CN108795007A - A kind of processing technology of flame-proof weather-resisting type PC/ABS composite materials - Google Patents
A kind of processing technology of flame-proof weather-resisting type PC/ABS composite materials Download PDFInfo
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- CN108795007A CN108795007A CN201810573433.4A CN201810573433A CN108795007A CN 108795007 A CN108795007 A CN 108795007A CN 201810573433 A CN201810573433 A CN 201810573433A CN 108795007 A CN108795007 A CN 108795007A
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- 239000002131 composite material Substances 0.000 title claims abstract description 49
- 229920007019 PC/ABS Polymers 0.000 title claims abstract description 47
- 238000005516 engineering process Methods 0.000 title claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 51
- 239000000843 powder Substances 0.000 claims abstract description 40
- 238000002360 preparation method Methods 0.000 claims abstract description 31
- 239000003063 flame retardant Substances 0.000 claims abstract description 24
- 230000004913 activation Effects 0.000 claims abstract description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 49
- 238000010992 reflux Methods 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- 230000008569 process Effects 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 23
- 239000003595 mist Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical class [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 17
- 239000003963 antioxidant agent Substances 0.000 claims description 16
- 230000003078 antioxidant effect Effects 0.000 claims description 16
- 229920002643 polyglutamic acid Polymers 0.000 claims description 16
- 108010020346 Polyglutamic Acid Proteins 0.000 claims description 15
- 235000019441 ethanol Nutrition 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 12
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 10
- 239000003999 initiator Substances 0.000 claims description 10
- DZBOAIYHPIPCBP-UHFFFAOYSA-L magnesium;2-methylprop-2-enoate Chemical compound [Mg+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O DZBOAIYHPIPCBP-UHFFFAOYSA-L 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 230000005855 radiation Effects 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 3
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims description 2
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 claims description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- 239000002975 chemoattractant Substances 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 10
- 239000004417 polycarbonate Substances 0.000 description 14
- 239000007789 gas Substances 0.000 description 9
- 238000000227 grinding Methods 0.000 description 7
- 230000007246 mechanism Effects 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 5
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 229910003978 SiClx Inorganic materials 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- -1 phosphate ester Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- WXQDFOGZIYLEGP-UHFFFAOYSA-N C(C(C)C)#N.C(C(C)C)#N.[N] Chemical compound C(C(C)C)#N.C(C(C)C)#N.[N] WXQDFOGZIYLEGP-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004425 Makrolon Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- DWLAVVBOGOXHNH-UHFFFAOYSA-L magnesium;prop-2-enoate Chemical compound [Mg+2].[O-]C(=O)C=C.[O-]C(=O)C=C DWLAVVBOGOXHNH-UHFFFAOYSA-L 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of processing technologys of flame-proof weather-resisting type PC/ABS composite materials, are related to technical field of composite materials, include the following steps：(1) activation of molecular screen primary powder, the preparation of (2) carrier, the preparation of (3) weather resisting agent, the preparation of (4) PC/ABS composite materials.The made PC/ABS composite materials of the present invention have excellent weather resistance by the addition for making weather resisting agent by oneself, simultaneously there is good flame retardant property and physical mechanical property, solve conventional flame retardants it is a large amount of addition can cause material weather resistance and physical mechanical property reduction the technical issues of.
Description
Technical field：
The present invention relates to technical field of composite materials, and in particular to a kind of processing of flame-proof weather-resisting type PC/ABS composite materials
Technique.
Background technology：
Makrolon abbreviation PC, acrylonitrile-butadiene-styrene copolymer abbreviation ABS, the PC/ABS that the two is formed are compound
Material is a kind of important engineering plastics, can not only improve the heat resistance and tensile strength of ABS, moreover it is possible to reduce the melt viscosity of PC
So as to improve processing performance.
On the one hand, due to containing unsaturated double-bond in ABS structure so that the weatherability of PC/ABS composite materials is poor.Separately
On the one hand, phosphate ester flame retardants are often added in order to enhance the flame retardant property of PC/ABS composite materials, but the based flame retardant adds
Toughness of material can inevitably be reduced by adding；To ensure the toughness of PC/ABS composite materials, methyl methacrylate-fourth is often added
Styrene (MBS) can further decrease PC/ as toughener due to also containing unsaturated double-bond in MBS structures
The weatherability of ABS composite material.
