CN108753162A - A kind of fluorine carbon-nano anti-pollution anti-scratch varnish and its preparation method and application - Google Patents
A kind of fluorine carbon-nano anti-pollution anti-scratch varnish and its preparation method and application Download PDFInfo
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- CN108753162A CN108753162A CN201810548504.5A CN201810548504A CN108753162A CN 108753162 A CN108753162 A CN 108753162A CN 201810548504 A CN201810548504 A CN 201810548504A CN 108753162 A CN108753162 A CN 108753162A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The present invention provides a kind of fluorine carbon-nano anti-pollution anti-scratch varnish, count in parts by weight, including 30~60 parts of fluorocarbon resin, 30~60 parts of fluorine silicon resin, containing 10~20 parts of amino resins, 0~5 part of auxiliary agent, 2~10 parts of solvent.The fluorine carbon-nano anti-pollution anti-scratch varnish of the present invention has excellent gloss and hardness, and there is splendid effect at the anti-graffiti aspect of stain resistance, especially there is excellent anti-scratch performance, it can meet to the higher region of erasibility demand, expand the use scope of fluorocarbon varnish, the fluorine carbon-nano anti-pollution anti-scratch varnish also has preferable compatibility, it can be coated on routine PVDF fluororine-carbon coatings, and it has fabulous ply adhesion with conventional PVDF fluororine-carbon coatings, after baking-curing, neither sacrifice the weatherability and other traditional performances of script fluororine-carbon coating, more former coating provides excellent gloss and hardness.The present invention also provides a kind of preparation method and application of above-mentioned fluorine carbon-nano anti-pollution anti-scratch varnish.
Description
Technical field
The present invention relates to fluorocarbon varnish technical field more particularly to a kind of fluorine carbon-nano anti-pollution anti-scratch varnish and its preparation sides
Method and application.
Background technology
With the development of social science and technology, coating products show high performance development trend.PVDF fluorocarbon coatings are as " painting
The king of material " is favored by market always because of its excellent weatherability, but F-C paint coating hardness is low, gloss is mute, is easy contaminated
And property easy to clean is bad, is easy to be scratched, and reduces the performance of F-C paint coating；Especially decorated using fluororine-carbon coating plank
Build low layer or hall channel, the big place of flow of the people, coating is easily by contact to easy damaged and dirty.
In this regard, it is necessary to develop a kind of fluorine carbon-nano anti-pollution anti-scratch varnish to solve above-mentioned technical problem.
Invention content
An object of the present invention is to provide a kind of fluorine carbon-nano anti-pollution anti-scratch varnish, the fluorine carbon-nano anti-pollution anti-scratch varnish
It is decorative good when being used for the coating of plank with excellent gloss and hardness；There is pole at the anti-graffiti aspect of stain resistance simultaneously
Good effect especially has excellent anti-scratch performance, disclosure satisfy that the higher region of erasibility demand, it is clear to expand fluorine carbon
The use scope of paint.
The second object of the present invention is to provide the preparation method of above-mentioned fluorine carbon-nano anti-pollution anti-scratch varnish.
The third object of the present invention is to provide application of the above-mentioned fluorine carbon-nano anti-pollution anti-scratch varnish in plank.
To achieve the above object, the present invention provides a kind of fluorine carbon-nano anti-pollution anti-scratch varnish, which is characterized in that by weight
Number meter, including：
Wherein, fluorocarbon resin can be selected as 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts, 60 parts；Fluorine silicon resin can be with
It is selected as 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts, 60 parts；It can be selected as 10 parts, 15 parts, 20 parts containing amino resins；Auxiliary agent
It can be selected as 0 part, 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Solvent can be selected as 2 parts, 4 parts, 6 parts, 8 parts, 10 parts.
