CN108816523A - Double hydroxy fatty acid soap collecting agents of a kind of alpha-amido and the preparation method and application thereof - Google Patents
Double hydroxy fatty acid soap collecting agents of a kind of alpha-amido and the preparation method and application thereof Download PDFInfo
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- CN108816523A CN108816523A CN201810408978.XA CN201810408978A CN108816523A CN 108816523 A CN108816523 A CN 108816523A CN 201810408978 A CN201810408978 A CN 201810408978A CN 108816523 A CN108816523 A CN 108816523A
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- alpha
- amido
- fatty acid
- hydroxy fatty
- acid
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 49
- 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 35
- 239000000194 fatty acid Substances 0.000 title claims abstract description 35
- 229930195729 fatty acid Natural products 0.000 title claims abstract description 35
- -1 hydroxy fatty acid Chemical class 0.000 title claims abstract description 33
- 239000000344 soap Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000005188 flotation Methods 0.000 claims abstract description 37
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- 239000012141 concentrate Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 239000002002 slurry Substances 0.000 claims description 13
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 239000011574 phosphorus Substances 0.000 claims description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000012074 organic phase Substances 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- ONIHPYYWNBVMID-UHFFFAOYSA-N diethyl benzene-1,4-dicarboxylate Chemical compound CCOC(=O)C1=CC=C(C(=O)OCC)C=C1 ONIHPYYWNBVMID-UHFFFAOYSA-N 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims 1
- 229910001948 sodium oxide Inorganic materials 0.000 claims 1
- 239000010459 dolomite Substances 0.000 abstract description 6
- 229910000514 dolomite Inorganic materials 0.000 abstract description 6
- 150000002500 ions Chemical class 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000002686 phosphate fertilizer Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910014033 C-OH Inorganic materials 0.000 description 1
- 229910014570 C—OH Inorganic materials 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 1
- 229910001748 carbonate mineral Inorganic materials 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/06—Phosphate ores
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to double hydroxy fatty acid soap collecting agents of a kind of alpha-amido and its preparation method and application, the structural formula of the double hydroxy fatty acid soap collecting agents of the alpha-amido is：The C8H17For eight carbon alkyl of straight chain.Collecting agent provided by the invention has efficient selectivity to dolomite, carries that mine ability is strong, and dosing is small, and bubble mobility is good, can be used for key player on a team's desiliconization and be used for it is counter select de-magging, to Ca2+、Mg2+Ion has preferable sorting, have good collecting performance, ore dressing overall efficiency 82.91~84.64%, raw material is easy to get, and beneficiation cost is low, and can 10 DEG C or so flotation at low temperature, be suitable for Collophanite flotation field.
Description
Technical field
The present invention relates to a kind of collecting agents, and in particular to a kind of double hydroxy fatty acid soap collecting agents of alpha-amido and its preparation side
Method.
Background technique
Collophane is phosphate fertilizer and phosphatic basic material, has highly important work to agricultural production and grain security
With.The phosphorus ore " rich without richness " in China produces the grade of collophane in 17~18%P at present2O5.And it directly processes
The grade of phosphate fertilizer and phosphatic phosphorus ore has to be larger than 28%P2O5, therefore the collophane of these extraction has to pass through floating and enriching
After could processing and utilization.Moreover, collophane and the embedding earth relationship of dolomite are complicated in these collophanes, it is desirable that grinding fineness is high, choosing
Mine production cost increases considerably, and the development of floating agent focuses primarily upon the multifunctional dough of water-wet side in recent years, and current
Common fatty acid collecting agent bubble mobility is bad to cause the efficiency of separation low, and poor selectivity, intolerant to hard water, water solubility
Difference, poor performance at low temperatures, are not able to satisfy the ore dressing requirement of this kind of collophane.Therefore, the research efficiency of separation is high, bubble mobility is good,
Resistance to hard water, good water solubility, cryogenic property are well and the new collector of non-environmental-pollution has great importance.
Summary of the invention
It is a kind of novel the technical problem to be solved by the present invention is to aiming at the above shortcomings existing in the prior art, provide
Double hydroxy fatty acid soap collecting agents of alpha-amido and preparation method thereof, the collecting agent good water solubility, selectivity is high, bubble mobility
It is good, counter to collophane in acid condition de-magging can be selected, raw material is easy to get, and preparation is simple.
In order to solve the above technical problems, technical solution provided by the invention is：
A kind of double hydroxy fatty acid soap collecting agents of alpha-amido, the knot of the double hydroxy fatty acid soap collecting agents of the alpha-amido are provided
Structure formula is：
The C8H17For eight carbon alkyl of straight chain.