In order to improve the weatherability of PC/ABS composite materials, need to add weather resisting agent.At present frequently with benzophenone purple
Ultraviolet absorbers, Benzotriazole Ultraviolet Stabilizer and triazine-based ultraviolet absorbent are as weather resisting agent.Though this kind of weather resisting agent
Weatherability can so be enhanced, but the weather resistance of made PC/ABS composite materials is limited, especially with prolonging for materials'use time
Long weatherability drastically declines.The addition of weather resisting agent must just be increased by wanting raising weather resistance and extension weatherability action time
Amount, and the increase of weather resisting agent additive amount can influence the toughness of material.
Invention content：
It is easy, good process repeatability fire-retardant resistance to technical problem to be solved by the present invention lies in a kind of technological operation is provided
The processing technology of time type PC/ABS composite materials, and made PC/ABS composite materials have good physical mechanical property.
The technical problems to be solved by the invention are realized using technical solution below：
A kind of processing technology of flame-proof weather-resisting type PC/ABS composite materials, includes the following steps：
(1) activation of molecular screen primary powder：First 4A molecular screen primary powders are placed in 100-110 DEG C of baking oven and are dried to constant weight, and
1-3h is roasted at 500-600 DEG C to get activated molecular sieve original powder；
(2) preparation of carrier：Activated molecular sieve original powder is scattered in absolute ethyl alcohol, allyl glycidol is added
Ether, magnesium dimethacrylate and initiator are then heated to the reaction of reflux state insulated and stirred, continue back after polymerisation
Stream stirring 30min, gained mixture recycle ethyl alcohol through being concentrated under reduced pressure, and condensate residue removes unreacted monomer through washing,
It is placed in 100-110 DEG C of baking oven and dries to constant weight, micro mist is made to get carrier through micronizer in obtained solid；
(3) preparation of weather resisting agent：By made support dispersion in absolute ethyl alcohol, nano zine oxide and more polyglutamics are added
Then acid utilizes microwave reactor stir process 5min at reflux, continue in reflux shape after stopping microwave radiation 5min
Microwave reactor stir process 5min is utilized under state, repeatedly until load is completed, gained mixture is returned through being concentrated under reduced pressure
Ethyl alcohol is received, condensate residue is dried in 100-110 DEG C of baking oven to constant weight, and micro mist is made through micronizer in obtained solid, i.e.,
Obtain weather resisting agent；
(4) preparation of PC/ABS composite materials：By PC resin, ABS resin, fire retardant, aerosil, metering system
Sour methyl esters-butadiene-styrene copolymer, antioxidant and above-mentioned made weather resisting agent are added in high-speed mixer, after batch mixing is uniform
It is sent into double screw extruder, melting extrusion is granulated, double screw extruder temperature：One 185-200 DEG C of area, 200-215 DEG C of 2nd area,
Three 215-230 DEG C of areas, 230-245 DEG C of 4th area, 220-230 DEG C of 5th area, 210-220 DEG C of 6th area, twin-screw rotating speed 100-400r/
Min is to get PC/ABS composite materials.
The activated molecular sieve original powder, allyl glycidyl ether, magnesium dimethacrylate, initiator mass ratio be
50:5-15:5-15:0.05-0.5。
The initiator is selected from azodiisobutyronitrile, dibenzoyl peroxide, peroxidized t-butyl perbenzoate, di-t-butyl
One kind in peroxide.
The mass ratio of the carrier, nano zine oxide and polyglutamic acid is 5:1-10:0.1-1.
The polyglutamic acid is selected from water process grade polyglutamic acid.
The microwave frequency of the microwave reactor is 2450MHz, output power 700W.
The PC resin, ABS resin, fire retardant, aerosil, methyl methacrylate-butadiene-styrene are total
Polymers, antioxidant, weather resisting agent mass ratio be 50-70:10-25:7-12:3-8:1-5:0.3-0.8:0.3-0.8.
The fire retardant is phosphorus flame retardant.
The antioxidant be selected from antioxidant 1024, antioxidant 1330, antioxidant 1010, antioxidant 1076, antioxidant 245,
One or more of irgasfos 168, antioxidant 3114.
