CN108753845A - The method of carbon dioxide preparation methane and its setting - Google Patents
The method of carbon dioxide preparation methane and its setting Download PDFInfo
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- CN108753845A CN108753845A CN201810859436.4A CN201810859436A CN108753845A CN 108753845 A CN108753845 A CN 108753845A CN 201810859436 A CN201810859436 A CN 201810859436A CN 108753845 A CN108753845 A CN 108753845A
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 530
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 177
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 87
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 87
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 145
- 238000000926 separation method Methods 0.000 claims abstract description 91
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims abstract description 89
- 239000010802 sludge Substances 0.000 claims abstract description 51
- 208000005374 Poisoning Diseases 0.000 claims abstract description 41
- 231100000572 poisoning Toxicity 0.000 claims abstract description 41
- 230000000607 poisoning effect Effects 0.000 claims abstract description 41
- 230000009471 action Effects 0.000 claims abstract description 27
- 238000011084 recovery Methods 0.000 claims abstract description 27
- 238000011282 treatment Methods 0.000 claims abstract description 26
- 230000002194 synthesizing effect Effects 0.000 claims abstract description 20
- 239000007789 gas Substances 0.000 claims description 90
- 229960004424 carbon dioxide Drugs 0.000 claims description 85
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 70
- 239000001301 oxygen Substances 0.000 claims description 70
- 229910052760 oxygen Inorganic materials 0.000 claims description 70
- -1 oxonium ion Chemical class 0.000 claims description 50
- 239000001257 hydrogen Substances 0.000 claims description 45
- 229910052739 hydrogen Inorganic materials 0.000 claims description 45
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 40
- 239000003792 electrolyte Substances 0.000 claims description 39
- 239000012528 membrane Substances 0.000 claims description 39
- 238000005868 electrolysis reaction Methods 0.000 claims description 26
- 238000002485 combustion reaction Methods 0.000 claims description 23
- 239000000428 dust Substances 0.000 claims description 14
- 150000002431 hydrogen Chemical class 0.000 claims description 13
- 239000002912 waste gas Substances 0.000 claims description 13
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 238000010248 power generation Methods 0.000 claims description 5
- 238000012546 transfer Methods 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 241000894006 Bacteria Species 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 241001148470 aerobic bacillus Species 0.000 claims description 3
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 239000003337 fertilizer Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical compound [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- GCNLQHANGFOQKY-UHFFFAOYSA-N [C+4].[O-2].[O-2].[Ti+4] Chemical compound [C+4].[O-2].[O-2].[Ti+4] GCNLQHANGFOQKY-UHFFFAOYSA-N 0.000 claims 1
- 230000009466 transformation Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 241000790917 Dioxys <bee> Species 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000003716 rejuvenation Effects 0.000 description 2
- 238000002560 therapeutic procedure Methods 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 239000010908 plant waste Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
- C12P5/02—Preparation of hydrocarbons or halogenated hydrocarbons acyclic
- C12P5/023—Methane
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
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- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M43/00—Combinations of bioreactors or fermenters with other apparatus
- C12M43/04—Bioreactors or fermenters combined with combustion devices or plants, e.g. for carbon dioxide removal
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- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P3/00—Preparation of elements or inorganic compounds except carbon dioxide
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- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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Abstract
The setting of carbon dioxide preparation methane is made of methane phase device (1) and jet dynamic control (12) and recovery centre of methane backeria poisoning treatment (2).Methane phase device (1) includes diffluence room (3), methane phase room (4), anode chamber (5), cathode chamber (6), separation chamber (7).Further include gap between cathode plate (16) and cathode plate (16) it is cathode chamber (6), gap between anode plate (17) and anode plate (17) is anode chamber (5), and the gap between anode plate (17) and cathode plate (16) is methane phase room (4).The inner sludge water of recovery centre of methane backeria poisoning treatment (2) and carbon dioxide are sent into methane phase room (4), at this time, anode plate (17), cathode plate (16) are started to work, anode plate (17) generates hydrogen ion, forms hydrogen ion water and enters methane phase room (4).Hydrogen ion meets with methane backeria in methane phase room (4) with carbon dioxide, hydrogen ion and carbon dioxide synthesizing methane under the action of methane backeria.
Description
Technical field
The present invention designs method and its setting of a kind of carbon dioxide preparation methane.
Background technology
Currently, carbon dioxide preparation methane technology, also immature.On the other hand, first, energy shortages, the energy restrict the mankind
Social civilization develops.Second is that atmosphere pollution is serious, people's health is directly affected.Third, conventional energy resource is fired in the world today
Burn discharge high-temp waste gas handled as pollutant, there are no the high-temp waste gas of conventional energy resource burning and exhausting as resource
The precedent being used.Therefore, method and its setting for studying a kind of carbon dioxide preparation methane, make conventional energy resource burning and exhausting
Waste gas circulation utilize zero-emission, be the current technical issues that need to address.
Invention content
The technical problem to be solved by the present invention is to：A kind of technical solution of the method for carbon dioxide preparation methane is provided.
