CN108817852B - A kind of processing technology of pseudo-classic silver cup - Google Patents
A kind of processing technology of pseudo-classic silver cup Download PDFInfo
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- CN108817852B CN108817852B CN201810489534.3A CN201810489534A CN108817852B CN 108817852 B CN108817852 B CN 108817852B CN 201810489534 A CN201810489534 A CN 201810489534A CN 108817852 B CN108817852 B CN 108817852B
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- silver
- cup
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- silver cup
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
- B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G23/00—Other table equipment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/24—Pressing or stamping ornamental designs on surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Adornments (AREA)
Abstract
A kind of processing technology of pseudo-classic silver cup, the processing technology includes the following steps: that → pressing plate → blanking → stretching → molding → annealing → extrusion pattern → cleaning → pseudo-classic processing → packaging is forged in silver ingot → stripping and slicing → fusing → reverse mould →, the present invention provides a kind of processing technologys of pseudo-classic silver cup, the processing technology is a kind of new process researched and developed on the basis of traditional handicraft and modern technologies combine, compared with traditional handicraft, in pattern, lines and moulding etc., which have, to be greatly improved, and this technique is suitble to be mass produced, processing is fast, more prominent anaglyph, make silver cup that there is primitive color, fashion is beautiful, it is exquisite in workmanship.By pressure pattern and pseudo-classic technique, so that silver cup shape is more beautiful, pure color, stylishness is increased, there is good reserve value, and higher by the pseudo-classic silver cup hardness that this method is handled, it is unlikely to deform, without any chemical residual, meets the health preserving awareness of modern.
Description
Technical field
The present invention relates to silver cup processing technique field, specifically a kind of processing technology of pseudo-classic silver cup.
Background technique
Silver use medically can be traced B.C., and ancients just know that silver has and accelerate Wound healing, prevention and treatment infection, net
Change the effect of water quality and preservation and antisepsis, it can prevent bacterial growth, and five viscera settling, centering is refreshing, and stop palpitate with fear removes pathogenic factor.Silver has Zhuo
Sterilization functions more, general antibiotic can only averagely play a role 6 kinds of germs, but silver can eliminate 650 kinds of germs.Silver
Ion has very strong bactericidal effect, very good to human body.Therefore, food is stored with silverware, bacterial growth can be prevented, extend food
Object Storage period.In medical silver-colored diagnosis and treatment have related disorders, the silver-colored record for controlling ulcer of doctor trained in Western medicine also had more than 100 years.The ion and chemical combination of silver
Object shows toxicity to certain bacteriums, virus, algae and fungi, but almost completely harmless to human body, and silver-colored is this
Bactericidal effect kill it can in vitro by biology.
With the continuous social and economic development, improvement of living standard, demand of the people to daily necessity quality is also gradually
Increase, cup brings great convenience as a kind of article being filled with water with beverage to people's lives.Along with reflex in recent years
Ancient customs is popular, and some pseudo-classic, modelled after an antique craftworks and ornaments are pursued by people, but silver cup is mostly traditional smooth surface work at present
Therefore how skill closely follows fashion, develops pattern beauty, silver cup exquisite in workmanship becomes industry technical problems to be solved.
Summary of the invention
In order to solve the above-mentioned technical problems, the present invention provides a kind of processing technology of pseudo-classic silver cup, which is
A kind of new process researched and developed on the basis of traditional handicraft and modern technologies combine, compared with traditional handicraft, pattern, lines and
Moulding etc., which has, to be greatly improved, and this technique is suitble to be mass produced, and processing is fast, and more prominent anaglyph makes silver
Cup has primitive color, and fashion is beautiful, exquisite in workmanship.