The aerosil passes through modification, and method of modifying is：Aerosil is dispersed in nothing
In water-ethanol, PEG-60 rilanit specials are added after impregnating 10-15min, and be heated to reflux state insulated and stirred 15-30min,
Titanate coupling agent is added, insulated and stirred 0.5-2h at reflux, cooled to room temperature are continued, gained mixture turns
Enter sealing and standing 3-8h in -5 DEG C of environment, filter, gained filter residue is sent into after being washed with absolute ethyl alcohol in vacuum drier, dry institute
It obtains solid and micro mist is made through micronizer.
The aerosil, PEG-60 rilanit specials, titanate coupling agent mass ratio be 10-20:1-5:1-
5。
The beneficial effects of the invention are as follows：
(1) for the present invention using 4A molecular screen primary powders as support material, carrier is made in activated and modification；At modification
Using allyl glycidyl ether, magnesium dimethacrylate as modifying agent when reason, pass through allyl glycidyl ether and dimethyl
The polymerisation of Magnesium Acrylate Prepared generates acrylic resin, while the acrylic resin generated under microwave action penetrates into 4A immediately
In the structure pore of molecular screen primary powder, to enhance the load capacity of carrier and assign carrier certain weather resistance；
(2) present invention is made resistance to using inorganic UV shield agent nano zine oxide as load component after carrier loaded
Time is had excellent performance and the weather resisting agent of length of weather-proof time, while being used cooperatively for polyglutamic acid can improve the negative of nano zine oxide
Load rate, and polyglutamic acid synergistic carriers are solved to significantly improve the comixing compatibility of nano zine oxide and resin matrix
Directly using nano zine oxide as additive amount existing for weather resisting agent it is big, weather resistance is limited and cause toughness of material reduce technology
Problem；
(3) present invention is using PEG-60 rilanit specials and titanate coupling agent as modifying agent, by gas phase titanium dioxide
The modification of silicon improves the comixing compatibility of aerosil and resin matrix, and enhances aerosil as filling out
It fills the filling capacity of agent and improves the weather resistance of aerosil；
(4) the made PC/ABS composite materials of the present invention have excellent weather resistance by the addition for making weather resisting agent by oneself, together
When have good flame retardant property and physical mechanical property, solve conventional flame retardants it is a large amount of add can lead to material weatherability
The technical issues of capable of being reduced with physical mechanical property.
Specific implementation mode：
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, tie below
Specific embodiment is closed, the present invention is further explained.
The selection of each raw material：
The 4A Series Molecules that 4A molecular screen primary powders select Luoyang to build imperial micro-nano new material limited liability company sieve original powder；Allyl
Base glycidol ether selects the SILONG 191 of Hangzhou Silong Material Technology Co., Ltd.；Magnesium dimethacrylate selects Shanghai to step
The magnesium dimethacrylate of riel chemical technology Co., Ltd；Azodiisobutyronitrile selects the idol of Guangzhou Xiao Yu Chemical Co., Ltd.s
Nitrogen bis-isobutyronitrile；Nano zine oxide selects the LT-601 of Jiyuan City Shandong Turner rice Materials Co., Ltd；The more polyglutamics of water process grade
Acid selects the water process grade polyglutamic acid of the Xi'an bio tech ltd Shou He；PC resin selects Mitsubishi engineering plastics
The S-2000F of Co., Ltd.；ABS resin selects the AT-08 of Nippon A&L Inc.；Fire retardant selects refined gram of Jiangsu high-tech stock
The PhireGuard BDP of part Co., Ltd；Aerosil selects the M-5 of Guangzhou Yi Rui new materials Co., Ltd；Methyl
Methylacrylate-butadiene-styrol copolymer selects the TH-21 of Japan Electric chemical industry Co., Ltd.；Antioxidant 1010
Select the antioxidant 1010 of Changzhou Xin Ce high molecular materials Co., Ltd；PEG-60 rilanit specials select Shanghai City thick really fine
The PEG-60 rilanit specials of Chemical Co., Ltd.；Titanate coupling agent selects Changzhou new district profit into chemical inc
CT-2。
Embodiment 1
(1) activation of molecular screen primary powder：First 4A molecular screen primary powders are placed in 105-110 DEG C of baking oven and are dried to constant weight, and
