CN108754637A - A kind of the melt differential electric spinning equipment and method of the continuous direct plastication feed of film - Google Patents

A kind of the melt differential electric spinning equipment and method of the continuous direct plastication feed of film Download PDF

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Publication number
CN108754637A
CN108754637A CN201810929614.6A CN201810929614A CN108754637A CN 108754637 A CN108754637 A CN 108754637A CN 201810929614 A CN201810929614 A CN 201810929614A CN 108754637 A CN108754637 A CN 108754637A
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roller
melt
film
plate
heating roller
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CN201810929614.6A
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CN108754637B (en
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马东明
许浩
李好义
陈明军
丁玉梅
杨卫民
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Beijing University of Chemical Technology
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Beijing University of Chemical Technology
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • D01D5/0061Electro-spinning characterised by the electro-spinning apparatus
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The present invention proposes a kind of the melt differential electric spinning equipment and method of the continuous direct plastication feed of film, device includes mainly side plate, unreels roller, motor, heats roller, scraper plate, striker plate, blanking ring, electrode plate, HV generator, air compressor and take-up drums, by thinfilms on unreeling roller, heating roller both ends electrified regulation ensures that film can melt within a short period of time to set temperature;Film is drawn with insulating tool to heating roller surface, film is gradually tensed, and adjustment motor makes heating roller and unreels the feeding speed that roller reaches suitable rotational speed to be optimal;The film directly quickly squeezed out using extruder is solved the problems, such as melt degradation oxidation, significantly improves spinning quality, melt is flowed out by elongate slot in addition participates in spinning, and jet stream is more, and spinning efficiency is high as the thought of raw material.Apparatus structure is simple, while improving product efficiency, improves product quality, meets the requirement of industrialized production stability.

Description

A kind of the melt differential electric spinning equipment and method of the continuous direct plastication feed of film
Technical field
The invention patent relates to the melt differential electric spinning equipments and method of a kind of continuous direct plastication feed of film, belong to electrostatic Spinning field.
Background technology
It is the advantages that method of electrostatic spinning, adaptability to raw materials is wide, at low cost, equipment is simple, extensive by academia and industrial quarters It is considered that a kind of industrialization prepares the method for micro nanometer fiber being simple and efficient, and most promising process.It is basic Principle is that polymer solution or melt form taylor cone under the action of high-pressure electrostatic field force, in capillary end, and then fly to Reception device, the evaporation of the solvent in solution or melt solidification, finally form superfine fibre on the reception device.Wherein solution electrostatic Spin processes are due to the use of organic solvent, the problems such as bringing environmental pollution, thus in recent years melt electrostatic spinning gradually by Concern.
With the development of melt electrostatic spinning technology, melt electrostatic spinning process is plasticized plastics using extruder, Granular or block-like plastic solidification is melted into melt after spiro rod plasticizing in extruder and heating devices heat, and melt is from squeezing Go out in machine runner flow out after in high-voltage electrostatic field flow deformation, finally cooling and solidifying be collected device collection.Such as a kind of line Property jet stream needle-free electrostatic spinning apparatus (CN103590121A), utilize linear jet flow thought, material extruder be plasticized After melting, melt is attached to roller surface with roller rotation, and the flow deflector by being fixed on roller upper surface center, which is formed, to be connected Continuous linear discharge stream improves spinning quality and jet stream homogeneity, but there are still certain problem, profits for this device for spinning When with extruder plastifying material, extrusion channel is more complicated, and design and manufacture cost is high, on the other hand, work is squeezed out relative to conventional The low discharge of skill makes in melt electrospinning processes polymer melt be in the condition of high temperature for a long time, is oxidized easily and decomposed metamorphic, Influence the final performance of product.
How conventional thought limitation is broken through, and it is a difficulty that best spinning quality is reasonably reached using processing technology Point, patent of the present invention directly use manufactured plastic film as raw material, by heating roller on the basis of other processes Fused films make melt be put into spinning technique rank by shorter heating power journey, are one to solve the degradation problem of material Kind improves the new way of spinning quality.
