CN108777315A - A kind of solid oxide fuel cell of solid carbon as fuel - Google Patents
A kind of solid oxide fuel cell of solid carbon as fuel Download PDFInfo
- Publication number
- CN108777315A CN108777315A CN201810373982.7A CN201810373982A CN108777315A CN 108777315 A CN108777315 A CN 108777315A CN 201810373982 A CN201810373982 A CN 201810373982A CN 108777315 A CN108777315 A CN 108777315A
- Authority
- CN
- China
- Prior art keywords
- battery case
- fuel cell
- solid
- solid carbon
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1233—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with one of the reactants being liquid, solid or liquid-charged
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/102—Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
- H01M50/107—Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/138—Primary casings, jackets or wrappings of a single cell or a single battery adapted for specific cells, e.g. electrochemical cells operating at high temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0269—Separators, collectors or interconnectors including a printed circuit board
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
A kind of solid oxide fuel cell the present invention relates to field of fuel cell technology more particularly to solid carbon as fuel；Solid carbon including battery case and in battery case；Battery case side is equipped with cathodic coating, and diaphragm is covered between cathodic coating and battery case, conducting resinl is equipped on cathodic coating, conducting resinl distributes as net shape；Battery case side is arranged with the first filamentary silver contacted with cathodic coating, and battery case one end is equipped with the second filamentary silver being connect with battery case inside, and the first filamentary silver is anode, and the second filamentary silver is cathode；By simple structure, not only generating efficiency is high, and environmental protection, and no any pernicious gas or industrial waste generate；Both generate electricity safety, has been greatly reduced cost, is the following most attractive generation mode, is very suitable for widely available application.
Description
Technical field
A kind of solid oxide fuel the present invention relates to field of fuel cell technology more particularly to solid carbon as fuel
Battery.
Background technology
Fuel cell is a kind of power generator that will be present in fuel and be converted into an energy with the chemical energy in oxidant；
Fuel and air are fed separately to fuel cell, and electricity is just rumly produced, it exteriorly has positive and negative anodes and electrolyte
Deng as an accumulator, but substantially it cannot " storing up electricity " but one " power plant ".
For the maximum feature of fuel cell power generating system precisely due to reaction process is not related to burning, energy conversion efficiency can
Up to 60%-80%, efficiency of actual is then 2-3 times of ordinary internal combustion engine；Fuel cell be referred to as after waterpower, firepower,
The 4th power generator after nuclear force, it will become the most attractive generation mode of future world；Currently, all solid oxygen
Fuel used generally hydrogen, natural gas, methane, town gas etc. the gases of compound fuel cell, gas are transported as fuel inconvenience
It is defeated, in high-temperature fuel cell battery once have leakage or it is damaged easily explode, danger coefficient height, and cost of electricity-generating compared with
It is high.
Invention content
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, a kind of solid of solid carbon as fuel is provided
Oxide fuel cell.
The technical solution adopted by the present invention to solve the technical problems is：
It constructs a kind of solid oxide fuel cell of solid carbon as fuel, including battery case and is set to the battery
Solid carbon in shell；The battery case side is equipped with cathodic coating, and diaphragm, institute are covered between the cathodic coating and the battery case
It states and is equipped with conducting resinl on cathodic coating, the conducting resinl distributes as net shape；The battery case side is arranged with and the cathode
First filamentary silver of film contact, described battery case one end are equipped with the second filamentary silver being connect with battery case inside, first silver medal
Silk is anode, and second filamentary silver is cathode.
Solid oxide fuel cell of the solid carbon of the present invention as fuel, wherein the solid carbon includes coal
It is one or more in charcoal, activated carbon, biological carbon, coke or lignite.
Solid oxide fuel cell of the solid carbon of the present invention as fuel, wherein the material of the battery case
For yttria-stabilized zirconia.
Solid oxide fuel cell of the solid carbon of the present invention as fuel, wherein the battery case is tubulose；
The a diameter of 13.5mm of battery case, a length of 24mm.