The method and technology scheme that the present invention solves its technical problem is：
The method of carbon dioxide preparation methane, comprises the following steps that：The method of carbon dioxide preparation methane, including with
Lower processing step：Carbon dioxide includes carbon dioxide in the exhaust gas of conventional energy resource burning and exhausting and the dioxy extracted from air
Change carbon.The hydrogen ion that carbon dioxide is generated with water electrolysis meets with methane backeria, under the conditions of anaerobic environment, carbon dioxide and hydrogen from
Son synthesizing methane under the action of methane backeria further includes 1. first matching methane strain, nitrogen and phosphorus fertilizer, water as required, is packed into first
Recovery centre of Wan Jun poisoning treatments, stirs evenly, and forms sludge water, and the diffluence room that sludge water is sent into methane phase device rises to methane phase
Room continues to rise, and into separation chamber, sludge water overflows to recovery centre of methane backeria poisoning treatment, sludge water cycle from separation chamber
Utilize zero-emission.2. water forms electrolysis water by water electrolyzer, electrolysis water is sent into water tank, and the electrolysis water in water tank flows to cathode
Room, anode chamber form certain hydraulic pressure between water tank and anode chamber, cathode chamber, the electrolysis water in water tank is enable smoothly to flow to
Cathode chamber, anode chamber, and the hole on the anode plate, the hole on cathode plate, electrolyte membrane enter methane phase room, 3. anode plate and
Cathode plate opens power supply simultaneously, start to work, anode plate generate hydrogen ion, hydrogen ion anode chamber formed hydrogen ion water, hydrogen from
Sub- water one is to enter methane phase room across electrolyte membrane under the action of hydraulic pressure, second is that hydrogen ion is under the attraction of cathode plate, to
Cathode plate shifts, and hydrogen ion, into cathode chamber transfer process, is passing by methane phase room from anode chamber.4. the pressurized note of carbon dioxide
Enter diffluence room, ascends into methane phase room, at this point, carbon dioxide, hydrogen ion meet in methane phase room and methane backeria, carbon dioxide
And hydrogen ion, synthesizing methane under the action of methane backeria, meanwhile, discharge oxygen.Methane, oxygen rise, into separation chamber, first
Alkane, oxygen are discharged from the gas discharge outlet of separation chamber.5. further including in methane phase room, hydrogen ion and carbon dioxide are in methane backeria
The lower synthesizing methane of effect, the hydrogen ion slipped through the net enter cathode chamber, and hydrogen ion is combined in cathode chamber, hydrogen ion with hydrogen ion, is generated
Hydrogen, the topmost that hydrogen rises to cathode chamber pass through the hole of cathode plate, electrolyte membrane to enter methane phase room, rise to separation
Room, hydrogen are discharged from the gas discharge outlet of separation chamber, and hydrogen can also be from the top hydrogen discharge discharge of cathode chamber, hydrogen row
Outlet is connected to the air inlet of diffluence room, and the oxonium ion that 6. cathode plate generates forms oxonium ion water, work of the oxonium ion water in hydraulic pressure
Under, methane phase room is passed by across electrolyte membrane, into anode chamber, oxonium ion can also be under the attraction of anode plate, by cathode
Room is shifted to anode chamber, and oxonium ion passes through electrolyte membrane, passes by methane phase room, enters sun by the hole of electrolyte membrane and anode plate
Pole room, oxonium ion are combined with oxonium ion in anode chamber, oxonium ion, generate oxygen, and oxygen rises, passed through from the topmost of anode chamber
Hole, electrolyte membrane on anode plate enter methane phase room, and oxygen continues to rise, into separation chamber, gas of the oxygen from separation chamber
Outlet is discharged, and oxygen can also be set from the top oxygen discharge discharge of anode chamber, oxygen discharge with conventional energy resource burning
Standby air inlet is connected to, the gas componant being discharged from the gas discharge outlet of separation chamber：The gas such as methane, carbon dioxide, oxygen, hydrogen
Body is referred to as：Methane mixed gas.7. oxygen can make methane backeria be poisoned, or even keep methane backeria dead.The methane backeria of poisoning is with dirt
Muddy water enters separation chamber from methane phase room, and sludge water overflows to methane backeria poisoning treatment health from the sludge water outlet of separation chamber
Multiple center, for the methane backeria of poisoning in recovery centre of methane backeria poisoning treatment, aerobic bacteria eats up the oxygen that the methane backeria of poisoning carries
Gas obtains rehabilitation, and rejuvenation of recuperating, sludge water is re-fed into methane phase room, and methane backeria recycles.8. methane mixed gas is from separation chamber
Gas discharge outlet discharge, be pipelined to conventional energy resource combustion apparatus, jet dynamic control, realize conventional energy resource burning
Equipment jet dynamic control waste gas circulation utilizes zero-emission, zero consumption conventional energy resource.
The technical problem to be solved by the present invention is to：A kind of setting of carbon dioxide preparation methane is provided.
