened, and solid material powder is made, liquid styrene-acrylic emulsion, silica solution, salicylic acid, benzoic acid are put into instead
It answers in kettle, is warming up to 82-85 DEG C and is reacted, carry out stirring 50-60min at the uniform velocity with the speed of 500-600r/min, it is sufficiently anti-
Reaction material uniformly should be made；
B. solid material powder is added to reaction kettle, is at the uniform velocity stirred in the speed of 500-600r/min, stir 30-
40min；Adjust viscosity after, be at the uniform velocity stirred in the speed of 1000-1200r/min, stirring 15-20min, to raw material into
Row premixing；
C. the raw material after premixing is stirred, mixing speed 2200-2300r/min, mixing time 1-2h, stands 4-
After 5h, after at the uniform velocity stirring 30-40min under 900-1000r/min speed, investment is ground into grinder, grinds 3-5h；
D. it will be delivered to after grinding in dispersing apparatus and carry out high speed dispersion, after extrusion in the case where revolving speed is 3200-3500r/min revolving speed
High speed dispersion 20-30min, it is evenly dispersed, fineness is ground to less than 50 μm, and corresponding pigment is added according to required color, is made
Aqueous epoxide resin paint.
Beneficial effect：Coating of the invention only needs a small amount of cosolvent, greatly reducing volatility has using lotion as medium
The content of machine compound, environmental pollution is small, improves the environmental-protecting performance of aqueous epoxide resin paint, makes aqueous epoxide resin paint
With good adhesive force, the scour & wear resistance energy of aqueous epoxide resin paint is improved, making for aqueous epoxide resin paint is extended
With the service life, this aqueous epoxide resin paint preparation process is simple, easy to implement, reduces the labor intensity of operator, improves
The preparation efficiency of aqueous epoxide resin paint, improves economic benefit.
Specific embodiment
Embodiment one
A kind of aqueous epoxide resin paint, the weight proportion of the aqueous epoxide resin paint each component are liquid-state epoxy resin
25 parts, 15 parts of styrene-acrylic emulsion, 15 parts of silica solution, 8 parts of salicylic acid, 8 parts of benzoic acid, 6 parts of water-compatible amino resin, rare earth aluminate 6
Part, 6 parts of surfactant, 3 parts of levelling agent, 3 parts of curing agent, 2 parts of defoaming agent, 1 part of Graphene powder, 1 part of titanium dioxide, dispersing agent 1
Part, 1 part of pigment.
The surfactant is neopelex, cetyl trimethylammonium bromide by weight 1:1
Mixture.
The levelling agent is polyacrylic acid, acrylate, butadiene-styrene rubber by weight 1:1:1 mixture.
The curing agent is di-2-ethylhexylphosphine oxide hexamethylene alkanamine.
The defoaming agent is n-butanol, phosphate, polyether-silicone by weight 1:2:2 mixture.
The dispersing agent is modified polyacrylate solution.
The preparation method includes the following steps：
A. raw material is subjected to title choosing according to parts by weight formula, and solid material is subjected to pulverization process respectively, smash it through 250 mesh
Sieve screened, be made solid material powder, liquid styrene-acrylic emulsion, silica solution, salicylic acid, benzoic acid are put into reaction kettle
In, it is warming up to 84 DEG C and is reacted, carry out stirring 55min at the uniform velocity with the speed of 700r/min, uniformly, reaction is made in sufficiently reaction
Material；
B. solid material powder is added to reaction kettle, is at the uniform velocity stirred in the speed of 600r/min, stir 30min；
It after adjusting viscosity, is at the uniform velocity stirred in the speed of 1100r/min, stirs 20min, raw material is pre-mixed；
C. the raw material after premixing is stirred, mixing speed 2200r/min, mixing time 1h, after standing 5h,
After at the uniform velocity stirring 35min under 1000r/min speed, investment is ground into grinder, grinds 3h；
D. it will be delivered to after grinding in dispersing apparatus and carry out high speed dispersion, after extrusion at a high speed in the case where revolving speed is 3300r/min revolving speed
Disperse 30min, it is evenly dispersed, fineness is ground to less than 50 μm, and corresponding pigment is added according to required color, water-base epoxy is made
Cold coating.
