CN108794916A - A kind of antibiotic plastic - Google Patents

A kind of antibiotic plastic Download PDF

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Publication number
CN108794916A
CN108794916A CN201710314888.XA CN201710314888A CN108794916A CN 108794916 A CN108794916 A CN 108794916A CN 201710314888 A CN201710314888 A CN 201710314888A CN 108794916 A CN108794916 A CN 108794916A
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China
Prior art keywords
parts
plastic
antibiotic
antibiotic plastic
plastics
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CN201710314888.XA
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Chinese (zh)
Inventor
高伟
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Zibo Qidingli Patent Information Consulting Co Ltd
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Zibo Qidingli Patent Information Consulting Co Ltd
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Priority to CN201710314888.XA priority Critical patent/CN108794916A/en
Publication of CN108794916A publication Critical patent/CN108794916A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/372—Sulfides, e.g. R-(S)x-R'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45—Heterocyclic compounds having sulfur in the ring
    • C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0893—Zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of antibiotic plastics, include the component of following parts by weight：300~500 parts of plastic raw materials, 5~10 parts of phenol, 5~10 parts of tetramethyl piperidine nitrogen oxides, 6~12 parts of thiodiglycolic acid dimethyl ester, 5~10 parts of bergamio, 10~30 parts of nano material, 10~30 parts of carrier, 5~12 parts of plasticizer.Plastics provided by the invention, sterilization, good antimicrobial effect, the duration is long, and durability is strong, and service life is long, has a wide range of application.