The present invention also provides the preparation methods of the double hydroxy fatty acid soap collecting agents of above-mentioned alpha-amido, and specific step is as follows：
1) alpha-amido epoxyfatty acid is prepared：Alpha-amido oleic acid is mixed with Peracetic acid, the concentrated sulfuric acid, then stirring heating
It is reacted 4~8 hours to 60~100 DEG C, isolates organic phase after reaction and obtain alpha-amido epoxyfatty acid；
2) the double hydroxy fatty acid soap collecting agents of alpha-amido are prepared：By alpha-amido epoxyfatty acid obtained by step 1) and tristearin
Acid, sodium hydroxide, water, diethyl phthalate mixing, are then heated to 80~120 DEG C and are stirred to react 4~8 hours, reaction knot
It discharges after beam, cooling obtains the double hydroxy fatty acid soap collecting agents of alpha-amido.
Preferably, the step 1) concentrated sulfuric acid concentration is 98%.
According to the above scheme, step 1) the stirring heating rate is 1~2 DEG C/min.
According to the above scheme, step 1) the alpha-amido oleic acid and the mass ratio of Peracetic acid, the concentrated sulfuric acid are 40：10.2~
15：0.8~1.2.
According to the above scheme, the step 2) diethyl phthalate is diethyl phthalate, terephthalic acid (TPA) diethyl
The mixture of one or both of ester.
According to the above scheme, step 2) the alpha-amido epoxyfatty acid and stearic acid, sodium hydroxide, water, phthalic acid two
The mass ratio of ethyl ester is 60：20~50：6~15：20~50：0.1~0.3.
The present invention also provides double applications of the hydroxy fatty acid soap collecting agent in Collophanite flotation of above-mentioned alpha-amido.
The application method of the double hydroxy fatty acid soap collecting agents of above-mentioned alpha-amido, carries out flotation using direct-reverse flotation method, specifically
Steps are as follows：
1) direct flotation：By collophane ore grinding to grinding fineness -0.074mm mass fraction up to 85~90%, flotation cell is poured into,
Water is added to obtain the ore pulp that mass concentration is 20~35%, adjusting slurry pH with sodium carbonate is 9~10, and sodium metasilicate inhibition is added
Then the double hydroxy fatty acid soap collecting agents of the alpha-amido are added in ore pulp by silicate, additional amount is 0.8-1.2Kg/t glue
Phosphorus ore stirs, and progress one thick two is single-minded in flotation cell sweeps flotation, obtains concentrate slurry；
2) reverse flotation：Concentrate slurry obtained by step 1) is poured into flotation cell, water is added to obtain the mine that mass concentration is 20~35%
Slurry adjusts slurry pH to 4~5 with dilute sulfuric acid, and phosphorus inhibitor (phosphoric acid) is added, by the double hydroxy fatty acid soaps of the alpha-amido
Collecting agent is added in ore pulp, additional amount be 0.8-1.2Kg/t collophane, stir, using one thick two sweep technique into
Row flotation.
The double hydroxy fatty acid soap collecting agents of alpha-amido provided by the invention since the alpha-position of fatty acid is replaced by amino,
Water-wet side can form inner salt in the solution, increase the polarity of water-wet side, improve collecting agent and mineral surfaces metal ion
Electrostatic force, increase the conductivity of solution, reduce surface tension；Also, due to introducing hydrophobicity in hydrophobic side
The mobility of foam can be improved in weaker hydroxyl；In addition collaboration work occurs for the N atomic energy on the O atom and amino on carboxyl
Stable five-membered ring chelate is formed with the metal ion with mineral surfaces, improves the collecting ability of collecting agent, NH2Base is to Ca2+、
Mg2+The difference of ionic interaction power is big compared with carboxyl, can improve collecting agent to Ca2+、Mg2+The sorting capability of ion.
The beneficial effects of the present invention are：1, collecting agent provided by the invention is compared with existing collecting agent, to dolomite
With efficient selectivity, load mine ability is strong, and dosing is small (dosing is in 0.8-1.2Kg/t collophane), foam flowing
Property it is good, scrape bubble time about 5~7min, foam time about 7~10min, can be used for key player on a team's desiliconization and be used for it is counter select de-magging,
To Ca2+、Mg2+Ion has preferable sorting, has good collecting performance, and ore dressing overall efficiency 82.91~84.64% is former
Material is easy to get, and beneficiation cost is low (about 4.8-7.2 member/t mine), and can 10 DEG C or so flotation at low temperature, be suitable for Collophanite flotation
Field.2, collecting agent preparation process provided by the invention is simple, and reaction condition is mild, easy to industrialized production, and prepare and
There is no the discharge of " three wastes " during use, it is environmental-friendly.