Patent of invention content
Patent of the present invention directly uses manufactured film as former on the basis of original melt differential spining technology Material is supplied with polymer melt continuous uniform, is avoided long-time heating that material modification is caused to be target, is proposed that a kind of film is continuous The melt differential electric spinning equipment and method of direct plastication feed.
A kind of melt differential electric spinning equipment for the continuous direct plastication feed of film that patent of the present invention proposes, includes mainly side Plate unreels roller, motor, heating roller, scraper plate, striker plate, blanking ring, electrode plate, HV generator, air compression It is direct-connected by shaft coupling and motor respectively and rotated to unreel roller, heating roller and take-up drums for machine and take-up drums Movement, installation unreels roller, heating roller, blanking ring, electrode plate and take-up drums respectively from top to bottom, is connected by screw On side plate, the arc surface of scraper plate is parallel with the heating cylindrical outer surface of roller and clearance fit, scraper plate are located at heating roller shaft Groove is arranged in two end surfaces in line direction, is fixed by the bar being fixed on side plate, and striker plate is located at scraper plate oblique upper, heating Striker plate one end of roller axis direction is equipped with through-hole, by coordinating with shaft clearance, realizes around axis itself rotary motion, striker plate It is adjustable by the rotary motion of striker plate with scraper plate slit gap, setting blanking ring and electrode plate, electrode sleeve-board immediately below gap Outside blanking ring, and it is located in the middle part of blanking ring in short transverse, blanking ring provides high-speed flow, air pressure by air compressor For contracting machine by conduit to air blowing below blanking ring, electrode plate connects HV generator high-voltage output end, provides spinning needs High-voltage electrostatic field, striker plate and scrapes plate earthing.
A kind of melt differential electric spinning equipment for the continuous direct plastication feed of film that patent of the present invention proposes, raw material is thin Film, film come from extruder and quickly squeeze out tape casting or blowfilm shaping, and the rotating speed of roller can be heated by setting and is added Hot-rolling drum surface temperature makes film that there is suitable fusion time, film to rotate by a certain angle the thin of transporting molten with heating roller Film material melt is connect guided on scraper plate in time when then melt rotates to wiper positions with heating roller, with directly by squeezing The melt electrostatic spinning technique for going out machine feed is compared, this process substantially reduces the time that melt is heated continuously, and melt will not Apparent degradation is generated, ensure that the homogeneity of melt and the stability of physical property.
A kind of melt differential electric spinning equipment for the continuous direct plastication feed of film that patent of the present invention proposes, wherein heating roller Cylinder can use the carbon resistances such as graphite or graphene mode of heating as roll body material, and graphite has good thermal conductivity and conduction Property, heat transfer is very fast, and temperature-controllable is good.Also it can be heated using heat medium inside heating roller, heat medium can be The media such as high temperature heat conductive oil, high-temperature gas or other high-temperature resisting liquids.Common plastics thin film melt temperature range is 100 DEG C -300 DEG C, the controllable setting range of heating roller drum surface temperature is 40 DEG C -500 DEG C, it is ensured that most plastic films can melt, dress Set wide adaptability.It is such as directly heated as heating resistor using roll body material, roller surface electrification, to prevent from coming from spinning high pressure The electrostatic interference of electrostatic field and electrostatic breakdown are smearing one layer of heat safe insulation on the scraper plate arc surface of heating roller cooperation Material, material can be hexagonal boron nitride, fluorubber or polytetrafluoroethylene (PTFE) etc..
A kind of melt differential electric spinning equipment for the continuous direct plastication feed of film that patent of the present invention proposes, striker plate can lead to The shaft adjustment being fixedly connected is crossed with the gap range between scraper plate, gap adjustable range is 0.05-3mm.The setting of striker plate It plays heat preservation and protection melt and contacts caused melt oxidation with air, while striker plate contributes to the gap between scraper plate So that the melt flow of film conversion, melt is improved in the linear directional spreding homogeneity of slit, helps to obtain the more of stable uniform Jet stream.Striker plate is located at scraper plate oblique upper and blocks melt, if gap will not flow out less than 0.05mm melts, if more than 3mm backgauges Plate loses backgauge effect, and gap range is set as 0.05mm-3mm.