The technical solution that the present invention uses to solve above-mentioned technical problem are as follows: a kind of processing technology of pseudo-classic silver cup should add
Work technique includes the following steps:
Step 1: carrying out stripping and slicing to silver ingot under the pressure condition of 18-22MPa, the silver ingot after obtaining stripping and slicing is spare;
Step 2: the silver ingot after step 1 stripping and slicing is heated to be fused into silver-colored water, cooling and shaping in mold is poured into later, is obtained
Silver bullion after sizing, it is spare;
Step 3: the silver bullion after step 2 is formed forges, later with trigger squeeze in 13-17kg/cm2Pressure
Under, the silver bullion after forging is pressed into the silver-colored band of 0.1-0.5mm thickness, it is spare;
Step 4: the silver-colored band that step 3 is pressed is cut into round silver strip with blanking mold, round silver strip is being stretched later
Every equal through one of mold by the way that if from tubbiness to elongated arterial highway mold, round silver strip to be pulled into the silver cup of different model on machine
Annealing is primary, obtains silver cup after molding;
Step 5: filler will be filled inside step 4 silver cup after molding, the mold of outside fitting setting different pattern, it
Filler expansion must press the silver cup of pattern to squeeze silver cup under the pressure of 15-20MPa afterwards;
Step 6: being dried after the silver cup surface cleaning agent that step 5 presses pattern is sufficiently cleaned, after must cleaning
Silver cup;
Step 7: the silver cup after step 6 is cleaned is placed in the potassium sulfide solution that concentration is 8-12%, temperature control 90-110
DEG C, it places 25-35s and pulls out later, obtain a kind of pseudo-classic silver cup.
As a preferred embodiment, step 7 replaces with the silver cup after cleaning step 6 and is placed in the sulphur that concentration is 8-12%
Change in potassium solution, 90-110 DEG C of temperature control, places 25-35s and pull out later, a kind of pseudo-classic silver cup liner is obtained, by pseudo-classic silver cup liner
It is inlayed together with transparent outer cover, pattern gap is perfused with calcium plaster, drying in drying box is put into later, by cup after taking-up
Surface is thoroughly cleaned, and a kind of pseudo-classic silver cup is obtained.
As a preferred embodiment, step 7 replaces with the silver cup after cleaning step 6 and is placed in the sulphur that concentration is 8-12%
Change in potassium solution, 90-110 DEG C of temperature control, places 25-35s and pull out later, a kind of pseudo-classic silver cup housing is obtained, by pseudo-classic silver cup housing
It is inlayed together with stainless steel heat-preservation liner, pattern gap is perfused with calcium plaster, drying in drying box is put into later, after taking-up
Cup's surface is thoroughly cleaned, a kind of pseudo-classic silver cup is obtained.
As a preferred embodiment, the drying temperature is 60-150 DEG C, drying time 1.5-4h.
As a preferred embodiment, annealing described in step 4 uses the firelock of liquefied gas and oxygen.
As a preferred embodiment, the mold of different pattern described in step 5 includes internal model and external mold, and internal model and external mold are equal
For cylindrical shape, internal model inner wall is provided with pattern, and along the circumferential direction trisection, as a preferred embodiment, the external mold wall thickness
2-4cm, and external mold pressure resistance upper limit value is greater than 20MPa.
As a preferred embodiment, filler described in step 5 is polyurethane glue stick or micelle.
Compared with prior art, the invention has the following advantages:
(1) the present invention provides a kind of processing technology of pseudo-classic silver cup, which is in traditional handicraft and modern skill
A kind of new process that art is researched and developed on the basis of combining is pressed and is matched when pattern using internal model and external mold, and external mold is used to fix internal model,
By the way that pattern is arranged in internal model inner wall, by internal model, along the circumferential direction filler is filled in trisection, silver cup inside after molding later, outside
The internal model of portion's fitting setting different pattern, filler are expanded outward by pressure, carry out pressure pattern, through the invention processing technology system
Pseudo-classic silver cup pattern, lines and in terms of have and greatly improve, more prominent anaglyph, and this technique is suitable
Large-scale production is closed, processing is fast, and yield is high, can bring preferable economic benefit and social benefit;Silver cup has primitive color, when
It is still beautiful, it is exquisite in workmanship, more enter the eyeball of consumer, there is the bigger market space;
(2) the present invention provides a kind of processing technologys of pseudo-classic silver cup, handle before pressing pattern process silver ingot,
Silver is set to have more ductility;Pseudo-classic technique is carried out after pressure pattern, only with potassium sulfide solution in pseudo-classic technique, is more advantageous to
Environmental protection, and make silver cup shape more beautiful, pure color increases stylishness, has good reserve value, and by being somebody's turn to do
The pseudo-classic silver cup hardness of method processing is higher, is unlikely to deform, without any chemical residual, meets the health preserving awareness of modern.