Detailed description of the invention
Fig. 1 is the infrared spectroscopy of the double hydroxy fatty acid soap collecting agents of resulting alpha-amido prepared by the embodiment of the present invention 1
Figure.
Specific embodiment
Technical solution in order to enable those skilled in the art to better understand the present invention, with reference to the accompanying drawing to the present invention make into
One step detailed description.
Embodiment 1
The double hydroxy fatty acid soap collecting agents of alpha-amido are prepared, specific step is as follows：
It takes 42.2g alpha-amido oleic acid in beaker, is slowly added to the concentrated sulfuric acid and 10.8g Peracetic acid of 0.8g 98%, with
The heating rate stirring of 1 DEG C/min is warming up to 60 DEG C and reacts 8 hours, and reaction solution is transferred in separatory funnel again after reaction,
Lower aqueous solution is separated, organic phase is washed with water for several times, obtains alpha-amido epoxyfatty acid.
Ingredient by weight percentage, take 25g alpha-amido epoxyfatty acid, 10g stearic acid, 5g sodium hydroxide, 20g water and
0.04g diethyl phthalate is placed in flask, is uniformly mixed, and is heated to 120 DEG C and is stirred to react 6 hours, after reaction
The double hydroxy fatty acid soap collophane collecting agents of alpha-amido are obtained after discharging, cooling.
Fig. 1 is the infrared spectrogram of the double hydroxy fatty acid soap collecting agents of the resulting alpha-amido of the present embodiment.Such as Fig. 1,
1563.06cm-1And 1447.18cm-1Strong absworption peak be COO—Absorption band due to the formation of inner salt be carboxyl C-O bond distance
Equalization.Two peaks near 722 are the absorption band of C-N key.1240.26cm-1And 1072.64cm-1Strong absworption peak be C-OH
Absorption band, in 3421.47cm-1Wide absorption peak is the absorption band of CO-H, in 3332.15cm-1Absorption peak be N-H absorption
Band is covered by strong hydroxyl peak.In 2923.05cm-1And 2653.08cm-1Strong absworption peak methyl and methylene absorption
Band can deduce the following (C of structural formula of the collecting agent of preparation8H17For eight carbon alkyl of straight chain)：
Embodiment 2
The double hydroxy fatty acid soap collecting agents of alpha-amido are prepared, specific step is as follows：
Take 211g alpha-amido oleic acid in beaker, be slowly added to the concentrated sulfuric acid and 75g Peracetic acid of 6g 98%, with 2 DEG C/
The heating rate stirring of min is warming up to 100 DEG C and reacts 4 hours, and reaction solution is transferred in separatory funnel again after reaction, is separated
Lower aqueous solution, organic phase are washed with water for several times, obtain alpha-amido epoxyfatty acid.
Ingredient by weight percentage, take 100g alpha-amido epoxyfatty acid, 83.33g stearic acid, 25g sodium hydroxide,
83.33g water and 0.5g diethyl phthalate are placed in flask, are uniformly mixed, and are heated to 80 DEG C and are stirred to react 8 hours, instead
It discharges after answering, obtain the double hydroxy fatty acid soap collophane collecting agents of alpha-amido after cooling.
Embodiment 3
Use embodiment 1 and the double hydroxy fatty acid soap collophane collecting agents of the alpha-amido of the preparation of embodiment 2 as collecting respectively
Agent carries out direct-reverse flotation to the big exit of valley collophane in Hubei using reverse floatation process, and the chemical composition of essential element is shown in Table 1：
Table 1
Specifically method for floating is：
1. direct flotation：By collophane ore grinding to grinding fineness -0.074mm mass fraction up to 85~90%, flotation cell is poured into,
Water is added to obtain the ore pulp that mass concentration is 35%, adjusting slurry pH with 10% sodium carbonate liquor is 9~10, and silicic acid is added
Sodium inhibits silicate, and a small amount of calgon is then added and plays dispersing agent, prevents ore particle from assembling agglomerating, presses down at the same time
Other metal ions are made, then the double hydroxy fatty acid soap collophane collecting agents of alpha-amido are added in ore pulp, additional amount is
0.8Kg/t collophane (beneficiation cost is about 4.8 yuan/t mine), stirs, and progress one thick two is single-minded in flotation cell sweeps
Flotation obtains concentrate slurry；
2. reverse flotation：Gained concentrate slurry is poured into flotation cell, adds water to obtain the ore pulp that mass concentration is 20~35%, adds dilute
Sulfuric acid adjusts slurry pH to 4~5, adds phosphoric acid and inhibits collophane, is eventually adding the double hydroxy fatty acid soap glue phosphorus of alpha-amido
Mine collecting agent, additional amount are 1.2Kg/t collophane (beneficiation cost is about 7.2 yuan/t mine), are stirred, using one thick two
Technique is swept to flotate dolomite.
