CN108773869A - A kind of low-temperature multi-effect is concentrated by evaporation the processing system and its processing method of high-salt wastewater - Google Patents

A kind of low-temperature multi-effect is concentrated by evaporation the processing system and its processing method of high-salt wastewater Download PDF

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Publication number
CN108773869A
CN108773869A CN201810463675.8A CN201810463675A CN108773869A CN 108773869 A CN108773869 A CN 108773869A CN 201810463675 A CN201810463675 A CN 201810463675A CN 108773869 A CN108773869 A CN 108773869A
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China
Prior art keywords
evaporator
effect
preheaters
temperature
salt wastewater
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CN201810463675.8A
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Inventor
沈胜强
龚路远
郭亚丽
孙瑜
张留阳
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Dalian University of Technology
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Dalian University of Technology
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Priority to CN201810463675.8A priority Critical patent/CN108773869A/en
Publication of CN108773869A publication Critical patent/CN108773869A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/041Treatment of water, waste water, or sewage by heating by distillation or evaporation by means of vapour compression
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/043Details
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

Abstract

A kind of low-temperature multi-effect is concentrated by evaporation the processing system and its processing method of high-salt wastewater, belongs to high-salt wastewater processing field of energy-saving technology.The charging pump discharge of the processing system is sequentially connected an effect brine inlet of each preheater and 1st effective evaporator through pipeline;The quadruple effect brine inlet of four-effect evaporator connects vacuum extractor through pipeline all the way, and another way is sequentially connected the steam inlet of vapour compression machine, temperature-decreased pressure reducer and 1st effective evaporator through pipeline.The indirect steam of preceding 1st effective evaporator is as lower 1st effective evaporator heat source.Temperature-decreased pressure reducer is connected using the water outlet pipe of pipeline and 1st effective evaporator.The indirect steam that the processing system is generated using last effect of multi-effect evaporator, as the heat source of 1st effective evaporator after recompression, reduce the processing cost of high-salt wastewater, the safety and stability performance of sewage treatment equipment is improved, the energy consumption that low-temperature multi-effect evaporates processing system 1 ton of fresh water of generation of high-salt wastewater is about the 14% of conventional evaporator.

