CN108816035A - Micro-nano oxygen bubbles synergistic carriers biology VOCS waste gas processing method and system - Google Patents
Micro-nano oxygen bubbles synergistic carriers biology VOCS waste gas processing method and system Download PDFInfo
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
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- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
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- B01D—SEPARATION
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
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Abstract
The present invention relates to VOCS technical field of waste gas treatment, refer in particular to micro-nano oxygen bubbles synergistic carriers biology VOCS waste gas processing method and system.Method of the invention is to be sprayed to VOCS exhaust gas using micro-nano oxygen is soaked and enable VOCS exhaust gas by being equipped with the bio-carrier of strain, and system of the invention includes sequentially connected micro-nano oxygen bubbles processing unit and biological treatment device and for feeding the micro-nano oxygen bubbles generator of the soaked convolution of micro-nano oxygen inside micro-nano oxygen bubbles processing unit.The present invention has preferable clean-up effect to VOCS exhaust gas and can prevent secondary pollution.
Description
Technical field
The present invention relates to VOCS technical field of waste gas treatment, refer in particular to the VOCS of micro-nano oxygen bubbles synergistic carriers biology
Waste gas processing method and system.
Background technique
VOCS (volatile organic compounds) volatile organic matter, refers to that saturated vapor pressure is greater than under room temperature
In 260 DEG C of organic compounds below, or at 20 °C, vapour pressure has boiling point more than or equal to 10Pa under 70Pa, normal pressure
There are corresponding volatile whole organic compounds.
Currently, the organic pollutant (VOCS) etc. largely discharged in industrial production, communications and transportation and daily life threatens
Mankind itself's health and the environment depended on for existence.Traditional air purifying process such as spray, absorption, filtering, dosing, UF membrane and
Selective reduction technology etc., that there are purification efficiencies is low, clean-up effect is poor, operating cost is high, easily causes asking for secondary environmental pollution
Topic.For this purpose, seek a kind of VOCS waste gas pollution control and treatment purification method of novelty, it is difficult to point with solving the organic VOCS exhaust gas of current VOCS
The problem of solving and leading to environmental pollution.
Summary of the invention
The present invention provides a kind of good purification for problem of the prior art and does not easily cause the micro- of secondary environmental pollution
The VOCS waste gas processing method of nanometer oxygen bubbles synergistic carriers biology.
The present invention adopts the following technical scheme that：A kind of exhaust-gas treatment side VOCS of micro-nano oxygen bubbles synergistic carriers biology
Method, including the following steps successively carried out：
A：Mixing water and oxygen, and pressurize to the mixture of water and oxygen, so that it is micro- less than 30 to form diameter in water
The oxygen bubbles of rice；
B:It boosts to the mixture of water and oxygen, so that generating nanoscale oxygen bubbles in water, forms micro-nano oxygen
Air-bubble；
C：It is soaked to micro-nano oxygen to ionize, it is soaked to form the micro-nano oxygen of ionization；
D：Using the VOCS exhaust gas for ionizing micro-nano oxygen bubbles water spray and rising flowing, ionize micro-nano oxygen it is soaked with
Become water after VOCS exhaust gas contact；
E：Utilize VOCS exhaust gas of the micro-nano oxygen bubbles water spray of ionization generated in step C after step D spray, ionization
Micro-nano oxygen it is soaked with VOCS exhaust gas contact after become water；
F：The water that collection step D and step E is generated, circulation step A to step E；
G:Enable the VOCS exhaust gas after step E spray by being provided with the bio-carrier of flora.
Preferably, the bio-carrier in step G is polyurethane foamed blocks.
Preferably, flora used in step G is PSB bacterium, B350 bacterium and B110 bacterium.
Preferably, the number ratio of PSB bacterium, B350 bacterium and B110 bacterium is 1:2:1.5.