Embodiment two：
A kind of aqueous epoxide resin paint, the weight proportion of the aqueous epoxide resin paint each component are liquid-state epoxy resin
20 parts, it is 13 parts of styrene-acrylic emulsion, 10 parts of distilled water, 8 parts of silica solution, 8 parts of salicylic acid, 8 parts of benzoic acid, 6 parts of water-compatible amino resin, dilute
6 parts of native aluminate, 5 parts of surfactant, 5 parts of aqueous carbon black, 3 parts of levelling agent, 1 part of curing agent, 2 parts of defoaming agent, Graphene powder 1
Part, 1 part of titanium dioxide, 1 part of coalescing agent, 1 part of dispersing agent, 1 part of antibacterial agent, 1 part of pigment.
The surfactant be neopelex, cetyl trimethylammonium bromide, stearic acid by weight
Than 2:1:1 mixture.
The levelling agent is carboxymethyl cellulose.
The curing agent is di-2-ethylhexylphosphine oxide hexamethylene alkanamine, diethyl amino propylamine by weight 1:1 mixture.
The defoaming agent is polyethylene wax, magnesium hydroxide, phosphate, organic silicon defoamer by weight 2:2:3:1
Mixture.
The dispersing agent is modified siloxane, polymeric carboxylic, sodium sulfite, ethyl acetate by weight 1:2:1:1
Mixture.
The antibacterial agent is montmorillonite germicide.
The preparation method includes the following steps：
A. raw material is subjected to title choosing according to parts by weight formula, and solid material is subjected to pulverization process respectively, smash it through 290 mesh
Sieve screened, be made solid material powder, liquid styrene-acrylic emulsion, silica solution, salicylic acid, benzoic acid are put into reaction kettle
In, it is warming up to 86 DEG C and is reacted, carry out stirring 40min at the uniform velocity with the speed of 700r/min, uniformly, reaction is made in sufficiently reaction
Material；
B. solid material powder is added to reaction kettle, is at the uniform velocity stirred in the speed of 650r/min, stir 50min；
It after adjusting viscosity, is at the uniform velocity stirred in the speed of 1300r/min, stirs 30min, raw material is pre-mixed；
C. the raw material after premixing is stirred, mixing speed 2400r/min, mixing time 3h, after standing 6h,
After at the uniform velocity stirring 50min under 1100r/min speed, investment is ground into grinder, grinds 4h；
D. it will be delivered to after grinding in dispersing apparatus and carry out high speed dispersion, after extrusion at a high speed in the case where revolving speed is 3600r/min revolving speed
Disperse 40min, it is evenly dispersed, fineness is ground to less than 40 μm, and corresponding pigment is added according to required color, water-base epoxy is made
Cold coating.
Embodiment three：
A kind of aqueous epoxide resin paint, the weight proportion of the aqueous epoxide resin paint each component are liquid-state epoxy resin
15 parts, 12 parts of styrene-acrylic emulsion, 10 parts of maleic anhydride, 8 parts of silica solution, 8 parts of water-soluble cellulose ether, 8 parts of salicylic acid, benzoic acid 6
Part, 6 parts of water-compatible amino resin, 5 parts of rare earth aluminate, 5 parts of surfactant, 3 parts of superfine talcum powder, 2 parts of levelling agent, mica powder
1 part, 1 part of curing agent, 2 parts of defoaming agent, 1 part of Graphene powder, 1 part of bentonite in powder, 1 part of titanium dioxide, 1 part of coalescing agent, dispersing agent 1
Part, 1 part of antibacterial agent, 1 part of corrosion inhibiter, 1 part of pigment.
The surfactant is neopelex.
The levelling agent is polyacrylic acid, carboxymethyl cellulose, acrylate by weight 1:1:2 mixture.
The curing agent is di-2-ethylhexylphosphine oxide hexamethylene alkanamine, isophorone diamine, diethyl amino propylamine by weight 1:1:1
Mixture.
The defoaming agent is n-butanol, phosphate by weight 1:1:1 mixture.
The antibacterial agent is bentonite bactericidal agent.
