CN108802107A - A method of based on resistance measurement concentration of hydrogen sulfide - Google Patents
A method of based on resistance measurement concentration of hydrogen sulfide Download PDFInfo
- Publication number
- CN108802107A CN108802107A CN201710299970.XA CN201710299970A CN108802107A CN 108802107 A CN108802107 A CN 108802107A CN 201710299970 A CN201710299970 A CN 201710299970A CN 108802107 A CN108802107 A CN 108802107A
- Authority
- CN
- China
- Prior art keywords
- hydrogen sulfide
- concentration
- resistance
- method based
- sample
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/06—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a liquid
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Abstract
The invention discloses a kind of methods based on resistance measurement concentration of hydrogen sulfide.Described method includes following steps：A carries out sampling and sample treatment to hydrogen sulfide, obtains the solution of Containing Sulfur silver colloid；The resistance value of solution, the concentration of hydrogen sulfide in sample is calculated using the resistance value measured where b measures vulcanization silver colloid.The method of the present invention is for optical colorimetry, the influence of the factors such as ambient light illumination and the collimation error can effectively be avoided, the configuration and drafting of standard curve, and the method for calculating concentration of hydrogen sulfide by measurement vulcanizes silver colloid resistance need not be carried out, the accuracy of measurement can be improved.
Description
Technical field
The present invention relates to a kind of methods based on resistance measurement concentration of hydrogen sulfide.
Background technology
It is related to occupational sulfurated hydrogen detection, refers to carrying out occupational in air of workplace to vulcanize
Hydrogen samples, and is then measured sample, obtains the concentration of hydrogen sulfide.
Occupational hydrogen sulfide in air of workplace at this stage is mainly carried out using silver nitrate colorimetic method
Detection.
Sample solution and placebo solution are carried out colorimetric by such method using optical colorimetry, the disadvantage is that
It is affected by factors such as ambient light illumination, the collimation errors, easily there is error, and accuracy is relatively low.
For these reasons, existing concentration of hydrogen sulfide detection method requires further improvement.
Invention content
It is an object of the invention to propose a kind of method based on resistance measurement concentration of hydrogen sulfide, this method is by measuring sample
The resistance of product solution, concentration of hydrogen sulfide when extrapolating sampling in air, to improve measuring accuracy.
To achieve the goals above, the present invention adopts the following technical scheme that：
A method of based on resistance measurement concentration of hydrogen sulfide, include the following steps：
A carries out sampling and sample treatment to hydrogen sulfide, obtains the solution of Containing Sulfur silver colloid；
The resistance value of solution where b measures vulcanization silver colloid calculates the dense of hydrogen sulfide in sample using the resistance value that measures
Degree.
Preferably, in the step a, sampling and sample treatment are carried out to hydrogen sulfide using standard GB/T Z160.33.
Preferably, in the step b, the resistance value of solution where measuring vulcanization silver colloid using resistance measuring module.
Preferably, in the step b, resistance measuring module uses liquid resistivity measuring instrument.
Preferably, in the step b, the concentration of hydrogen sulfide in sample is calculated using data processing module.
Preferably, in the step b, data processing module uses microcontroller.
Preferably, in the step b, the reckoning step of concentration of hydrogen sulfide is in sample：
Vulcanization silver colloid proportion in the solution is calculated using resistance value, extrapolates the dense of hydrogen sulfide in sample according to this
Degree.
Preferably, further include step after the step b：
C shows resistance value and final concentration of hydrogen sulfide result in measurement process.
Preferably, in the step c, resistance value and concentration of hydrogen sulfide result are shown using display module.
Preferably, in the step c, display module uses LED display.
The invention has the advantages that：
The present invention passes through the resistance of sample solution, concentration of hydrogen sulfide when extrapolating sampling in air, compared to mesh
For colorimetric method, the influence of the factors such as ambient light illumination and the collimation error can be avoided, the configuration of standard curve need not be carried out
With drafting, and by measurement vulcanize silver colloid resistance so that reckoning concentration of hydrogen sulfide method, the accuracy of measurement can be improved.