The present invention also provides a kind of VOCS exhaust gas of micro-nano oxygen bubbles synergistic carriers biology for realizing the above method
Processing system, including micro-nano oxygen bubbles processing unit, biological treatment device and the micro-nano oxygen bubbles generator of convolution；It is described
Micro-nano oxygen bubbles processing unit includes first passage, the second channel being connected to the first passage, is used for described first
The micro-nano oxygen bubbles release head of level-one and be set to that channel is passed through the air inlet of VOCS exhaust gas, is set to inside first passage
The micro-nano oxygen bubbles release head of second level inside second channel, the air inlet are equipped with positive pressure pressing mechanism；The convolution micro-nano
The delivery outlet of rice oxygen bubbles generator and the input port of the micro-nano oxygen bubbles release head of the level-one and the second level are micro-nano
The input port of oxygen bubbles release head is connected to, and the micro-nano oxygen bubbles release head of level-one is located at the top of the air inlet, institute
The inside for the micro-nano oxygen bubbles generator that circles round is stated equipped with the magnetic sheet for ionizing micro-nano oxygen bubbles；The biological treatment device
Third channel including being connected to the second channel, the Biotrickling filter inside the third channel and for institute
The nutrient solution spray head of Biotrickling filter sprinkling nutrient solution is stated, the third channel is equipped with for flowing out third channel for VOCS exhaust gas
Gas outlet, the gas outlet be equipped with negative pressure pressing mechanism.
Preferably, further including gas-liquid mixing pump, the micro-nano oxygen bubbles generator of convolution is equipped with rotary compression chamber, gas
Liquid mixing chamber and as the gas-liquid mixed room extend made of input channel, the gas-liquid mixed room it is closed at one end, it is described
The other end of gas-liquid mixed room is connected to one end of the rotary compression chamber, the output of the micro-nano oxygen bubbles generator of convolution
Mouth is located at the other end of the rotary compression chamber, and the output end of the gas-liquid mixing pump passes through the input channel and the gas-liquid
Mixing chamber connection, the magnetic sheet are set to the inner wall of the rotary compression chamber.
Preferably, further including the micro-nano oxygen bubbles circulating water pool being connected to the first passage, the micro-nano oxygen
The water outlet in circulation of bubbles pond passes through the input pipe after the gas-liquid mixing pump with the micro-nano oxygen bubbles generator of convolution
Road connection.
Preferably, the nutrient solution spray head is equipped with atomizer.
Preferably, the Biotrickling filter be equipped with polyurethane foamed blocks, the polyurethane foamed blocks be equipped with PSB bacterium,
B350 bacterium and B110 bacterium.
Preferably, further including booster pump and the nutrient solution circulatory pool being connected to the third channel, the nutrient solution
The water outlet of circulatory pool is connected to after passing through the booster pump with the input terminal of the nutrient solution spray head.
Beneficial effects of the present invention：By cooperateing with bio-carrier to carry out at purification VOCS exhaust gas using micro-nano oxygen bubbles
Reason, not only has preferable clean-up effect and can prevent secondary pollution.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is the top view of the micro-nano oxygen bubbles generator of convolution of the invention.
Fig. 3 is the internal structure chart of the micro-nano oxygen bubbles generator of convolution of the invention.
Appended drawing reference is：1-micro-nano oxygen bubbles processing unit, 11-first passages, 12-second channels, 13-air inlets
Mouthful, 14-positive pressure pressing mechanisms, the micro-nano oxygen bubbles release head of 15-level-ones, the micro-nano oxygen bubbles release head of 16-second levels, 2-
Biological treatment device, 21-third channels, 22-Biotrickling filters, 23-nutrient solution spray heads, 231-atomizers, 24-outlets
Mouthful, 25-negative pressure pressing mechanisms, the 3-micro-nano oxygen bubbles generators of convolution, 31-magnetic sheets, 32-gas-liquid mixing pumps, 33-rotations
Turn compression chamber, 34-gas-liquid mixed rooms, 35-input channels, 4-micro-nano oxygen bubbles circulating water pools, 5-booster pumps, 6-battalion
Nutrient solution circulatory pool.