Solid oxide fuel cell of the solid carbon of the present invention as fuel, wherein the conducting resinl is silver paste.
Solid oxide fuel cell of the solid carbon of the present invention as fuel, wherein first filamentary silver is in institute
Cathodic coating is stated to fix by conducting resinl.
Solid oxide fuel cell of the solid carbon of the present invention as fuel, wherein first silver wire and
Two silver wires include that more silver wires form.
The beneficial effects of the present invention are：A kind of solid oxide fuel cell of the solid carbon of the present invention as fuel,
Filled solid carbon and add 700~850 degrees Celsius of high temperature to can be realized power generation in outside batteries in battery case, electricity generating principle be by
Fuel is converted into the Chemically generation of electric energy with the chemical energy in oxidant, as long as fuel supply is continuous in principle, battery can be held
Supervention electricity, actual power efficiency is 2~3 times of current thermal power generation, realizes the most efficiently utilization of energy in fuel, generated electricity
Cheng Huanbao, no any pernicious gas or industrial waste generate, and the problem of will not then exploding using solid, and use solid
Cost of electricity-generating will be less than gas cost；By simple structure, not only generating efficiency is high, and environmental protection, no any harmful
Gas or industrial waste generate；Both generate electricity safety, has been greatly reduced cost, is the following most attractive generation mode,
It is very suitable for widely available application.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, below in conjunction with attached drawing and reality
Applying example, the invention will be further described, and the accompanying drawings in the following description is only the section Example of the present invention, for this field
For those of ordinary skill, without creative efforts, other accompanying drawings are can also be obtained according to these attached drawings：
Fig. 1 is structural representation of the solid carbon mentioned of baffle of the present invention as the solid oxide fuel cell of fuel
Figure；
Fig. 2 be present pre-ferred embodiments solid carbon as fuel solid oxide fuel cell vertical view；
Wherein, 1- battery cases, 11- cathodic coatings, 111- conducting resinls, the first filamentary silvers of 21-, the second filamentary silvers of 22-.
Specific implementation mode
In order to keep the purpose, technical scheme and advantage of the embodiment of the present invention clearer, implement below in conjunction with the present invention
Technical solution in example carries out clear, complete description, it is clear that and described embodiment is the section Example of the present invention, and
It is not all of embodiment.Based on the embodiment of the present invention, those of ordinary skill in the art are not before making the creative labor
The every other embodiment obtained is put, protection scope of the present invention is belonged to.
Therefore, below the detailed description of the embodiment of the present invention to providing in the accompanying drawings be not intended to limit it is claimed
The scope of the present invention, but be merely representative of the present invention selected embodiment.Based on the embodiments of the present invention, this field is common
The every other embodiment that technical staff is obtained without creative efforts belongs to the model that the present invention protects
It encloses.
In the description of the present invention, it should be noted that term "center", "upper", "lower", "left", "right", "vertical",
The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" is to be based on the orientation or positional relationship shown in the drawings, or be somebody's turn to do
Invention product using when the orientation or positional relationship usually put, be merely for convenience of description of the present invention and simplification of the description, without
It is instruction or implies that signified device or element must have a particular orientation, with specific azimuth configuration and operation, therefore not
It can be interpreted as limitation of the present invention.
Term " first ", " second ", " third " etc. are only used for distinguishing description, are not understood to indicate or imply relatively heavy
The property wanted.
In the description of the present invention, it is also necessary to which explanation is unless specifically defined or limited otherwise, term " setting ",
" installation ", " connected ", " connection " shall be understood in a broad sense, for example, it may be fixedly connected, may be a detachable connection or one
Connect to body；It can be directly connected, can also can be indirectly connected through an intermediary the connection inside two elements.
For the ordinary skill in the art, the concrete meaning of above-mentioned term in the present invention can be understood with concrete condition.