The present invention the technical solution to solve the technical problem is that：
The setting of carbon dioxide preparation methane, by methane phase device and jet dynamic control and the rehabilitation of methane backeria poisoning treatment
Center forms.Methane phase device includes diffluence room, methane phase room, anode chamber, cathode chamber, separation chamber.Further include cathode plate and the moon
Gap between pole plate is cathode chamber, and the gap between anode plate and anode plate is anode chamber, between anode plate and cathode plate
Gap is methane phase room.Further include recovery centre of methane backeria poisoning treatment sludge water outlet and diffluence room into the sludge mouth of a river
Connection, sludge water ascend into methane phase room in diffluence room, and sludge water continues to ascend into separation chamber, and separation chamber is equipped with dirt
Muddy water outlet, sludge water outlet are connected to recovery centre of methane backeria poisoning treatment into the sludge mouth of a river, sludge water cycle profit
Use zero-emission.The sludge water outlet of recovery centre of methane backeria poisoning treatment, is additionally provided with anti-siphonage pipe.Methane backeria poisoning treatment health
Multiple center is equipped with biogas delivery outlet, and biogas delivery outlet is connected to the air inlet of conventional energy resource combustion apparatus.Conventional energy resource burning is set
It is standby：The various forms such as boiler, internal combustion engine, various modes are burnt the equipment of conventional energy resource.Further include conventional energy resource combustion apparatus row
Carbon dioxide in the high-temp waste gas put is pipelined to temperature-reducing dust remover, and temperature-reducing dust remover is discharged equipped with carbon dioxide
Mouthful, carbon dioxide outlet is connected to the air inlet of diffluence room.Temperature-reducing dust remover top is recovery centre of methane backeria poisoning treatment,
Temperature-reducing dust remover and recovery centre of methane backeria poisoning treatment are integral types.It is water in temperature-reducing dust remover, high-temp waste gas leads in water
Later, first, the heat that high-temp waste gas carries, transmits water supply.After water heating, hot water gives thermal energy conduction to methane backeria poisoning treatment
The sludge water of bottom in recovery centre of methane backeria poisoning treatment is heated in the bottom of recovery centre.Pulp pump stirs methane backeria poisoning
Sludge water in therapy rehabilitation center makes sludge water thermally equivalent；Second is that the dust in high-temp waste gas, because than great, and precipitate,
Gas rises because light, and gas is discharged from the gas discharge outlet on temperature-reducing dust remover top.The dioxy that can also be extracted from air
Change carbon and is sent directly into diffluence room.Carbon dioxide rises in diffluence room, and into methane phase room, a part of carbon dioxide generates first
Alkane, methane and remaining carbon dioxide continue to ascend into separation chamber, are discharged from the gas discharge outlet of separation chamber.It is discharged in gas
The interior of mouth is then equipped with gas block panel.The effect of gas block panel：Gas block panel stops the speed of gas flowing, makes swiftly flowing gas, point
Diffusing is dynamic, reduces the speed of gas flowing, and the sludge water that swiftly flowing gas carries is prevented directly to be discharged from gas discharge outlet.
Further include that running water pipe is connected to water electrolyzer water inlet, the electrolysis water outlet of water electrolyzer is connected to the water inlet of water tank,
The electrolysis water outlet of water tank respectively with anode chamber, cathode chamber into electrolysis the mouth of a river be connected to.Tap water is formed by water electrolyzer
Electrolysis water, electrolysis water remove scale removal, prevent incrustation scale from blocking electrolyte membrane, influence hydrogen ion water, oxonium ion water passes through, influence dioxy
Change carbon and generates methane rate.Further include that the binding post of jet dynamic control is connect with the binding post of alternating current-direct current transformer, alternating current-direct current becomes
The output positive and negative terminal of pressure is connect with the binding post of anode plate, cathode plate binding post respectively, at this point, cathode plate, anode plate
It starts to work, the hydrogen ion that anode plate generates forms hydrogen ion water, and hydrogen ion water passes through anode plate under the action of hydraulic pressure
(17) hole, electrolyte membrane on enter methane phase room (1)；Hydrogen ion shifts, hydrogen ion under the attraction of cathode plate to cathode chamber
Enter methane phase room across electrolyte membrane, hydrogen ion meets in methane phase room and carbon dioxide, methane backeria, carbon dioxide and hydrogen from
Son synthesizing methane under the action of methane backeria discharges oxygen.Methane, oxygen ascend into separation chamber, are arranged from the gas of separation chamber
Outlet discharge.Further include carbon dioxide and hydrogen ion, synthesizing methane under the action of methane backeria, the hydrogen ion slipped through the net is across cathode
Hole, electrolyte membrane on plate enter cathode chamber, and for hydrogen ion in cathode chamber, hydrogen ion is combined with hydrogen ion generates hydrogen, hydrogen
Rise one be from cathode chamber topmost pass through cathode plate on hole, electrolyte membrane enter methane phase room, ascend into separation chamber, hydrogen
Gas is discharged from the gas discharge outlet of separation chamber.Second is that hydrogen can also be discharged from the hydrogen gas outlet at the top of cathode chamber (6), hydrogen
Delivery outlet is connected to the air inlet of diffluence room, and hydrogen ascends into methane phase room, and hydrogen meets with carbon dioxide and methane backeria, hydrogen
Gas and carbon dioxide synthesizing methane, methane under the action of methane backeria ascend into separation chamber, continue to rise, and methane is from separation chamber
Gas discharge outlet discharge, further include cathode plate at work, the oxonium ion of generation, formed oxonium ion water, oxonium ion water is in water
Under the action of pressure, methane phase room is passed by across electrolyte membrane, into anode chamber；Oxonium ion can also under the attraction of anode plate,
It is shifted from cathode chamber to anode chamber, oxonium ion enters anode chamber across electrolyte membrane by methane phase room, and oxonium ion is in anode chamber
Interior, oxonium ion is combined with oxonium ion generation oxygen, oxygen passed through from the topmost of anode chamber hole on anode plate, electrolyte membrane into
Enter methane phase room, oxygen ascends into separation chamber, and oxygen is discharged from the gas discharge outlet of separation chamber.Anode plate, cathode plate are equipped with
Multiple permeable holes.Oxygen can also be discharged from the oxygen discharge at the top of separation chamber.Oxygen discharge is set with conventional energy resource burning
Standby air inlet is connected to.The gas being discharged from the gas discharge outlet of separation chamber has：The gases such as methane, carbon dioxide, oxygen, hydrogen,
It is referred to as methane mixed gas.Gas discharge outlet is connected to the air inlet of conventional energy resource combustion apparatus；Gas discharge outlet can also be with
The air inlet of jet dynamic control is connected to, and jet dynamic control power generation, electric energy is for anode plate, cathode plate energy.Conventional energy resource fires
It burns plant waste gases outlet and jet dynamic control outlet port is connected to the air inlet of temperature-reducing dust remover respectively, cool down dedusting
The gas discharge outlet of device is connected to the air inlet of diffluence room, and exhaust gas rises in diffluence room, into methane phase room, two in exhaust gas
Carbonoxide and hydrogen ion meet in methane phase room, carbon dioxide and hydrogen ion, synthesizing methane under the action of methane backeria, to real
Existing conventional energy resource combustion apparatus acting, jet dynamic control power generation, zero consumption conventional energy resource, the oxygen of zero consumption nature, exhaust gas follow
Ring utilizes zero-emission.