Description of the drawings
Fig. 1 is a kind of flow diagram of the method based on resistance measurement concentration of hydrogen sulfide in the embodiment of the present invention 1；
Fig. 2 is a kind of flow diagram of the method based on resistance measurement concentration of hydrogen sulfide in the embodiment of the present invention 2.
Specific implementation mode
Below in conjunction with the accompanying drawings and specific implementation mode invention is further described in detail：
Embodiment 1
In conjunction with shown in Fig. 1, a method of based on resistance measurement concentration of hydrogen sulfide, include the following steps：
A carries out sampling and sample treatment to hydrogen sulfide, obtains the solution of Containing Sulfur silver colloid；
The resistance value of solution where b measures vulcanization silver colloid calculates the dense of hydrogen sulfide in sample using the resistance value that measures
Degree.
A and b through the above steps so that the method in the present embodiment 1 has the following advantages that：
One, it is avoided that the interference of environmental factor and the sense of vision factor of people, reduces error；
Two, the configuration and drafting of standard curve need not be carried out；
Three, the method by measuring resistance can improve the accuracy of concentration of hydrogen sulfide measurement.
In step a, sampling and sample treatment are carried out to hydrogen sulfide using standard GB/T Z160.33.
The sampling process of hydrogen sulfide is specific as follows：In sampled point, series connection two is respectively equipped with the porous of 10.0ml absorbing liquids
Plate absorption tube, with 0.5L/min flow collection 15min air samples.
After sampling, close absorption tube into and out of tracheae, be placed in transport in clean container and preserve.
The processing procedure of hydrogen sulfide sample is：With the air inlet inside pipe wall 3 times for the absorbing liquid washing absorption pipe for adopting sample.It is front and back
Pipe respectively takes 5.0ml absorbing liquids in color-comparison tube, shakes up, for measuring.
Wherein, the effect of washing is that a small amount of liquid for allowing air inlet inside pipe wall to attach also is mixed into absorbing liquid, prevents from causing
Loss.
It, can be with being measured after diluted absorption solution if the concentration of determinand is more than measurement range in sample liquid, when calculating, is multiplied by dilute
Release multiple.
In stepb, the resistance value of solution where measuring vulcanization silver colloid using resistance measuring module.
Preferably, above-mentioned resistance measuring module uses liquid resistivity measuring instrument.
In stepb, the concentration of hydrogen sulfide in sample is calculated using data processing module.
Preferably, above-mentioned data processing module uses microcontroller.
In stepb, the reckoning step of concentration of hydrogen sulfide is in sample：
Vulcanization silver colloid proportion in the solution is calculated using resistance value, extrapolates the dense of hydrogen sulfide in sample according to this
Degree.
There are following functional relations with resistance value for concentration of hydrogen sulfide, i.e.,：C(H2S)=F (x)；
Wherein, C (H2S) indicate that concentration of hydrogen sulfide, x indicate that resistance value, F () indicate corresponding functional relation.
It was proved that with the increase of vulcanization silver colloid proportion, resistance value increases, and concentration of hydrogen sulfide increases.
The cooperative working process of resistance measuring module and data processing module is：
The resistance value of resistance measuring module sample solution (solution where vulcanizing silver colloid), the resistance value measured are defeated
It send to data processing module, calculates to obtain the concentration of hydrogen sulfide in sample by data processing module.
Embodiment 2
The present embodiment 2 has addressed a kind of method based on resistance measurement concentration of hydrogen sulfide, and this method removes following technical characteristic
Except 1 difference of above-described embodiment, remaining technical characteristic can refer to above-described embodiment 1.
As shown in Fig. 2, further including step after step b：
C shows resistance value and final concentration of hydrogen sulfide result in measurement process.
