CN108819527A - The electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable - Google Patents

The electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable Download PDF

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Publication number
CN108819527A
CN108819527A CN201810727118.2A CN201810727118A CN108819527A CN 108819527 A CN108819527 A CN 108819527A CN 201810727118 A CN201810727118 A CN 201810727118A CN 108819527 A CN108819527 A CN 108819527A
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CN
China
Prior art keywords
parts
film
glue
layer
cold wave
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810727118.2A
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Chinese (zh)
Inventor
陈绍亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Liang Yu Laser New Material Co Ltd
Original Assignee
Jiangsu Liang Yu Laser New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Liang Yu Laser New Material Co Ltd filed Critical Jiangsu Liang Yu Laser New Material Co Ltd
Priority to CN201810727118.2A priority Critical patent/CN108819527A/en
Publication of CN108819527A publication Critical patent/CN108819527A/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14Security printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/03Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by pressure
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C09J163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of electrochemical aluminium thermoprinting films of the cold wave technology of UV energy-curable, it includes sequentially connected basal layer, peeling layer, color layers, electroplated layer and glue layer;The glue layer includes UV glue;The UV glue includes following components in parts by weight:65-80 parts of polyurethane acrylic resin, 15-30 parts of vinylite, solid propenoic acid resin 10-30 parts pure, 5-10 parts of adhesion promoter, 25-45 parts of solvent, 5-10 parts of initiator, 1-5 parts of auxiliary agent.Electrochemical aluminium thermoprinting film provided by the invention, in UV adhesive curing, easy-stripping type anodized aluminium paper tinsel film after not needing removing synchronizes conveying, at this moment, it can will be not required to the corresponding easy-stripping type anodized aluminium paper tinsel film in cold wave position and pack up or stopping transport by paper tinsel film rewinding device to application film length into film direction, need not continue to next step, can effectively avoid in next step may the waste caused by easy-stripping type anodized aluminium paper tinsel film, and then greatly reduce production cost.

Description

The electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable
Technical field
The present invention relates to electrochemical aluminium thermoprinting technical field of membrane, and in particular to a kind of electrification of the cold wave technology of UV energy-curable Aluminium blocking film.
Background technique
Blocking film, which refers to, combines laser hologram electrification aluminium film with thermoprint technology, is formed in printed matter surface bright and colourful Laser holographic mark and space pattern anti-counterfeiting mark technology.This technology can increase laser cryptography and back side tamper-evident Layer, for the anti-fake of certificate, card, bill, trade mark etc..If plus this anti-counterfeiting mark, its is anti-fake on product external packaging Dynamics is that present single laser holographic anti counterfeiting label cannot compare.Furthermore it is possible to be to produce according to the requirement of different user Product make special edition laser hologram electrification aluminium film.Due to special edition pattern production in contain the particular requirement of businessman, then incorporate constantly The laser holography of development.Either the anti-fake supply and marketing mode of special edition or its decorative effect are all more skillful.
Thermoprint printing refers on the objects such as paper, cardboard, fabric, coating class, with hot pressure method by thermoprint material or boiling hot version Pattern is shifted in the processing scalded on object.The thermoprint processing of bookbinding is more generally on cover, and form is a variety of, such as single material Thermoprint, hybrid thermoprint, covers the printing processes such as boiling hot at the thermoprint without boiling hot material.
The essence of thermoprint is exactly to transfer, and is that anodized aluminium draw above case is transferred to stock by the effect of heat and pressure Above process process.When printing plate heats up to a certain extent with appended electric heating negative, carried out across electrochemical aluminium film and paper Coining, using the effect of temperature and pressure, is transferred to the glue-line being attached on mylar, metallic aluminum and chromatograph on paper. But problem is that cold wave printing machine volume production utilization rate due to process materials are limited is low and cold wave technology is because of complex process, and unstable And cost depletions are high.
Summary of the invention
The present invention overcomes the deficiencies in the prior art, provide a kind of electrochemical aluminium thermoprinting of the cold wave technology of UV energy-curable Film.
In order to solve the above technical problems, the present invention uses following technical scheme:
A kind of electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable, it includes sequentially connected basal layer, peeling layer, color Layer, electroplated layer and glue layer;The glue layer includes UV glue;The UV glue includes following components in parts by weight: 65-80 parts of polyurethane acrylic resin, 15-30 parts of vinylite, solid propenoic acid resin 10-30 parts pure, adhesive force promote 5-10 parts of agent, 25-45 parts of solvent, 5-10 parts of initiator, 1-5 parts of auxiliary agent.
Further technical solution is that the auxiliary agent is plasticizer.
It further includes 2-5 parts of inorganic filler that further technical solution is the UV glue in parts by weight.
Further technical solution is that the inorganic filler is organobentonite, titanium dioxide or the oxidation of nanometer three two Aluminium.
Compared with prior art, the beneficial effects of the invention are as follows:Electrochemical aluminium thermoprinting film provided by the invention, when in use, It can be cooperated by UV glue and impression roller, realize and first remove easy-stripping type anodized aluminium paper tinsel film, then carry out UV adhesive curing, effectively solved Certainly commonly from dry glue water sticky end the problem of, in UV adhesive curing, the easy-stripping type anodized aluminium paper tinsel film after not needing removing is carried out At this moment synchronous conveying can will be not required to the corresponding easy-stripping type anodized aluminium paper tinsel film in cold wave position into the long to application film of film direction Degree is packed up by paper tinsel film rewinding device or stops transporting, and next step is needed not continue to, and can effectively avoid may in next step It is wasted caused by easy-stripping type anodized aluminium paper tinsel film, and then greatly reduces production cost.
Specific embodiment
Below with reference to embodiment, the present invention is further elaborated.
The electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable disclosed in the present embodiment, it includes sequentially connected basis Layer, peeling layer, color layers, electroplated layer and glue layer;The structure sheaf of the present embodiment electrochemical aluminium thermoprinting film is existing structure sheaf, this Glue layer is to be coated on electroplated layer to be formed by special UV glue in embodiment;Specifically, the UV glue is according to parts by weight Calculating includes following components:70 parts of polyurethane acrylic resin, 21 parts of vinylite, 17 parts of pure solid propenoic acid resin, attachment 8 parts of power promotor, 30 parts of solvent, 6 parts of initiator, the organobentonite of 3 parts and 2 parts of plasticizer, titanium dioxide or nanometer three aoxidize Two aluminium.
Specifically, the present embodiment is further disclosed in detail in such a way that cold foil technology is using the electrochemical aluminium thermoprinting film, packet Include following steps:
Step 1, the position printing UV glue for needing cold wave on the substrate, and the hue adjustment easy-stripping type according to needed for product The tone and form and aspect of anodized aluminium paper tinsel film.The UV glue can be set on stock by way of offset printing, silk-screen or gravure, no It is confined to equipment, suitable application area is wider.
Easy-stripping type anodized aluminium paper tinsel film and stock are passed through impression roller to pressure, so that easy-stripping type is electrochemical by step 2 Aluminium foil film is combined with stock by UV sticker.
The easy-stripping type anodized aluminium paper tinsel film that step 3, removing are not bonded with stock, passes through UV glue laminating with stock Easy-stripping type anodized aluminium paper tinsel film on easily peelable aluminium layer be then transferred on stock.
At this moment, the easy-stripping type anodized aluminium paper tinsel film after removing can pass through paper tinsel film to using film length into film direction Rewinding device is temporarily packed up or stops transporting, and does not need to carry out next step, that is, realizes " jumping for easy-stripping type anodized aluminium paper tinsel film Step connects film ", can effectively avoid in next step may the waste caused by easy-stripping type anodized aluminium paper tinsel film, and then greatly reduce Production cost.
Step 4 solidifies the UV glue by ultraviolet lamp.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification is applied directly or indirectly in other relevant technical fields, Similarly it is included within the scope of the present invention.