Description

A kind of antibiotic plastic
Technical field
The present invention relates to plastics arts more particularly to a kind of antibiotic plastics.
Background technology
The type of plastic products is various, has a wide range of application, and the example of plastic products can be found everywhere in daily life, such as shoes Bottom, mineral water bottle, cup, mouse, cutlery box, preservative film etc..More and more wider with the use scope of plastic products, people are to plastics The requirement of product is also higher and higher.However, present plastic products long-time service can still there are problems that, such as plastic products Use for a long time can be in surface of plastic products and internal growth bacterium, this both will have a direct impact on the health of people, and also could Cause the self property of plastic products to change, shortens the working life.
Invention content
Technical problems based on background technology, the present invention propose a kind of antibiotic plastic.
A kind of antibiotic plastic proposed by the present invention, includes the component of following parts by weight：300~500 parts of plastic raw materials, phenol 5~10 parts, 5~10 parts of tetramethyl piperidine nitrogen oxides, 6~12 parts of thiodiglycolic acid dimethyl ester, 5~10 parts of bergamio, 10~30 parts of nano material, 10~30 parts of carrier, 5~10 parts of n-octyl-isothiazolin ketone, 5~12 parts of plasticizer.
Preferably, a kind of antibiotic plastic includes the component of following parts by weight：450 parts of plastic raw materials, 8 parts of phenol, tetramethyl 7 parts of piperidines nitrogen oxides, 9 parts of thiodiglycolic acid dimethyl ester, 7 parts of bergamio, 20 parts of nano material, 20 parts of carrier are just pungent 7 parts of base isothiazolinone, 8 parts of plasticizer.
Preferably, the plastic raw materials are one kind in Corvic and phenolic resin.
Preferably, the nano material uses one or both of nano silver and Nano-Zinc.
Preferably, the carrier is using one or more of zeolite, titanium dioxide, basic zirconium phosphate, silica gel.
Preferably, the plasticizer is one kind in phosphate, chlorinated paraffin, phthalic acid ester, polyester.
Plastics provided by the invention, the addition of nano material can both improve the ageing-resistant of plastics, corrosion resistance, and can be with It interacts, can effectively sterilize with carrier, make plastics that there is antibiotic property；The bergamio of addition further enhances plastics Anti-microbial property, while the smell of plastics being made to make moderate progress again, increase the use scope of plastic products；N-octyl-isothiazolin ketone energy It is effective to inhibit the growth of the microorganisms such as mould, prevent plastic degradation；And phenol, tetramethyl piperidine nitrogen oxides and thio diethyl Dimethyl phthalate cooperates with the antioxygenic property that plastics can be improved as antioxidant, prolongs the service life.
Specific implementation mode
The present invention is made further to explain with reference to specific embodiment.
Embodiment one
A kind of antibiotic plastic proposed by the present invention, includes the component of following parts by weight：450 parts of Corvic, 8 parts of phenol, 7 parts of tetramethyl piperidine nitrogen oxides, 9 parts of thiodiglycolic acid dimethyl ester, 7 parts of bergamio, 20 parts of nano silver, titanium dioxide 20 Part, 7 parts of n-octyl-isothiazolin ketone, 8 parts of phthalic acid ester.
Embodiment two
A kind of antibiotic plastic proposed by the present invention, includes the component of following parts by weight：500 parts of phenolic resin, 5 parts of phenol, tetramethyl 8 parts of piperidine nitroxide, 12 parts of thiodiglycolic acid dimethyl ester, 10 parts of bergamio, 5 parts of nano silver, 10 parts of Nano-Zinc, phosphorus 20 parts of sour zirconium, 10 parts of n-octyl-isothiazolin ketone, 7 parts of chlorinated paraffin.
Embodiment three
A kind of antibiotic plastic proposed by the present invention, includes the component of following parts by weight：450 parts of Corvic, 10 parts of phenol, 10 parts of tetramethyl piperidine nitrogen oxides, 12 parts of thiodiglycolic acid dimethyl ester, 8 parts of bergamio, 30 parts of nano silver, zeolite 30 Part, 5 parts of n-octyl-isothiazolin ketone, 12 parts of polyester.
Example IV
A kind of antibiotic plastic proposed by the present invention, includes the component of following parts by weight：350 parts of phenolic resin, 10 parts of phenol, tetramethyl 7 parts of piperidine nitroxide, 8 parts of thiodiglycolic acid dimethyl ester, 10 parts of bergamio, 15 parts of nano silver, 10 parts of Nano-Zinc, phosphorus 15 parts of sour zirconium, 10 parts of silica gel, 8 parts of n-octyl-isothiazolin ketone, 7 parts of phthalic acid ester.
Antibiotic plastic prepared by embodiment one~tetra- is according to the People's Republic of China's light industry standard QB/T2591-2003 《Antibiotic plastic-Anti-microbial Performance Tests method and antibacterial effect》, tested, surveyed using staphylococcus aureus ATCC 6538 Test result is as follows；
Title Viable count (CFU/ pieces) after 24 hours
Embodiment one 5
Embodiment two 7
Embodiment three 8
Example IV 7
Plastics provided by the invention, the addition of nano material can both improve the ageing-resistant of plastics, corrosion resistance, and can be with load Body interacts, and can effectively sterilize, and plastics is made to have antibiotic property；The bergamio of addition further enhances the antibacterial of plastics Performance, while the smell of plastics being made to make moderate progress again, increase the use scope of plastic products；N-octyl-isothiazolin ketone can be effective The microorganisms growth such as inhibition mould, prevent plastic degradation；And phenol, tetramethyl piperidine nitrogen oxides and thiodiglycolic acid two Methyl esters cooperates with the antioxygenic property that plastics can be improved as antioxidant, prolongs the service life.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. a kind of antibiotic plastic, which is characterized in that include the component of following parts by weight：300~500 parts of plastic raw materials, phenol 5~ 10 parts, 5~10 parts of tetramethyl piperidine nitrogen oxides, 6~12 parts of thiodiglycolic acid dimethyl ester, 5~10 parts of bergamio, nanometer 10~30 parts of material, 10~30 parts of carrier, 5~10 parts of n-octyl-isothiazolin ketone, 5~12 parts of plasticizer.
2. a kind of antibiotic plastic, which is characterized in that include the component of following parts by weight：450 parts of plastic raw materials, 8 parts of phenol, tetramethyl 7 parts of piperidine nitroxide, 9 parts of thiodiglycolic acid dimethyl ester, 7 parts of bergamio, 20 parts of nano material, 20 parts of carrier, just 7 parts of octylisothiazolinone, 8 parts of plasticizer.
3. a kind of antibiotic plastic according to claim 1, which is characterized in that the plastic raw materials be Corvic and One kind in phenolic resin.
4. a kind of antibiotic plastic according to claim 1, which is characterized in that the nano material uses nano silver and nanometer One or both of zinc.
5. a kind of antibiotic plastic according to claim 3, which is characterized in that the carrier is using zeolite, titanium dioxide, phosphorus One or more of sour zirconium, silica gel.
6. a kind of antibiotic plastic according to claim 1, which is characterized in that the plasticizer be phosphate, chlorinated paraffin, One kind in phthalic acid ester, polyester.
CN201710314888.XA 2017-05-07 2017-05-07 A kind of antibiotic plastic Withdrawn CN108794916A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110317419A (en) * 2019-06-10 2019-10-11 金达科技股份有限公司 A kind of antibiotic plastic sheet material
KR20220006129A (en) * 2019-06-03 2022-01-14 가부시키가이샤 케미크레아 Stable Microbicide Composition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220006129A (en) * 2019-06-03 2022-01-14 가부시키가이샤 케미크레아 Stable Microbicide Composition
KR102445338B1 (en) 2019-06-03 2022-09-20 가부시키가이샤 케미크레아 Stable Microbicide Composition
CN110317419A (en) * 2019-06-10 2019-10-11 金达科技股份有限公司 A kind of antibiotic plastic sheet material

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Application publication date: 20181113

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