Specific embodiment
For the ease of the understanding of those skilled in the art, the present invention is made further below with reference to embodiment and attached drawing
Bright, the content that embodiment refers to not is limitation of the invention.The present invention is described in detail below in conjunction with attached drawing.
Embodiment one
A kind of VOCS waste gas processing method of micro-nano oxygen bubbles synergistic carriers biology, including the following step successively carried out
Suddenly：
A：Mixing water and oxygen, and pressurize to the mixture of water and oxygen, so that it is micro- less than 30 to form diameter in water
The oxygen bubbles of rice；
B:It boosts to the mixture of water and oxygen, so that generating nanoscale oxygen bubbles in water, forms micro-nano oxygen
Air-bubble；
C：It is soaked to micro-nano oxygen to ionize, it is soaked to form the micro-nano oxygen of ionization；
D：Using the VOCS exhaust gas for ionizing micro-nano oxygen bubbles water spray and rising flowing, ionize micro-nano oxygen it is soaked with
Become water after VOCS exhaust gas contact；
E：Utilize VOCS exhaust gas of the micro-nano oxygen bubbles water spray of ionization generated in step C after step D spray, ionization
Micro-nano oxygen it is soaked with VOCS exhaust gas contact after become water；
F：The water that collection step D and step E is generated, circulation step A to step E；
G:Enable the VOCS exhaust gas after step E spray by being provided with the bio-carrier of flora.
Micro-nano oxygen bubbles surface band positive and negative charge, and relative to common blister, institute's band positive and negative charge is relatively high, benefit
With micro-nano oxygen bubbles with positive elecrtonegativity, can adsorb with plus-minus electric substance.VOCS exhaust gas and the micro-nano oxygen bubbles of ionization
After water contact, all hydrophobicity finely ground particle substances can be adsorbed on the surface of micro-nano oxygen bubbles, adsorpting polymerization in VOCS exhaust gas
The macromolecular resin formed afterwards is not soluble in water, therefore can precipitate and fall and separate with VOCS exhaust gas.User periodically recycles whereabouts
Macromolecular resin.
In the case where continuous shrink, the density of the charge of electric double layer can increase rapidly 10um micro-nano oxygen bubbles below
Height, when bubbles burst, the positive and negative charge for having reached high concentration, which sparks, discharges the energy of savings, generates a large amount of
Radical ion, such as oxonium ion, hydrogen ion, hydroxyl ion.And hydroxyl radical free radical therein has very strong oxidation,
Purification reduction effect well can be played with some organic pollutants for being difficult to degrade of oxygenolysis.Micro-nano oxygen bubbles rupture
When, the tension force effect of walls will discharge huge explosion energy, ultrasonic energy, and this ultrasonic wave is made with very strong sterilization
With can produce a large amount of anion, destroy pollutant and be covalently keyed, the chemical bond that can also be destroyed inside pollutant connects
It connects, completes oxidative degradation pollutant.When VOCS exhaust gas continues flowing and second spray soaked by the micro-nano oxygen of ionization
When, VOCS substance in VOCS exhaust gas by the continuous oxygenolysis of micro-nano oxygen bubbles at small molecule or monomolecular substance, while it is micro-
The ultrasonic energy that nano oxygen bubbles burst generates sterilizes VOCS exhaust gas, to realize purification.In VOCS exhaust gas still at this time
There is part VOCS substance not to be decomposed, therefore military order VOCS exhaust gas utilizes the flora pair on bio-carrier by bio-carrier
VOCS adsorbed, nitrification and denitrification, final 95% or more VOCS substance be oxidized be reduced to carbon dioxide, water, oxygen,
Hydrogen realizes that VOCS waste gas purification handles qualified discharge, and can prevent secondary pollution.
During processing, VOCS exhaust gas is made to rise flowing using the positive pressures pressurizing device such as air blower, it is useless compared to VOCS
Gas nature Doenward flow, the flow velocity of VOCS exhaust gas is slower, and soaked time of contact is also longer with micro-nano oxygen, effectively improves net
Change effect.