Description

A kind of low-temperature multi-effect is concentrated by evaporation the processing system and its processing method of high-salt wastewater
Technical field
The present invention relates to processing systems and its processing method that a kind of low-temperature multi-effect is concentrated by evaporation high-salt wastewater, belong to high Salt wastewater treatment field of energy-saving technology.
Background technology
Currently, the industries such as plating, water filling, papermaking, chlor-alkali generate a large amount of industrial wastewaters, it is inorganic often to contain high concentration in waste water Salt.High-salt wastewater direct emission will be done great harm to the environment.
Low-temperature multi-effect evaporation technique is widely used in high-salt wastewater process field.Usual multi-effect evaporation system end effect generates Indirect steam cannot again utilize become heat source.It needs constantly to provide external steam source to system to realize desalination work( Energy.High-salt wastewater processing system, emphasis that is energy saving and being efficiently the development technology are evaporated for low-temperature multi-effect.MVC vapo(u)rization systems It is based on evaporation concentration system of new generation made of traditional multi-effect evaporation system base growth.The system is using multi-effect evaporator as core Heart heat exchanger components improve steam quality and are recycled by being recompressed to end effect secondary steam.
Invention content
In order to overcome problems of the prior art, the present invention provides a kind of low-temperature multi-effect and is concentrated by evaporation high-salt wastewater Processing system and its processing method, which should utilize the indirect steam that last effect of multi-effect evaporator generates, through again As the heat source of 1st effective evaporator after compression, the processing cost of high-salt wastewater is reduced, improves the safety of sewage treatment equipment Stability.
The technical solution adopted by the present invention is:A kind of low-temperature multi-effect is concentrated by evaporation the processing system of high-salt wastewater, it includes Feed pump, charging water pot, centrifuge, preheater, evaporator and vacuum extractor, it further includes temperature-decreased pressure reducer and both vapor compression Machine, the preheater include that No.1 preheater, No. two preheaters, No. three preheaters and No. four preheaters, the evaporator include Sequentially connected 1st effective evaporator, 2nd effect evaporator, triple effect evaporator and four-effect evaporator, each steam inlet for imitating evaporator with Water outlet is connected in bottom;The import of the feed pump connects charging water pot through pipeline, and outlet is sequentially connected parallel connection through pipeline No.1 preheater and No. two preheaters, No. three preheaters and No. four preheaters, No. four preheaters through pipeline connection one effect evaporate One effect brine inlet of device;The quadruple effect brine inlet of the four-effect evaporator connects vacuum extractor, another way through pipeline all the way The steam inlet of vapour compression machine, temperature-decreased pressure reducer and 1st effective evaporator is sequentially connected through pipeline;The two of the 1st effective evaporator Secondary steam all the way enter 2nd effect evaporator steam inlet, another way enter No. four preheaters, the 2nd effect evaporator it is secondary Steam enters the steam inlet of triple effect evaporator all the way, and another way enters No. three preheaters, the quadruple effect salt of the four-effect evaporator Water out connects No. two preheaters, centrifuge and charging water pot through pipeline, and the water outlet of four-effect evaporator connects one through pipeline Number preheater;The temperature-decreased pressure reducer is connected using the water outlet pipe of pipeline and 1st effective evaporator.
The No.1 preheater and No. two preheaters use plate heat exchanger, and No. three preheaters and No. four preheaters are using pipe Shell heat exchanger.
A kind of low-temperature multi-effect is concentrated by evaporation the processing method of high-salt wastewater:
(a)It it is 20 DEG C temperature, the high-salt wastewater that salinity is 15%-25% is delivered to an effect by feed pump after level Four preheater and steams It sends out in device, wherein the heat source of No.1 preheater is that the strong brine of four-effect evaporator drains, the heat source of No. two preheaters It is drained for the fresh water of four-effect evaporator, the heat source of No. three preheaters is the indirect steam of 2nd effect evaporator, No. four preheaters Heat source be 1st effective evaporator indirect steam;
