CN108773115A - A kind of macromolecule high fire-retardance synthetic leather - Google Patents
A kind of macromolecule high fire-retardance synthetic leather Download PDFInfo
- Publication number
- CN108773115A CN108773115A CN201810857474.6A CN201810857474A CN108773115A CN 108773115 A CN108773115 A CN 108773115A CN 201810857474 A CN201810857474 A CN 201810857474A CN 108773115 A CN108773115 A CN 108773115A
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- China
- Prior art keywords
- retardant
- flame
- layer
- fire
- leather
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- 239000002649 leather substitute Substances 0.000 title claims abstract description 23
- 229920002521 macromolecule Polymers 0.000 title claims abstract description 19
- 239000003063 flame retardant Substances 0.000 claims abstract description 120
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000010985 leather Substances 0.000 claims abstract description 48
- 239000000758 substrate Substances 0.000 claims abstract description 18
- -1 perfluoroethylene-propylene Chemical group 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 10
- 229910000831 Steel Inorganic materials 0.000 claims description 9
- 239000010959 steel Substances 0.000 claims description 9
- 239000003365 glass fiber Substances 0.000 claims description 7
- CHJAYYWUZLWNSQ-UHFFFAOYSA-N 1-chloro-1,2,2-trifluoroethene;ethene Chemical group C=C.FC(F)=C(F)Cl CHJAYYWUZLWNSQ-UHFFFAOYSA-N 0.000 claims description 6
- 229920001780 ECTFE Polymers 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000000395 magnesium oxide Substances 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 9
- 235000019504 cigarettes Nutrition 0.000 abstract description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract description 6
- 239000000347 magnesium hydroxide Substances 0.000 abstract description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract description 6
- 239000000654 additive Substances 0.000 abstract description 4
- 230000000996 additive effect Effects 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 4
- 230000003000 nontoxic effect Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910000851 Alloy steel Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- KOUNOBXGDXRSLR-UHFFFAOYSA-N 3-fluoropent-2-ene Chemical compound CCC(F)=CC KOUNOBXGDXRSLR-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
- B32B17/10027—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet the glass sheet not being an outer layer
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
- B32B3/085—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts spaced apart pieces on the surface of a layer
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- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
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- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
- B32B9/025—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch comprising leather
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses a kind of macromolecule high fire-retardance synthetic leather, including fire-retardant leather, the front of fire-retardant leather is fixedly connected with fire-retardant piece, fire-retardant piece of the front offers heat emission hole, the fire-retardant leather includes the first flame-retardant layer, second flame-retardant layer, third flame-retardant layer, first fibrous layer, enhancement layer, second fibrous layer and leather substrate, the front of first flame-retardant layer is bonded with the second flame-retardant layer, the front of second flame-retardant layer is bonded with third flame-retardant layer, the front of the third flame-retardant layer is bonded with the first fibrous layer, the front of first fibrous layer is bonded with enhancement layer, the front of the enhancement layer is bonded with the second fibrous layer.The macromolecule high fire-retardance synthetic leather, the magnesium hydroxide added in leather substrate is a kind of faster additive flame retardant of development, low cigarette, nontoxic and can neutralize acidity in combustion process, corrosive gas, realizes purpose that can be fire-retardant, the sprawling of fire behavior is avoided, fire odds is reduced.
Description
Technical field
The present invention relates to integrated library systems field, specially a kind of macromolecule high fire-retardance synthetic leather.
Background technology
It simulates the Nomenclature Composition and Structure of Complexes of natural leather and can be used as the plastic products of its substitute material, usually with the nonwoven through dipping
Cloth is lamina reticularis, and microporous polyurethane layer is made as grain layer, and positive and negative are all quite similar with leather, and has centainly
Gas permeability is widely used in than common artificial leather closer to natural leather and makes shoes, boots, luggage and ball etc..
Existing synthetic leather has certain gas permeability, than common artificial leather closer to natural leather, but existing synthesis
Generally there are not fire-retardant disadvantages for leather, and when encountering open fire burning, these synthetic leather can match combination burning, to cause fire
Calamity causes the threat to life safety and property safety, so a kind of macromolecule high fire-retardance synthetic leather is proposed to solve above-mentioned institute
The problem of proposition.
Invention content
It is mentioned above in the background art to solve the purpose of the present invention is to provide a kind of macromolecule high fire-retardance synthetic leather
There are problems that not fire-retardant disadvantage.
To achieve the above object, the present invention provides the following technical solutions:A kind of macromolecule high fire-retardance synthetic leather, including it is fire-retardant
Leather, the front of fire-retardant leather are fixedly connected with fire-retardant piece, and fire-retardant piece of the front offers heat emission hole.