Compared with prior art, fluorine carbon-nano anti-pollution anti-scratch varnish of the invention uses fluorocarbon resin and fluorine silicon resin conduct
Matrix resin, cooperation is containing amino resins, auxiliary agent and solvent composition.Wherein, it is C-F using the primary structure of fluorocarbon resin, F is in member
In plain periodic table, electronegativity is most strong, and C-F keys are extremely short, and bond energy is up to 486KT/mol, it is difficult to by heat, light and chemical factor
It destroys, obtained fluorine carbon-nano anti-pollution anti-scratch varnish has anti-scratch performance；Fluorine silicon resin refers generally to nano fluorine-silicon resin, also known as fluorine
Silicon copolymer resins, nano fluorine-silicon resin have both the characteristic of fluorocarbon resin and organic siliconresin, and organic siliconresin hardness is high, decorative
Good, fluorination rear surface can be reduced greatly, there is splendid reprimand oiliness (anti-stickiness) and repellency (anti-pollution)；By containing ammonia
Base resin and fluorocarbon resin and fluorine silicon resin carry out crosslinking film forming, due to the functional group of amino and fluorocarbon resin and fluorine silicon resin into
Row reaction, while polycondensation reaction can also occur between molecule containing amino resins, therefore can make the film that there is three-dimensional (solid) netted knot
Structure possesses excellent compactness, i.e. anti-scratch performance.Therefore the fluorine carbon-nano anti-pollution anti-scratch varnish of gained is with excellent gloss and firmly
Degree, and have splendid effect at the anti-graffiti aspect of stain resistance, especially there is excellent anti-scratch performance, disclosure satisfy that anti-scratch
The property higher region of demand, expands the use scope of fluorocarbon varnish.
Preferably, the present invention containing amino resins be selected from melamine formaldehyde resin, benzoguanamine formaldehyde resin and
Any one or more in hexamethoxymethyl melamine, it is highly preferred that at least trimerization of methyl containing hexakis-methoxy containing amino resins
Cyanamide, the film not softened can be generated by carrying out cross-linking reaction using hexamethoxymethyl melamine and fluorocarbon resin and fluorine silicon resin,
Keep the anti-scratch performance of fluorine carbon-nano anti-pollution anti-scratch varnish more excellent.
Preferably, the solid content containing hydroxyl is 50~80% in fluorine silicon resin, since amino can be with the hydroxyl of fluorine silicon resin
Base is reacted, and the solid content of hydroxyl has an impact the compactness of film, therefore, selects proper amount of hydroxyl extremely important, is passed through
Experiment, it is preferably 50~80% that fluorine silicon resin, which is the solid content containing hydroxyl, in the application, for example, 50%, 60%, 70%,
80%, anti-scratch performance is preferable.
Preferably, the one kind of solvent in ethyl acetate, butyl acetate, propylene glycol methyl ether acetate and nylon acid methyl esters
Or it is a variety of.There is positive effect to the luster performance of fluorine carbon-nano anti-pollution anti-scratch varnish using esters solvent, gloss is beautiful, can get
The effect of good decorative property.
Preferably, the auxiliary agent of the present invention is levelling agent, levelling agent is selected from polyether polyester azo polyether polyeste, dimethyl-silicon
One kind in oxygen alkane and fluorine richness polyacrylate.More preferably levelling agent selects fluorine richness polyacrylate, which contains
Fluorine can generate certain effect with fluorocarbon resin and fluorine silicon resin, improve coating effect so that coating surface flatness is good.
Preferably, the auxiliary agent of the present invention is ethers antifoaming agent, ethers antifoaming agent is selected from polyoxyethylene polyoxypropylene Ji Wusi
Alcohol ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and one kind or more in polyoxyethylene polyoxypropylene glycerin ether
Kind.The introducing of ethers antifoaming agent can make fluorine carbon-nano anti-pollution anti-scratch varnish have good diffusivity and adhesive force.
The present invention also provides a kind of preparation methods of fluorine carbon-nano anti-pollution anti-scratch varnish, including：
1) fluorocarbon resin and fluorine silicon resin is added according to proportioning in the reaction vessel and is stirred；
2) it sequentially adds containing amino resins and auxiliary agent, and stirs evenly during stirring；
3) solvent of recipe ratio is added in the reaction vessel, and stirred evenly.
The present invention also provides a kind of application of above-mentioned fluorine carbon-nano anti-pollution anti-scratch varnish in plank.The fluorine carbon of the present invention
Nanometer anti-pollution anti-scratch varnish can be coated on routine PVDF fluororine-carbon coatings, meanwhile, fluorine carbon-nano anti-pollution anti-scratch of the invention is clear
Paint has a fabulous ply adhesion with routine PVDF fluororine-carbon coatings, and after baking-curing, neither sacrifice script fluororine-carbon coating is resistance to
It waits and other traditional performances, more former coating provides excellent gloss and hardness, therefore, compatibility is very good.Fluorine carbon-nano
Anti-pollution anti-scratch varnish can also be individually coated on plank, to adapt to the demand in a variety of regions.It is particularly suitable for both in weather-proof side
Face has higher requirements, and to the anti-graffiti region for having demand of stain resistance.