In the description of the present invention, it should be noted that term "center", "upper", "lower", "left", "right", "vertical",
The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" is to be based on the orientation or positional relationship shown in the drawings, or be somebody's turn to do
Invention product using when the orientation or positional relationship usually put, be merely for convenience of description of the present invention and simplification of the description, without
It is instruction or implies that signified device or element must have a particular orientation, with specific azimuth configuration and operation, therefore not
It can be interpreted as limitation of the present invention.
Referenced herein " embodiment " is it is meant that a particular feature, structure, or characteristic described can wrap in conjunction with the embodiments
Containing at least one embodiment of the present invention.Each position in the description occur the phrase might not each mean it is identical
Embodiment, nor the independent or alternative embodiment with other embodiments mutual exclusion.Those skilled in the art explicitly and
Implicitly understand, embodiment described herein can be combined with other embodiments.
A kind of solid oxide fuel cell of the solid carbon of present pre-ferred embodiments as fuel, as shown in Figs. 1-2,
Solid carbon including battery case 1 and in the battery case 1, the solid carbon are activated carbon；1 side of the battery case is set
It is in black to have cathodic coating 11, the cathodic coating 11, is covered with diaphragm between the cathodic coating 11 and the battery case 1, passes through institute
It states diaphragm to separate the cathodic coating 11 and the battery case 1, conducting resinl 111 is equipped on the cathodic coating 11, it is described
Conducting resinl 111 distributes as net shape；1 side of the battery case is arranged with the first filamentary silver 21 contacted with the cathodic coating 11, institute
It states 1 one end of battery case and is equipped with the second filamentary silver 22 being connect with 1 inside of the battery case, first filamentary silver 21 and second silver medal
Silk 22 is made of 4 filamentary silvers, and first filamentary silver 21 is anode, and second filamentary silver 22 is cathode；The filling in battery case 1
Solid carbon simultaneously adds 700~850 degrees Celsius of high temperature that power generation can be realized in outside batteries, and electricity generating principle is by fuel and oxidant
In chemical energy be converted into the Chemically generation of electric energy, as long as fuel supply is continuous in principle, battery can continue to generate electricity, practical to send out
Electrical efficiency is 2~3 times of current thermal power generation, realizes the most efficiently utilization of energy in fuel, power generation process environmental protection, without any
Pernicious gas or industrial waste generate, and the problem of will not then being exploded using solid, and are wanted using the cost of electricity-generating of solid
Less than the cost of gas；By simple structure, not only generating efficiency is high, and environmental protection, without any pernicious gas or Industry Waste
Object generates；Both generate electricity safety, has been greatly reduced cost, is the following most attractive generation mode.
It is used as the solid oxide fuel cell of fuel by solid carbon, output power 1-100W can be used for open air
Small-sized electric generating apparatus product, Small SOFCs units be used for border district substituting battery；Output power is the available of 100W-1KW
In the power requirement for the communication and weapon that military field, army carry, light weight is easy to carry；Output power is 1-5KW, can
Applied to unmanned captain's endurance power supply, the common fault and pain spot in unmanned plane cruise duration are solved；Output power is 5-100KW, can be used
It in household electricity or the accessory power supply of vehicle, solves the problems, such as that electric vehicle limits in by conventional batteries, row is determined by fuel used to generate electricity
Sail mileage；Output power is used for distributed power generation station for 1MW's or more, and realization is generated electricity by way of merging two or more grid systems, 0.6 yuan of kilowatt-hour objective cost,
It is suitable with thermoelectricity, without complex devices such as boiler, water and turbines, the generating efficiency of existing turbine power plant can be increased, reduced
The discharge of pollutant, is combined with combustion gas turbine, can transformation efficiency be improved 70% or more.
In addition, solid carbon of the present invention includes one or more in coal, activated carbon, biological carbon, coke or lignite,
It can be used as fuel by one such, can also fuel be used as by many of mixing, convenient for being used not according to different situations
Same solid carbon is as fuel.
