CN108795714A - A kind of biogas Preparation equipment and its method - Google Patents

A kind of biogas Preparation equipment and its method Download PDF

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Publication number
CN108795714A
CN108795714A CN201710301850.9A CN201710301850A CN108795714A CN 108795714 A CN108795714 A CN 108795714A CN 201710301850 A CN201710301850 A CN 201710301850A CN 108795714 A CN108795714 A CN 108795714A
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tank
biogas
level
dehydration
gas
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马宏波
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New Energy Developments Ltd In Yongqing Yangzhou
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New Energy Developments Ltd In Yongqing Yangzhou
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    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
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    • B01D53/26Drying gases or vapours
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    • B01D53/26Drying gases or vapours
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/58Reaction vessels connected in series or in parallel
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    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
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    • C12M27/00Means for mixing, agitating or circulating fluids in the vessel
    • C12M27/02Stirrer or mobile mixing elements
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    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
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    • C12M41/00Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/12Means for regulation, monitoring, measurement or control, e.g. flow regulation of temperature
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    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/023Methane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/80Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/05Biogas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
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    • Y02P20/59Biological synthesis; Biological purification
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing

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Abstract

The present invention proposes a kind of biogas Preparation equipment and its method, including biogas fermentation device, desulfurizer, decarbonization device and dehydration device, biogas fermentation device is connected to level-one entrance separator, stage compressor is connected to level-one entrance separator, split-compressor is connected to stage compressor, secondary inlet separator is connected to split-compressor, desulfurizer is connected to secondary inlet separator, decarbonization device, dehydration device is sequentially communicated with decarbonization device, biogas fermentation device includes pretreatment warming tank, level-one anaerobic fermentation gas production tank and B grade anaerobic fermentation aerogenesis tank, enhance the activity of anaerobic bacteria, so that raw material and anaerobic bacteria are uniformly mixed, biogas output amount is high;Desulfurizer coordinates desulfurization using dry and wet, and desulfurizing agent is connect by storage vat with desulfurizing tower, and it is convenient to replace, using two level dehydration package so that dehydration is more thorough.

Description

A kind of biogas Preparation equipment and its method
Technical field
The invention belongs to field of renewable energy technology, a kind of biogas Preparation equipment and its method are particularly related to.
Background technology
Energy and environmental problem has become two big outstanding problem of today's society, non-renewable energy resources increasingly reduce and at In the case of this is increasingly raised, large and medium-sized biogas engineering is to solve one of the important means of energy and environmental problem.
All contain more insoluble solid in fermentation raw material used in most biogas engineering.For detesting containing solid material Oxygen digestion techniques mixs unevenness with anaerobic species from the point of view of practice there are still material, high energy consumption, be discharged carry secretly strain sludge compared with The problems such as more, seriously restricts the treatment effeciency of such anaerobic reactor;Secondly there are big after methane pool reverse has been answered for waste water etc. Amount sludge etc. is inconvenient to clear, and some biogas are blended in material mud and can not rule out, and have in turn resulted in the wave of biogas Take.
The ingredient of biogas generally has methane (CH4), carbon dioxide (CO2), oxygen (O2), nitrogen (N2), carbon monoxide (CO), hydrogen (H2), water (H2) and hydrogen sulfide (H O2Other gases compositions such as S).It is flammable that the purifying process of biogas mainly retains its With combustion-supporting components methane (CH4), oxygen (O2), carbon monoxide (CO) and hydrogen (H2), to the H in biogas2S, H2O, CO2With it is other Impurity is removed.
Desulfurization is in order to avoid hydrogen sulfide (H2S) etching apparatus and pipeline, hydrogen sulfide is in methane fuelled engine and internal combustion engine Bearing and some matching surfaces can be made to corrode, make the deterioration of lubricant of engine, to accelerate engine scuffing;And leakage H2S can cause to be poisoned, and burn the product SO released2、SO3It is the arch-criminal for causing acid rain, compares H2It endangers caused by S and also wants Greatly.It is more traditional in biogas desulfurization method to have two class of dry desulfurization and wet desulphurization, the dry desulfurization in industrial applications Easy to operate, equipment investment is small, and outstanding advantages are degree of purification height, and can remove a variety of organic sulfur compounds, are suitable for scale Small, biogas desulfurization when sulfur content is relatively low application, otherwise desulfurizing agent replace frequent, it is difficult to solve that sulphur, which cannot effectively recycle problem, Such as iron oxide process, activated carbon method, sieve method.Wet desulphurization is with specific solvent and feed gas, and removing is therein Hydrogen sulfide, the method are generally used for that treatment scale is big, the high thick desulfurization of sulfur content, but its that there is also Sulfur capacity is low, purify low precision Disadvantage does not remove organic sulfur generally, applicable to have pressurization WATER-WASHING METHOD, Alkali absorption method, ferrous solution absorption process, tannin extract (tannin) Method etc..In addition, novel biogas desulfurization technique also has the methods of UF membrane desulfurization and biological desulphurization, but operation and maintenance cost Height, difficulty are big, not yet industrially universal extensive use.And in large-sized biogas industrial applications there are no a kind of big ability, Precision is high, technique for applying at low cost and can recycling Sulphur ressource to greatest extent.
