CN108772046A - A kind of polyester active carbon adsorption material and preparation method thereof - Google Patents
A kind of polyester active carbon adsorption material and preparation method thereof Download PDFInfo
- Publication number
- CN108772046A CN108772046A CN201810520418.3A CN201810520418A CN108772046A CN 108772046 A CN108772046 A CN 108772046A CN 201810520418 A CN201810520418 A CN 201810520418A CN 108772046 A CN108772046 A CN 108772046A
- Authority
- CN
- China
- Prior art keywords
- added
- taken
- active carbon
- polyester
- ammonium persulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of polyester active carbon adsorption material and preparation method thereof, what which was made of the raw material of following weight parts：Butyl acrylate 50-60, ammonium persulfate 0.1-0.13, methyl methacrylate 10-14, nylon acid methyl esters 20-30, polytetrafluoroethylwax wax 2-4, carbon dust 100-140, silane coupling agent kh560 0.3-1.The present invention is using butyl acrylate, methyl methacrylate as monomer, and using ammonium persulfate as initiator, the carbon dust aqueous solution being modified using silane coupling agent kh560 is polymerize under nitrogen effect as reaction dissolvent, sorbing material obtained, with good adsorption effect.
Description
Technical field
The invention belongs to Material Fields, and in particular to a kind of polyester active carbon adsorption material and preparation method thereof.
Background technology
Activated carbon, which is the one kind prepared using carbonaceous materials such as timber, shell, coals as raw material, has flourishing pore structure, huge
The material of specific surface area, strong adsorption capacity, the application in the fields such as environmental protection, national defence, chemical industry, food, medicine, weaving are increasingly wide
It is general.In recent years, coal, sawdust resource shortage were on the rise, therefore continually developed the raw material of Activated Carbon Production, explore new technique item
Part increases the vital task that new varieties are China or even World Activated Carbon industrial development.Raw material wood is prepared for conventional carbon
The problem of material shortage of resources, it is that raw material prepares activity to develop peanut shell, walnut shell, almond, bagasse, rice straw in recent years
Charcoal, and achieve preferable achievement.
Invention content
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of polyester active carbon adsorption material and
Preparation method.
To achieve the above object, the present invention uses following technical scheme：
A kind of polyester active carbon adsorption material, it is made of the raw material of following weight parts：
Butyl acrylate 50-60, ammonium persulfate 0.1-0.13, methyl methacrylate 10-14, nylon acid methyl esters 20-30, poly- four
Vinyl fluoride wax 2-4, carbon dust 100-140, silane coupling agent kh560 0.3-1.
The preparation method of the polyester active carbon adsorption material, includes the following steps：
（1）Ammonium persulfate is taken, is added in the deionized water of 20-30 times of its weight, stirs evenly；
（2）Carbon dust is taken, is added in the absolute ethyl alcohol of 6-10 times of its weight, stirs evenly, silane coupling agent kh560 is added, is risen
High-temperature is 50-55 DEG C, and insulated and stirred 20-30 minutes obtains silane dispersion fluid；
（3）Methyl methacrylate, butyl acrylate mixing are taken, is added in the deionized water of 10-17 times of mixture weight, stirs
It mixes uniformly, mixes, be sent in reaction kettle with above-mentioned silane dispersion fluid, be passed through nitrogen, it is 65-70 DEG C to adjust temperature of reaction kettle,
Above-mentioned ammonium persulfate aqueous solution, insulated and stirred 3-5 hours is added, discharging cooling obtains polyester emulsion；
（4）Polytetrafluoroethylwax wax is taken, is added in nylon acid methyl esters, stirs evenly, obtains ester dispersion liquid；
（5）Above-mentioned polyester emulsion is taken, mixes, stirs evenly with ester dispersion liquid, filters, filter cake is washed, is done at 60-70 DEG C of vacuum
It is 1-2 hours dry, it is cooled to room temperature to get the polyester active carbon adsorption material.
Advantages of the present invention
The present invention is using butyl acrylate, methyl methacrylate as monomer, using ammonium persulfate as initiator, with silane coupling agent
The carbon dust aqueous solution that kh560 is modified is reaction dissolvent, polymerize under nitrogen effect, obtains sorbing material, has and inhale well
Attached effect.
Specific implementation mode
Embodiment 1
A kind of polyester active carbon adsorption material, it is made of the raw material of following weight parts：
Butyl acrylate 50, ammonium persulfate 0.1, methyl methacrylate 10, nylon acid methyl esters 20, polytetrafluoroethylwax wax 2, carbon dust
100, silane coupling agent kh560 0.3.
The preparation method of the polyester active carbon adsorption material, includes the following steps：
（1）Ammonium persulfate is taken, is added in the deionized water of 20 times of its weight, stirs evenly；
（2）Carbon dust is taken, is added in the absolute ethyl alcohol of 6 times of its weight, stirs evenly, silane coupling agent kh560 is added, increases temperature
Degree is 50 DEG C, and insulated and stirred 20 minutes obtains silane dispersion fluid；
（3）Methyl methacrylate, butyl acrylate mixing are taken, is added in the deionized water of 10 times of mixture weight, stirs
Uniformly, it mixes, is sent in reaction kettle with above-mentioned silane dispersion fluid, be passed through nitrogen, it is 65 DEG C to adjust temperature of reaction kettle, in addition
Ammonium persulfate aqueous solution, insulated and stirred 3 hours are stated, discharging cooling obtains polyester emulsion；
（4）Polytetrafluoroethylwax wax is taken, is added in nylon acid methyl esters, stirs evenly, obtains ester dispersion liquid；
（5）Above-mentioned polyester emulsion is taken, mixes, stirs evenly with ester dispersion liquid, filters, filter cake is washed, dry 1 at 60 DEG C of vacuum
Hour, it is cooled to room temperature to get the polyester active carbon adsorption material.