In step c, resistance value and concentration of hydrogen sulfide result are shown using display module.
Preferably, display module uses LED display.
By above-mentioned display module, the data such as the resistance value in concentration of hydrogen sulfide and measurement process can be inquired in time.
The cooperative working process of resistance measuring module, data processing module and display module is：
The resistance value of resistance measuring module sample solution (solution where vulcanizing silver colloid), the resistance value measured are defeated
It send to data processing module, after data processing, the resistance in concentration of hydrogen sulfide and measurement process is inquired using display module
Value.
Certainly, described above is only that presently preferred embodiments of the present invention is answered the present invention is not limited to enumerate above-described embodiment
When explanation, any technical person familiar with the field is all equivalent substitutes for being made, bright under the introduction of this specification
Aobvious variant, all falls within the essential scope of this specification, ought to be protected by the present invention.
Claims (10)
1. a kind of method based on resistance measurement concentration of hydrogen sulfide, which is characterized in that include the following steps：
A carries out sampling and sample treatment to hydrogen sulfide, obtains the solution of Containing Sulfur silver colloid；
The resistance value of solution, the concentration of hydrogen sulfide in sample is calculated using the resistance value measured where b measures vulcanization silver colloid.
2. a kind of method based on resistance measurement concentration of hydrogen sulfide according to claim 1, which is characterized in that the step
In a, sampling and sample treatment are carried out to hydrogen sulfide using standard GB/T Z160.33.
3. a kind of method based on resistance measurement concentration of hydrogen sulfide according to claim 1, which is characterized in that the step
In b, the resistance value of solution where measuring vulcanization silver colloid using resistance measuring module.
4. a kind of method based on resistance measurement concentration of hydrogen sulfide according to claim 3, which is characterized in that the step
In b, resistance measuring module uses liquid resistivity measuring instrument.
5. a kind of method based on resistance measurement concentration of hydrogen sulfide according to claim 1, which is characterized in that the step
In b, the concentration of hydrogen sulfide in sample is calculated using data processing module.
6. a kind of method based on resistance measurement concentration of hydrogen sulfide according to claim 5, which is characterized in that the step
In b, data processing module uses microcontroller.
7. a kind of method based on resistance measurement concentration of hydrogen sulfide according to claim 5, which is characterized in that the step
In b, the reckoning step of concentration of hydrogen sulfide is in sample：
Vulcanization silver colloid proportion in the solution is calculated using resistance value, extrapolates the concentration of hydrogen sulfide in sample according to this.
8. a kind of method based on resistance measurement concentration of hydrogen sulfide according to any one of claims 1 to 7, feature exist
In the step b further includes later step：
C shows resistance value and final concentration of hydrogen sulfide result in measurement process.
9. a kind of method based on resistance measurement concentration of hydrogen sulfide according to claim 8, which is characterized in that the step
In c, resistance value and concentration of hydrogen sulfide result are shown using display module.