Remove CO in biogas2It is because of CO2Energy density, calorific value, the burning velocity of biogas are reduced, and increases biogas Firing temperature just must be to it if biogas used needs to reach Natural gas standard or is used as motor vehicle fuel In CO2It is removed.Decarbonization method in biogas is mainly liquid absorption method and solid absorption method, and liquid absorption method is divided into two Major class:One kind is Physical Absorption method, that is, utilizes CO2This characteristic that certain liquid can be dissolved in isolates it from mixture Come, different solvent absorption CO2Ability it is different, the purification degrees being finally reached are also different, but general all than chemical absorbing Purification degrees are low.Another kind of is chemical absorption method, according to CO2It is the characteristic of sour gas, utilizes alkaline absorbent and CO2Changed Reaction is learned to remove.Chemical absorption method can be by the CO in gas under less high pressure2It is refined to very high degree.But work as When with chemical absorbing, just no longer has after chemical absorbent has reacted completely and absorb CO2Characteristic, so chemical absorbent Absorbability is limited.CO is being removed using alkaline solution method2Technique in, gas is typically directly passed through alkaline solution In, there are CO2Gas cannot cause carbon-drop rate relatively low effectively fully with alkaline solution contact problems;Meanwhile alkaline solution and CO2Reaction, can reduce the concentration of alkaline solution, to make absorption efficiency reduce.
Biogas from anaerobic ferment devices output when, carry a large amount of moisture, especially in medium temperature or hot fermentation, biogas With higher humidity.When the biogas of higher levels of humidity flows in pipeline, since the variation dew point of temperature, pressure reduces, water steams Air cooling is solidifying to increase the resistance that biogas flows in pipeline, and the presence of vapor also reduces the calorific value of biogas, therefore needs Condensed water in biogas is removed, currently, common biogas dewatering is dehydrated for gravitational method, cold partition method, solvent Absorption process and solid-state physics water suction method, gravitational method dehydration are removed the part vapor in biogas with biogas gas-water separator, This biogas gas-water separator mainly installs horizontal strainer and vertical strainer respectively up and down in tower, and the water in biogas is promoted to steam Gas and biogas separation, but this device cannot simply and easily collect condensed water, need to additionally increase water collector equipment, increase into This;Cold partition method is to cause temperature change using pressure energy variation, the method for making vapor be condensed out from gas phase, such dress Pressurization or decompression processing, complicated and energy consumption need to be carried out by setting;Solvent absorption be using dehydrated solvent such as calcium chloride, lithium chloride and Glycols absorb vapor, this method brings the possibility of other impurities into having to biogas while absorbing vapor, simultaneously Regularly replace dehydrated solvent;Solid-state physics water suction method, which is adsorbed under surface of solids force effect, to be generated, and adsorbent exists de- It is the problem of cannot regenerating and need to regularly replacing after water, complicated for operation while of high cost.
Invention content
A kind of biogas Preparation equipment of present invention proposition and its method, solve material in marsh gas fermentation processes in the prior art Unevenness, high energy consumption are mixed with anaerobic species, the problems such as strain sludge is more is carried in water outlet secretly;It is inconvenient that desulfurizing agent is replaced, and de- Sulphur is not thorough;And carbon-drop rate and the lower defect of dehydration rate.
The technical proposal of the invention is realized in this way:
A kind of biogas Preparation equipment, including biogas fermentation device, desulfurizer, decarbonization device and dehydration device further include Level-one entrance separator, stage compressor, split-compressor and secondary inlet separator, the stage compressor and the level-one Entrance separator is connected to, and the split-compressor is connected to stage compressor, the secondary inlet separator and split-compressor Connection, the biogas fermentation device are connected to level-one entrance separator, and the desulfurizer connects with the secondary inlet separator Logical, the decarbonization device is connected to desulfurizer, and the dehydration device is connected to decarbonization device, the stage compressor and two level First-level buffer tank is provided between compressor, the dehydration device connects level 2 buffering tank, the level 2 buffering tank and three-level pressure Contracting machine connects, and the three-stage blower is connect with biogas storage device.