Specific implementation mode
The technical solution further illustrated the present invention below by specific implementation mode, but do not constitute and the present invention is appointed
What is limited.
Embodiment 1
The fluorine carbon-nano anti-pollution anti-scratch varnish of the present embodiment, is counted in parts by weight, including：
The method that fluorine carbon-nano anti-pollution anti-scratch varnish is prepared using above-mentioned composition, including：
1) 60 parts of 30 parts of fluorocarbon resin and fluorine silicon resin are added in the reaction vessel and is stirred, the rotating speed of stirring is
800r/min；
2) 10 parts of melamine formaldehyde resin is added during stirring, and stirs evenly；
3) by ethyl acetate 2 parts be added in reaction vessel, adjust suitable viscosity, and stir evenly, you can obtain fluorine
Carbon nanometer anti-pollution anti-scratch varnish.
Embodiment 2
The fluorine carbon-nano anti-pollution anti-scratch varnish of the present embodiment, is counted in parts by weight, including：
The method that fluorine carbon-nano anti-pollution anti-scratch varnish is prepared using above-mentioned composition, including：
1) 40 parts of 40 parts of fluorocarbon resin and fluorine silicon resin are added in the reaction vessel and is stirred, the rotating speed of stirring is
800r/min；
2) sequentially added during stirring 13.5 parts of benzoguanamine formaldehyde resin, 0.5 part of dimethyl siloxane,
0.5 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, and stir evenly；
3) by ethyl acetate 5.5 parts be added in reaction vessel, adjust suitable viscosity, and stir evenly, you can obtain
Fluorine carbon-nano anti-pollution anti-scratch varnish.
Embodiment 3
The fluorine carbon-nano anti-pollution anti-scratch varnish of the present embodiment, is counted in parts by weight, including：
Wherein, the preparation method of the embodiment fluorine carbon-nano anti-pollution anti-scratch varnish is identical as the preparation method of embodiment 2,
This does not elaborate.
Embodiment 4
The fluorine carbon-nano anti-pollution anti-scratch varnish of the present embodiment, is counted in parts by weight, including：
Wherein, the preparation method of the embodiment fluorine carbon-nano anti-pollution anti-scratch varnish is identical as the preparation method of embodiment 2,
This does not elaborate.
Embodiment 5~7
The fluorine carbon-nano anti-pollution anti-scratch varnish of embodiment 5~7, is counted in parts by weight, including：
The wherein component of embodiment 5~7 and content all same, unlike：
In embodiment 5, fluorine silicon resin is that the solid content containing hydroxyl is 20%；
In embodiment 6, fluorine silicon resin is that the solid content containing hydroxyl is 60%；
In embodiment 7, fluorine silicon resin is that the solid content containing hydroxyl is 90%.
Wherein, the preparation method of the embodiment fluorine carbon-nano anti-pollution anti-scratch varnish is identical as the preparation method of embodiment 2,
This does not elaborate.
Embodiment 8
The fluorine carbon-nano anti-pollution anti-scratch varnish of the present embodiment, is counted in parts by weight, including：
Wherein, the preparation method of the embodiment fluorine carbon-nano anti-pollution anti-scratch varnish is identical as the preparation method of embodiment 2,
This does not elaborate.
Comparative example 1
The fluorine carbon-nano anti-pollution anti-scratch varnish of the comparative example, is counted in parts by weight, including：
Wherein, the preparation method of the comparative example fluorine carbon-nano anti-pollution anti-scratch varnish is identical as the preparation method of embodiment 2,
This does not elaborate.
Comparative example 2
The fluorine carbon-nano anti-pollution anti-scratch varnish of this comparative example, is counted in parts by weight, including：
Wherein, the preparation method of the comparative example fluorine carbon-nano anti-pollution anti-scratch varnish is identical as the preparation method of embodiment 2,
This does not elaborate.
Comparative example 3
The fluorine carbon-nano anti-pollution anti-scratch varnish of this comparative example, is counted in parts by weight, including：
Wherein, the preparation method of the comparative example fluorine carbon-nano anti-pollution anti-scratch varnish is identical as the preparation method of embodiment 2,
This does not elaborate.