Micro-nano oxygen ducks in drink ramp after can make oxygen from the water surface scatter and disappear, so as to cause micro-nano in water
Oxygen bubbles content is few, then causes to purify insufficient.Micro-nano oxygen in the present invention is soaked sprayed before by magnetic field
Ionization, therefore the ion that the micro-nano oxygen bubbles formed is generated with ionization, so that micro-nano oxygen bubbles forms ion air mass.
Under the action of these ions, bubble surface tension gradually increases, and keeps the diameter of bubble smaller and smaller, and with the dissolution of ion
And it is gradually dissolved in water, and this ionization power and surface tension have completely or partially resisted liquid and floated to bubble generation
Power effect, so that bubble is steadily stayed in liquid, be effectively ensured micro-nano oxygen it is soaked in have higher micro-nano oxygen
Air bubble content, to improve purification efficiency and clean-up effect.
Further, the bio-carrier in step G is polyurethane foamed blocks.Polyurethane foamed blocks shape is similar to sponge, hole
Cave specific surface area reaches 250 meters squared per grams or more, provides 1 to microorganism：The habitat of 250 huge growth and breeding.By biology
The carrier biofilm that carrier is formed can be carried out biofiltration, decompose and convert the harmful substance in VOCS exhaust gas.
Further, flora used in step G is PSB bacterium, B350 bacterium and B110 bacterium.PSB bacterium is facultative type mushroom：
Such as swamp Rhodopseudomonas, green pseudomonas, Rhodococcus sp, it can utilize and decompose ammonia, hydrogen sulfide, mercaptan.B350 bacterium is facultative type
Mushroom：Such as Nocard's bacillus, Bacillus foecalis alkaligenes, aspergillus niger, can utilize and Decomposition of benzene, aldehyde, Trimethylamine, furfural.B110 bacterium is preferably
Oxygen type mushroom：Such as bacillus subtilis, bacillus megaterium, saccharomyces cerevisiae, can utilize with decompose saturated hydrocarbons, cyclic hydrocarbon, ether, ketone,
Ester, phenolic compounds.
Further, the number ratio of PSB bacterium, B350 bacterium and B110 bacterium is 1:2:1.5.Can effectively prevent flora it
Between swallow mutually, guarantee that PSB bacterium, B350 bacterium and B110 bacterium can steadily coexist on bio-carrier.
With the composition before four groups of VOCS exhaust-gas treatments, composition compares following table with treated, it is seen that various in VOCS
Organic VOCS exhaust gas constituents removal rate reaches 90-99%, and average removal rate is 95% or more, and standard biologic liquid spray process
Removal rate is usual<50%, originally water spray removal rate is usual<45%, it is seen that method treatment effect provided by the invention it is more preferable and
Treatment effeciency is higher.
Embodiment two
The present embodiment provides a kind of VOCS of micro-nano oxygen bubbles synergistic carriers biology based on method described in embodiment one
Exhaust treatment system.
As shown in Figure 1, the present invention includes that micro-nano oxygen bubbles processing unit 1, biological treatment device 2 and convolution are micro-nano
Oxygen bubbles generator 3；The micro-nano oxygen bubbles processing unit 1 includes first passage 11, is connected to the first passage 11
Second channel 12, is set to inside first passage 11 air inlet 13 for being passed through VOCS exhaust gas to the first passage 11
The micro-nano oxygen bubbles release head 15 of level-one and the micro-nano oxygen bubbles release head 16 of second level being set to inside second channel 12, institute
Air inlet 13 is stated equipped with positive pressure pressing mechanism 14；The delivery outlet of the micro-nano oxygen bubbles generator 3 of convolution and the level-one are micro-
The input port of nanometer oxygen bubbles release head 15 and the input port of the micro-nano oxygen bubbles release head 16 of the second level are connected to, described
The micro-nano oxygen bubbles release head 15 of level-one is located at the top of the air inlet 13, the micro-nano oxygen bubbles generator 3 of convolution
Inside is equipped with the magnetic sheet 31 for ionizing micro-nano oxygen bubbles；The biological treatment device 2 includes connecting with the second channel 12
Logical third channel 21, the Biotrickling filter 22 inside the third channel 21 and for the Biotrickling filter 22
The nutrient solution spray head 23 of nutrient solution is sprayed, the third channel 21 is equipped with for the outlet for VOCS exhaust gas outflow third channel 21
Mouth 24, the gas outlet 24 are equipped with negative pressure pressing mechanism 25.
