CN108795208B - Preparation method of flame-retardant water-based core-shell acrylate resin coating and paint - Google Patents
Preparation method of flame-retardant water-based core-shell acrylate resin coating and paint Download PDFInfo
- Publication number
- CN108795208B CN108795208B CN201810773980.7A CN201810773980A CN108795208B CN 108795208 B CN108795208 B CN 108795208B CN 201810773980 A CN201810773980 A CN 201810773980A CN 108795208 B CN108795208 B CN 108795208B
- Authority
- CN
- China
- Prior art keywords
- parts
- flame
- retardant
- water
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 75
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 69
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 239000003973 paint Substances 0.000 title claims abstract description 49
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 44
- 239000011248 coating agent Substances 0.000 title claims abstract description 43
- 238000000576 coating method Methods 0.000 title claims abstract description 41
- 239000011258 core-shell material Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 238000010438 heat treatment Methods 0.000 claims abstract description 37
- 239000000839 emulsion Substances 0.000 claims abstract description 36
- 239000000178 monomer Substances 0.000 claims abstract description 36
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 33
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 31
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 238000010992 reflux Methods 0.000 claims abstract description 15
- 238000001816 cooling Methods 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010410 layer Substances 0.000 claims abstract description 10
- 239000012792 core layer Substances 0.000 claims abstract description 9
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000003999 initiator Substances 0.000 claims abstract description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims description 25
- 229920000178 Acrylic resin Polymers 0.000 claims description 19
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical compound OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 claims description 18
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 15
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 15
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 15
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 14
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 14
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 14
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 9
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 8
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 claims description 8
- PTFIPECGHSYQNR-UHFFFAOYSA-N 3-Pentadecylphenol Chemical compound CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims description 8
- ZGTNBBQKHJMUBI-UHFFFAOYSA-N bis[tetrakis(hydroxymethyl)-lambda5-phosphanyl] sulfate Chemical compound OCP(CO)(CO)(CO)OS(=O)(=O)OP(CO)(CO)(CO)CO ZGTNBBQKHJMUBI-UHFFFAOYSA-N 0.000 claims description 8
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- 239000013067 intermediate product Substances 0.000 claims description 7
- 229960001124 trientine Drugs 0.000 claims description 7
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 6
- DFNYGALUNNFWKJ-UHFFFAOYSA-N aminoacetonitrile Chemical compound NCC#N DFNYGALUNNFWKJ-UHFFFAOYSA-N 0.000 claims description 5
- XIMFCGSNSKXPBO-UHFFFAOYSA-N ethyl 2-bromobutanoate Chemical compound CCOC(=O)C(Br)CC XIMFCGSNSKXPBO-UHFFFAOYSA-N 0.000 claims description 5
- IRXSLJNXXZKURP-UHFFFAOYSA-N fluorenylmethyloxycarbonyl chloride Chemical compound C1=CC=C2C(COC(=O)Cl)C3=CC=CC=C3C2=C1 IRXSLJNXXZKURP-UHFFFAOYSA-N 0.000 claims description 5
- BSRDNMMLQYNQQD-UHFFFAOYSA-N iminodiacetonitrile Chemical compound N#CCNCC#N BSRDNMMLQYNQQD-UHFFFAOYSA-N 0.000 claims description 5
- NUXCOKIYARRTDC-UHFFFAOYSA-N o-ethylhydroxylamine;hydron;chloride Chemical compound Cl.CCON NUXCOKIYARRTDC-UHFFFAOYSA-N 0.000 claims description 5