Claims (2)
1. a kind of polyester active carbon adsorption material, which is characterized in that it is made of the raw material of following weight parts：
Butyl acrylate 50-60, ammonium persulfate 0.1-0.13, methyl methacrylate 10-14, nylon acid methyl esters 20-30, poly- four
Vinyl fluoride wax 2-4, carbon dust 100-140, silane coupling agent kh560 0.3-1.
2. a kind of preparation method of polyester active carbon adsorption material as described in claim 1, which is characterized in that including following step
Suddenly：
（1）Ammonium persulfate is taken, is added in the deionized water of 20-30 times of its weight, stirs evenly；
（2）Carbon dust is taken, is added in the absolute ethyl alcohol of 6-10 times of its weight, stirs evenly, silane coupling agent kh560 is added, is risen
High-temperature is 50-55 DEG C, and insulated and stirred 20-30 minutes obtains silane dispersion fluid；
（3）Methyl methacrylate, butyl acrylate mixing are taken, is added in the deionized water of 10-17 times of mixture weight, stirs
It mixes uniformly, mixes, be sent in reaction kettle with above-mentioned silane dispersion fluid, be passed through nitrogen, it is 65-70 DEG C to adjust temperature of reaction kettle,
Above-mentioned ammonium persulfate aqueous solution, insulated and stirred 3-5 hours is added, discharging cooling obtains polyester emulsion；
（4）Polytetrafluoroethylwax wax is taken, is added in nylon acid methyl esters, stirs evenly, obtains ester dispersion liquid；
（5）Above-mentioned polyester emulsion is taken, mixes, stirs evenly with ester dispersion liquid, filters, filter cake is washed, is done at 60-70 DEG C of vacuum
It is 1-2 hours dry, it is cooled to room temperature to get the polyester active carbon adsorption material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810520418.3A CN108772046A (en) | 2018-05-28 | 2018-05-28 | A kind of polyester active carbon adsorption material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810520418.3A CN108772046A (en) | 2018-05-28 | 2018-05-28 | A kind of polyester active carbon adsorption material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108772046A true CN108772046A (en) | 2018-11-09 |
Family
ID=64027795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810520418.3A Withdrawn CN108772046A (en) | 2018-05-28 | 2018-05-28 | A kind of polyester active carbon adsorption material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108772046A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109574120A (en) * | 2018-12-16 | 2019-04-05 | 陈绪涛 | A kind of graphene doping textile dyestuff Wastewater purification material and preparation method thereof |
-
2018
- 2018-05-28 CN CN201810520418.3A patent/CN108772046A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109574120A (en) * | 2018-12-16 | 2019-04-05 | 陈绪涛 | A kind of graphene doping textile dyestuff Wastewater purification material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104448158B (en) | A kind of preparation method of lithium battery aqueous binder | |
| CN105540869B (en) | A kind of modified graphene oxide composite for loading Paracoccus denitrificans and its production and use | |
| CN103253886B (en) | A kind of Polycarboxylate superplasticizer synergist and preparation method thereof | |
| CN108772046A (en) | A kind of polyester active carbon adsorption material and preparation method thereof | |
| WO2019128420A1 (en) | Long-effect desert expansion inhibitor and long-effect desert expansion inhibiting method | |
| CN102502628A (en) | Preparation method of granular activated carbon by chemical activation | |
| CN110437843B (en) | Preparation method of oil shale semicoke-based composite water-retaining agent | |
| CN103539116A (en) | Process for producing activated carbon by means of phosphoric acid method | |
| CN101812277A (en) | Pressure-sensitive adhesive formula and preparation method thereof | |
| CN105273111B (en) | A kind of method of stripper plant fouling in reduction Production of PVC | |
| CN108314042A (en) | A kind of complex spherical active carbon purifying particle and preparation method thereof | |
| CN104694057A (en) | Breaking-resistant acrylate pressure-sensitive adhesive for walls and preparation method thereof | |
| CN102774833A (en) | Method of preparing active carbon from cork wood | |
| CN104193901A (en) | Preparation method for carboxymethyl cellulose type water absorbent | |
| CN103920511A (en) | Catalyst for preparing vinyl chloride by acetylene hydrochlorination and preparation method thereof | |
| CN100404612C (en) | Preparation method of swelled vermiculite/ polyacrylic acid potassium- acrylamide high water absorption composite material | |
| CN102898666A (en) | Method for preparing high-degree double-crosslinked amphoteric grafted tapioca starch resin | |
| CN102989428A (en) | Composite absorption material capable of removing scandium ions in natural water body as well as preparation method thereof | |
| CN109731547B (en) | Modified activated carbon for efficient adsorption and dearomatization and preparation method thereof | |
| CN106824125A (en) | A kind of preparation method of the cellulose base composite of high absorption property | |
| CN108847299B (en) | A kind of polyaniline-coated graphene microballoon and preparation method thereof | |
| CN102532374A (en) | Polymerization process of acrylic trifluoro-phenylester monomer | |
| CN108380192A (en) | A kind of compound bamboo charcoal powder of colloidal sol and preparation method thereof | |
| CN108704628A (en) | A kind of modified activated carbon sorbing material and preparation method thereof | |
| CN108129891A (en) | It is a kind of that there is mussel shell coating to purify the air of a room and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181109 |