2h is roasted at 550 DEG C to get activated molecular sieve original powder；
(2) preparation of carrier：50g activated molecular sieve original powders are scattered in absolute ethyl alcohol, 5g allyl glycidyls are added
Glycerin ether, 10g magnesium dimethacrylates and 0.5g initiator azodiisobutyronitriles, it is anti-to be then heated to reflux state insulated and stirred
It answers, continues return stirring 30min after polymerisation, gained mixture recycles ethyl alcohol, condensate residue through being concentrated under reduced pressure
Unreacted monomer is removed through washing, is placed in 105-110 DEG C of baking oven and dries to constant weight, obtained solid is through ultramicro grinding mechanism
At micro mist to get carrier；
(3) preparation of weather resisting agent：By the made support dispersions of 50g in absolute ethyl alcohol, 50g nano zine oxides and 3g are added
Then water process grade polyglutamic acid utilizes the microwave reaction of microwave frequency 2450MHz, output power 700W at reflux
Device stir process 5min continues to utilize microwave reactor stir process 5min at reflux after stopping microwave radiation 5min,
Repeatedly, total microwave irradiation time 30min, gained mixture recycle ethyl alcohol through being concentrated under reduced pressure, and condensate residue is in 105-
It is dried to constant weight in 110 DEG C of baking ovens, micro mist is made to get weather resisting agent through micronizer in obtained solid；
(4) preparation of PC/ABS composite materials：By 65g PC resins, 15g ABS resins, 10g fire retardants, 5g gas phase dioxies
SiClx, 4g Methyl Methacrylate-Butadiene-Styrene Copolymer, 0.5g antioxidant 1010s and the above-mentioned made weather resisting agents of 0.5g
It is added in high-speed mixer, batch mixing is uniformly sent into double screw extruder afterwards, and melting extrusion is granulated, double screw extruder temperature：
One 190-195 DEG C of area, 205-210 DEG C of 2nd area, 215-220 DEG C of 3rd area, 235-240 DEG C of 4th area, 220-225 DEG C of 5th area, 6th area
215-220 DEG C, twin-screw rotating speed 300r/min is to get PC/ABS composite materials.
Embodiment 2
(1) activation of molecular screen primary powder：First 4A molecular screen primary powders are placed in 105-110 DEG C of baking oven and are dried to constant weight, and
2h is roasted at 550 DEG C to get activated molecular sieve original powder；
(2) preparation of carrier：50g activated molecular sieve original powders are scattered in absolute ethyl alcohol, 8g allyl glycidyls are added
Glycerin ether, 10g magnesium dimethacrylates and 0.5g initiator azodiisobutyronitriles, it is anti-to be then heated to reflux state insulated and stirred
It answers, continues return stirring 30min after polymerisation, gained mixture recycles ethyl alcohol, condensate residue through being concentrated under reduced pressure
Unreacted monomer is removed through washing, is placed in 105-110 DEG C of baking oven and dries to constant weight, obtained solid is through ultramicro grinding mechanism
At micro mist to get carrier；
(3) preparation of weather resisting agent：By the made support dispersions of 50g in absolute ethyl alcohol, 50g nano zine oxides and 5g are added
Then water process grade polyglutamic acid utilizes the microwave reaction of microwave frequency 2450MHz, output power 700W at reflux
Device stir process 5min continues to utilize microwave reactor stir process 5min at reflux after stopping microwave radiation 5min,
Repeatedly, total microwave irradiation time 30min, gained mixture recycle ethyl alcohol through being concentrated under reduced pressure, and condensate residue is in 105-
It is dried to constant weight in 110 DEG C of baking ovens, micro mist is made to get weather resisting agent through micronizer in obtained solid；
(4) preparation of PC/ABS composite materials：By 65g PC resins, 15g ABS resins, 10g fire retardants, 5g gas phase dioxies
SiClx, 4g Methyl Methacrylate-Butadiene-Styrene Copolymer, 0.5g antioxidant 1010s and the above-mentioned made weather resisting agents of 0.5g
It is added in high-speed mixer, batch mixing is uniformly sent into double screw extruder afterwards, and melting extrusion is granulated, double screw extruder temperature：
One 190-195 DEG C of area, 205-210 DEG C of 2nd area, 215-220 DEG C of 3rd area, 235-240 DEG C of 4th area, 220-225 DEG C of 5th area, 6th area
215-220 DEG C, twin-screw rotating speed 300r/min is to get PC/ABS composite materials.