A kind of melt differential electric spinning equipment for the continuous direct plastication feed of film that patent of the present invention proposes, scraper plate and backgauge Gap between plate is located at the surface of blanking ring through-hole, sees that gap is fully located within the scope of through-hole from top to bottom, and melt is from seam Jet stream is formed at gap all passes through blanking ring.Secondary air is larger to blanking ring inner wall percussion when spinning, is ensureing jet stream Under conditions of all passing through, blanking ring design shape, which is annular, prevents stress concentration.Electrode plate center through hole shape and blanking ring Shape is identical, can more preferably be fixed with blanking ring, and electrode plate voltage range is 10-50kV.
A kind of melt differential electric spinning equipment for the continuous direct plastication feed of film that patent of the present invention proposes, the shell of blanking ring There is blowhole in internal portion, is connect by conduit with air compressor, in spinning, opens air compressor and blows to blowhole, Blanking ring lower air is blown away to form negative pressure, and blanking ring upper air can be pressed against lower section and form top-down air blast, Air blast makes jet stream accelerate and applies friction draw power, and the refinement of fiber, blanking ring blowing wind-force power is promoted to be compressed by air Valve control on machine.
A kind of melt differential electric spinning equipment for the continuous direct plastication feed of film that patent of the present invention proposes, wherein heating roller Cylinder rotating speed naWith the rotating speed n for unreeling rollertMeet na≥nt, heating roller and the film unreeled between roller are heated always The draw of roller, it is continuous to should be at tensioned state guarantee feed for film when rotating with heating roller.
A kind of corresponding operation of melt differential electric spinning equipment for the continuous direct plastication feed of film that patent of the present invention proposes Method:By thinfilms on unreeling roller, the gap size of scraper plate and striker plate, heating roller both ends electrified regulation are adjusted Ensure that film can melt within a short period of time to set temperature;Start and adjust motor speed and slowly drives heating roller, Film is drawn with insulating tool to heating roller surface, film gradually tensed, and drive motor, which makes to unreel roller, slowly to be revolved Turn, adjustment motor makes heating roller and unreels the feeding speed that roller reaches suitable rotational speed to be optimal;Film is heating It is connect and is guided on scraper plate with the heating roller rotation short period after being melted on roller, melt heating time is shorter, and melt, which flows to, to be scraped Before gap between plate and striker plate, start take-up drums, opens HV generator and form high-voltage electrostatic field, open air Compressor makes blanking port form air blast from up to down, and the more jet streams of melt composition are drawn under the action of electric field and secondary air It stretches and is cured as fiber, be finally collected roller collection.
The melt differential electric spinning equipment for the continuous direct plastication feed of a kind of film that patent of the present invention proposes, directly using crowded Go out the thought of film that machine quickly squeezes out as raw material, solve the problems, such as melt degradation oxidation, significantly improve spinning quality, In addition melt is flowed out by elongate slot participates in spinning, and jet stream is more, and spinning efficiency is high.Apparatus structure is simple, is improving product effect While rate, product quality is improved, meets the requirement of industrialized production stability.
Description of the drawings
Fig. 1 is a kind of melt differential electric spinning equipment overall structure signal of the continuous direct plastication feed of film of patent of the present invention Figure;
Fig. 2 is the faces electric spinning equipment X-X shown in FIG. 1 sectional view;
Fig. 3 is blanking ring blowing mouth schematic cross-section shown in FIG. 1;
Fig. 4 is gap enlarged cross-sectional view between scraper plate and striker plate shown in FIG. 1;
In figure:1- side plates;2- is for deflector roll cylinder;3- motor;4- shaft couplings;5- heats roller;6- scraper plates;7- striker plates; 8- HV generators;9- electrode plates;10- blanking rings;11- air compressors;12- take-up drums.