In floatation process, bubble time about 7min, foam time about 10min are scraped, bubble mobility is good.
Data are as shown in table 2 before and after flotation：
Table 2
| P2O5/ % | The rate of recovery/% | MgO/% | ||
| Experimental example 1 | Concentrate | 29.36 | 84.64 | 0.81 |
| Tailing | 4.16 | |||
| Experimental example 2 | Concentrate | 29.85 | 82.91 | 0.83 |
| Tailing | 4.34 |
The grade and the rate of recovery that can be seen that concentrate after reverse flotation by above-mentioned data are all higher, by just in embodiment 1
Select one thick two it is single-minded sweep, anti-choosing sweeps to obtain concentrate grade 29.36% by one thick two.Pass through same dresser in embodiment 2
Skill obtains the floatation indicators of concentrate grade 29.85%.
The carbonate mineral of DOLOMITE CRYSTALS category trigonal system, chemical component are CaMg (CO3)2, selected collophane raw ore
Content of MgO 5.16%, after the collecting agent flotation that 2 concentrate content of MgO of table can be seen that using Examples 1 and 2 synthesis, concentrate
Content of MgO is reduced to 0.81~0.83%, illustrates that collecting agent provided in this embodiment is selectively good to dolomite.
In addition, remaining above-mentioned floatation process is constant, flotation temperature is to carry out flotation at 10 DEG C, the results showed that flotation effect is poor
Not less, illustrate that such collecting agent is also suitable under 10 DEG C or so low temperature.
Claims (9)
1. a kind of double hydroxy fatty acid soap collecting agents of alpha-amido, which is characterized in that the double hydroxy fatty acid soap collectings of the alpha-amido
The structural formula of agent is：
The C8H17For eight carbon alkyl of straight chain.
2. a kind of preparation method of the double hydroxy fatty acid soap collecting agents of alpha-amido described in claim 1, which is characterized in that specific
Steps are as follows：
1) alpha-amido epoxyfatty acid is prepared：Alpha-amido oleic acid is mixed with Peracetic acid, the concentrated sulfuric acid, then stirring is warming up to 60
~100 DEG C are reacted 4~8 hours, are isolated organic phase after reaction and are obtained alpha-amido epoxyfatty acid；
2) the double hydroxy fatty acid soap collecting agents of alpha-amido are prepared：By alpha-amido epoxyfatty acid obtained by step 1) and stearic acid, hydrogen
Sodium oxide molybdena, water, diethyl phthalate mixing, are then heated to 80~120 DEG C and are stirred to react 4~8 hours, go out after reaction
Material, cooling obtain the double hydroxy fatty acid soap collecting agents of alpha-amido.
3. preparation method according to claim 2, which is characterized in that the step 1) concentrated sulfuric acid concentration is 98%.
4. preparation method according to claim 2, which is characterized in that step 1) the stirring heating rate be 1~2 DEG C/
min。
5. preparation method according to claim 2, which is characterized in that step 1) the alpha-amido oleic acid and Peracetic acid,
The mass ratio of the concentrated sulfuric acid is 40：10.2~15：0.8~1.2.
6. preparation method according to claim 2, which is characterized in that the step 2) diethyl phthalate is adjacent benzene two
The mixture of one or both of formic acid diethylester, diethyl terephthalate.
7. preparation method according to claim 2, which is characterized in that step 2) the alpha-amido epoxyfatty acid and tristearin
Acid, sodium hydroxide, water, diethyl phthalate mass ratio be 60：20~50：6~15：20~50：0.1~0.3.
8. a kind of double applications of the hydroxy fatty acid soap collecting agent in Collophanite flotation of alpha-amido described in claim 1.