Further include the shell of methane phase device by qqc planks as a kind of preferred embodiment of present invention setting technical solution
It is a module that raw material, which casts shunting room module, separation room module, multiple cathode chambers and multiple anode chambers and multiple methane phase rooms,
It is composed, can also be assembled with qqc planks, diffluence room is suitable for reading to be equipped with trouser legs, and the lower mouth of separation chamber is equipped with trouser legs, multiple
The module of cathode chamber and multiple anode chambers and multiple methane phase rooms, following are inserted in the trouser legs of diffluence room, and top is inserted in separation chamber
Trouser legs in, formed methane phase device.Diffluence room communicates with methane phase room, and methane phase room is communicated with separation chamber.It further include cathode
Between plate and cathode plate, between anode plate and anode plate, between anode plate and cathode plate, separated respectively with multiple qqc planks items,
It is screwed, prevents cathode plate, anode plate transverse shifting.Electrolyte membrane is attached to cathode plate, on anode plate, and fixed.
Operation principle：Operation principle is identical as the method for carbon dioxide preparation methane.
Compared with prior art, the method for carbon dioxide preparation methane of the invention and its setting are more perfect.
Description of the drawings
Fig. 1 is the system schematic of the present invention；
Fig. 2 is the partial schematic diagram of the present invention.
Specific implementation mode
The method of carbon dioxide preparation methane, comprises the following steps that：Carbon dioxide includes conventional energy resource burning and exhausting
Exhaust gas in carbon dioxide and the carbon dioxide that is extracted from air, the hydrogen ion and methane that carbon dioxide and water electrolysis generate
Bacterium meets, carbon dioxide and hydrogen ion synthesizing methane under the action of methane backeria, further includes 1. first by methane strain, nitrogenous fertilizer phosphorus
Fertilizer, water match as required, are packed into recovery centre of methane backeria poisoning treatment, stir evenly, and form sludge water, and sludge water is sent into methane phase dress
The diffluence room set rises to methane phase room, continues to rise, and into separation chamber, sludge water overflows to methane backeria poisoning from separation chamber and controls
Treat recovery centre, sludge water circulation use zero-emission, 2. water pass through water electrolyzer formed electrolysis water, electrolysis water be sent into water tank, water
Electrolysis water in case flows to cathode chamber, anode chamber, forms certain hydraulic pressure between water tank and anode chamber, cathode chamber, makes in water tank
Electrolysis water can smoothly flow to cathode chamber, anode chamber, and the hole on anode plate, the hole on cathode plate, electrolyte membrane into
Enter methane phase room, 3. the cathode plate of the anode plate in anode chamber and cathode chamber, while opening power supply, cathode plate, anode plate start
Work, anode plate generate hydrogen ion, hydrogen ion anode chamber formed hydrogen ion water, hydrogen ion water one be under the action of hydraulic pressure,
Enter methane phase room across electrolyte membrane, second is that hydrogen ion under the attraction of cathode plate, shifts, hydrogen ion is by sun to cathode plate
Pole room passes by methane phase room into cathode chamber transfer process, and 4. the pressurized injection diffluence room of carbon dioxide, ascends into methane phase
Room, at this point, carbon dioxide, hydrogen ion meet in methane phase room and methane backeria, carbon dioxide and hydrogen ion, in the effect of methane backeria
Lower synthesizing methane, meanwhile, oxygen is discharged, methane, oxygen rise, and into separation chamber, methane, oxygen are discharged from the gas of separation chamber
Mouthful discharge, 5. also anode plate generates hydrogen ion, and hydrogen ion is under the attraction of cathode plate, from anode chamber to cathode chamber transfer process
In, methane phase room, hydrogen ion and carbon dioxide synthesizing methane under the action of methane backeria are passed by, the hydrogen ion slipped through the net enters cathode
Room, hydrogen ion are combined in cathode chamber, hydrogen ion with hydrogen ion, and hydrogen is generated, and the topmost that hydrogen rises to cathode chamber passes through the moon
The hole of pole plate, electrolyte membrane enter methane phase room, rise to separation chamber, and hydrogen is discharged from the gas discharge outlet of separation chamber, hydrogen
Can also be individually discharged from the top gas outlet of cathode chamber, 6. cathode plate generate oxonium ion, formed oxonium ion water, oxygen from
Son is shifted under the attraction of anode plate from cathode chamber to anode chamber, and oxonium ion passes through electrolyte membrane, passes by methane phase room, passes through
The hole of electrolyte membrane and anode plate enters anode chamber, and oxonium ion is combined with oxonium ion in anode chamber, oxonium ion, generates oxygen, oxygen
Gas rises, and the hole on anode plate, electrolyte membrane is passed through to enter methane phase room from the topmost of anode chamber, and oxygen continues to rise, into
Enter separation chamber, oxygen is discharged from the gas discharge outlet of separation chamber, and the top gas outlet that oxygen can also be from anode chamber is independent
Discharge, the gas componant being discharged from the gas discharge outlet of separation chamber：Methane, carbon dioxide, oxygen, hydrogen, are referred to as：Methane is mixed
Gas is closed, 7. oxygen can make methane backeria be poisoned, or even keep methane backeria dead, and the methane backeria of poisoning is with sludge water, from methane phase room
Into separation chamber, sludge water overflows to recovery centre of methane backeria poisoning treatment, the first of poisoning from the sludge water outlet of separation chamber
For alkane bacterium in recovery centre of methane backeria poisoning treatment, aerobic bacteria eats up the oxygen that the methane backeria of poisoning carries, and obtains rehabilitation, recuperates
Rejuvenation, sludge water are re-fed into methane phase room, and methane backeria recycles, and 8. methane mixed gas is arranged from the gas discharge outlet of separation chamber
Go out, is pipelined to boiler, jet dynamic control, internal combustion engine acting, realizes that boiler, jet dynamic control, internal combustion engine are useless
Gas recycles zero-emission, zero consumption conventional energy resource.