The micro-nano oxygen bubbles release of level-one after VOCS exhaust gas enters first passage 11 by air inlet 13, in first passage 11
First 15 pairs of VOCS exhaust gas sprays, and after VOCS exhaust gas and the soaked contact of micro-nano oxygen, all hydrophobicitys are small in VOCS exhaust gas
Particulate matter can be adsorbed on the surface of micro-nano oxygen bubbles, and the macromolecular resin formed after adsorpting polymerization is not soluble in water, therefore
It can precipitate and fall and separated with VOCS exhaust gas.VOCS exhaust gas continues to flow and enter second channel 12 and be discharged by second level bubble
The soaked spray of micro-nano oxygen of first 16 release, the VOCS substance in VOCS exhaust gas is by the continuous oxygenolysis of micro-nano oxygen bubbles
At small molecule or monomolecular substance, while the ultrasonic energy that the rupture of micro-nano oxygen bubbles generates carries out disinfection to VOCS exhaust gas, from
And realize the purification of VOCS exhaust gas.Still there is part VOCS substance not to be decomposed in VOCS exhaust gas at this time, therefore military order VOCS exhaust gas
By Biotrickling filter 22, VOCS is adsorbed using the microorganism on Biotrickling filter 22, nitrification and denitrification, finally
95% or more VOCS substance, which is oxidized, is reduced to carbon dioxide, water, oxygen, hydrogen, realizes that the processing of VOCS waste gas purification is up to standard
Discharge, and secondary pollution can be prevented.
The micro-nano oxygen bubbles release head 15 of level-one and the micro-nano oxygen bubbles release head 16 of second level are the release spray head that is vortexed.
The micro-nano oxygen bubbles generator 3 that circles round is equipped with magnetic sheet 31, after being powered using external power supply to magnetic sheet 31, magnetic sheet
31 magnetic field energies generated ionize micro-nano oxygen bubbles.The ion that micro-nano oxygen bubbles after ionization is generated with ionization,
So that micro-nano oxygen bubbles forms ion air mass.Under the action of these ions, bubble surface tension gradually increases, and makes bubble
Diameter it is smaller and smaller, and be gradually dissolved in water with the dissolution of ion, and this ionization power and surface tension are complete
The buoyancy that liquid generates bubble has been resisted in portion or part, so that bubble is steadily stayed in liquid, is effectively ensured
There is higher micro-nano oxygen bubbles content during micro-nano oxygen is soaked, to improve purification efficiency and clean-up effect.
Positive pressure pressing mechanism 14 is specially air blower, can be pressurizeed to gas, so that gas is entering micro-nano oxygen
Flowing can be risen after bubble processing unit 1.Compared to VOCS exhaust gas nature Doenward flow, the flow velocity of VOCS exhaust gas is slower, and micro-
The time of contact of nano oxygen air-bubble is also longer, effectively improves clean-up effect.
Negative pressure pressing mechanism 25 is specially air-introduced machine, can attract VOCS exhaust gas that VOCS exhaust gas is made to pass through biological drop
Filter bed 22 and the outside that third pipeline is discharged.
Nutrient solution is sprayed to Biotrickling filter 22 using nutrient solution spray head 23, is able to maintain 22 surface wettability of Biotrickling filter
And it is being rich in nutrition, it is grown convenient for microorganism.