9. application according to claim 8, which is characterized in that carry out flotation using direct-reverse flotation method, specific steps are such as
Under：
1) direct flotation：By collophane ore grinding to grinding fineness -0.074mm mass fraction up to 85~90%, flotation cell is poured into, water is added
The ore pulp that mass concentration is 20~35% is obtained, adjusting slurry pH with sodium carbonate is 9~10, and sodium metasilicate is added and inhibits silicic acid
Then the double hydroxy fatty acid soap collecting agents of the alpha-amido are added in ore pulp by salt, additional amount is 0.8-1.2Kg/t glue phosphorus
Mine stirs, and progress one thick two is single-minded in flotation cell sweeps flotation, obtains concentrate slurry；
2) reverse flotation：Concentrate slurry obtained by step 1) is poured into flotation cell, water is added to obtain the ore pulp that mass concentration is 20~35%, is used
Dilute sulfuric acid adjusts slurry pH to 4~5, and phosphorus inhibitor is added, and the double hydroxy fatty acid soap collecting agents of the alpha-amido are added
Into ore pulp, additional amount is 0.8-1.2Kg/t collophane, is stirred, and sweeps technique using one thick two and carries out flotation.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109290061A (en) * | 2018-11-29 | 2019-02-01 | 武汉工程大学 | A kind of trihydroxy fatty acid soaps collecting agent and its preparation method and application |
| CN112221718A (en) * | 2020-09-17 | 2021-01-15 | 宜都兴发化工有限公司 | Collecting agent applied to normal-temperature alkali-free flotation of collophanite and preparation method thereof |
| CN114011580A (en) * | 2021-10-29 | 2022-02-08 | 宜都兴发化工有限公司 | Impurity removal method for low-grade micro-fine particle phosphate ore |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1730161A (en) * | 2005-07-30 | 2006-02-08 | 中蓝连海设计研究院 | Collophanite direct flotation and reverse flotation technique |
| CN103990550A (en) * | 2014-05-28 | 2014-08-20 | 中蓝连海设计研究院 | Collophanite direct flotation collector, and preparation method, purposes and application method thereof |
| CN105344492A (en) * | 2015-11-04 | 2016-02-24 | 武汉工程大学 | Collophanite direct-reverse flotation collecting agent and preparation method and application thereof |
| US20160114338A1 (en) * | 2014-10-23 | 2016-04-28 | Georgia-Pacific Chemicals Llc | Cationic collectors with mixed polyamidoamines and methods for making and using same |
| CN106238216A (en) * | 2016-08-03 | 2016-12-21 | 湖北富邦科技股份有限公司 | A kind of low-temperature instant type rock phosphate in powder flotation collector and preparation method |
-
2018
- 2018-05-02 CN CN201810408978.XA patent/CN108816523A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1730161A (en) * | 2005-07-30 | 2006-02-08 | 中蓝连海设计研究院 | Collophanite direct flotation and reverse flotation technique |
| CN103990550A (en) * | 2014-05-28 | 2014-08-20 | 中蓝连海设计研究院 | Collophanite direct flotation collector, and preparation method, purposes and application method thereof |
| US20160114338A1 (en) * | 2014-10-23 | 2016-04-28 | Georgia-Pacific Chemicals Llc | Cationic collectors with mixed polyamidoamines and methods for making and using same |
| CN105344492A (en) * | 2015-11-04 | 2016-02-24 | 武汉工程大学 | Collophanite direct-reverse flotation collecting agent and preparation method and application thereof |
| CN106238216A (en) * | 2016-08-03 | 2016-12-21 | 湖北富邦科技股份有限公司 | A kind of low-temperature instant type rock phosphate in powder flotation collector and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| 张泾生: "《现代选矿技术手册 第2册 浮选与化学选矿》", 28 February 2011, 冶金工业出版社 * |
| 李静等: "油酸多元醇的合成研究", 《林产化学与工业》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109290061A (en) * | 2018-11-29 | 2019-02-01 | 武汉工程大学 | A kind of trihydroxy fatty acid soaps collecting agent and its preparation method and application |
| CN112221718A (en) * | 2020-09-17 | 2021-01-15 | 宜都兴发化工有限公司 | Collecting agent applied to normal-temperature alkali-free flotation of collophanite and preparation method thereof |
| CN114011580A (en) * | 2021-10-29 | 2022-02-08 | 宜都兴发化工有限公司 | Impurity removal method for low-grade micro-fine particle phosphate ore |
| CN114011580B (en) * | 2021-10-29 | 2024-03-12 | 宜都兴发化工有限公司 | Impurity removing method for low-grade fine-particle phosphorite |
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