Further, the biogas fermentation device includes that pretreatment warming tank, level-one anaerobic fermentation gas production tank and two level are detested Aerobe fermentation aerogenesis tank, the pretreatment warming tank, level-one anaerobic fermentation gas production tank and B grade anaerobic fermentation aerogenesis tank are sequentially connected, Wherein, the level-one anaerobic fermentation gas production tank includes the first tank body, and hyperboloid guide shell, hyperboloid water conservancy diversion are equipped in the first tank body The outside of cylinder constitutes a water outlet stabilizing feed well, the bottom company of the hyperboloid guide shell and the first tank body together with the first inner tank wall It connects, by-pass filtration guard is provided in the open top of the hyperboloid guide shell, the first tank body lower part is equipped with water distributor, described Water distributor is connected in hyperboloid guide shell, and sludge pipe is provided in the hyperboloid guide shell, and the top of the first tank body is equipped with First biogas discharge pipe is provided with the first water outlet, first water outlet and secondary anaerobic on the water outlet stabilizing feed well side wall Fermentation gas tank connects, and the B grade anaerobic fermentation aerogenesis tank includes the second tank body, and second tank base is provided with double spiral shells Bar mixing plant, the twin-screw mixing plant include two opposite conveying augers of direction of rotation, two conveying augers and electricity Machine connects, and is provided with the second biogas discharge pipe above second tank body, discharge outlet is provided with below second tank body, The first biogas discharge pipe is connected to the second biogas discharge pipe and is connected to level-one entrance separator.
Further, the bottom of second tank body and first tank body is taper.
Further, it is provided with secondary filtration net on first water outlet.
Further, the pretreatment warming tank includes third tank body, and the third tank body is provided with guarantor on its external wall Warm chamber is provided with the hot-water circulation pipe around tank skin setting in the incubation cavity, heat preservation is provided on the outer wall of the incubation cavity Layer, the third tank body are provided with temperature sensor, the pre- solar thermal collector connection of hot-water circulation pipe, institute on its inner wall Solar thermal collector is stated to connect with water butt.
It is provided with pretreatment warming tank, waste water etc. is first preheated to set temperature, is then added in fermentation tank, can be improved The activity of anaerobic bacteria, improves the quantum of output of biogas, while being provided with level-one anaerobic fermentation gas production tank and B grade anaerobic fermentation aerogenesis The bottom of tank, B grade anaerobic fermentation aerogenesis tank is provided with agitating device, while utilizing and fermenting in level-one anaerobic fermentation gas production tank Residual temperature so that fermentation is more complete, and by by-pass filtration guard and secondary filtration net, can remove addition B grade anaerobic fermentation Greasy dirt in aerogenesis tank and large granular impurity.
Further, the desulfurizer includes desulfurizing tower tower body and the spray chamber that is set in tower body, the spray chamber Top be provided with atomizer, the atomizer is connect with input duct, the input duct, is set at the top of the tower body It is equipped with the first gas outlet, the bottom of the tower body is provided with the first air inlet, the first air guide is provided on first gas outlet Pipe, first gas-guide tube are connected to desulfurization oxidant layer, the desulfurization oxidant layer storage in storage device, the storage device it is upper Lower section is respectively arranged with the second air inlet and the second gas outlet upwards, and the bore of second air inlet is more than the second gas outlet Bore, the storage device are detachably connected with desulfurizing tower tower body.
Further, extend the cavity of a sealing on the side of the desulfurizing tower tower body, the storage device includes one The opening of cylindrical storage vat and connector, the cylinder storage vat is provided with the first external screw thread, the connector it is outer It is provided with the second external screw thread on surface, a cylindrical storage vat holding tank is provided in the cavity, it is corresponding, on cavity wall It is provided with the opening being connected to holding tank, internal thread, the cylinder storage vat clamping and holding tank are provided in the opening It is interior, when installation, cylindrical storage vat is filled in holding tank, and by connector connecting cylinder shape storage vat and cavity.
Further, the holding tank includes that two symmetrically arranged arcs are clamped pieces, the arc clamping piece and cavity Inner wall is fixedly connected, and the two arc clamping pieces form the cylindrical reception groove of a upper and lower opening.
Further, it is provided with sealing ring between the outer wall and the inner wall of holding tank of the cylindrical storage vat.