The above-described embodiments are merely illustrative of preferred embodiments of the present invention, not to the guarantor of the present invention
Shield range is defined, and without departing from the spirit of the design of the present invention, this field ordinary engineering and technical personnel is to skill of the present invention
The various modifications and improvement that art scheme is made should all be fallen into the protection domain of claims of the present invention determination.
The setting of carbon dioxide preparation methane as shown in the figure, by methane phase device 1 and jet dynamic control 12 and methane backeria
Recovery centre of poisoning treatment 2 forms, which is characterized in that methane phase device 1 includes diffluence room 3, methane phase room 4, anode chamber 5, the moon
It is cathode chamber 6, anode plate 17 and anode plate 17 that pole room 6, separation chamber 7, which further include gap between cathode plate 16 and cathode plate 16,
Between gap be anode chamber 5, gap between anode plate 17 and cathode plate 16 is methane phase room 4, further includes methane backeria poisoning
The sludge water outlet at therapy rehabilitation center 2 is connected to diffluence room 3 into the sludge mouth of a river 8, and sludge water rises in diffluence room 3
Into methane phase room 4, sludge water continues to ascend into separation chamber 7, and separation chamber 7 is equipped with sludge water outlet 9, sludge water outlet
9 are connected to recovery centre of methane backeria poisoning treatment 2 into the sludge mouth of a river, sludge water circulation use zero-emission, and methane backeria poisoning is controlled
It treats recovery centre 2 and is equipped with biogas delivery outlet 27, biogas delivery outlet 27 is connected to the air inlet 31 of conventional energy resource combustion apparatus 13, also
Carbon dioxide in the high-temp waste gas discharged including conventional energy resource combustion apparatus 13 is pipelined to temperature-reducing dust remover 10, drops
Warm deduster 10 is equipped with carbon dioxide outlet 11, and carbon dioxide outlet 11 is connected to the air inlet 30 of diffluence room 3, can be with
The carbon dioxide extracted from air is sent directly into diffluence room 3, and carbon dioxide rises in diffluence room 3, into methane phase room 4,
Partial CO 2 continues to ascend into separation chamber 7, is discharged from the gas discharge outlet 29 of separation chamber 7, in gas discharge outlet 29
It is inside then equipped with gas block panel 28, further includes that running water pipe 20 is connected to 21 water inlet of water electrolyzer, the electrolysis water row of water electrolyzer 21
Outlet 22 is connected to the water inlet of water tank 23, the electrolysis water outlet 22 of water tank 23 respectively with anode chamber 5, cathode chamber 6 into electricity
Mouth of a river connection is solved, further includes that the binding post 14 of jet dynamic control 12 is connect with the binding post 14 of alternating current-direct current transformer 15, is handed over straight
The positive and negative terminal 14 of rheology pressure 15 is connect with the binding post of anode plate 17 14,16 binding post 14 of cathode plate respectively, at this point, cloudy
Pole plate 16, anode plate 17 are started to work, and the hydrogen ion that anode plate 17 generates forms hydrogen ion water, and hydrogen ion is in cathode plate 16
It under attraction, is shifted to cathode chamber 6, hydrogen ion passes through electrolyte membrane 19 to enter methane phase room 4, and hydrogen ion is in methane phase room 4 and two
Carbonoxide, methane backeria meet, carbon dioxide and hydrogen ion synthesizing methane under the action of methane backeria, discharge oxygen, methane, oxygen
Separation chamber 7 is ascended into, is discharged from the gas discharge outlet 29 of separation chamber 7, further includes carbon dioxide and hydrogen ion, in methane backeria
The lower synthesizing methane of effect, the hydrogen ion slipped through the net pass through hole 18 on cathode plate 16, electrolyte membrane 19 to enter cathode chamber 6, hydrogen ion
In cathode chamber 6, hydrogen ion is combined with hydrogen ion generates hydrogen, and it is to pass through cathode plate from 6 topmost of cathode chamber that hydrogen, which rises one,
Hole 18, electrolyte membrane 19 on 16 enter methane phase room 4, ascend into separation chamber 7, gas discharge outlet of the hydrogen from separation chamber 7
29 discharges, second is that hydrogen can also be discharged from the hydrogen gas outlet 32 at 6 top of cathode chamber, hydrogen gas outlet 32 and diffluence room 3
Air inlet 30 is connected to, and hydrogen ascends into methane phase room 4, and hydrogen meets with carbon dioxide and methane backeria, hydrogen and carbon dioxide
Synthesizing methane under the action of methane backeria, methane ascend into separation chamber 7, continue to rise, and methane is discharged from the gas of separation chamber 7
Mouth (29) discharge.Further include cathode plate 16 at work, the oxonium ion of generation, formed oxonium ion water, oxonium ion water is in hydraulic pressure
Under effect, electrolyte membrane 19 is passed through, methane phase room is passed by, into anode chamber；Oxonium ion is under the attraction of anode plate 17, to anode
Room 5 is shifted, and oxonium ion passes through electrolyte membrane 19 to enter anode chamber 5 by methane phase room 4, and oxonium ion is in anode chamber 5, oxonium ion
It is combined with oxonium ion generation oxygen, oxygen passes through hole 18 on anode plate 17, electrolyte membrane 19 to enter from the topmost of anode chamber 5