The fire-retardant leather includes the first flame-retardant layer, the second flame-retardant layer, third flame-retardant layer, the first fibrous layer, enhancement layer, second
The front of fibrous layer and leather substrate, first flame-retardant layer is bonded with the second flame-retardant layer, and the front of second flame-retardant layer is viscous
It is connected to third flame-retardant layer, the front of the third flame-retardant layer is bonded with the first fibrous layer, the front bonding of first fibrous layer
There are enhancement layer, the front of the enhancement layer to be bonded with the second fibrous layer, the front of second fibrous layer is bonded with leather substrate.
Preferably, it is made of heat-resistant steel for fire-retardant piece, the aperture of the heat emission hole is not more than five millimeters.
Preferably, the first flame-retardant layer is made of polyvinylidene chloride, and second flame-retardant layer is made of perfluoroethylene-propylene,
The thickness of first flame-retardant layer is more than the thickness of the second flame-retardant layer.
Preferably, the third flame-retardant layer is made of ethylene chlorotrifluoroethylene, the thickness of first flame-retardant layer
More than the thickness of the second flame-retardant layer.
Preferably, first fibrous layer is made of glass fibre, and the enhancement layer is made of polypropylene flame redardant.
Preferably, second fibrous layer contains fire resistance fibre and nylon, and the thickness of the leather substrate is not less than a milli
Rice, the leather substrate contain magnesium hydroxide.
Compared with prior art, the beneficial effects of the invention are as follows:A kind of macromolecule high fire-retardance synthetic leather, is fixed on fire-retardant
It is a kind of steel alloy with higher intensity and good chemical stability at high temperature to remove from office positive fire-retardant piece, is played heat-resisting
Fire-retardant effect, the fire-retardant piece of heat emission hole opened up with fire-retardant leather cooperation coordinate exchange of air to play the heat that sheds on monoblock leather material
The effect of amount, the polyvinylidene chloride that the first flame-retardant layer for including in fire-retardant leather uses has resistance to combustion, corrosion-resistant, air-tightness is good etc.
Characteristic, the perfluoroethylene-propylene that the second flame-retardant layer uses do not ignite, and can prevent the diffusion of flame, it has excellent weatherability,
Friction coefficient is relatively low, can be used from low temperature to 392 ℉, the ethylene chlorotrifluoroethylene that third flame-retardant layer uses is not
Fire can prevent flame spread, when being exposed in flame, will resolve into the carbon of hard, the glass fibre that the first fibrous layer uses
Heat-resist, temperature does not influence intensity up at 300 DEG C, and the polypropylene flame redardant that enhancement layer uses has the function of fire-retardant, suppression cigarette,
The fire resistance fibre that second fibrous layer uses refers to only glowing in flame, and flame does not occur in itself, leaves flame, glows and voluntarily put out
The fiber to go out, the magnesium hydroxide added in leather substrate are a kind of faster additive flame retardant of development, low cigarette, nontoxic and energy
Acidity, corrosive gas in neutralization combustion process, realize purpose that can be fire-retardant, avoid the sprawling of fire behavior, reduce fire hair
Raw probability.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of macromolecule high fire-retardance synthetic leather of this practicality;
Fig. 2 is the structural schematic diagram of fire-retardant leather in a kind of macromolecule high fire-retardance synthetic leather of this practicality.