The corrosion inhibiter is trbasic zinc phosphate, aluminium dihydrogen tripolyphosphate, composite iron-titanium powder by weight 1:1:1 mixture.
The preparation method includes the following steps：
A. raw material is subjected to title choosing according to parts by weight formula, and solid material is subjected to pulverization process respectively, smash it through 200 mesh
Sieve screened, be made solid material powder, by liquid styrene-acrylic emulsion, maleic anhydride, silica solution, water-soluble cellulose ether,
Salicylic acid, benzoic acid, water-compatible amino resin are put into reaction kettle, are warming up to 80 DEG C and are reacted, with the speed of 600r/min into
Row at the uniform velocity stirs 70min, and uniformly, reaction material is made in sufficiently reaction；
B. solid material powder is added to reaction kettle, is at the uniform velocity stirred in the speed of 700r/min, stir 30min；
It after adjusting viscosity, is at the uniform velocity stirred in the speed of 1000r/min, stirs 10min, raw material is pre-mixed；
C. the raw material after premixing is stirred, mixing speed 2100r/min, mixing time 3h, after standing 3h,
After at the uniform velocity stirring 50min under 900r/min speed, investment is ground into grinder, grinds 4h；
D. it will be delivered to after grinding in dispersing apparatus and carry out high speed dispersion, after extrusion at a high speed in the case where revolving speed is 3000r/min revolving speed
Disperse 40min, it is evenly dispersed, fineness is ground to less than 30 μm, and corresponding pigment is added according to required color, water-base epoxy is made
Cold coating.
The present invention is exemplarily described above in conjunction with embodiment, it is clear that the present invention implements not by above-mentioned side
The limitation of formula, if the improvement for the various unsubstantialities that the inventive concept and technical scheme of the present invention carry out is used, or without
It improves the conception and technical scheme of the invention are directly applied to other occasions, it is within the scope of the present invention.
Part that the present invention does not relate to is the same as those in the prior art or can be realized by using the prior art.
Claims (7)
1. a kind of aqueous epoxide resin paint, the weight proportion of the aqueous epoxide resin paint each component is liquid epoxy tree
20-30 parts of rouge, 10-15 parts of styrene-acrylic emulsion, 10-15 parts of silica solution, 5-10 parts of salicylic acid, 5-10 parts of benzoic acid, aqueous amino tree
4-6 parts of rouge, 4-6 parts of rare earth aluminate, 4-6 parts of surfactant, 2-3 parts of levelling agent, 2-3 parts of curing agent, 1-2 parts of defoaming agent,
1-2 parts of Graphene powder, 1-2 parts of titanium dioxide, 1-2 parts of dispersing agent, 1-2 parts of pigment.
2. aqueous epoxide resin paint according to claim 1, it is characterised in that：The surfactant is dodecane
Any one or more mixing in base benzene sulfonic acid sodium salt, cetyl trimethylammonium bromide, stearic acid or fatty glyceride.
3. aqueous epoxide resin paint according to claim 1, it is characterised in that：The levelling agent be polyacrylic acid,
Carboxymethyl cellulose, acrylate, Lauxite, butadiene-styrene rubber, any one or more mixing in tetrasodium pyrophosphate.
4. aqueous epoxide resin paint according to claim 1, it is characterised in that：The curing agent is that methylene is bicyclic
Any one or more mixing in hexane amine, isophorone diamine or diethyl amino propylamine.
5. aqueous epoxide resin paint according to claim 1, it is characterised in that：The defoaming agent is polyether silicone
Copolymer emulsion, polyethylene wax, n-butanol, tributyl phosphate, magnesium hydroxide, phosphate, organic silicon defoamer, amide, poly- two
Any one or more mixing in methylsiloxane, polyether-silicone.
6. aqueous epoxide resin paint according to claim 1, it is characterised in that：The dispersing agent is modified polypropene
Acid esters solution, modified siloxane, polymeric carboxylic, sodium tripolyphosphate, acrylic acid, sodium sulfite, ethyl acetate, calgon
In any one or more mixing.