As shown in Figure 1 to Figure 3, the invention also includes gas-liquid mixing pump 32, the micro-nano oxygen bubbles generator 3 of convolution is set
Input channel 35 made of having rotary compression chamber 33, gas-liquid mixed room 34 and being extended as the gas-liquid mixed room 34, the gas
Liquid mixing chamber 34 it is closed at one end, the other end of the gas-liquid mixed room 34 is connected to one end of the rotary compression chamber 33, institute
The delivery outlet for stating the micro-nano oxygen bubbles generator 3 that circles round is located at the other end of the rotary compression chamber 33, the gas-liquid mixing pump
32 output end is connected to by the input channel 35 with the gas-liquid mixed room 34, and the magnetic sheet 31 is set to the rotation pressure
The inner wall of contracting chamber 33.
Gas-liquid mixing pump 32 is mixed and is pressurizeed to water and oxygen, and air-water mixture with pressure is enabled to pass through input channel
35 enter gas-liquid mixed room 34.Tangent line due to air-water mixture with pressure and along gas-liquid mixed room 34 enters gas-liquid mixed room
34, therefore air-water mixture can be revolved with high speed vorticity and be risen, and be sprayed by the delivery outlet of rotary compression chamber 33, kept constant
Under conditions of pressure and flow, since the cavity diameter of 33 cavity of rotary compression chamber gradually subtracts along the flow direction of air-water mixture
It is small, therefore air-water mixture can be accelerated and with the propulsion of accelerator, liquid internal pressure in rotary compression chamber 33
It gradually increases, bubble forms the nano grade air bubbles of high energy electrification by limited compression.
As shown in Figure 1, the invention also includes the micro-nano oxygen bubbles circulating water pool 4 being connected to the first passage 11, institute
The water outlet of micro-nano oxygen bubbles circulating water pool 4 is stated by being soaked after the gas-liquid mixing pump 32 with the micro-nano oxygen of convolution
The input channel 35 of raw device 3 is connected to.Water is recycled by micro-nano oxygen bubbles circulating water pool 4, effectively reduces processing cost.
As shown in Figure 1, the nutrient solution spray head 23 is equipped with atomizer 231.Make nutrient solution fog-like by atomizer 231
It sprays, to utilize the whole surface of lesser water wetting Biotrickling filter 22.
The Biotrickling filter 22 be equipped with polyurethane foamed blocks, the polyurethane foamed blocks be equipped with PSB bacterium, B350 bacterium and
B110 bacterium.Polyurethane foamed blocks are bio-carrier.For polyurethane foamed blocks shape similar to sponge, it is flat that hole specific surface area reaches 250
Square rice/gram or more, 1 is provided to microorganism：The habitat of 250 huge growth and breeding.The life that flora on bio-carrier is formed
Object film can be carried out biofiltration, decompose and convert the harmful substance in VOCS exhaust gas.PSB bacterium is facultative type mushroom：As marsh is red
Pseudomonas, green pseudomonas, Rhodococcus sp can utilize and decompose ammonia, hydrogen sulfide, mercaptan.B350 bacterium is facultative type mushroom：Such as promise
Cattell bacterium, Bacillus foecalis alkaligenes, aspergillus niger can utilize and Decomposition of benzene, aldehyde, Trimethylamine, furfural.B110 bacterium is aerobic mushroom：
Such as bacillus subtilis, bacillus megaterium, saccharomyces cerevisiae, it can utilize and decompose saturated hydrocarbons, cyclic hydrocarbon, ether, ketone, ester, phenolate conjunction
Object.
As shown in Figure 1, further include booster pump 5 and the nutrient solution circulatory pool 6 that is connected to the third channel 21, the battalion
The water outlet of nutrient solution circulatory pool 6 is connected to after passing through the booster pump 5 with the input terminal of the nutrient solution spray head 23.To nutrient solution into
Row recycles, to reduce processing cost.