In figure:The fire-retardant leather of 1-;The first flame-retardant layers of 11-;The second flame-retardant layers of 12-;13- third flame-retardant layers;The first fibers of 14-
Layer;15- enhancement layers;The second fibrous layers of 16-;17- leather substrates;Fire-retardant piece of 2-;3- heat emission holes.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
- 2 are please referred to Fig.1, a kind of embodiment provided by the invention:A kind of macromolecule high fire-retardance synthetic leather, including fire-retardant leather
1, the front of fire-retardant leather 1 is fixedly connected with fire-retardant piece 2, and fire-retardant piece 2 of front offers heat emission hole 3, and fire-retardant piece 2 by heat-resisting steel
At heat resisting steel includes two class of oxidation resistant steel and refractory steel, the load that oxidation resistant steel generally requires preferable chemical stability, but bears
Lotus is relatively low, and then more demanding elevated temperature strength and corresponding inoxidizability, heat resisting steel are usually used in manufacturing boiler, steamer refractory steel
The aperture of the parts to work at high temperature in the industrial departments such as machine, dynamic power machine, aviation and petrochemical industry, heat emission hole 3 is little
In five millimeters, fire-retardant leather 1 includes the first flame-retardant layer 11, the second flame-retardant layer 12, third flame-retardant layer 13, the first fibrous layer 14, reinforces
The 15, second fibrous layer 16 of layer and leather substrate 17, the front of the first flame-retardant layer 11 are bonded with the second flame-retardant layer 12, the second flame-retardant layer
12 front is bonded with third flame-retardant layer 13, and the first flame-retardant layer 11 is made of polyvinylidene chloride, and the second flame-retardant layer 12 is by poly- complete
Fluoro ethyl propene is made, and perfluoroethylene-propylene can be made into sheet material, tubing, molded item, film and fiber, and fiber China is referred to as inclined chlorine
Synthetic fibre, american goods name saran, in order to overcome dissolubility poor, the shortcomings that processing difficulties, usually by vinylidene chloride and a small amount of chloroethene
The monomers such as alkene, acrylonitrile and acrylate are copolymerized, and obtain binary or ternary copolymer, vinylidene chloride copolymer also serves as painting
Material, adhesive etc. are additionally operable to since it is very sensitive to irradiation such as ultraviolet, electron beams and decomposes a small amount of hydrogen chloride of generation
Acid-sensitive recording materials, the thickness of the first flame-retardant layer 11 are more than the thickness of the second flame-retardant layer 12, and third flame-retardant layer 13 is by ethylene trifluoro
Vinyl chloride copolymer is made, and ethylene chlorotrifluoroethylene is a kind of soft plastic, tensile strength, wearability and creep resistant
Property be less than many engineering plastics, it is chemically inert, in very wide temperature and frequency range have lower dielectric constant,
The thickness of first flame-retardant layer 11 is more than the thickness of the second flame-retardant layer 12, and the front of third flame-retardant layer 13 is bonded with the first fibrous layer
14, the front of the first fibrous layer 14 is bonded with enhancement layer 15, and the first fibrous layer 14 is made of glass fibre, and glass fibre has excellent
Electrical insulating property, be advanced electrically insulating material, be also used for heat-insulating material and fire-proof shield material, it is general only by concentrated base, hydrogen fluorine
Acid and concentrated phosphoric acid corrosion, enhancement layer 15 is made of polypropylene flame redardant, and the front of enhancement layer 15 is bonded with the second fibrous layer 16, and second
The front of fibrous layer 16 is bonded with leather substrate 17, and the second fibrous layer 16 contains fire resistance fibre and nylon, the thickness of leather substrate 17
Degree be not less than one millimeter, leather substrate 17 contains magnesium hydroxide, be fixed on it is fire-retardant leather 1 positive fire-retardant piece 2 be one kind in high temperature
Steel alloy with higher intensity and good chemical stability down, plays the effect of heat-proof combustion-resistant, fire-retardant piece 2 and fire-retardant leather
1 coordinates the effect that the heat emission hole 3 opened up coordinates exchange of air to play the heat that sheds on monoblock leather material, includes in fire-retardant leather 1
The polyvinylidene chloride that uses of the first flame-retardant layer 11 have that resistance to combustion, corrosion-resistant, air-tightness is good etc., and characteristics, the second flame-retardant layer 12 are adopted
Perfluoroethylene-propylene does not ignite, and can prevent the diffusion of flame, it has excellent weatherability, and friction coefficient is relatively low, from low
Temperature can be used to 392 ℉, and the ethylene chlorotrifluoroethylene that third flame-retardant layer 13 uses is missing of ignition, can prevent flame from expanding
It dissipates, when being exposed in flame, the carbon of hard will be resolved into, the glass fiber heat-resistant that the first fibrous layer 14 uses is good, temperature
Intensity is not influenced up at 300 DEG C, the polypropylene flame redardant that enhancement layer 15 uses has the function of fire-retardant, suppression cigarette, the second fibrous layer
16 fire resistance fibres used refer to only glowing in flame, and flame does not occur in itself, leaves flame, the fibre for the self-extinguish that glows
Dimension, the magnesium hydroxide added in leather substrate 17 are a kind of faster additive flame retardants of development, low cigarette, nontoxic and can neutralize
Acidity, corrosive gas in combustion process realize purpose that can be fire-retardant, avoid the sprawling of fire behavior, reduce what fire occurred
Probability.