Specific implementation mode
Patent of the present invention proposes a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film.Such as the institutes of Fig. 1~4 Show, the electric spinning equipment mainly by side plate 1, unreel roller 2, motor 3, shaft coupling 4, heating roller 5, scraper plate 6, striker plate 7, high It presses electrostatic generator 8, electrode plate 9, blanking ring 10, air compressor 11, take-up drums 12 to form, unreels roller 2, heating roller 5 is direct-connected by shaft coupling 4 and motor 3 with take-up drums 11, and installation unreels roller 2, heating roller 5, falls respectively from top to bottom Expect ring 10 and electrode plate 9, take-up drums 12, is connected by screw on side plate 1, the faces arc surface C and the heating roller of scraper plate 6 5 cylindrical outer surface is parallel and clearance fit, scraper plate 6 are fastened by bar cramp, and hole is opened in 7 side of striker plate, and striker plate 7 passes through wedge Key is fixed on axis, and the both ends of axis are threadedly coupled the gap between accurate adjustment scraper plate 6 and striker plate 7, scraper plate 6 with side plate 1 The faces B it is minimum be gap in same level, between both sides while minimum with the faces A of striker plate 7, be blanking immediately below gap Ring 10 and electrode plate 9, electrode plate 9 are sleeved on outside blanking ring 10, and are located at the middle part of blanking ring 10 in short transverse, electrode plate 9 with 8 high-voltage output end of HV generator is connected, and 10 lateral opening hole of blanking ring is connected with air compressor 11.
Use patent of the present invention carry out the processing step of spinning for:It carries out heating roller 5 to be heated to set temperature, start Motor 3 gives heating roller 5 offer one compared with the slow-speed of revolution, then electric by packaging film feeding to heating 5 surface suitable position of roller Slowly driving unreels the rotation of roller 2 to motivation 3, adjusts motor speed later, makes heating roller 5 and unreel roller 2 and reach suitable Rotating speed, film with heating roller 5 rotate to suitable position melt, when bath movement is to 6 position of scraper plate, is connect and guide to scraper plate 6 Surface B, motor start-up take-up drums 12 rotate, and open HV generator 8, high pressure is generated between metallic plate 9 and scraper plate 6 Electrostatic field opens 11 valve of air compressor, when melt flows are to gap between scraper plate 6 and striker plate 7, in high-voltage electrostatic field Under blowing effect, start spinning, spinning fibre is collected by take-up drums 12.
One of melt electrostatic spinning specific example is as follows:It is 120mm to unreel 2 outer diameter of roller, and be connected motor speed 3 It is set as 2r/min, using PLA films, film thickness 0.02, film width is 350mm, and heating 5 outer diameter of roller is 120mm, heating roller 5 roll body surface set temperature of cylinder are 220 DEG C, and 3 rotating speed of motor that is connected is set as 2r/min, the gap between scraper plate 6 and striker plate 7 It is set as 0.5mm, the 50mm immediately below gap of blanking ring 10,300mm is take-up drums 12 below blanking ring 10, a diameter of 100mm, when melt is flowed out from gap, electrode plate adds 35kV cathode voltages, and scraper plate 6 and striker plate 7 are grounded, and jet stream quantity is 170, spinning efficiency 170g/h, spinning fibre diameter is in the range of 200-800nm.

Claims (9)

1. a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film, it is characterised in that:Include mainly side plate, unreel Roller, motor, heating roller, scraper plate, striker plate, blanking ring, electrode plate, HV generator, air compressor and receipts Collect roller, it is direct-connected by shaft coupling and motor respectively and obtain rotary motion to unreel roller, heating roller and take-up drums, from Top to bottm is installed respectively unreels roller, heating roller, blanking ring, electrode plate and take-up drums, is connected by screw in side plate On, the arc surface of scraper plate is parallel with the heating cylindrical outer surface of roller and clearance fit, scraper plate are located at heating roller axis direction Two end surfaces groove is set, fixed by the bar being fixed on side plate, striker plate is located at scraper plate oblique upper, heating roller shaft The striker plate one end in line direction is equipped with through-hole, by coordinating with shaft clearance, realizes around axis itself rotary motion, striker plate and scraper plate Slit gap is adjustable by the rotary motion of striker plate, and setting blanking ring and electrode plate, electrode plate are sleeved on blanking immediately below gap Outside ring, and it is located in the middle part of blanking ring in short transverse, blanking ring provides high-speed flow by air compressor, and air compressor is logical Conduit is crossed to air blowing below blanking ring, electrode plate connects HV generator high-voltage output end, and the high pressure for providing spinning needs is quiet Electric field, striker plate and scrapes plate earthing.