(b)The temperature of heating steam is 60 DEG C when high-salt wastewater enters 1st effective evaporator, and the evaporating temperature of high-salt wastewater is 65 DEG C By 1st effective evaporator to four-effect evaporator, evaporating temperature is successively decreased 2.5 DEG C successively;High-salt wastewater is between each effect evaporator with fair current Form flows;
(c)The indirect steam that preceding 1st effective evaporator evaporation generates enters lower 1st effective evaporator as heat source, until quadruple effect steams Device is sent out, after vapour compression machine compresses, temperature, pressure increases the indirect steam that four-effect evaporator generates, and enthalpy increases, then It is back to 1st effective evaporator as heat source through temperature-decreased pressure reducer, the steam closed loop in completion system;
(d)Except system startup and stabilization sub stage, steam source is provided without extraneous in operational process, four-effect evaporator discharges dense Brine removes crystal therein after centrifuge;
(e)System is run under vacuum degree condition, and vacuum extractor ensures not containing incondensable gas in system.
The beneficial effects of the invention are as follows:The processing system that this low-temperature multi-effect is concentrated by evaporation high-salt wastewater include feed pump, Feed water pot, centrifuge, preheater, evaporator, vacuum extractor, temperature-decreased pressure reducer and vapour compression machine.The outlet of feed pump An effect brine inlet of each preheater and 1st effective evaporator is sequentially connected through pipeline;The quadruple effect brine inlet of four-effect evaporator is all the way Vacuum extractor is connected through pipeline, another way is sequentially connected vapour compression machine, temperature-decreased pressure reducer and 1st effective evaporator through pipeline Steam inlet.The indirect steam of preceding 1st effective evaporator is as lower 1st effective evaporator heat source.Temperature-decreased pressure reducer using pipeline with The water outlet pipe of 1st effective evaporator connects.The indirect steam that the processing system is generated using last effect of multi-effect evaporator, As the heat source of 1st effective evaporator after recompression, the processing cost of high-salt wastewater is reduced, sewage treatment equipment is improved Safety and stability performance, the energy consumption that low-temperature multi-effect evaporates processing system 1 ton of fresh water of generation of high-salt wastewater is about conventional evaporator 14%。
Description of the drawings
Fig. 1 is a kind of schematic diagram of the processing system of low-temperature multi-effect evaporation and concentration high-salt wastewater.
In figure:1, feed pump, 2, charging water pot, 3, centrifuge, 4, No.1 preheater, 5, No. two preheaters, 6, No. three are pre- Hot device, 7, No. four preheaters, 8, temperature-decreased pressure reducer, 9,1st effective evaporator, 9a, an effect brine inlet, 9b, an effect brine outlet, 10,2nd effect evaporator, 10a, two effect brine inlets, 10b, two effect brine outlets, 11, triple effect evaporator, 11a, effect brine inlet, 11b, triple effect brine outlet, 12, vapour compression machine, 13, four-effect evaporator, 13a, quadruple effect brine inlet, 14b, quadruple effect brine go out Mouthful, 14, vacuum extractor.
Specific implementation mode
Fig. 1 shows that a kind of low-temperature multi-effect is concentrated by evaporation the processing system schematic diagram of high-salt wastewater.This low-temperature multi-effect steams The processing system of hair concentration high-salt wastewater includes feed pump 1, charging water pot 2, centrifuge 3, preheater, evaporator, vacuum means Set 14, temperature-decreased pressure reducer 8 and vapour compression machine 12.Preheater includes the preheater 6 of preheater 5, three of No.1 preheater 4, two With No. four preheaters 7.Evaporator includes sequentially connected 1st effective evaporator 9,2nd effect evaporator 10, triple effect evaporator 11 and quadruple effect Evaporator 13, each steam inlet for imitating evaporator are connected to water outlet in bottom.The import of feed pump 1 is connected through pipeline and is fed Water pot 2, outlet are sequentially connected No.1 preheater 4 in parallel and 5, No. three preheaters 6 of No. two preheaters and No. four preheatings through pipeline Device 7, No. four preheaters 7 connect an effect brine inlet 9a of 1st effective evaporator 9 through pipeline.The quadruple effect brine of four-effect evaporator 13 into Mouth mono- tunnels 13a connect vacuum extractor 14 through pipeline, and another way is sequentially connected vapour compression machine 12, temperature-decreased pressure reducer 8 through pipeline With the steam inlet of 1st effective evaporator 9.The indirect steam of 1st effective evaporator 9 enters the steam inlet of 2nd effect evaporator 10 all the way, Another way enters No. four preheaters 7.The indirect steam of 2nd effect evaporator 10 enters the steam inlet of triple effect evaporator 11 all the way, separately Enter No. three preheaters 6 all the way.The quadruple effect brine outlet 13b of four-effect evaporator 13 connects No. two preheaters 5, centrifuges through pipeline 3 connect No.1 preheater 4 with charging water pot 2, the water outlet of four-effect evaporator 13 through pipeline.Temperature-decreased pressure reducer 8 uses pipeline It is connect with the water outlet pipe of 1st effective evaporator 9.No.1 preheater 4 and No. two preheaters 5 use plate heat exchanger, No. three preheatings Device 6 and No. four preheaters 7 use shell-and-tube heat exchanger.