Further, it is provided with mesh screen on second air inlet and the second gas outlet, prevents filler from falling.
Further, spray liquid is caustic lime slurries.
Further, the decarbonization device includes decarbonizing tank, alkaline solution tank, waste collection tank, the 4th air inlet and Four gas outlets, set cylindrical guide shell in the decarbonizing tank, the top seal of the cylinder guide shell, bottom and decarbonizing tank Bottom surface connects, and the 4th air inlet is connected in cylindrical guide shell, is arranged on the top side wall of the cylinder guide shell There are several ventholes, the 4th gas outlet to be set to the top of decarbonizing tank, be provided on the top of the cylinder guide shell Spray head, the spray head are connect by pipeline with alkaline solution tank, the bottom surface of the cylinder guide shell and waste collection tank It connects, is additionally provided with except carbon film component above the cylinder guide shell.
Further, described except the filter assemblies being arranged in carbon film component are Polyimide Hollow Fiber silk.
Further, the dehydration device includes level-one dehydration package and two level dehydration package, the level-one dehydration package It is connected with each other with two level dehydration package, the level-one dehydration package includes dehydration tank body, and the bottom of the dehydration tank body is provided with 5th air inlet is connected with filtering water suction guard in the drain sump body, rotating flow guidance is provided at the top of the dehydration tank body Column, the rotating flow guidance column are placed in filtering water suction guard and are connect with motor, and deflector is provided on the rotating flow guidance column, It is provided with the 5th gas outlet on the top of the dehydration tank body, the 5th gas outlet is connect with two level dehydration package, and described two Grade dehydration package includes two gas-guide tubes, and drier is filled in two gas-guide tubes, is connected between two gas-guide tubes and partly leads Body heater.
Further, the section of the filtering water suction guard is U-shaped.
Further, the S-shaped arrangement of the gas-guide tube.
Further, the deflector is twist arranged.
Further, the bottom of the dehydration tank body is provided with water outlet, and the water outlet is connect with catch basin.
Further, the two level dehydration package connects wind turbine.
Further, the control system connects alarm device, and alarm is sent out when gas componant exception.
A kind of preparation of marsh-gas, includes the following steps:
S1:Industrial wastewater is introduced into fermentation in biogas fermentation device and generates biogas;
S2:Biogas in step 1 is introduced into level-one entrance separator, the graininess in the biogas that removing biogas source generates Solid matter and moisture form the first purifying marsh gas;
S3:First purifying marsh gas, which is compressed, by stage compressor forms the first compressed biogas;
S4:First compressed biogas, which is compressed, by split-compressor forms the second compressed biogas;
S5:Solids in second compressed biogas are removed by secondary inlet separator and moisture is formed Second purifying marsh gas;
S6:Second purifying marsh gas is introduced into desulfurizer and carries out desulfurization by desulfurization, and the concentration of hydrogen sulfide in biogas is made to reduce To 300ppm or less;
S7:Carbon dioxide removal, purified biogas enter dehydration procedure;
S9:Compressed filling is carried out after the completion of dehydration.
In conclusion the advantage of the invention is that:Biogas fermentation device includes pretreatment warming tank, the production of level-one anaerobic fermentation Gas tank and B grade anaerobic fermentation aerogenesis tank, enhance the activity of anaerobic bacteria so that raw material and anaerobic bacteria are uniformly mixed, biogas output amount It is high;Desulfurizer coordinates desulfurization using dry and wet, and desulfurizing agent is connect by storage vat with desulfurizing tower, and it is convenient to replace, using two level Dehydration package so that dehydration is more thorough.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention without having to pay creative labor, may be used also for those of ordinary skill in the art With obtain other attached drawings according to these attached drawings.
Fig. 1 is a kind of biogas Preparation equipment structural schematic diagram of the present invention;
Fig. 2 is desulfurizer structural schematic diagram in Fig. 1;
Fig. 3 is that warming tank structural schematic diagram is pre-processed in Fig. 1;
Fig. 4 is dehydration device structural schematic diagram in Fig. 1;
Fig. 5 is decarbonization device structural schematic diagram in Fig. 1.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without creative efforts Embodiment shall fall within the protection scope of the present invention.