Methane phase room 4, oxygen ascend into separation chamber 7, and oxygen is discharged from the gas discharge outlet 29 of separation chamber 7；Oxygen can also from point
Oxygen discharge 33 from 7 top of room is discharged, and oxygen discharge 33 is connected to conventional energy resource combustion apparatus air inlet 31, from separation
The gas that the gas discharge outlet 29 of room 7 is discharged has：The gases such as methane, carbon dioxide, oxygen, hydrogen, are referred to as methane mixed gas,
Gas discharge outlet 29 is connected to the air inlet 31 of conventional energy resource combustion apparatus 13, gas discharge outlet 29 also with jet dynamic control 12
Air inlet connection, jet dynamic control 12 generates electricity, and electric energy is for anode plate 17, the energy of cathode plate 16, conventional energy resource combustion apparatus
13 outlet ports and 12 outlet port of jet dynamic control are connected to the air inlet of temperature-reducing dust remover 10 respectively, and cool down dedusting
The gas discharge outlet 11 of device 10 is connected to the air inlet 30 of diffluence room 3, and exhaust gas rises in diffluence room (3), into methane phase room
4, carbon dioxide and hydrogen ion in exhaust gas meet in methane phase room 4, and carbon dioxide and hydrogen ion close under the action of methane backeria
At methane, to realize that conventional energy resource combustion apparatus 13 does work, jet dynamic control power generation, zero consumption conventional energy resource, zero consumption nature
The oxygen on boundary, waste gas circulation utilize zero-emission.
The shell for further including methane phase device 1 casts 3 module of diffluence room, 7 module of separation chamber, multiple by qqc plank raw materials
Cathode chamber 6 and multiple anode chambers 5 and multiple methane phase rooms 4 are a module, are composed, can also be assembled with qqc planks and
It is equipped with trouser legs 24 at, diffluence room 3 is suitable for reading, the lower mouth of separation chamber 7 is equipped with trouser legs 24, multiple cathode chambers 6 and multiple anode chambers 5 and more
The module of a methane phase room 4, following are inserted in the trouser legs 24 of diffluence room 3, and top is inserted in the trouser legs 24 of separation chamber 7, form production
Methane device 1, further include between cathode plate 16 and cathode plate 16, between anode plate 17 and anode plate 17, anode plate 17 and cathode
It between plate 16, is separated respectively with qqc planks item 25, is fixed with screw 26, prevent cathode plate 16,17 transverse shifting of anode plate.
Further include this field construction and installation company according to present specification, Figure of description, specific embodiment and sets
Standby specification and construction site ambient enviroment, from market purchase of equipment, installed, debugged, trial operation, operation.
Claims (3)
1. the method for carbon dioxide preparation methane, which is characterized in that comprise the following steps that：Carbon dioxide includes conventional energy resource
Carbon dioxide in the exhaust gas of burning and exhausting and the carbon dioxide extracted from air, the hydrogen that carbon dioxide is generated with water electrolysis from
Son meets with methane backeria, and under the conditions of anaerobic environment, carbon dioxide and hydrogen ion synthesizing methane under the action of methane backeria also wrap
It includes and 1. first matches methane strain, nitrogen and phosphorus fertilizer, water as required, be packed into recovery centre of methane backeria poisoning treatment, stir evenly, formed dirty
Muddy water, the diffluence room that sludge water is sent into methane phase device rises to methane phase room, continues to rise, into separation chamber, sludge water from
Separation chamber overflows to recovery centre of methane backeria poisoning treatment, sludge water circulation use zero-emission, and 2. water is formed by water electrolyzer
Electrolysis water, electrolysis water are sent into water tank, and the electrolysis water in water tank flows to cathode chamber, anode chamber, between water tank and anode chamber, cathode chamber
Certain hydraulic pressure is formed, the electrolysis water in water tank is enable smoothly to flow to cathode chamber, anode chamber, and hole on anode plate,
Hole, electrolyte membrane on cathode plate enter methane phase room, and 3. anode plate and cathode plate open power supply simultaneously, start to work, anode
Plate generate hydrogen ion, hydrogen ion anode chamber formed hydrogen ion water, hydrogen ion water one be under the action of hydraulic pressure, pass through electrolysis every
Film enters methane phase room, second is that hydrogen ion is under the attraction of cathode plate, is shifted to cathode plate, and hydrogen ion is from anode chamber to cathode
In the transfer process of room, methane phase room is passed by, 4. the pressurized injection diffluence room of carbon dioxide, ascends into methane phase room, at this point, two
Carbonoxide, hydrogen ion meet in methane phase room and methane backeria, and carbon dioxide and hydrogen ion synthesize first under the action of methane backeria
Alkane, meanwhile, oxygen is discharged, methane, oxygen rise, and into separation chamber, methane, oxygen are discharged from the gas discharge outlet of separation chamber,
5. further including that synthesizing methane, the hydrogen ion slipped through the net enter under the action of methane backeria in methane phase room, hydrogen ion and carbon dioxide
Cathode chamber, hydrogen ion are combined in cathode chamber, hydrogen ion with hydrogen ion, and hydrogen is generated, and the topmost that hydrogen rises to cathode chamber is worn