In conclusion the macromolecule high fire-retardance synthetic leather, it is one kind in high temperature to be fixed on 1 positive fire-retardant piece 2 of fire-retardant leather
Steel alloy with higher intensity and good chemical stability down, plays the effect of heat-proof combustion-resistant, fire-retardant piece 2 and fire-retardant leather
1 coordinates the effect that the heat emission hole 3 opened up coordinates exchange of air to play the heat that sheds on monoblock leather material, includes in fire-retardant leather 1
The polyvinylidene chloride that uses of the first flame-retardant layer 11 have that resistance to combustion, corrosion-resistant, air-tightness is good etc., and characteristics, the second flame-retardant layer 12 are adopted
Perfluoroethylene-propylene does not ignite, and can prevent the diffusion of flame, it has excellent weatherability, and friction coefficient is relatively low, from low
Temperature can be used to 392 ℉, and the ethylene chlorotrifluoroethylene that third flame-retardant layer 13 uses is missing of ignition, can prevent flame from expanding
It dissipates, when being exposed in flame, the carbon of hard will be resolved into, the glass fiber heat-resistant that the first fibrous layer 14 uses is good, temperature
Intensity is not influenced up at 300 DEG C, the polypropylene flame redardant that enhancement layer 15 uses has the function of fire-retardant, suppression cigarette, the second fibrous layer
16 fire resistance fibres used refer to only glowing in flame, and flame does not occur in itself, leaves flame, the fibre for the self-extinguish that glows
It ties up, the magnesium hydroxide added in leather substrate 17 is to develop a kind of faster additive flame retardant, in low cigarette, nontoxic and energy
With the acidity in combustion process, corrosive gas, realizes purpose that can be fire-retardant, avoid the sprawling of fire behavior, reduce fire
Probability.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
Claims (6)
1. a kind of macromolecule high fire-retardance synthetic leather, including fire-retardant leather (1), which is characterized in that the front of fire-retardant leather (1) is fixedly connected
Have fire-retardant piece (2), the front of fire-retardant piece (2) offers heat emission hole (3);
The fire-retardant leather (1) includes the first flame-retardant layer (11), the second flame-retardant layer (12), third flame-retardant layer (13), the first fibrous layer
(14), the front of enhancement layer (15), the second fibrous layer (16) and leather substrate (17), first flame-retardant layer (11) is bonded with
The front of two flame-retardant layers (12), second flame-retardant layer (12) is bonded with third flame-retardant layer (13), the third flame-retardant layer (13)
Front be bonded with the first fibrous layer (14), the front of first fibrous layer (14) is bonded with enhancement layer (15), the reinforcement
The front of layer (15) is bonded with the second fibrous layer (16), and the front of second fibrous layer (16) is bonded with leather substrate (17).
2. a kind of macromolecule high fire-retardance synthetic leather according to claim 1, it is characterised in that:Fire-retardant piece (2) are by resistance to
Hot steel is made, and the aperture of the heat emission hole (3) is not more than five millimeters.
3. a kind of macromolecule high fire-retardance synthetic leather according to claim 1, it is characterised in that:First flame-retardant layer (11)
It is made of polyvinylidene chloride, second flame-retardant layer (12) is made of perfluoroethylene-propylene, first flame-retardant layer (11)
Thickness is more than the thickness of the second flame-retardant layer (12).
4. a kind of macromolecule high fire-retardance synthetic leather according to claim 1, it is characterised in that:The third flame-retardant layer (13)
It is made of ethylene chlorotrifluoroethylene, the thickness of first flame-retardant layer (11) is more than the thickness of the second flame-retardant layer (12).
5. a kind of macromolecule high fire-retardance synthetic leather according to claim 1, it is characterised in that:First fibrous layer (14)
It is made of glass fibre, the enhancement layer (15) is made of polypropylene flame redardant.
6. a kind of macromolecule high fire-retardance synthetic leather according to claim 1, it is characterised in that:Second fibrous layer (16)
Containing fire resistance fibre and nylon, the thickness of the leather substrate (17) is not less than one millimeter, and the leather substrate (17) contains hydrogen
Magnesia.
Priority Applications (1)
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CN201810857474.6A CN108773115A (en) | 2018-07-31 | 2018-07-31 | A kind of macromolecule high fire-retardance synthetic leather |
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Application Number | Priority Date | Filing Date | Title |
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CN201810857474.6A CN108773115A (en) | 2018-07-31 | 2018-07-31 | A kind of macromolecule high fire-retardance synthetic leather |
Publications (1)
Publication Number | Publication Date |
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CN108773115A true CN108773115A (en) | 2018-11-09 |
Family
ID=64028413
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Application Number | Title | Priority Date | Filing Date |
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CN201810857474.6A Withdrawn CN108773115A (en) | 2018-07-31 | 2018-07-31 | A kind of macromolecule high fire-retardance synthetic leather |
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Country | Link |
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CN (1) | CN108773115A (en) |
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2018
- 2018-07-31 CN CN201810857474.6A patent/CN108773115A/en not_active Withdrawn
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