As shown in Figs. 1-5, a kind of biogas Preparation equipment, including it is biogas fermentation device 1, desulfurizer 2, decarbonization device 9, de- Water installations 3, further include level-one entrance separator 5, stage compressor 6, split-compressor 7 and secondary inlet separator 8, and described one Grade compressor 6 is connected to the level-one entrance separator 5, and the split-compressor 7 is connected to stage compressor 6, the two level Entrance separator 8 is connected to split-compressor 7, and the biogas fermentation device 1 is connected to level-one entrance separator 5, the desulfurization Device 2 is connected to the secondary inlet separator 8, and the decarbonization device 9 is connected to desulfurizer 2, the dehydration device 3 with it is de- Carbon device 9 is connected to, and first-level buffer tank is provided between the stage compressor 6 and split-compressor 7, and the dehydration device 3 connects Level 2 buffering tank is connect, the level 2 buffering tank is connect with three-stage blower 10, the three-stage blower 10 and biogas storage device 11 connections, the biogas fermentation device 1 include pretreatment warming tank 12, level-one anaerobic fermentation gas production tank 13 and B grade anaerobic fermentation Aerogenesis tank 14, the pretreatment warming tank 12, level-one anaerobic fermentation gas production tank 13 and B grade anaerobic fermentation aerogenesis tank 14 connect successively It connects, wherein the level-one anaerobic fermentation gas production tank 13 includes the first tank body, and hyperboloid guide shell 15 is equipped in the first tank body, double The outside of curved surface guide shell 15 constitutes a water outlet stabilizing feed well, the hyperboloid guide shell 15 and first together with the first inner tank wall The bottom of tank body connects, and is provided with by-pass filtration guard 16 in the open top of the hyperboloid guide shell 15, under the first tank body Portion is equipped with water distributor, and the water distributor is connected in hyperboloid guide shell 15, and spoil disposal is provided in the hyperboloid guide shell 15 The top of pipe, the first tank body is equipped with the first biogas discharge pipe 18, and the first water outlet, institute are provided on the water outlet stabilizing feed well side wall The first water outlet to be stated to connect with B grade anaerobic fermentation aerogenesis tank 14, the B grade anaerobic fermentation aerogenesis tank 14 includes the second tank body, Second tank base is provided with twin-screw mixing plant 17, and the twin-screw mixing plant 17 includes that direction of rotation is opposite Two conveying augers, two conveying augers are connect with motor, and the second biogas discharge pipe 19 is provided with above second tank body, Be provided with discharge outlet below second tank body, the second biogas discharge pipe 19 be connected to the first biogas discharge pipe 18 and with Level-one entrance separator 5 is connected to, and the bottom of second tank body and first tank body is taper, is set on first water outlet It is equipped with secondary filtration net, the pretreatment warming tank 12 includes third tank body, and the third tank body is provided with guarantor on its external wall Warm chamber 20 is provided with the hot-water circulation pipe 21 around tank skin setting in the incubation cavity 20, is set on the outer wall of the incubation cavity 20 It is equipped with insulating layer, the third tank body is provided with temperature sensor, the hot-water circulation pipe 21 and solar energy collection on its inner wall Hot device connection, the solar thermal collector are connect with water butt, are provided with level-one anaerobic fermentation gas production tank 13 and secondary anaerobic hair The bottom of ferment aerogenesis tank 14, B grade anaerobic fermentation aerogenesis tank 14 is provided with agitating device, while being produced using in level-one anaerobic fermentation The residual temperature fermented in gas tank 13 so that fermentation is more complete, and by by-pass filtration guard 16 and secondary filtration net, can remove and add Enter the greasy dirt and large granular impurity in B grade anaerobic fermentation aerogenesis tank 14, the desulfurizer 2 includes desulfurizing tower tower body, setting Atomizer is provided at the top of the spray chamber in tower body, the spray chamber, the atomizer is connect with input duct, institute Input duct to be stated, the first gas outlet 24 is provided at the top of the tower body, the bottom of the tower body is provided with the first air inlet 23, The first gas-guide tube is provided on first gas outlet 24, first gas-guide tube is connected to desulfurization oxidant layer, the desulfurization oxidant layer Storage is respectively arranged with the second air inlet and the second outlet in storage device 25 in the upper and lower directions of the storage device 25 Mouthful, the bore of second air inlet is more than the bore of the second gas outlet, and the storage device 25 and desulfurizing tower tower body are detachable It connects, extends the cavity of a sealing on the side of the desulfurizing tower tower body, the storage device 25 includes a cylindrical storing The opening of bucket and connector 26, the cylinder storage vat is provided with the first external screw thread, on the outer surface of the connector 26 It is provided with the second external screw