A kind of low-temperature multi-effect is concentrated by evaporation the processing method of high-salt wastewater:
(a)It it is 20 DEG C temperature, salinity is that the high-salt wastewater of 15%-25% is delivered to an effect after level Four preheater by feed pump 1 In evaporator 9, wherein the heat source of No.1 preheater 4 is that the strong brine of four-effect evaporator 13 drains, No. two preheaters 5 Heat source is that the fresh water of four-effect evaporator 13 drains, and the heat source of No. three preheaters 6 is the secondary steaming of 2nd effect evaporator 10 Vapour, the heat source of No. four preheaters 7 are the indirect steam of 1st effective evaporator 9;
(b)The temperature of heating steam is 60 DEG C when high-salt wastewater enters 1st effective evaporator 9, and the evaporating temperature of high-salt wastewater is 65 DEG C By 1st effective evaporator 9 to four-effect evaporator 13, evaporating temperature is successively decreased 2.5 DEG C successively;High-salt wastewater between each effect evaporator with Fair current form flows;
(c)The indirect steam that preceding 1st effective evaporator evaporation generates enters lower 1st effective evaporator as heat source, until quadruple effect steams Device 13 is sent out, after the compression of vapour compression machine 12, temperature, pressure increases the indirect steam that four-effect evaporator 13 generates, and enthalpy increases Add, being then back to 1st effective evaporator 9 through temperature-decreased pressure reducer 8 is used as heat source, the steam closed loop in completion system;
(d)Except system startup and stabilization sub stage, steam source is provided without extraneous in operational process, what four-effect evaporator 13 discharged Strong brine removes crystal therein after centrifuge 3;
(e)System is run under vacuum degree condition, and vacuum extractor 14 ensures not containing incondensable gas in system.
Using above-mentioned technical proposal, the high-salt wastewater that temperature is 20 DEG C, salinity is 15% is divided to two branches to be transported to respectively The heat source of board-like No.1 preheater 4 and No. two preheaters 5, No.1 preheater 4 drains for the fresh water of four-effect evaporator 13, and two The heat source of number preheater 5 is that the strong brine of four-effect evaporator 13 drains.Two above branch brine is in outflow No.1 preheating Device 4 and No. two preheaters 5 converge after exporting, and flow successively through No. three preheaters 6 of shell-and-tube and No. four preheaters 7, heat source The respectively indirect steam of 2nd effect evaporator 10 and 1st effective evaporator 9.After one to No. four preheaters preheat, brine temp connects Nearly preset effect evaporating temperature.Brine is followed by 1st effective evaporator 9,2nd effect evaporator 10,11 and of triple effect evaporator Four-effect evaporator 13, and evaporate, concentrate, the cocnentration factor ranging from 1.5-4 of seawater, finally in four-effect evaporation in each effect evaporator Device 13 is discharged to centrifuge 3.After highly concentrated seawater removes crystal therein in centrifuge 3, it is transported to strong brine Holding vessel 2.Steam, which discharges heat and condensed in heat-transfer pipe of evaporator, becomes fresh water, manages outer brine and is heated as secondary steaming Vapour.The indirect steam that upper 1st effective evaporator generates enters next effect evaporator tube and surveys as heat source;Upper 1st effective evaporator Water outlet is connected with the bottom of lower 1st effective evaporator front head, and the fresh water that upper 1st effective evaporator generates is flashed in next effect part After enter and be used as heat source in heat-transfer pipe.The indirect steam of four-effect evaporator 13 flow to vapour compression machine 12, improves its temperature It flow to temperature-decreased pressure reducer after degree, pressure, enthalpy.In temperature-decreased pressure reducer 8, part fresh water and compression that 1st effective evaporator 9 generates 12 outlet vapor of machine blends so that superheated steam enters in 1st effective evaporator 9 after becoming saturated vapor again as heating heat Source.