Cross the hole of cathode plate, electrolyte membrane enters methane phase room, rises to separation chamber, hydrogen is discharged from the gas discharge outlet of separation chamber,
Hydrogen can also be connected to from the top hydrogen discharge discharge of cathode chamber, hydrogen discharge with the air inlet of diffluence room, 6. cathode
The oxonium ion that plate generates forms oxonium ion water, and oxonium ion water passes through the hole on anode plate, is electrolysed under the action of hydraulic pressure
Diaphragm passes by methane phase room, and into anode chamber, oxonium ion can also be turned under the attraction of anode plate from cathode chamber to anode chamber
It moves, oxonium ion passes through electrolyte membrane, passes by methane phase room, enters anode chamber, oxonium ion by the hole of electrolyte membrane and anode plate
In anode chamber, oxonium ion is combined with oxonium ion, and generates oxygen, and oxygen rises, and is passed through on anode plate from the topmost of anode chamber
Hole, electrolyte membrane enter methane phase room, and oxygen continues to rise, and into separation chamber, oxygen is discharged from the gas discharge outlet of separation chamber,
Oxygen can also connect from the top oxygen discharge discharge of anode chamber, oxygen discharge with conventional energy resource combustion apparatus air inlet
Gas componant that is logical, being discharged from the gas discharge outlet of separation chamber：Methane, carbon dioxide, oxygen, hydrogen, are referred to as：Methane blended
Gas, 7. oxygen can make methane backeria be poisoned, or even keep methane backeria dead, the methane backeria of poisoning with sludge water, from methane phase room into
Enter separation chamber, sludge water overflows to recovery centre of methane backeria poisoning treatment, the methane of poisoning from the sludge water outlet of separation chamber
For bacterium in recovery centre of methane backeria poisoning treatment, aerobic bacteria eats up the oxygen that the methane backeria of poisoning carries, and obtains rehabilitation, recuperation is multiple
Strong, sludge water is re-fed into methane phase room, and methane backeria recycles, and 8. methane mixed gas is discharged from the gas discharge outlet of separation chamber,
It is pipelined to conventional energy resource combustion apparatus, jet dynamic control, conventional energy resource combustion apparatus, jet dynamic control are done
Work(realizes that conventional energy resource combustion apparatus, jet dynamic control waste gas circulation utilize zero-emission, zero consumption conventional energy resource.
2. the setting of carbon dioxide preparation methane is controlled by methane phase device (1) and the poisoning of jet dynamic control (12) and methane backeria
It treats recovery centre (2) to form, which is characterized in that methane phase device (1) includes diffluence room (3), methane phase room (4), anode chamber
(5), it is cathode chamber (6), sun that cathode chamber (6), separation chamber (7), which further include gap between cathode plate (16) and cathode plate (16),
Gap between pole plate (17) and anode plate (17) is anode chamber (5), and the gap between anode plate (17) and cathode plate (16) is
Methane phase room (4) further includes sludge water outlet and the diffluence room (3) of recovery centre of methane backeria poisoning treatment (2) into sludge
The mouth of a river (8) is connected to, and sludge water ascends into methane phase room (4), sludge water continues to ascend into separation chamber in diffluence room (3)
(7), separation chamber (7) are equipped with sludge water outlet (9), sludge water outlet (9) and recovery centre of methane backeria poisoning treatment (2)
It is connected into the sludge mouth of a river, sludge water circulation use zero-emission, recovery centre of methane backeria poisoning treatment (2) is equipped with biogas delivery outlet
(27), biogas delivery outlet (27) is connected to the air inlet (31) of conventional energy resource combustion apparatus (13), further includes conventional energy resource burning
Carbon dioxide in the high-temp waste gas of equipment (13) discharge is pipelined to temperature-reducing dust remover (10), temperature-reducing dust remover (10)
Equipped with carbon dioxide outlet (11), carbon dioxide outlet (11) is connected to the air inlet (30) of diffluence room (3), can also be from
The carbon dioxide extracted in air is sent directly into diffluence room (3), and carbon dioxide rises in diffluence room (3), into methane phase room
(4), partial CO 2 continues to ascend into separation chamber (7), is discharged from the gas discharge outlet (29) of separation chamber (7), in gas
The interior of outlet (29) is then equipped with gas block panel (28), further includes that running water pipe (20) is connected to water electrolyzer (21) water inlet, water
The electrolysis water outlet (22) of electrolyzer (21) is connected to the water inlet of water tank (23), the electrolysis water outlet (22) of water tank (23)
Respectively with anode chamber (5), cathode chamber (6) into electrolysis the mouth of a river be connected to, further include the binding post (14) of jet dynamic control (12)
Connect with the binding post (14) of alternating current-direct current transformer (15), the positive and negative terminal (14) of alternating current-direct current transformation (15) respectively with anode
The binding post (14) of plate (17), cathode plate (16) binding post (14) connection, at this point, cathode plate (16), anode plate (17) start work