10. a kind of method based on resistance measurement concentration of hydrogen sulfide according to claim 9, which is characterized in that the step
In rapid c, display module uses LED display.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710299970.XA CN108802107B (en) | 2017-05-02 | 2017-05-02 | Method for measuring concentration of hydrogen sulfide based on resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710299970.XA CN108802107B (en) | 2017-05-02 | 2017-05-02 | Method for measuring concentration of hydrogen sulfide based on resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108802107A true CN108802107A (en) | 2018-11-13 |
| CN108802107B CN108802107B (en) | 2021-02-09 |
Family
ID=64054014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710299970.XA Active CN108802107B (en) | 2017-05-02 | 2017-05-02 | Method for measuring concentration of hydrogen sulfide based on resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108802107B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114577793A (en) * | 2022-05-07 | 2022-06-03 | 北京大学 | Multi-scene hydrogen sulfide gas content online monitoring method and monitoring device |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RO79527A2 (en) * | 1980-05-03 | 1982-07-06 | Institutul De Cercetari Si Proiectari Pentru Gospodarirea Apelor,Ro | ELECTROCHEMICAL CELL HAVING A SYSTEM FOR MEASURING THE CONCENTRATION OF WATER CHLORIDES AND THE CONCENTRATION OF WATER CHLORIDES |
| CN1040866A (en) * | 1988-09-01 | 1990-03-28 | 中国人民解放军防化研究院第三所 | Detect the sensor of sulfuretted hydrogen in the atmosphere |
| CN1311433A (en) * | 2000-03-03 | 2001-09-05 | 中国石油化工集团公司 | Method for measuring total active sulfur in petroleum fractions |
| CN1376915A (en) * | 2002-04-12 | 2002-10-30 | 浙江大学 | Electrochemical sensor of dissolved hydrogen sulfide in extreme exvironment |
| CN1710417A (en) * | 2005-02-06 | 2005-12-21 | 张荣华 | High-temp, high-pressure H2S chemical sensor and making method |
| WO2010128280A2 (en) * | 2009-05-05 | 2010-11-11 | Medermica Limited | Ph measurement device |
| CN102538869A (en) * | 2011-01-06 | 2012-07-04 | 北京盈胜泰科技术有限公司 | System and method for monitoring liquid oil quality |
| CN102585991A (en) * | 2011-12-22 | 2012-07-18 | 北京盈胜泰科技术有限公司 | Method and system for removing and supplying antioxidant from/to transformer insulating oil impurities |
| CN104122301A (en) * | 2014-08-05 | 2014-10-29 | 江南大学 | Detergent concentration detection device for washing machine and detection method thereof |
| WO2016079356A1 (en) * | 2014-11-18 | 2016-05-26 | Universitat Rovira I Virgili | Resistive sensor for detecting benzene gas and method for the production thereof |
| CN105842292A (en) * | 2016-03-28 | 2016-08-10 | 安徽芯核防务装备技术股份有限公司 | Semiconductor for normal-temperature gas-sensitive detection of hydrogen sulfide, and preparation and application thereof |
| CN108139342A (en) * | 2015-10-07 | 2018-06-08 | 株式会社日立制作所 | Corrosive environment monitoring device and method |
-
2017
- 2017-05-02 CN CN201710299970.XA patent/CN108802107B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RO79527A2 (en) * | 1980-05-03 | 1982-07-06 | Institutul De Cercetari Si Proiectari Pentru Gospodarirea Apelor,Ro | ELECTROCHEMICAL CELL HAVING A SYSTEM FOR MEASURING THE CONCENTRATION OF WATER CHLORIDES AND THE CONCENTRATION OF WATER CHLORIDES |
| CN1040866A (en) * | 1988-09-01 | 1990-03-28 | 中国人民解放军防化研究院第三所 | Detect the sensor of sulfuretted hydrogen in the atmosphere |
| CN1311433A (en) * | 2000-03-03 | 2001-09-05 | 中国石油化工集团公司 | Method for measuring total active sulfur in petroleum fractions |
| CN1376915A (en) * | 2002-04-12 | 2002-10-30 | 浙江大学 | Electrochemical sensor of dissolved hydrogen sulfide in extreme exvironment |
| CN1710417A (en) * | 2005-02-06 | 2005-12-21 | 张荣华 | High-temp, high-pressure H2S chemical sensor and making method |
| WO2010128280A2 (en) * | 2009-05-05 | 2010-11-11 | Medermica Limited | Ph measurement device |
| CN102538869A (en) * | 2011-01-06 | 2012-07-04 | 北京盈胜泰科技术有限公司 | System and method for monitoring liquid oil quality |