- GBBSAMQTQCPOBF-UHFFFAOYSA-N 2,4,6-trimethyl-1,3,5,2,4,6-trioxatriborinane Chemical compound CB1OB(C)OB(C)O1 GBBSAMQTQCPOBF-UHFFFAOYSA-N 0.000 claims description 4
- MWVTWFVJZLCBMC-UHFFFAOYSA-N 4,4'-bipyridine Chemical group C1=NC=CC(C=2C=CN=CC=2)=C1 MWVTWFVJZLCBMC-UHFFFAOYSA-N 0.000 claims description 4
- KLUDQUOLAFVLOL-UHFFFAOYSA-N acetyl propanoate Chemical compound CCC(=O)OC(C)=O KLUDQUOLAFVLOL-UHFFFAOYSA-N 0.000 claims description 4
- HDMGAZBPFLDBCX-UHFFFAOYSA-M potassium;sulfooxy sulfate Chemical compound [K+].OS(=O)(=O)OOS([O-])(=O)=O HDMGAZBPFLDBCX-UHFFFAOYSA-M 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- -1 methyl propyl Chemical group 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000002523 gelfiltration Methods 0.000 description 6
- 239000010985 leather Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 150000001450 anions Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- 241000047703 Nonion Species 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- WCNPOPMNDBXYLF-UHFFFAOYSA-N butyl prop-2-enoate;methyl prop-2-enoate;prop-2-enenitrile Chemical compound C=CC#N.COC(=O)C=C.CCCCOC(=O)C=C WCNPOPMNDBXYLF-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Description
Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
Oxygen index/% | 29.4 | 29.6 | 30.4 | 29.8 | 29.8 |
Flame combustion time/s | 1.1 | 1.6 | 0.8 | 1.2 | 2.1 |
Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
Oxygen index/% | 21.6 | 22.7 | 20.4 | 21.2 | 21.7 |
Flame combustion time/s | 31.2 | 32.7 | 29.4 | 22.1 | 25.7 |
Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
Oxygen index/% | 25.2 | 24.7 | 26.4 | 25.3 | 27.2 |
Flame combustion time/s | 11.2 | 22.7 | 25.4 | 16.1 | 18.2 |
Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
Oxygen index/% | 26.3 | 25.8 | 27.1 | 26.1 | 27.3 |
Flame combustion time/s | 10.3 | 14.2 | 18.3 | 12.0 | 12.4 |
Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
Chemical resistance stability | Stable and non-laminated | Stable and non-laminated | Stable and non-laminated | Stable and non-laminated | Stable and non-laminated |
Gel filtration/% | 1.6 | 2.1 | 1.7 | 1.1 | 0.8 |
Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
Chemical resistance stability | Stable and non-laminated | Layering | Stable and non-laminated | Layering | Layering |
Gel filtration/% | 7.6 | 5.8 | 6.2 | 4.8 | 6.6 |
Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
Chemical resistance stability | Layering | Layering | Layering | Layering | Layering |
Gel filtration/% | 7.7 | 10.3 | 12.7 | 8.6 | 14.3 |
Claims (3)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011369854.9A CN112409877B (en) | 2018-07-15 | 2018-07-15 | Preparation method of flame-retardant water-based core-shell acrylic resin coating |
CN201810773980.7A CN108795208B (en) | 2018-07-15 | 2018-07-15 | Preparation method of flame-retardant water-based core-shell acrylate resin coating and paint |
PCT/CN2018/120939 WO2020015289A1 (en) | 2018-07-15 | 2018-12-13 | Flame-retardant, aqueous, core-shell acrylate resin coating and paint preparation method |
CA3028455A CA3028455A1 (en) | 2018-07-15 | 2018-12-27 | Preparation for acrylate resin coating and paint of flame-retardant, water-proof and water-based core-shell type |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810773980.7A CN108795208B (en) | 2018-07-15 | 2018-07-15 | Preparation method of flame-retardant water-based core-shell acrylate resin coating and paint |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011369854.9A Division CN112409877B (en) | 2018-07-15 | 2018-07-15 | Preparation method of flame-retardant water-based core-shell acrylic resin coating |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108795208A CN108795208A (en) | 2018-11-13 |
CN108795208B true CN108795208B (en) | 2020-12-18 |
Family
ID=64076628
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011369854.9A Active CN112409877B (en) | 2018-07-15 | 2018-07-15 | Preparation method of flame-retardant water-based core-shell acrylic resin coating |