Claims (3)

1. a kind of low-temperature multi-effect is concentrated by evaporation the processing system of high-salt wastewater, it includes feed pump(1), charging water pot(2), centrifugation Machine(3), preheater, evaporator and vacuum extractor(14), it is characterized in that:It further includes temperature-decreased pressure reducer(8)And both vapor compression Machine(12), the preheater includes No.1 preheater(4), No. two preheaters(5), No. three preheaters(6)With No. four preheaters (7), the evaporator includes sequentially connected 1st effective evaporator(9), 2nd effect evaporator(10), triple effect evaporator(11)And quadruple effect Evaporator(13), each steam inlet for imitating evaporator is connected to water outlet in bottom;The feed pump(1)Import through pipeline Connection charging water pot(2), outlet is sequentially connected No.1 preheater in parallel through pipeline(4)With No. two preheaters(5), No. three preheatings Device(6)With No. four preheaters(7), No. four preheaters(7)1st effective evaporator is connected through pipeline(9)One effect brine inlet(9a); The four-effect evaporator(13)Quadruple effect brine inlet(13a)All the way vacuum extractor is connected through pipeline(14), another way is through pipe Road is sequentially connected vapour compression machine(12), temperature-decreased pressure reducer(8)And 1st effective evaporator(9)Steam inlet;The one effect evaporation Device(9)Indirect steam all the way enter 2nd effect evaporator(10)Steam inlet, another way enter No. four preheaters(7), described 2nd effect evaporator(10)Indirect steam all the way enter triple effect evaporator(11)Steam inlet, another way enter No. three preheaters (6), the four-effect evaporator(13)Quadruple effect brine outlet(13b)No. two preheaters are connected through pipeline(5), centrifuge(3)With Feed water pot(2), four-effect evaporator(13)Water outlet through pipeline connect No.1 preheater(4);The temperature-decreased pressure reducer(8) Using pipeline and 1st effective evaporator(9)Water outlet pipe connection.
2. a kind of low-temperature multi-effect according to claim 1 is concentrated by evaporation high-salt wastewater processing system, it is characterized in that:Described one Number preheater(4)With No. two preheaters(5)Using plate heat exchanger, No. three preheaters(6)With No. four preheaters(7)Using shell Formula heat exchanger.
3. a kind of low-temperature multi-effect according to claim 1 is concentrated by evaporation the processing method of high-salt wastewater, it is characterized in that:
(a)It it is 20 DEG C temperature, the high-salt wastewater that salinity is 15%-25% is after level Four preheater by feed pump(1)It is delivered to one Imitate evaporator(9)In, wherein No.1 preheater(4)Heat source be four-effect evaporator(13)Strong brine draining, No. two are pre- Hot device(5)Heat source be four-effect evaporator(13)Fresh water draining, No. three preheaters(6)Heat source be two effect evaporate Device(10)Indirect steam, No. four preheaters(7)Heat source be 1st effective evaporator(9)Indirect steam;
(b)High-salt wastewater enters 1st effective evaporator(9)The temperature of Shi Jiare steam is 60 DEG C, and the evaporating temperature of high-salt wastewater is 65 DEG C by 1st effective evaporator(9)To four-effect evaporator(13), evaporating temperature successively decreases 2.5 DEG C successively;High-salt wastewater is in each effect evaporator Between in the form of fair current flow;
(c)The indirect steam that preceding 1st effective evaporator evaporation generates enters lower 1st effective evaporator as heat source, until quadruple effect steams Send out device(13), four-effect evaporator(13)The indirect steam of generation passes through vapour compression machine(12)After compression, temperature, pressure increases, enthalpy Value increases, then through temperature-decreased pressure reducer(8)It is back to 1st effective evaporator(9)As heat source, the steam in completion system closes Loop back path;
(d)Except system startup and stabilization sub stage, steam source, four-effect evaporator are provided without extraneous in operational process(13)Discharge Strong brine pass through centrifuge(3)After remove crystal therein;
(e)System is run under vacuum degree condition, vacuum extractor(14)Incondensable gas is not contained in guarantee system.
CN201810463675.8A 2018-05-15 2018-05-15 A kind of low-temperature multi-effect is concentrated by evaporation the processing system and its processing method of high-salt wastewater Pending CN108773869A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110384944A (en) * 2019-08-28 2019-10-29 南通晨光石墨设备有限公司 Spent acid evaporation concentration equipment and waste acid treatment method
CN110407385A (en) * 2019-07-12 2019-11-05 绍兴润泰环保科技有限公司 A kind of coal chemical industrial wastewater processing system and its processing method
CN112794390A (en) * 2020-12-31 2021-05-14 青海宜化化工有限责任公司 Treatment device for chlor-alkali chemical wastewater and use method thereof

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Publication number Priority date Publication date Assignee Title
CN201694861U (en) * 2010-04-27 2011-01-05 杭州华达喷射真空设备有限公司 Low-temperature multi-effect sea water desalination water treatment steam injection vacuum system
CN205773844U (en) * 2016-05-17 2016-12-07 常州泰特环境设备工程有限公司 A kind of high-salt wastewater triple effect evaporation crystallization apparatus without cooling down water
JP2017018927A (en) * 2015-07-15 2017-01-26 日立造船株式会社 Multi-utility type water producing apparatus

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201694861U (en) * 2010-04-27 2011-01-05 杭州华达喷射真空设备有限公司 Low-temperature multi-effect sea water desalination water treatment steam injection vacuum system
JP2017018927A (en) * 2015-07-15 2017-01-26 日立造船株式会社 Multi-utility type water producing apparatus
CN205773844U (en) * 2016-05-17 2016-12-07 常州泰特环境设备工程有限公司 A kind of high-salt wastewater triple effect evaporation crystallization apparatus without cooling down water

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110407385A (en) * 2019-07-12 2019-11-05 绍兴润泰环保科技有限公司 A kind of coal chemical industrial wastewater processing system and its processing method
CN110407385B (en) * 2019-07-12 2024-04-12 绍兴润泰环保科技有限公司 Coal chemical wastewater treatment system and treatment method thereof
CN110384944A (en) * 2019-08-28 2019-10-29 南通晨光石墨设备有限公司 Spent acid evaporation concentration equipment and waste acid treatment method
CN112794390A (en) * 2020-12-31 2021-05-14 青海宜化化工有限责任公司 Treatment device for chlor-alkali chemical wastewater and use method thereof

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Application publication date: 20181109