7. a kind of preparation method suitable for aqueous epoxide resin paint as described in claim 1, which is characterized in that described
Preparation method includes the following steps：
A. raw material is subjected to title choosing according to parts by weight formula, and solid material is subjected to pulverization process respectively, smash it through 220-
The sieve of 270 mesh is screened, and solid material powder is made, liquid styrene-acrylic emulsion, silica solution, salicylic acid, benzoic acid are put into instead
It answers in kettle, is warming up to 82-85 DEG C and is reacted, carry out stirring 50-60min at the uniform velocity with the speed of 500-600r/min, it is sufficiently anti-
Reaction material uniformly should be made；
B. solid material powder is added to reaction kettle, is at the uniform velocity stirred in the speed of 500-600r/min, stir 30-
40min；Adjust viscosity after, be at the uniform velocity stirred in the speed of 1000-1200r/min, stirring 15-20min, to raw material into
Row premixing；
C. the raw material after premixing is stirred, mixing speed 2200-2300r/min, mixing time 1-2h, stands 4-
After 5h, after at the uniform velocity stirring 30-40min under 900-1000r/min speed, investment is ground into grinder, grinds 3-5h；
D. it will be delivered to after grinding in dispersing apparatus and carry out high speed dispersion, after extrusion in the case where revolving speed is 3200-3500r/min revolving speed
High speed dispersion 20-30min, it is evenly dispersed, fineness is ground to less than 50 μm, and corresponding pigment is added according to required color, is made
Aqueous epoxide resin paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810530516.5A CN108822682A (en) | 2018-05-29 | 2018-05-29 | A kind of aqueous epoxide resin paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810530516.5A CN108822682A (en) | 2018-05-29 | 2018-05-29 | A kind of aqueous epoxide resin paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108822682A true CN108822682A (en) | 2018-11-16 |
Family
ID=64146196
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810530516.5A Withdrawn CN108822682A (en) | 2018-05-29 | 2018-05-29 | A kind of aqueous epoxide resin paint and preparation method thereof |
Country Status (1)
| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114318871A (en) * | 2021-11-30 | 2022-04-12 | 东莞职业技术学院 | Waterproof coating for textile and clothing and preparation process |
| CN116355465A (en) * | 2023-06-01 | 2023-06-30 | 涂果新材料科技(江苏)有限公司 | Up-conversion material reinforced water-based paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102816495A (en) * | 2011-06-10 | 2012-12-12 | 上海建冶科技工程股份有限公司 | Environment-friendly nano-epoxy silicone heavy anti-corrosion coating and preparation method and using method thereof |
| CN106811006A (en) * | 2017-02-14 | 2017-06-09 | 江苏艾科赛特新材料有限公司 | It is a kind of to can be used for the aqueous epoxy floor coating compositions and preparation method of outdoor |
| CN107418375A (en) * | 2017-07-27 | 2017-12-01 | 芜湖市三山龙城新材料有限公司 | A kind of aqueous epoxide resin paint and preparation method thereof |
-
2018
- 2018-05-29 CN CN201810530516.5A patent/CN108822682A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102816495A (en) * | 2011-06-10 | 2012-12-12 | 上海建冶科技工程股份有限公司 | Environment-friendly nano-epoxy silicone heavy anti-corrosion coating and preparation method and using method thereof |
| CN106811006A (en) * | 2017-02-14 | 2017-06-09 | 江苏艾科赛特新材料有限公司 | It is a kind of to can be used for the aqueous epoxy floor coating compositions and preparation method of outdoor |
| CN107418375A (en) * | 2017-07-27 | 2017-12-01 | 芜湖市三山龙城新材料有限公司 | A kind of aqueous epoxide resin paint and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114318871A (en) * | 2021-11-30 | 2022-04-12 | 东莞职业技术学院 | Waterproof coating for textile and clothing and preparation process |
| CN116355465A (en) * | 2023-06-01 | 2023-06-30 | 涂果新材料科技(江苏)有限公司 | Up-conversion material reinforced water-based paint and preparation method thereof |
| CN116355465B (en) * | 2023-06-01 | 2023-07-28 | 涂果新材料科技(江苏)有限公司 | Up-conversion material reinforced water-based paint and preparation method thereof |
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Application publication date: 20181116 |