CN201810773980.7A Active CN108795208B (en) | 2018-07-15 | 2018-07-15 | Preparation method of flame-retardant water-based core-shell acrylate resin coating and paint |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011369854.9A Active CN112409877B (en) | 2018-07-15 | 2018-07-15 | Preparation method of flame-retardant water-based core-shell acrylic resin coating |
Country Status (3)
Country | Link |
---|---|
CN (2) | CN112409877B (en) |
CA (1) | CA3028455A1 (en) |
WO (1) | WO2020015289A1 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112409877B (en) * | 2018-07-15 | 2023-08-01 | 广东省漆色彩新型材料有限公司 | Preparation method of flame-retardant water-based core-shell acrylic resin coating |
CN109468006A (en) * | 2018-11-15 | 2019-03-15 | 段瑶瑶 | A kind of preparation method of the core-shell type aqueous acrylic resin coating of antifriction |
CN109181458A (en) * | 2018-11-21 | 2019-01-11 | 段瑶瑶 | A kind of preparation method of waterproofness core-shell type aqueous acrylic resin coating and finishing agent |
CN109705681A (en) * | 2018-12-25 | 2019-05-03 | 杨记周 | A kind of new-energy automobile environment-friendly water-based paint and preparation method thereof |
CN110204989B (en) * | 2019-07-17 | 2020-12-15 | 烟台大学 | Preparation method of flame-retardant core-shell type environment-friendly water-based acrylate resin coating |
CN110642982B (en) * | 2019-09-17 | 2022-02-01 | 湖北工业大学 | Preparation method of high-tensile-strength amide benzene ring emulsion polymer with core-shell structure |
CN111794012B (en) * | 2020-06-24 | 2022-04-29 | 杭州华旺新材料科技股份有限公司 | High-strength water-resistant flame-retardant plain colored paper and preparation method thereof |
CN112625173B (en) * | 2020-12-17 | 2021-12-24 | 常熟国和新材料有限公司 | Water-based acrylic resin with good viscosity stability and preparation method thereof |
CN112646269B (en) * | 2020-12-17 | 2023-04-28 | 安徽强旭塑业科技有限公司 | Environment-friendly high-flame-retardance battery shell and preparation method thereof |
WO2023073470A1 (en) * | 2021-10-26 | 2023-05-04 | 3M Innovative Properties Company | Flame retardant pressure-sensitive adhesive and method of making |
CN115160480A (en) * | 2022-02-14 | 2022-10-11 | 上海金狮化工有限公司 | Waterborne acrylic resin for coloring woodware and preparation method thereof |
CN117024663B (en) * | 2023-08-08 | 2024-05-10 | 南京科工煤炭科学技术研究有限公司 | Acrylate emulsion for core-shell polymer cement and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102875723A (en) * | 2012-10-26 | 2013-01-16 | 烟台大学 | Preparation method of flame-retardant core-shell-type acrylic resin |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0794584B2 (en) * | 1987-01-07 | 1995-10-11 | 日本ペイント株式会社 | Method for producing aqueous dispersion of anionic gel particles |
CN1010589B (en) * | 1988-06-04 | 1990-11-28 | 薛志纯 | Modified acrylic ester resin emulsion and preparation thereof |
CN105111876B (en) * | 2014-07-27 | 2017-06-13 | 河北晨阳工贸集团有限公司 | Building, the preparation method of the core-shell type aqueous acrylic resin coating of furniture |
CN108459136A (en) * | 2018-05-29 | 2018-08-28 | 上海福乐医药科技有限公司 | A kind of method of three boroxane content of titration measuring front three basic ring |
CN112409877B (en) * | 2018-07-15 | 2023-08-01 | 广东省漆色彩新型材料有限公司 | Preparation method of flame-retardant water-based core-shell acrylic resin coating |
-
2018
- 2018-07-15 CN CN202011369854.9A patent/CN112409877B/en active Active
- 2018-07-15 CN CN201810773980.7A patent/CN108795208B/en active Active
- 2018-12-13 WO PCT/CN2018/120939 patent/WO2020015289A1/en active Application Filing
- 2018-12-27 CA CA3028455A patent/CA3028455A1/en not_active Abandoned
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102875723A (en) * | 2012-10-26 | 2013-01-16 | 烟台大学 | Preparation method of flame-retardant core-shell-type acrylic resin |
Also Published As
Publication number | Publication date |
---|---|
CA3028455A1 (en) | 2020-01-15 |
CN112409877A (en) | 2021-02-26 |
CN112409877B (en) | 2023-08-01 |
CN108795208A (en) | 2018-11-13 |
WO2020015289A1 (en) | 2020-01-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108795208B (en) | Preparation method of flame-retardant water-based core-shell acrylate resin coating and paint | |