Make, the hydrogen ion that anode plate (17) generates forms hydrogen ion water, and hydrogen ion water passes through anode plate (17) under the action of hydraulic pressure
On hole, electrolyte membrane enter methane phase room (4), hydrogen ion can also turn under the attraction of cathode plate (16) to cathode chamber (6)
Move, hydrogen ion pass through anode plate (17) on hole, electrolyte membrane (19) enter methane phase room (4), hydrogen ion is in methane phase room (4)
It meets with carbon dioxide, methane backeria, carbon dioxide and hydrogen ion synthesizing methane under the action of methane backeria, release oxygen, methane,
Oxygen ascends into separation chamber (7), is discharged from the gas discharge outlet (29) of separation chamber (7), further includes carbon dioxide and hydrogen ion,
Synthesizing methane under the action of methane backeria, the hydrogen ion slipped through the net pass through cathode plate (16) on hole (18), electrolyte membrane (19) into
Enter cathode chamber (6), hydrogen ion is in cathode chamber (6), and hydrogen ion is combined with hydrogen ion generates hydrogen, and hydrogen rises from cathode chamber
(6) topmost pass through cathode plate (16) on hole (18), electrolyte membrane (19) enter methane phase room (4), ascend into separation chamber
(7), hydrogen is discharged from the gas discharge outlet (29) of separation chamber (7), and hydrogen can also be from the hydrogen gas outlet at the top of cathode chamber (6)
(32) it is discharged, hydrogen gas outlet (32) is connected to the air inlet (30) of diffluence room (3), and hydrogen ascends into methane phase room (4), hydrogen
Gas meets with carbon dioxide and methane backeria, and hydrogen and carbon dioxide synthesizing methane, methane under the action of methane backeria ascend into
Separation chamber (7), continues to rise, and methane is discharged from the gas discharge outlet (29) of separation chamber (7), further includes that cathode plate (16) is working
When, the oxonium ion of generation forms oxonium ion water, and oxonium ion water passes by production first under the action of hydraulic pressure, across electrolyte membrane (19)
Alkane room (4), into anode chamber (5), oxonium ion can also be under the attraction of anode plate (17), from cathode chamber (6) to anode chamber (5)
Transfer, oxonium ion pass through electrolyte membrane (19) to enter anode chamber (5) by methane phase room (4), and oxonium ion is interior in anode chamber (5),
Oxonium ion is combined with oxonium ion generation oxygen, and oxygen passes through hole (18) on anode plate (17), electricity from the topmost of anode chamber (5)
It solves diaphragm (19) and enters methane phase room (4), oxygen ascends into separation chamber (7), gas discharge outlet of the oxygen from separation chamber (7)
(29) it is discharged, oxygen can also be discharged from the oxygen discharge (33) at the top of separation chamber (7), oxygen discharge (33) and conventional energy
Source combustion apparatus air inlet (31) is connected to, and the gas being discharged from the gas discharge outlet (29) of separation chamber (7) has：Methane, titanium dioxide
Carbon, oxygen, hydrogen are referred to as methane mixed gas, the air inlet of gas discharge outlet (29) and conventional energy resource combustion apparatus (13)
(31) it being connected to, gas discharge outlet (29) is also connected to the air inlet of jet dynamic control (12), jet dynamic control (12) power generation,
Electric energy is for anode plate (17), cathode plate (16) energy, conventional energy resource combustion apparatus (13) outlet port and jet dynamic control
(12) outlet port is connected to the air inlet of temperature-reducing dust remover (10) respectively, the carbon dioxide outlet of temperature-reducing dust remover (10)
(11) it is connected to the air inlet of diffluence room (3) (30), exhaust gas rises in the diffluence room (3), into methane phase room (4), in exhaust gas
Carbon dioxide meet in methane phase room (4) with methane backeria with hydrogen ion, carbon dioxide and hydrogen ion, under the action of methane backeria
Synthesizing methane, to realize that conventional energy resource combustion apparatus (13) does work, jet dynamic control power generation, zero consumption conventional energy resource, zero consumption
The oxygen of nature, waste gas circulation utilize zero-emission.
3. the setting of carbon dioxide preparation methane according to claim 2, which is characterized in that the shell of methane phase device (1)
Body by qqc plank raw materials cast diffluence room (3) module, separation chamber (7) module, multiple cathode chambers (6) and multiple anode chambers (5) and
Multiple methane phase rooms (4) are a module, are composed, can also be assembled with qqc planks, diffluence room (3) is suitable for reading to be equipped with
The lower mouth of trouser legs (24), separation chamber (7) is equipped with trouser legs (24), multiple cathode chambers (6), multiple anode chambers (5), multiple methane phase rooms
(4) module, the trouser legs (24) that following is inserted in diffluence room (3) is inner, and the trouser legs (24) that top is inserted in separation chamber (7) is inner, forms production
Methane device (1), further include between cathode plate (16) and cathode plate (16), between anode plate (17) and anode plate (17), anode
Between plate (17) and cathode plate (16), separated respectively with multiple qqc planks items (25), it is fixed with screw (26), prevent cathode plate
(16), anode plate (17) transverse shifting.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113234590A (en) * | 2021-05-18 | 2021-08-10 | 浙江大学 | Biogas preparation device and method |
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