As shown in Figs. 1-2, the battery case 1 is tubulose；The battery case 1 a diameter of 13.5mm, a length of 24mm, the electricity
The material of pond shell 1 is yttria-stabilized zirconia；The phase transformation temperature range for changing zirconium dioxide by addition yttrium oxide, generates
Stable cubic crystal and tetragonal crystal at room temperature；More stablize at high temperature convenient for battery case 1, not will produce microcrack.
In addition, conducting resinl 111 of the present invention is silver paste；Convenient for making silver electrode, it is by silver or its compound, fluxing
Agent, adhesive and diluent are formulated；By the existence form of silver, oxidation silver paste, carbonic acid silver paste, molecule silver paste can be divided by burning
Silver-colored temperature can be divided into high temperature silver paste and low temperature silver paste by coating method is covered and spray silver paste；Because battery needs Celsius 700~850
The high temperature of degree realizes power generation, it is possible to cover coating method by high temperature silver paste and spray silver paste.
In addition, the first filamentary silver 21 of the present invention is fixed in the cathodic coating 11 by conducting resinl 111, convenient for preferably will
First filamentary silver 21 is fixed on 1 side of the battery case.
As shown in Figs. 1-2, first silver wire and the second silver wire include that more silver wires form, convenient for making the first filamentary silver 21
It is more firm with the second filamentary silver 22, while keeping water conservancy diversion more stable.
It should be understood that for those of ordinary skills, it can be modified or changed according to the above description,
And all these modifications and variations should all belong to the protection domain of appended claims of the present invention.
Claims (7)
1. a kind of solid oxide fuel cell of solid carbon as fuel, which is characterized in that including battery case and be set to institute
State the solid carbon in battery case；The battery case side is equipped with cathodic coating, is covered between the cathodic coating and the battery case
Diaphragm is equipped with conducting resinl on the cathodic coating, and the conducting resinl distributes as net shape；The battery case side is arranged with and institute
The first filamentary silver of cathodic coating contact is stated, described battery case one end is equipped with the second filamentary silver being connect with battery case inside, described
First filamentary silver is anode, and second filamentary silver is cathode.
2. solid oxide fuel cell of the solid carbon as described in claim 1 as fuel, which is characterized in that the solid
Carbon includes one or more in coal, activated carbon, biological carbon, coke or lignite.
3. solid oxide fuel cell of the solid carbon as described in claim 1 as fuel, which is characterized in that the battery
The material of shell is yttria-stabilized zirconia.
4. solid oxide fuel cell of the solid carbon as claimed in claim 3 as fuel, which is characterized in that the battery
Shell is tubulose；The a diameter of 13.5mm of battery case, a length of 24mm.
5. solid oxide fuel cell of the solid carbon as described in claim 1 as fuel, which is characterized in that the conduction
Glue is silver paste.
6. solid oxide fuel cell of the solid carbon as described in claim 1 as fuel, which is characterized in that described first
Filamentary silver is fixed in the cathodic coating by conducting resinl.
7. solid oxide fuel cell of the solid carbon as described in claim 1 as fuel, which is characterized in that described first
Silver wire and the second silver wire include that more silver wires form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810373982.7A CN108777315A (en) | 2018-04-24 | 2018-04-24 | A kind of solid oxide fuel cell of solid carbon as fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810373982.7A CN108777315A (en) | 2018-04-24 | 2018-04-24 | A kind of solid oxide fuel cell of solid carbon as fuel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108777315A true CN108777315A (en) | 2018-11-09 |
Family
ID=64026663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810373982.7A Withdrawn CN108777315A (en) | 2018-04-24 | 2018-04-24 | A kind of solid oxide fuel cell of solid carbon as fuel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108777315A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110098428A (en) * | 2019-04-30 | 2019-08-06 | 昆明理工大学 | A kind of preparation method of the direct carbon solid oxide fuel cell of high-performance |
-
2018
- 2018-04-24 CN CN201810373982.7A patent/CN108777315A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110098428A (en) * | 2019-04-30 | 2019-08-06 | 昆明理工大学 | A kind of preparation method of the direct carbon solid oxide fuel cell of high-performance |
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Application publication date: 20181109 |