Embodiment 3
(1) activation of molecular screen primary powder：First 4A molecular screen primary powders are placed in 105-110 DEG C of baking oven and are dried to constant weight, and
2h is roasted at 550 DEG C to get activated molecular sieve original powder；
(2) preparation of carrier：50g activated molecular sieve original powders are scattered in absolute ethyl alcohol, 8g allyl glycidyls are added
Glycerin ether, 10g magnesium dimethacrylates and 0.5g initiator azodiisobutyronitriles, it is anti-to be then heated to reflux state insulated and stirred
It answers, continues return stirring 30min after polymerisation, gained mixture recycles ethyl alcohol, condensate residue through being concentrated under reduced pressure
Unreacted monomer is removed through washing, is placed in 105-110 DEG C of baking oven and dries to constant weight, obtained solid is through ultramicro grinding mechanism
At micro mist to get carrier；
(3) preparation of weather resisting agent：By the made support dispersions of 50g in absolute ethyl alcohol, 50g nano zine oxides and 5g are added
Then water process grade polyglutamic acid utilizes the microwave reaction of microwave frequency 2450MHz, output power 700W at reflux
Device stir process 5min continues to utilize microwave reactor stir process 5min at reflux after stopping microwave radiation 5min,
Repeatedly, total microwave irradiation time 30min, gained mixture recycle ethyl alcohol through being concentrated under reduced pressure, and condensate residue is in 105-
It is dried to constant weight in 110 DEG C of baking ovens, micro mist is made to get weather resisting agent through micronizer in obtained solid；
(4) preparation of PC/ABS composite materials：65g PC resins, 15g ABS resins, 10g fire retardants, 5g are modified gas phase
Silica, 4g Methyl Methacrylate-Butadiene-Styrene Copolymer, 0.5g antioxidant 1010s and 0.5g are above-mentioned made resistance to
It waits agent to be added in high-speed mixer, batch mixing is uniformly sent into double screw extruder afterwards, and melting extrusion is granulated, double screw extruder temperature
Degree：One 190-195 DEG C of area, 205-210 DEG C of 2nd area, 215-220 DEG C of 3rd area, 235-240 DEG C of 4th area, 220-225 DEG C of 5th area, 6th area
215-220 DEG C, twin-screw rotating speed 300r/min is to get PC/ABS composite materials.
The preparation of modified aerosil：20g aerosils are dispersed in absolute ethyl alcohol, are impregnated
3g PEG-60 rilanit specials are added after 15min, and are heated to reflux state insulated and stirred 30min, it is even to add 3g titanate esters
Join agent, continue insulated and stirred 2h at reflux, cooled to room temperature, gained mixture be transferred in -5 DEG C of environment seal it is quiet
5h is set, is filtered, gained filter residue is sent into after being washed with absolute ethyl alcohol in vacuum drier, and dry obtained solid is through ultramicro grinding mechanism
At micro mist.