Specific embodiment
The present invention will be described in detail below with reference to specific embodiments, the present embodiment based on the technical solution of the present invention,
The detailed implementation method and specific operation process are given.
A kind of processing technology of pseudo-classic silver cup, the processing technology include the following steps:
Step 1: stripping and slicing is carried out to silver ingot with dedicated blank mold under the pressure condition of 18-22MPa, after obtaining stripping and slicing
Silver ingot, it is spare;
Step 2: the silver ingot after step 1 stripping and slicing is put into the high-frequency circuit of 3-5kg, it is heated to being fused into silver-colored water, adds
Hot temperature is 1000 DEG C, pours into cooling and shaping in the mold of certain specification later, the silver bullion after must being formed is spare;
Step 3: the silver bullion after step 2 is formed forges, the stomata generated in the reverse mould on silver bullion is hit tight, later
With trigger squeeze in 13-17kg/cm2Pressure under, the silver bullion after forging is pressed into the silver-colored band of 0.1-0.5mm thickness, it is spare;
Step 4: the silver-colored band that step 3 is pressed is cut into round silver strip with blanking mold, round silver strip is being stretched later
If by from tubbiness to elongated arterial highway mold on machine or hydraulic press, preferably, by from tubbiness to elongated five
Round silver strip is pulled into the silver cup of different model by mold, every to anneal through one of mold once, obtains silver cup after molding;Annealing
Be by silver cup under the firelock of liquefied gas and oxygen, it is red with burning so that silver has more ductility, do standard for subsequent pressure pattern
It is standby;
Step 5: by filler is filled inside step 4 silver cup after molding, preferably, the filler is polyurethane glue
Stick or micelle, the mold of outside fitting setting different pattern, filler expands to silver cup under the pressure of 15-20MPa later
It is squeezed, the silver cup of pattern must be pressed;
Step 6: being dried after the silver cup surface cleaning agent that step 5 presses pattern is sufficiently cleaned, after must cleaning
Silver cup;
Step 7: the silver cup after step 6 is cleaned is placed in the potassium sulfide solution that concentration is 8-12%, temperature control 90-110
DEG C, it places 25-35s and pulls out later, obtain a kind of pseudo-classic silver cup, the pseudo-classic silver cup of gained is in dark brown, with classic color.It uses later
Ready-made pseudo-classic silver cup is put into the inside by exquisite gift box modelled after an antique, then red silk band is fixed, and the specification and fidelity of silver are put into
Card.
Preferably, the mold of different pattern described in step 5 includes internal model and external mold, internal model and external mold are cylinder
Shape;Internal model is along the circumferential direction cut into three with chromium 12# steel through fine turning lathe Che Haohou by the size of the size according to needed for internal model
Equal part, so that internal model is uniformly divided into three arc-like sheets;Internal model inner wall is provided with pattern, and the pattern in internal model is using the copper sun done
Pole, the pattern on copper anode be with Seiko engraving machine designed pattern finishing impression up, the pattern on anode is passed through into electricity
Spark is made on three arc-like sheets;The external mold be made into 45# steel and wall thickness 2-4cm, external mold pressure resistance upper limit value be greater than
20MPa, for fixing internal model.When pressing pattern, filler is filled inside silver cup after molding, three arc-like sheets are close to silver after molding
Cup outer wall, forms a columnar internal model, is then used to outer die casing outside internal model fix internal model, acts on later in pressure
Lower filler expansion is to squeeze silver cup, so that designed pattern is pressed on silver cup.