The above is only present pre-ferred embodiments, is not intended to limit the present invention in any form, although
The present invention is disclosed as above with preferred embodiment, and however, it is not intended to limit the invention, any person skilled in the art,
It does not depart within the scope of technical solution of the present invention, when the technology contents using the disclosure above make a little change or are modified to equivalent change
The equivalent embodiment of change, but without departing from the technical solutions of the present invention, technology refers to above embodiments according to the present invention
Made any simple modification, equivalent change and modification, belong in the range of technical solution of the present invention.
Claims (10)
1. a kind of VOCS waste gas processing method of micro-nano oxygen bubbles synergistic carriers biology, it is characterised in that：Including successively carrying out
Following steps：
A：Mixing water and oxygen, and pressurize to the mixture of water and oxygen, so that forming diameter in water less than 30 microns
Oxygen bubbles；
B:It boosts to the mixture of water and oxygen, so that generating nanoscale oxygen bubbles in water, forms micro-nano oxygen bubbles
Water；
C：It is soaked to micro-nano oxygen to ionize, it is soaked to form the micro-nano oxygen of ionization；
D：Rise the VOCS exhaust gas flowed using micro-nano oxygen bubbles water spray is ionized, it is soaked useless with VOCS to ionize micro-nano oxygen
Become water after gas contact；
E：Using VOCS exhaust gas of the micro-nano oxygen bubbles water spray of ionization generated in step C after step D spray, micro-nano is ionized
Rice oxygen it is soaked with VOCS exhaust gas contact after become water；
F：The water that collection step D and step E is generated, circulation step A to step E；
G:Enable the VOCS exhaust gas after step E spray by being provided with the bio-carrier of flora.
2. a kind of VOCS waste gas processing method of micro-nano oxygen bubbles synergistic carriers biology according to claim 1, special
Sign is：Bio-carrier in step G is polyurethane foamed blocks.
3. a kind of VOCS waste gas processing method of micro-nano oxygen bubbles synergistic carriers biology according to claim 1, special
Sign is：Flora used in step G is PSB bacterium, B350 bacterium and B110 bacterium.
4. a kind of VOCS waste gas processing method of micro-nano oxygen bubbles synergistic carriers biology according to claim 3, special
Sign is：The number ratio of PSB bacterium, B350 bacterium and B110 bacterium is 1:2:1.5.
5. a kind of micro-nano oxygen bubbles for realizing method described in any claim in claim 1 to claim 4
The VOCS exhaust treatment system of synergistic carriers biology, it is characterised in that：At micro-nano oxygen bubbles processing unit (1), biology
Manage device (2) and the micro-nano oxygen bubbles generator (3) of convolution；
The micro-nano oxygen bubbles processing unit (1) includes first passage (11), be connected to the first passage (11) second
Channel (12) is used to be passed through the air inlet (13) of VOCS exhaust gas to the first passage (11), be set in first passage (11)
The micro-nano oxygen bubbles release head (15) of the level-one in portion and the micro-nano oxygen bubbles of second level for being set to second channel (12) inside are released
It puts head (16), the air inlet (13) is equipped with positive pressure pressing mechanism (14)；
The delivery outlet of the micro-nano oxygen bubbles generator (3) of convolution is defeated with the micro-nano oxygen bubbles release head (15) of the level-one
The input port of entrance and the micro-nano oxygen bubbles release head (16) of the second level is connected to, the micro-nano oxygen bubbles release of level-one
Head (15) is located at the top of the air inlet (13), and the inside of the micro-nano oxygen bubbles generator (3) of convolution is equipped with for electricity
Magnetic sheet (31) from micro-nano oxygen bubbles；
The biological treatment device (2) includes the third channel (21) being connected to the second channel (12), is located at the third
The internal Biotrickling filter (22) in channel (21) and the nutrient solution spray for being used to spray nutrient solution to the Biotrickling filter (22)
Head (23), the third channel (21) be equipped with for for VOCS exhaust gas outflow third channel (21) gas outlet (24), it is described go out
Port (24) is equipped with negative pressure pressing mechanism (25).