Embodiment 4
(1) activation of molecular screen primary powder：First 4A molecular screen primary powders are placed in 105-110 DEG C of baking oven and are dried to constant weight, and
2h is roasted at 550 DEG C to get activated molecular sieve original powder；
(2) preparation of carrier：50g activated molecular sieve original powders are scattered in absolute ethyl alcohol, 8g allyl glycidyls are added
Glycerin ether, 10g magnesium dimethacrylates and 0.5g initiator azodiisobutyronitriles, it is anti-to be then heated to reflux state insulated and stirred
It answers, continues return stirring 30min after polymerisation, gained mixture recycles ethyl alcohol, condensate residue through being concentrated under reduced pressure
Unreacted monomer is removed through washing, is placed in 105-110 DEG C of baking oven and dries to constant weight, obtained solid is through ultramicro grinding mechanism
At micro mist to get carrier；
(3) preparation of weather resisting agent：By the made support dispersions of 50g in absolute ethyl alcohol, 50g nano zine oxides and 5g are added
Then water process grade polyglutamic acid utilizes the microwave reaction of microwave frequency 2450MHz, output power 700W at reflux
Device stir process 5min continues to utilize microwave reactor stir process 5min at reflux after stopping microwave radiation 5min,
Repeatedly, total microwave irradiation time 30min, gained mixture recycle ethyl alcohol through being concentrated under reduced pressure, and condensate residue is in 105-
It is dried to constant weight in 110 DEG C of baking ovens, micro mist is made to get weather resisting agent through micronizer in obtained solid；
(4) preparation of PC/ABS composite materials：65g PC resins, 15g ABS resins, 10g fire retardants, 5g are modified gas phase
Silica, 4g Methyl Methacrylate-Butadiene-Styrene Copolymer, 0.5g antioxidant 1010s and 0.5g are above-mentioned made resistance to
It waits agent to be added in high-speed mixer, batch mixing is uniformly sent into double screw extruder afterwards, and melting extrusion is granulated, double screw extruder temperature
Degree：One 190-195 DEG C of area, 205-210 DEG C of 2nd area, 215-220 DEG C of 3rd area, 235-240 DEG C of 4th area, 220-225 DEG C of 5th area, 6th area
215-220 DEG C, twin-screw rotating speed 300r/min is to get PC/ABS composite materials.
The preparation of modified aerosil：20g aerosils are dispersed in absolute ethyl alcohol, are impregnated
4g PEG-60 rilanit specials are added after 15min, and are heated to reflux state insulated and stirred 30min, it is even to add 2g titanate esters
Join agent, continue insulated and stirred 2h at reflux, cooled to room temperature, gained mixture be transferred in -5 DEG C of environment seal it is quiet
5h is set, is filtered, gained filter residue is sent into after being washed with absolute ethyl alcohol in vacuum drier, and dry obtained solid is through ultramicro grinding mechanism
At micro mist.
Reference examples 1
(1) activation of molecular screen primary powder：First 4A molecular screen primary powders are placed in 105-110 DEG C of baking oven and are dried to constant weight, and
2h is roasted at 550 DEG C to get activated molecular sieve original powder；
(2) preparation of carrier：50g activated molecular sieve original powders are scattered in absolute ethyl alcohol, 8g allyl glycidyls are added
Glycerin ether, 10g magnesium dimethacrylates and 0.5g initiator azodiisobutyronitriles, it is anti-to be then heated to reflux state insulated and stirred
It answers, continues return stirring 30min after polymerisation, gained mixture recycles ethyl alcohol, condensate residue through being concentrated under reduced pressure
Unreacted monomer is removed through washing, is placed in 105-110 DEG C of baking oven and dries to constant weight, obtained solid is through ultramicro grinding mechanism
At micro mist to get carrier；
(3) preparation of weather resisting agent：By the made support dispersions of 50g in absolute ethyl alcohol, 50g nano zine oxides are added, so
The microwave reactor stir process 5min for utilizing microwave frequency 2450MHz, output power 700W at reflux afterwards, stops micro-
Continue to utilize microwave reactor stir process 5min at reflux after wave radiation 5min, repeatedly, when total microwave radiation
Between 30min, gained mixture through being concentrated under reduced pressure to recycle ethyl alcohol, dry in 105-110 DEG C of baking oven to constant weight by condensate residue,
Micro mist is made to get weather resisting agent through micronizer in obtained solid；
(4) preparation of PC/ABS composite materials：By 65g PC resins, 15g ABS resins, 10g fire retardants, 5g gas phase dioxies
SiClx, 4g Methyl Methacrylate-Butadiene-Styrene Copolymer, 0.5g antioxidant 1010s and the above-mentioned made weather resisting agents of 0.5g
It is added in high-speed mixer, batch mixing is uniformly sent into double screw extruder afterwards, and melting extrusion is granulated, double screw extruder temperature：
One 190-195 DEG C of area, 205-210 DEG C of 2nd area, 215-220 DEG C of 3rd area, 235-240 DEG C of 4th area, 220-225 DEG C of 5th area, 6th area
215-220 DEG C, twin-screw rotating speed 300r/min is to get PC/ABS composite materials.