Embodiment one
A kind of processing technology of pseudo-classic silver cup, the processing technology include the following steps:
Step 1: stripping and slicing is carried out to silver ingot with dedicated blank mold under the pressure condition of 20MPa, the silver after obtaining stripping and slicing
Ingot, it is spare;
Step 2: the silver ingot after step 1 stripping and slicing is put into the high-frequency circuit of 4kg, it is heated to being fused into silver-colored water, heats
Temperature is 1000 DEG C, pours into cooling and shaping in the mold of certain specification later, the silver bullion after must being formed is spare;
Step 3: the silver bullion after step 2 is formed forges, the stomata generated in the reverse mould on silver bullion is hit tight, later
With trigger squeeze in 15kg/cm2Pressure under, the silver bullion after forging is pressed into the silver-colored band of 0.3mm thickness, it is spare;
Step 4: the silver-colored band that step 3 is pressed is cut into round silver strip with blanking mold, round silver strip is being stretched later
By the way that if from tubbiness to elongated arterial highway mold, round silver strip to be pulled into the silver cup of different model, every warp on machine or hydraulic press
One of mold is annealed once, and silver cup after molding is obtained;Annealing is by silver cup under the firelock of liquefied gas and oxygen, with baked wheaten cake
Red, such silver can extrude pattern with regard to more ductile;
Step 5: by filler is filled inside step 4 silver cup after molding, preferably, the filler is polyurethane glue
Stick or micelle, the mold of outside fitting setting different pattern, filler expands to carry out silver cup under the pressure of 18MPa later
It squeezes, the silver cup of pattern must be pressed;
Step 6: being dried after the silver cup surface cleaning agent that step 5 presses pattern is sufficiently cleaned, after must cleaning
Silver cup;
Step 7: the silver cup after step 6 is cleaned is placed in the potassium sulfide solution that concentration is 10%, 100 DEG C of temperature control, place
It is pulled out after 30s, obtains a kind of pseudo-classic silver cup.Later with exquisite gift box modelled after an antique, ready-made pseudo-classic silver cup is put into the inside, then
Red silk band is fixed, and the specification and fidelity card of silver are put into.
Embodiment two
A kind of processing technology of pseudo-classic silver cup, the processing technology include the following steps:
Step 1: carrying out stripping and slicing to silver ingot under the pressure condition of 18MPa, the silver ingot after obtaining stripping and slicing is spare;
Step 2: the silver ingot after step 1 stripping and slicing is heated to be fused into silver-colored water, cooling and shaping in mold is poured into later, is obtained
Silver bullion after sizing, it is spare;
Step 3: the silver bullion after step 2 is formed forges, later with trigger squeeze in 13kg/cm2Pressure under, will
Silver bullion after forging is pressed into the silver-colored band of 0.1mm thickness, spare;
Step 4: the silver-colored band that step 3 is pressed is cut into round silver strip with blanking mold, round silver strip is being stretched later
Every equal through one of mold by the way that if from tubbiness to elongated arterial highway mold, round silver strip to be pulled into the silver cup of different model on machine
Annealing is primary, obtains silver cup after molding;
Step 5: by filler is filled inside step 4 silver cup after molding, preferably, the filler is polyurethane glue
Stick or micelle.The mold of outside fitting setting different pattern, filler expands to carry out silver cup under the pressure of 15MPa later
It squeezes, the silver cup of pattern must be pressed;
Step 6: being dried after the silver cup surface cleaning agent that step 5 presses pattern is sufficiently cleaned, after must cleaning
Silver cup;
Step 7: the silver cup after step 6 is cleaned is placed in the potassium sulfide solution that concentration is 8%, 90 DEG C of temperature control, place
It is pulled out after 25s, obtains a kind of pseudo-classic silver cup liner, pseudo-classic silver cup liner and transparent outer cover inlayed together, pattern gap
It is perfused with calcium plaster, keeps it sufficiently honest, increase the perfection and robustness of cup.It is put into drying, the baking in drying box later
Dry temperature is 60 DEG C, drying time 1.5h.Scouring pad is finally used, dish washing liquid aqueous solution is dipped in and one is thoroughly cleaned again to cup's surface
Time, obtain a kind of pseudo-classic silver cup.
Preferably, the mold of different pattern described in step 5 includes internal model and external mold, internal model and external mold are cylinder
Shape, internal model inner wall are provided with pattern, and internal model along the circumferential direction trisection.The external mold wall thickness 2cm, and external mold pressure resistance upper limit value
Greater than 20MPa.