6. a kind of VOCS exhaust treatment system of micro-nano oxygen bubbles synergistic carriers biology according to claim 5, special
Sign is：Further include gas-liquid mixing pump (32), the micro-nano oxygen bubbles generator (3) of the convolution be equipped with rotary compression chamber (33),
Gas-liquid mixed room (34) and the input channel (35) as made of the gas-liquid mixed room (34) extension, the gas-liquid mixed room
(34) closed at one end, (33 one end is connected to the other end of the gas-liquid mixed room (34), and the convolution is micro- with rotary compression chamber
The delivery outlet of nano oxygen bubble generator (3) is located at rotary compression chamber (33) other end, the output of the gas-liquid mixing pump (32)
End is connected to by the input channel (35) with the gas-liquid mixed room (34), and the magnetic sheet (31) is set to the rotary compression
The inner wall of chamber (33).
7. a kind of VOCS exhaust treatment system of micro-nano oxygen bubbles synergistic carriers biology according to claim 6, special
Sign is：It further include the micro-nano oxygen bubbles circulating water pool (4) being connected to the first passage (11), the micro-nano oxygen bubbles
The water outlet of circulating water pool (4) by the gas-liquid mixing pump (32) afterwards with the micro-nano oxygen bubbles generator (3) of the convolution
Input channel (35) connection.
8. a kind of VOCS exhaust treatment system of micro-nano oxygen bubbles synergistic carriers biology according to claim 5, special
Sign is：The nutrient solution spray head (23) is equipped with atomizer (231).
9. a kind of VOCS exhaust treatment system of micro-nano oxygen bubbles synergistic carriers biology according to claim 5, special
Sign is：The Biotrickling filter (22) be equipped with polyurethane foamed blocks, the polyurethane foamed blocks be equipped with PSB bacterium, B350 bacterium with
And B110 bacterium.
10. a kind of VOCS exhaust treatment system of micro-nano oxygen bubbles synergistic carriers biology according to claim 5, special
Sign is：It further include booster pump (5) and the nutrient solution circulatory pool (6) being connected to the third channel (21), the nutrient solution
The water outlet of circulatory pool (6) is connected to the input terminal of the nutrient solution spray head (23) afterwards by the booster pump (5).
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| CN201810690535.4A CN108816035A (en) | 2018-06-28 | 2018-06-28 | Micro-nano oxygen bubbles synergistic carriers biology VOCS waste gas processing method and system |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701456A (en) * | 2012-07-02 | 2012-10-03 | 西藏国策环保科技股份有限公司成都分公司 | Micro-nano active oxygen treatment method of sewage |
| JP2013034993A (en) * | 2012-09-27 | 2013-02-21 | Daiichi Kankyo Kk | Water treatment apparatus |
| WO2014192896A1 (en) * | 2013-05-29 | 2014-12-04 | 株式会社アースリンク | Micronanobubble generation method, micronanobubble generator, and micronanobubble generation device |
| CN205073862U (en) * | 2015-08-29 | 2016-03-09 | 广东紫方环保技术有限公司 | VOCs exhaust treatment device |
-
2018
- 2018-06-28 CN CN201810690535.4A patent/CN108816035A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701456A (en) * | 2012-07-02 | 2012-10-03 | 西藏国策环保科技股份有限公司成都分公司 | Micro-nano active oxygen treatment method of sewage |
| JP2013034993A (en) * | 2012-09-27 | 2013-02-21 | Daiichi Kankyo Kk | Water treatment apparatus |
| WO2014192896A1 (en) * | 2013-05-29 | 2014-12-04 | 株式会社アースリンク | Micronanobubble generation method, micronanobubble generator, and micronanobubble generation device |
| CN205073862U (en) * | 2015-08-29 | 2016-03-09 | 广东紫方环保技术有限公司 | VOCs exhaust treatment device |
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