| CN102585991A (en) * | 2011-12-22 | 2012-07-18 | 北京盈胜泰科技术有限公司 | Method and system for removing and supplying antioxidant from/to transformer insulating oil impurities |
| CN104122301A (en) * | 2014-08-05 | 2014-10-29 | 江南大学 | Detergent concentration detection device for washing machine and detection method thereof |
| WO2016079356A1 (en) * | 2014-11-18 | 2016-05-26 | Universitat Rovira I Virgili | Resistive sensor for detecting benzene gas and method for the production thereof |
| CN108139342A (en) * | 2015-10-07 | 2018-06-08 | 株式会社日立制作所 | Corrosive environment monitoring device and method |
| CN105842292A (en) * | 2016-03-28 | 2016-08-10 | 安徽芯核防务装备技术股份有限公司 | Semiconductor for normal-temperature gas-sensitive detection of hydrogen sulfide, and preparation and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 朱姝婧等: ""测定工作场所空气中硫化氢的实验研究"", 《中国卫生检验杂志》 * |
| 李诚芳等: ""胶体电解液的研究-电阻率和活度"", 《化学世界》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114577793A (en) * | 2022-05-07 | 2022-06-03 | 北京大学 | Multi-scene hydrogen sulfide gas content online monitoring method and monitoring device |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108802107B (en) | 2021-02-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105067596B (en) | Ozone-detecting element and detection method | |
| EP2151679A3 (en) | Method and apparatus for the analysis of materials | |
| ATE552411T1 (en) | DEVICE FOR DISTINGUISHING A LIQUID REDUCING AGENT | |
| CN205879777U (en) | NO2 concentration measurement device in atmosphere based on chamber subtracts phase shift spectral technique | |
| CN108802107A (en) | A method of based on resistance measurement concentration of hydrogen sulfide | |
| RU2422802C1 (en) | Procedure for evaluation of dust content of working zone | |
| CN107817220B (en) | Method for measuring mass concentration of easily released cyanide in thiocyanate-containing water | |
| CN106769950A (en) | The detection method of Lead in Gasoline | |
| DE60334544D1 (en) | METHOD FOR MEASURING A SILANOL GROUP | |
| CN107247014B (en) | Device and method for measuring particle size distribution of vacuum intermediate infrared interference smoke screen | |
| CN101639438A (en) | Detection method of lead content in gasoline | |
| CN205301121U (en) | Viscometer | |
| CN103645070B (en) | A kind of toy respiration test is used radial without reflux gas sampling apparatus | |
| CN108152090A (en) | A kind of smoke dust sampling device | |
| CN107271318B (en) | Device and method for measuring mass concentration of vacuum intermediate infrared interference smoke screen | |
| CN207992028U (en) | A kind of novel filter paper smoke intensity detection device | |
| CN108956481A (en) | Alternately Aerosol Extinction and NO in measurement atmosphere2The device and method of concentration | |
| DE102017209923A1 (en) | A mouthpiece, device, system and method for testing the usability of a mouthpiece for measuring analytes in exhaled air | |
| CN203848871U (en) | Air quality detection system | |
| CN103592223B (en) | A kind of atomic fluorescence sampling needle cleaning device | |
| CN106769239A (en) | A kind of gas accommodating device and vehicle | |
| CN105606603A (en) | Method for determining content of formaldehyde in liquid | |
| CN203275128U (en) | Medical test specimen sampler | |
| RU2428686C1 (en) | Method of determining cobalt (ii) using polymethacrylate matrix | |
| CN205067357U (en) | Mobile detection device of online intermittent type of quality of water |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220901 Address after: Yanan City, Shandong province Qingdao City three road 266071 No. 218 Patentee after: CHINA PETROLEUM & CHEMICAL Corp. Patentee after: Sinopec Safety Engineering Research Institute Co.,Ltd. Patentee after: Sinopec Engineering Quality Monitoring Co.,Ltd. Address before: Yanan City, Shandong province Qingdao City three road 266071 No. 218 Patentee before: CHINA PETROLEUM & CHEMICAL Corp. Patentee before: SINOPEC Research Institute OF SAFETY ENGINEERING |