Reference examples 2
(1) activation of molecular screen primary powder：First 4A molecular screen primary powders are placed in 105-110 DEG C of baking oven and are dried to constant weight, and
2h is roasted at 550 DEG C to get activated molecular sieve original powder；
(2) preparation of weather resisting agent：50g activated molecular sieve original powders are scattered in absolute ethyl alcohol, it is nano oxidized to add 50g
Zinc and 5g water process grade polyglutamic acids, then at reflux utilize microwave frequency 2450MHz, output power 700W it is micro-
Wave reactor stir process 5min continues to utilize microwave reactor stir process at reflux after stopping microwave radiation 5min
5min, repeatedly, total microwave irradiation time 30min, gained mixture through being concentrated under reduced pressure to recycle ethyl alcohol, condensate residue in
It is dried to constant weight in 105-110 DEG C of baking oven, micro mist is made to get weather resisting agent through micronizer in obtained solid；
(4) preparation of PC/ABS composite materials：By 65g PC resins, 15g ABS resins, 10g fire retardants, 5g gas phase dioxies
SiClx, 4g Methyl Methacrylate-Butadiene-Styrene Copolymer, 0.5g antioxidant 1010s and the above-mentioned made weather resisting agents of 0.5g
It is added in high-speed mixer, batch mixing is uniformly sent into double screw extruder afterwards, and melting extrusion is granulated, double screw extruder temperature：
One 190-195 DEG C of area, 205-210 DEG C of 2nd area, 215-220 DEG C of 3rd area, 235-240 DEG C of 4th area, 220-225 DEG C of 5th area, 6th area
215-220 DEG C, twin-screw rotating speed 300r/min is to get PC/ABS composite materials.
Reference examples 3
The preparation of PC/ABS composite materials：By 65g PC resins, 15g ABS resins, 10g fire retardants, 5g gas phase titanium dioxides
Silicon, 4g Methyl Methacrylate-Butadiene-Styrene Copolymer, 0.5g antioxidant 1010s and 0.5g nano zine oxides are added high
In fast mixing machine, batch mixing is uniformly sent into double screw extruder afterwards, and melting extrusion is granulated, double screw extruder temperature：One area
190-195 DEG C, 205-210 DEG C of 2nd area, 215-220 DEG C of 3rd area, 235-240 DEG C of 4th area, 220-225 DEG C of 5th area, six area 215-220
DEG C, twin-screw rotating speed 300r/min is to get PC/ABS composite materials.
Reference examples 4
The preparation of PC/ABS composite materials：By 65g PC resins, 15g ABS resins, 10g fire retardants, 5g gas phase titanium dioxides
Silicon, 4g Methyl Methacrylate-Butadiene-Styrene Copolymer, 0.5g antioxidant 1010s and 0.5g ultra-violet absorber agent
Tinuvin234 is added in high-speed mixer, and batch mixing is uniformly sent into double screw extruder afterwards, and melting extrusion is granulated, and twin-screw squeezes
Out-of-machine temperature：One 190-195 DEG C of area, 205-210 DEG C of 2nd area, 215-220 DEG C of 3rd area, 235-240 DEG C of 4th area, five area 220-225
DEG C, 215-220 DEG C of 6th area, twin-screw rotating speed 300r/min is to get PC/ABS composite materials.
Embodiment 5
Based on embodiment 2, be arranged do not added when prepared by weather resisting agent water process grade polyglutamic acid reference examples 1,
Reference examples 2 directly using activated molecular sieve original powder as carrier, the reference examples 3 directly using nano zine oxide as weather resisting agent, with
Reference examples 4 of the ultra-violet absorber agent Tinuvin234 (German BASF) as weather resisting agent.
It is utilized respectively embodiment 1-4, reference examples 1-4 preparation PC/ABS composite materials, and is used for performance and is tested,
Test result is as shown in table 1.