Embodiment three
A kind of processing technology of pseudo-classic silver cup, the processing technology include the following steps:
Step 1: carrying out stripping and slicing to silver ingot under the pressure condition of 22MPa, the silver ingot after obtaining stripping and slicing is spare;
Step 2: the silver ingot after step 1 stripping and slicing is heated to be fused into silver-colored water, cooling and shaping in mold is poured into later, is obtained
Silver bullion after sizing, it is spare;
Step 3: the silver bullion after step 2 is formed forges, later with trigger squeeze in 17kg/cm2Pressure under, will
Silver bullion after forging is pressed into the silver-colored band of 0.5mm thickness, spare;
Step 4: the silver-colored band that step 3 is pressed is cut into round silver strip with blanking mold, round silver strip is being stretched later
Every equal through one of mold by the way that if from tubbiness to elongated arterial highway mold, round silver strip to be pulled into the silver cup of different model on machine
Annealing is primary, obtains silver cup after molding;
Step 5: by filler is filled inside step 4 silver cup after molding, preferably, the filler is polyurethane glue
Stick or micelle.The mold of outside fitting setting different pattern, filler expands to carry out silver cup under the pressure of 20MPa later
It squeezes, the silver cup of pattern must be pressed;
Step 6: being dried after the silver cup surface cleaning agent that step 5 presses pattern is sufficiently cleaned, after must cleaning
Silver cup;
Step 7: the silver cup after step 6 is cleaned is placed in the potassium sulfide solution that concentration is 12%, 110 DEG C of temperature control, place
It is pulled out after 35s, obtains a kind of pseudo-classic silver cup housing, pseudo-classic silver cup housing and stainless steel heat-preservation liner inlayed together, pattern
Gap is perfused with calcium plaster, is put into drying in drying box later, and the drying temperature is 150 DEG C, drying time 4h.It takes out
Cup's surface is thoroughly cleaned afterwards, obtains a kind of pseudo-classic silver cup.
The mold of different pattern described in step 5 includes internal model and external mold, and internal model and external mold are cylindrical shape, internal model inner wall
It is provided with pattern, and internal model along the circumferential direction trisection.The external mold wall thickness 4cm, and external mold pressure resistance upper limit value is greater than 20MPa.
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, though
So the present invention is as above with preferred embodiment description, and however, it is not intended to limit the invention, any technology people for being familiar with this profession
Member, without departing from the scope of the present invention, when a little change or modification made using technology contents described above
It is the equivalent embodiment of equivalent variations, but without departing from the technical solutions of the present invention, according to the technical essence of the invention
Any simple modification, equivalent change and modification to the above embodiments, all of which are still within the scope of the technical scheme of the invention.
Claims (8)
1. a kind of processing technology of pseudo-classic silver cup, it is characterised in that: the processing technology includes the following steps:
Step 1: carrying out stripping and slicing to silver ingot under the pressure condition of 18-22MPa, the silver ingot after obtaining stripping and slicing is spare;
Step 2: the silver ingot after step 1 stripping and slicing is heated to be fused into silver-colored water, cooling and shaping in mold is poured into later, must be formed
Silver bullion afterwards, it is spare;
Step 3: the silver bullion after step 2 is formed forges, later with trigger squeeze in 13-17kg/cm2Pressure under, will hammer into shape
Silver bullion after refining is pressed into the silver-colored band of 0.1-0.5mm thickness, spare;
Step 4: the silver-colored band that step 3 is pressed is cut into round silver strip with blanking mold, later by round silver strip on stretching-machine
It is every to anneal through one of mold if round silver strip to be pulled into the silver cup of different model by from tubbiness to elongated arterial highway mold
Once, silver cup after molding is obtained;
Step 5: filler will be filled inside step 4 silver cup after molding, and the mold of outside fitting setting different pattern, Zhi Hou
Filler expansion must press the silver cup of pattern to squeeze silver cup under the pressure of 15-20MPa;
Step 6: being dried after the silver cup surface cleaning agent that step 5 presses pattern is sufficiently cleaned, the silver cup after must cleaning;
Step 7: the silver cup after step 6 is cleaned is placed in the potassium sulfide solution that concentration is 8-12%, 90-110 DEG C of temperature control, put
It sets 25-35s to pull out later, obtains a kind of pseudo-classic silver cup.