CN102605648B (en) | Textile water-based pigment printing binding agent and preparation method | |
CN102471632B (en) | Aqueous polymer dispersion as a binding agent for plasters and coating materials having improved fire behavior | |
CA1145871A (en) | Process for preparing aqueous emulsions of copolymers of n-methylol derivatives | |
CN111454402B (en) | Acrylate emulsion leather finishing agent and preparation method thereof | |
EP0209325A2 (en) | Polymer emulsion containing an interpenetrating polymer network | |
CN103108779B (en) | Sound insulation composite containing protected colloid-stabilised emulsion polymer | |
CN110229594A (en) | A kind of preparation method of the super-hydrophobic composite anticorrosion coating of terpolymer doped polyaniline | |
CN101809047A (en) | Cross-linkable monomers and polymers and the use thereof | |
CA3028431A1 (en) | Flame-retardant, waterproof water-based core-shell acrylate resin coating and preparation method of paint | |
CN109679468A (en) | A kind of waterborne polyester-acrylic resin hybrid and preparation method | |
US4734454A (en) | Aqueous coating composition | |
CN102807643A (en) | Emulsifying agent for emulsion polymerization and preparation method thereof | |
CN116987427B (en) | Water-based acrylic resin coating for building and preparation method thereof | |
CN111748301B (en) | Low-temperature-resistant acrylic coating adhesive and preparation method and application thereof | |
ES2870454T3 (en) | Polymodal polymer compositions for coating applications | |
CN109942742A (en) | A kind of water dispersion glass coated polymeric and preparation method thereof | |
CN106188402A (en) | A kind of waterborne epoxy modified acrylic emulsion and preparation method thereof | |
CN103781807A (en) | Vinyl acetate/vinyl 3,5,5-trimethylhexanoate copolymer binder resins | |
CN113321960A (en) | Water-based flame-retardant emulsion and method for preparing flame-retardant acrylic emulsion | |
CN109337019B (en) | Polyether-ether-ketone modified acrylic waterborne resin synthesized by ATRP | |
CN109593157B (en) | Melamine modified waterborne acrylic flame-retardant resin and preparation method thereof | |
CN106700749A (en) | Waterborne flame-retardant emulsion | |
CN112778470A (en) | Single-component water-based resin for high-barrier bottom surface combination and preparation method thereof | |
CN112063281B (en) | Water-based two-component wood paint and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Duan Baorong Inventor after: Zhao Yuzhen Inventor after: Feng Lianxiang Inventor after: Tang Zhihai Inventor after: Zhang Mengmeng Inventor after: Wang Qiyan Inventor after: Zhang Tiantian Inventor after: Wang Quanjie Inventor before: Duan Baorong Inventor before: Zhao Yuzhen Inventor before: Zhang Mengmeng |
|
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20201202 Address after: 264005 School of chemistry and chemical engineering, Yantai University, 30 Qingquan Road, Laishan District, Shandong, Yantai Applicant after: Yantai University Address before: 264000 16-2, Fu Qing Street, Zhifu District, Shandong, Yantai Applicant before: Duan Baorong |
|
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method of flame retardant waterborne core-shell acrylate resin coating and paint Effective date of registration: 20211214 Granted publication date: 20201218 Pledgee: Yantai financing guarantee Group Co.,Ltd. Pledgor: Yantai University Registration number: Y2021980014777 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220317 Granted publication date: 20201218 Pledgee: Yantai financing guarantee Group Co.,Ltd. Pledgor: Yantai University Registration number: Y2021980014777 |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230117 Address after: Building 4, Science Park, No. 37, Daoyi South Street, Shenbei New District, Shenyang, Liaoning 110000 Patentee after: Shenyang Naisi Industrial Co.,Ltd. Address before: 264005 College of Chemistry and Chemical Engineering, Yantai University, 30 Qingquan Road, Laishan District, Yantai City, Shandong Province Patentee before: Yantai University |