thread, a cylindrical storage vat holding tank is provided in the cavity, it is corresponding, it is provided on cavity wall The opening being connected to holding tank, is provided with internal thread in the opening, the cylinder storage vat clamping in holding tank, installation When, cylindrical storage vat is filled in holding tank, and by 26 connecting cylinder shape storage vat of connector and cavity, the receiving Slot includes that two symmetrically arranged arcs are clamped piece, and the arc clamping piece is fixedly connected with the inner wall of cavity, the two arc cards Contact pin forms the cylindrical reception groove of a upper and lower opening, is arranged between the outer wall and the inner wall of holding tank of the cylinder storage vat There is sealing ring, is provided with mesh screen on second air inlet and the second gas outlet, prevents filler from falling, spray liquid is caustic lime Slurries, the decarbonization device 9 include decarbonizing tank, alkaline solution tank 27, waste collection tank, the 4th air inlet 28 and the 4th gas outlet 29, set cylindrical guide shell in the decarbonizing tank, the bottom surface of the top seal of the cylinder guide shell, bottom and decarbonizing tank connects It connects, the 4th air inlet 28 is connected in cylindrical guide shell, if being provided on the top side wall of the cylinder guide shell Stomata is done, the 4th gas outlet 29 is set to the top of decarbonizing tank, spray is provided on the top of the cylinder guide shell Head is drenched, the spray head is connect by pipeline with alkaline solution tank 27, the bottom surface of the cylinder guide shell and waste collection tank It connects, is additionally provided with above the cylinder guide shell except carbon film component 30, it is described except the filtering being arranged in carbon film component 30 Component be Polyimide Hollow Fiber silk, the dehydration device 3 include level-one dehydration package and two level dehydration package, described one Grade dehydration package and two level dehydration package are connected with each other, and the level-one dehydration package includes dehydration tank body 31, the dehydration tank body 31 bottom is provided with the 5th air inlet 32, and filtering water suction guard 33, the dehydration tank body are connected in the dehydration tank body 31 31 top is provided with rotating flow guidance column, and the rotating flow guidance column is placed in filtering water suction guard 33 and is connect with motor, described It is provided with deflector on rotating flow guidance column, is provided with the 5th gas outlet 34 on the top of the dehydration tank body 31, the described 5th goes out Gas port 34 is connect with two level dehydration package, and the two level dehydration package includes two gas-guide tubes 35, is filled in two gas-guide tubes 35 There is drier, semiconductor heat booster is connected between two gas-guide tubes 35, the section of the filtering water suction guard 33 is U-shaped, 35 S-shaped arrangement of the gas-guide tube, the deflector are twist arranged, and the bottom of the dehydration tank body 31 is provided with water outlet Mouthful, the water outlet is connect with catch basin, and the two level dehydration package connects wind turbine.
A kind of preparation of marsh-gas, includes the following steps:
S1:Industrial wastewater is introduced into fermentation in biogas fermentation device 1 and generates biogas;
S2:Biogas in step 1 is introduced into level-one entrance separator 5, the particle in the biogas that removing biogas source generates Shape solid matter and moisture form the first purifying marsh gas;
S3:First purifying marsh gas, which is compressed, by stage compressor 6 forms the first compressed biogas;
S4:First compressed biogas, which is compressed, by split-compressor 7 forms the second compressed biogas;
S5:The solids and moisture shape in second compressed biogas are removed by secondary inlet separator 8 At the second purifying marsh gas;
S6:Second purifying marsh gas is introduced into desulfurizer 2 and carries out desulfurization by desulfurization, and the concentration of hydrogen sulfide in biogas is made to drop As low as 300ppm or less;
S7:Carbon dioxide removal, purified biogas enter dehydration procedure;
S9:Compressed filling is carried out after the completion of dehydration.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (8)

1. a kind of biogas Preparation equipment, it is characterised in that:Including biogas fermentation device, desulfurizer, decarbonization device and dehydration dress It sets, further includes level-one entrance separator, stage compressor, split-compressor and secondary inlet separator, the stage compressor Be connected to the level-one entrance separator, the split-compressor is connected to stage compressor, the secondary inlet separator with Split-compressor is connected to, and the biogas fermentation device is connected to level-one entrance separator, and the desulfurizer enters with the two level Mouth separator connection, the decarbonization device are connected to desulfurizer, and the dehydration device is connected to decarbonization device, the level-one pressure First-level buffer tank is provided between contracting machine and split-compressor, the dehydration device connects level 2 buffering tank, the level 2 buffering Tank is connect with three-stage blower, and the three-stage blower is connect with biogas storage device.