Claims (4)

1. a kind of electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable, it includes sequentially connected basal layer, peeling layer, face Chromatograph, electroplated layer and glue layer;It is characterized in that:The glue layer includes UV glue;The UV glue is in parts by weight Including following components:65-80 parts of polyurethane acrylic resin, 15-30 parts of vinylite, pure solid propenoic acid resin 10-30 Part, 5-10 parts of adhesion promoter, 25-45 parts of solvent, 5-10 parts of initiator, 1-5 parts of auxiliary agent.
2. the electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable according to claim 1, it is characterised in that described Auxiliary agent is plasticizer.
3. the electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable according to claim 1, it is characterised in that described UV glue further includes 2-5 parts of inorganic filler in parts by weight.
4. the electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable according to claim 3, it is characterised in that described Inorganic filler is organobentonite, titanium dioxide or nano-aluminium oxide.
CN201810727118.2A 2018-07-05 2018-07-05 The electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable Withdrawn CN108819527A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810727118.2A CN108819527A (en) 2018-07-05 2018-07-05 The electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810727118.2A CN108819527A (en) 2018-07-05 2018-07-05 The electrochemical aluminium thermoprinting film of the cold wave technology of UV energy-curable

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113693038A (en) * 2021-07-27 2021-11-26 界首市汇珠渔具有限公司 Production process method of paillette thermoprint plastic bionic bait
CN117025122A (en) * 2023-10-08 2023-11-10 汕头市恒顺包装材料有限公司 Lens cold-stamping film and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113693038A (en) * 2021-07-27 2021-11-26 界首市汇珠渔具有限公司 Production process method of paillette thermoprint plastic bionic bait
CN117025122A (en) * 2023-10-08 2023-11-10 汕头市恒顺包装材料有限公司 Lens cold-stamping film and preparation method thereof
CN117025122B (en) * 2023-10-08 2024-02-06 汕头市恒顺包装材料有限公司 Lens cold-stamping film and preparation method thereof

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WW01 Invention patent application withdrawn after publication

Application publication date: 20181116

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