2. a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film according to claim 1, feature exist In:Heating roller can use the carbon resistances such as graphite or graphene mode of heating as roll body material.
3. a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film according to claim 2, feature exist In:One layer of heat safe insulating materials is smeared on the scraper plate arc surface coordinated with heating roller, material can be six sides nitridation Boron, fluorubber or polytetrafluoroethylene (PTFE) etc..
4. a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film according to claim 1, feature exist In:It is heated using heat medium inside heating roller, heat medium can be high temperature heat conductive oil, high-temperature gas or other are resistance to The media such as high-temp liquid.
5. a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film according to claim 1, feature exist In:Striker plate can be adjusted by the shaft being fixedly connected with the gap range between scraper plate, and gap adjustable range is 0.05-3mm.
6. a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film according to claim 1, feature exist In:Gap between scraper plate and striker plate is located at the surface of blanking ring through-hole, sees that gap is fully located at through-hole model from top to bottom In enclosing, melt forms jet stream all by blanking ring from gap.
7. a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film according to claim 1, feature exist In:The enclosure interior of blanking ring has blowhole, and connecting blanking ring by conduit with air compressor dries wind-force power by air Valve control on compressor.
8. a kind of melt differential electric spinning equipment of the continuous direct plastication feed of film according to claim 1, feature exist In:Wherein heating roller rotating speed, which is greater than or equal to, unreels the rotating speed of roller, heats roller and unreels film between roller always The draw of heated roller, it is continuous to should be at tensioned state guarantee feed for film when rotating with heating roller.
9. a kind of melt differential electrospinning method of the continuous direct plastication feed of film, it is characterised in that:Thinfilms are existed first It unreels on roller, adjusts the gap size of scraper plate and striker plate, heating roller both ends electrified regulation ensures thin to set temperature Film can melt within a short period of time;Start and adjust motor speed and slowly drive heating roller, by film insulating tool To heating roller surface, film gradually tensed for traction, and drive motor, which makes to unreel roller, slowly to be rotated, adjustment motor make plus Heat roller tube and unreel the feeding speed that roller reaches suitable rotational speed to be optimal;Film is on heating roller with heating after melting The roller rotation short period, which is connect, to be guided on scraper plate, and melt heating time is shorter, and melt flows to the seam between scraper plate and striker plate Before gap, start take-up drums, open HV generator and form high-voltage electrostatic field, opening air compressor makes blanking port from upper It is formed down air blast, the more jet streams of melt composition are stretched under the action of electric field and secondary air and are cured as fiber, finally quilt Take-up drums are collected.
CN201810929614.6A 2018-08-15 2018-08-15 Melt differential electrospinning device and method for continuous direct plasticizing and feeding of film Active CN108754637B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109440201A (en) * 2018-12-10 2019-03-08 武汉华威科智能技术有限公司 A kind of electrofluid ejecting device for melt electrostatic spinning
CN118544498A (en) * 2024-05-28 2024-08-27 徐州屹之澜光电科技有限公司 Thermal insulation frame for POF film production and processing

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CN106283220A (en) * 2016-11-08 2017-01-04 北京化工大学 A kind of double electrostatic field electrostatic spinning apparatus of thermal current auxiliary
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JPH07268753A (en) * 1994-03-28 1995-10-17 Mitsubishi Chem Corp Production of web for broad nonwoven fabric
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CN109440201A (en) * 2018-12-10 2019-03-08 武汉华威科智能技术有限公司 A kind of electrofluid ejecting device for melt electrostatic spinning
CN118544498A (en) * 2024-05-28 2024-08-27 徐州屹之澜光电科技有限公司 Thermal insulation frame for POF film production and processing

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