2. a kind of biogas Preparation equipment according to claim 1, it is characterised in that:The biogas fermentation device includes pre- place Manage warming tank, level-one anaerobic fermentation gas production tank and B grade anaerobic fermentation aerogenesis tank, the pretreatment warming tank, level-one anaerobic fermentation Aerogenesis tank and B grade anaerobic fermentation aerogenesis tank are sequentially connected, wherein and the level-one anaerobic fermentation gas production tank includes the first tank body, the Hyperboloid guide shell is equipped in one tank body, the outside of hyperboloid guide shell constitutes a water outlet current stabilization together with the first inner tank wall Cylinder, the hyperboloid guide shell are connect with the bottom of the first tank body, and one is provided in the open top of the hyperboloid guide shell Grade filtering screen, the first tank body lower part are equipped with water distributor, and the water distributor is connected in hyperboloid guide shell, and the hyperboloid is led Sludge pipe is provided in flow cartridge, the top of the first tank body is equipped with the first biogas discharge pipe, is arranged on the water outlet stabilizing feed well side wall There are the first water outlet, first water outlet to be connect with B grade anaerobic fermentation aerogenesis tank, the B grade anaerobic fermentation aerogenesis tank packet The second tank body is included, second tank base is provided with twin-screw mixing plant, and the twin-screw mixing plant includes rotation side To two opposite conveying augers, two conveying augers are connect with motor, and the second biogas is provided with above second tank body Discharge pipe is provided with discharge outlet below second tank body, and the first biogas discharge pipe is connected to the second biogas discharge pipe And be connected to level-one entrance separator, the bottom of second tank body and first tank body is taper, first water outlet On be provided with secondary filtration net.
3. a kind of biogas Preparation equipment according to claim 2, it is characterised in that:The pretreatment warming tank includes third Tank body, the third tank body are provided with incubation cavity on its external wall, and the hot water around tank skin setting is provided in the incubation cavity Circulation pipe is provided with insulating layer on the outer wall of the incubation cavity, and the third tank body is provided with temperature sensor on its inner wall, The pre- solar thermal collector connection of hot-water circulation pipe, the solar thermal collector are connect with water butt.
4. a kind of biogas Preparation equipment according to claim 1, it is characterised in that:The desulfurizer includes desulfurizing tower tower Body and the spray chamber being set in tower body are provided with atomizer, the atomizer and inlet tube at the top of the spray chamber Road connects, the input duct, is provided with the first gas outlet at the top of the tower body, the bottom of the tower body be provided with first into Gas port is provided with the first gas-guide tube on first gas outlet, and first gas-guide tube is connected to desulfurization oxidant layer, the desulfurizing agent Layer storage is respectively arranged with the second air inlet and the second gas outlet in storage device in the upper and lower directions of the storage device, The bore of second air inlet is more than the bore of the second gas outlet, and the storage device is detachably connected with desulfurizing tower tower body.
5. a kind of biogas Preparation equipment according to claim 4, it is characterised in that:Prolong on the side of the desulfurizing tower tower body The cavity of a sealing is stretched out, the storage device includes that a cylindrical storage vat and connector, the cylinder storage vat are opened It is provided with the first external screw thread at mouthful, the second external screw thread is provided on the outer surface of the connector, one is provided in the cavity Cylindrical storage vat holding tank, it is corresponding, it is provided with the opening being connected to holding tank on cavity wall, is provided in the opening When installation, cylindrical storage vat is filled in holding tank, and is led to in holding tank for internal thread, the cylinder storage vat clamping Connector connecting cylinder shape storage vat is crossed on cavity, the holding tank includes that two symmetrically arranged arcs are clamped piece, the arc Shape clamping piece is fixedly connected with the inner wall of cavity, and the two arc clamping pieces form the cylindrical reception groove of a upper and lower opening, institute It states and is provided with sealing ring between the outer wall of cylindrical storage vat and the inner wall of holding tank, second air inlet and the second gas outlet On be provided with mesh screen.
6. a kind of biogas Preparation equipment according to claim 1, it is characterised in that:The decarbonization device include decarbonizing tank, Alkaline solution tank, waste collection tank, the 4th air inlet and the 4th gas outlet set cylindrical guide shell in the decarbonizing tank, described The bottom surface of the top seal of cylindrical guide shell, bottom and decarbonizing tank connects, and the 4th air inlet is connected to cylindrical water conservancy diversion In cylinder, several ventholes are provided on the top side wall of the cylinder guide shell, the 4th gas outlet is set to decarbonizing tank Top, be provided with spray head on the top of the cylinder guide shell, the spray head passes through pipeline and connects with alkaline solution tank It connects, the bottom surface of the cylinder guide shell is connect with waste collection tank, is additionally provided with except carbon above the cylinder guide shell Membrane module.