2. a kind of processing technology of pseudo-classic silver cup as described in claim 1, it is characterised in that: step 7 is replaced with step 6
Silver cup after cleaning is placed in the potassium sulfide solution that concentration is 8-12%, 90-110 DEG C of temperature control, is placed 25-35s and is pulled out later, obtain
A kind of pseudo-classic silver cup liner inlays pseudo-classic silver cup liner and transparent outer cover together, and pattern gap is perfused with calcium plaster, it
After be put into drying in drying box, cup's surface is thoroughly cleaned after taking-up, obtains a kind of pseudo-classic silver cup.
3. a kind of processing technology of pseudo-classic silver cup as described in claim 1, it is characterised in that: step 7 is replaced with step 6
Silver cup after cleaning is placed in the potassium sulfide solution that concentration is 8-12%, 90-110 DEG C of temperature control, is placed 25-35s and is pulled out later, obtain
A kind of pseudo-classic silver cup housing is inlayed pseudo-classic silver cup housing and stainless steel heat-preservation liner together, pattern gap calcium plaster
Perfusion is put into drying in drying box later, thoroughly cleans cup's surface after taking-up, obtain a kind of pseudo-classic silver cup.
4. a kind of processing technology of pseudo-classic silver cup as claimed in claim 2 or claim 3, it is characterised in that: the drying temperature is 60-
150 DEG C, drying time 1.5-4h.
5. a kind of processing technology of pseudo-classic silver cup as described in claim 1, it is characterised in that: annealing described in step 4 uses liquid
Change the firelock of gas and oxygen.
6. a kind of processing technology of pseudo-classic silver cup as described in claim 1, it is characterised in that: different pattern described in step 5
Mold includes internal model and external mold, and internal model and external mold are cylindrical shape, and internal model inner wall is provided with pattern, and internal model along the circumferential direction three
Equal part.
7. a kind of processing technology of pseudo-classic silver cup as claimed in claim 6, it is characterised in that: the external mold wall thickness 2-4cm, and
External mold pressure resistance upper limit value is greater than 20MPa.
8. a kind of processing technology of pseudo-classic silver cup as described in claim 1, it is characterised in that: filler described in step 5 is poly- ammonia
Rouge glue stick or micelle.
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CN108817852B true CN108817852B (en) | 2019-05-31 |
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JPH09140537A (en) * | 1995-11-22 | 1997-06-03 | Nippon Sanso Kk | Tableware and tableware cover |
CN104372330A (en) * | 2013-08-12 | 2015-02-25 | 国金黄金集团有限公司 | Preparation method of silver product with colored surface |
CN104924827A (en) * | 2015-05-08 | 2015-09-23 | 河南梦祥纯银制品有限公司 | Manufacturing method of antiqued silver |
CN105925975A (en) * | 2016-05-12 | 2016-09-07 | 上海渊泉集币收藏品有限公司 | Method for preparing yellow chemical conversion film on surface of silver product |
CN107022756A (en) * | 2017-05-18 | 2017-08-08 | 依波精品(深圳)有限公司 | The passivation technology of silver and silver alloy |
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2018
- 2018-05-21 CN CN201810489534.3A patent/CN108817852B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09140537A (en) * | 1995-11-22 | 1997-06-03 | Nippon Sanso Kk | Tableware and tableware cover |
CN104372330A (en) * | 2013-08-12 | 2015-02-25 | 国金黄金集团有限公司 | Preparation method of silver product with colored surface |
CN104924827A (en) * | 2015-05-08 | 2015-09-23 | 河南梦祥纯银制品有限公司 | Manufacturing method of antiqued silver |
CN105925975A (en) * | 2016-05-12 | 2016-09-07 | 上海渊泉集币收藏品有限公司 | Method for preparing yellow chemical conversion film on surface of silver product |
CN107022756A (en) * | 2017-05-18 | 2017-08-08 | 依波精品(深圳)有限公司 | The passivation technology of silver and silver alloy |
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