The performance of the made PC/ABS composite materials of 1 embodiment of the present invention of table
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (9)
1. a kind of processing technology of flame-proof weather-resisting type PC/ABS composite materials, which is characterized in that include the following steps：
(1) activation of molecular screen primary powder：First 4A molecular screen primary powders are placed in 100-110 DEG C of baking oven and are dried to constant weight, and in
1-3h is roasted at 500-600 DEG C to get activated molecular sieve original powder；
(2) preparation of carrier：Activated molecular sieve original powder is scattered in absolute ethyl alcohol, allyl glycidyl ether, two are added
Magnesinm methacrylate and initiator, are then heated to the reaction of reflux state insulated and stirred, continue reflux after polymerisation and stir
30min is mixed, gained mixture recycles ethyl alcohol through being concentrated under reduced pressure, and condensate residue removes unreacted monomer, juxtaposition through washing
It is dried to constant weight in 100-110 DEG C of baking oven, micro mist is made to get carrier through micronizer in obtained solid；
(3) preparation of weather resisting agent：By made support dispersion in absolute ethyl alcohol, nano zine oxide and polyglutamic acid are added,
Then microwave reactor stir process 5min is utilized at reflux, is continued at reflux after stopping microwave radiation 5min
Using microwave reactor stir process 5min, repeatedly until load is completed, gained mixture recycles second through being concentrated under reduced pressure
Alcohol, condensate residue are dried in 100-110 DEG C of baking oven to constant weight, and micro mist is made to get resistance to through micronizer in obtained solid
Wait agent；
(4) preparation of PC/ABS composite materials：By PC resin, ABS resin, fire retardant, aerosil, methyl methacrylate
Ester-butadiene-styrene copolymer, antioxidant and above-mentioned made weather resisting agent are added in high-speed mixer, and batch mixing is uniformly sent into afterwards
In double screw extruder, melting extrusion is granulated, double screw extruder temperature：One 185-200 DEG C of area, 200-215 DEG C of 2nd area, 3rd area
215-230 DEG C, 230-245 DEG C of 4th area, 220-230 DEG C of 5th area, 210-220 DEG C of 6th area, twin-screw rotating speed 100-400r/min, i.e.,
Obtain PC/ABS composite materials.
2. the processing technology of flame-proof weather-resisting type PC/ABS composite materials according to claim 1, it is characterised in that：The work
Chemoattractant molecule sieve original powder, allyl glycidyl ether, magnesium dimethacrylate, initiator mass ratio be 50:5-15:5-15:
0.05-0.5。
3. the processing technology of flame-proof weather-resisting type PC/ABS composite materials according to claim 1, it is characterised in that：It is described to draw
Send out one of agent in azodiisobutyronitrile, dibenzoyl peroxide, peroxidized t-butyl perbenzoate, di-tert-butyl peroxide
Kind.
4. the processing technology of flame-proof weather-resisting type PC/ABS composite materials according to claim 1, it is characterised in that：The load
The mass ratio of body, nano zine oxide and polyglutamic acid is 5:1-10:0.1-1.
5. the processing technology of flame-proof weather-resisting type PC/ABS composite materials according to claim 1, it is characterised in that：It is described more
Polyglutamic acid is selected from water process grade polyglutamic acid.
6. the processing technology of flame-proof weather-resisting type PC/ABS composite materials according to claim 1, it is characterised in that：It is described micro-
The microwave frequency of wave reactor is 2450MHz, output power 700W.
7. the processing technology of flame-proof weather-resisting type PC/ABS composite materials according to claim 1, it is characterised in that：The PC
It is resin, ABS resin, fire retardant, aerosil, Methyl Methacrylate-Butadiene-Styrene Copolymer, antioxidant, resistance to
The mass ratio for waiting agent is 50-70:10-25:7-12:3-8:1-5:0.3-0.8:0.3-0.8.
8. the processing technology of flame-proof weather-resisting type PC/ABS composite materials according to claim 1, it is characterised in that：The resistance
Combustion agent is phosphorus flame retardant.
9. the processing technology of flame-proof weather-resisting type PC/ABS composite materials according to claim 1, it is characterised in that：It is described anti-
Oxygen agent is selected from antioxidant 1024, antioxidant 1330, antioxidant 1010, antioxidant 1076, antioxidant 245, irgasfos 168, antioxygen
One or more of agent 3114.
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| US20160137752A1 (en) * | 2009-10-27 | 2016-05-19 | Halosource, Inc. | Packaging formulation for preventing the insolubility of chitosan-containing compositions |
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