7. a kind of biogas Preparation equipment according to claim 1, it is characterised in that:The dehydration device includes level-one dehydration Component and two level dehydration package, the level-one dehydration package and two level dehydration package are connected with each other, the level-one dehydration package packet Dehydration tank body is included, the bottom of the dehydration tank body is provided with the 5th air inlet, filtering water absorbent net is connected in the drain sump body Cover, is provided with rotating flow guidance column at the top of the dehydration tank body, the rotating flow guidance column be placed in filtering water suction guard it is interior and with electricity Machine connects, and deflector is provided on the rotating flow guidance column, the 5th gas outlet is provided on the top of the dehydration tank body, described 5th gas outlet is connect with two level dehydration package, and the two level dehydration package includes two gas-guide tubes, is filled in two gas-guide tubes There is drier, semiconductor heat booster is connected between two gas-guide tubes, the bottom of the dehydration tank body is provided with water outlet, institute It states water outlet to connect with catch basin, the two level dehydration package connects wind turbine.
8. a kind of preparation of marsh-gas, it is characterised in that:Described method includes following steps:
S1:Industrial wastewater is introduced into fermentation in biogas fermentation device and generates biogas;
S2:Biogas in step 1 is introduced into level-one entrance separator, the granular solids in the biogas that removing biogas source generates Substance and moisture form the first purifying marsh gas;
S3:First purifying marsh gas, which is compressed, by stage compressor forms the first compressed biogas;
S4:First compressed biogas, which is compressed, by split-compressor forms the second compressed biogas;
S5:Solids and the moisture formation second in second compressed biogas are removed by secondary inlet separator Purifying marsh gas;
S6:Second purifying marsh gas is introduced into desulfurizer and carries out desulfurization by desulfurization, and the concentration of hydrogen sulfide in biogas is made to be reduced to 300ppm or less;
S7:Carbon dioxide removal, purified biogas enter dehydration procedure;
S9:Compressed filling is carried out after the completion of dehydration.
CN201710301850.9A 2017-05-02 2017-05-02 A kind of biogas Preparation equipment and its method Pending CN108795714A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202193660U (en) * 2010-12-23 2012-04-18 河南天冠工业沼气有限公司 Powerless self-circulation perfectly-stirred anaerobic reactor
CN103013600A (en) * 2012-11-19 2013-04-03 河南天冠工业沼气有限公司 Biogas desulfurization method in series of wet method with dry method
CN103113946A (en) * 2013-02-01 2013-05-22 王仕华 Marsh gas purification system and marsh gas purification method
CN103721537A (en) * 2013-12-13 2014-04-16 广西奥士达环境工程有限公司 Spray tower with two chambers
CN204656306U (en) * 2015-04-13 2015-09-23 天紫环保投资控股有限公司 Biogas desulfurization decarburization purification system
CN204981794U (en) * 2015-07-21 2016-01-20 蓝德环保科技集团股份有限公司 Dry dewatering device of marsh gas
US20160166980A1 (en) * 2013-06-24 2016-06-16 Beijing Helee Bio-Energy Ltd. Container-type biogas purification film method purification system
CN206902139U (en) * 2017-05-02 2018-01-19 扬州永清新能源发展有限公司 A kind of biogas Preparation equipment

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202193660U (en) * 2010-12-23 2012-04-18 河南天冠工业沼气有限公司 Powerless self-circulation perfectly-stirred anaerobic reactor
CN103013600A (en) * 2012-11-19 2013-04-03 河南天冠工业沼气有限公司 Biogas desulfurization method in series of wet method with dry method
CN103113946A (en) * 2013-02-01 2013-05-22 王仕华 Marsh gas purification system and marsh gas purification method
US20160166980A1 (en) * 2013-06-24 2016-06-16 Beijing Helee Bio-Energy Ltd. Container-type biogas purification film method purification system
CN103721537A (en) * 2013-12-13 2014-04-16 广西奥士达环境工程有限公司 Spray tower with two chambers
CN204656306U (en) * 2015-04-13 2015-09-23 天紫环保投资控股有限公司 Biogas desulfurization decarburization purification system
CN204981794U (en) * 2015-07-21 2016-01-20 蓝德环保科技集团股份有限公司 Dry dewatering device of marsh gas
CN206902139U (en) * 2017-05-02 2018-01-19 扬州永清新能源发展有限公司 A kind of biogas Preparation equipment

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Application publication date: 20181113