The fluorine carbon-nano anti-pollution anti-scratch varnish obtained to above-described embodiment 1~8 and comparative example 1~3 carries out resistance to MEK (first and second
Ketone) rubbing test and anti-pollution test, test result such as table 1.
Wherein, the test method of resistance to MEK (methyl ethyl ketone) wiping is as follows：
On index finger and four layers of gauze of MEK solvents are impregnated with volume when test, with about 19.6~24.5N pressure to be measured
Test product surface is moved forward and backward wiping, and round trip is at least 200mm, and wiping speed is about 100 times/min round-trip (past previous
It is secondary, once can be regarded as round trip backward), until paint film destroys, record wiping number.
The test method of anti-pollution is as follows：
It is scribbled to fluorine carbon-nano anti-pollution anti-scratch enamelled coating using aqueous marking pen, sees whether markedness.
Table 1：Resistance to MEK (methyl ethyl ketone) wiping and anti-pollution test
| Resistance to MEK wipings | Anti-pollution is tested | |
| Embodiment 1 | 1100 times | Without mark |
| Embodiment 2 | 1120 times | Without mark |
| Embodiment 3 | 1180 times | Without mark |
| Embodiment 4 | 1290 times | Without mark |
| Embodiment 5 | 1080 | Without mark |
| Embodiment 6 | 1110 | Without mark |
| Embodiment 7 | 1070 | Without mark |
| Embodiment 8 | 1200 | Without mark |
| Comparative example 1 | 600 | Markedness |
| Comparative example 2 | 530 | Markedness |
| Comparative example 3 | 360 | Markedness |
As can be known from Table 1, the resistance to wiping in Examples 1 to 8 and stain resistance antigraffiti properties be far superior to comparative example 1~
3, the reason is that Examples 1 to 8 uses the synergistic effect of fluorocarbon resin and fluorine silicon resin, improve fluorine carbon-nano anti-pollution anti-scratch varnish
Repellency, i.e. anti-pollution；Crosslinking film forming is carried out by with fluorocarbon resin and fluorine silicon resin again, due to amino and fluorocarbon resin
It is reacted with the functional group of fluorine silicon resin, while polycondensation reaction occurs between molecule containing amino resins, make the film that there is three-dimensional
(solid) reticular structure, possesses excellent compactness, i.e., resistance to wiping properties.
Compared with Example 2, the anti-scratch performance of fluorine carbon-nano anti-pollution anti-scratch varnish is more excellent in embodiment 4 for embodiment 4, be by
Make for hexamethoxymethyl melamine containing amino resins in embodiment 4, hexamethoxymethyl melamine and fluorocarbon resin and fluorine
Silicones, which carries out cross-linking reaction, can generate the film not softened, and keep the anti-scratch performance of fluorine carbon-nano anti-pollution anti-scratch varnish more excellent.
Embodiment 5~7 is compared, and the anti-scratch performance of fluorine carbon-nano anti-pollution anti-scratch varnish is more excellent in embodiment 6, it may be possible to due to
Amino can be reacted with the hydroxyl of fluorine silicon resin, and the solid content of hydroxyl has an impact the compactness of film, it is therefore preferable that being fluorine silicon
The solid content containing hydroxyl is 60% in resin.
Compared with Example 2, the anti-scratch performance of fluorine carbon-nano anti-pollution anti-scratch varnish is more excellent in embodiment 8 for embodiment 8, be by
It is fluorine richness polyacrylate in levelling agent, the levelling agent is fluorine-containing, may generate certain effect with fluorocarbon resin and fluorine silicon resin,
Improve coating effect so that coating surface flatness is good, has good effect to anti-scratch performance.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than is protected to the present invention
The limitation of range is protected, although the present invention is described in detail with reference to preferred embodiment, the invention is not limited in above
Embodiments of the disclosure, and modification, equivalent combinations that various essence according to the present invention carry out should be covered.
Claims (10)
1. a kind of fluorine carbon-nano anti-pollution anti-scratch varnish, which is characterized in that it counts in parts by weight, including：
2. fluorine carbon-nano anti-pollution anti-scratch varnish as described in claim 1, which is characterized in that described to be selected from trimerization containing amino resins
Any one or more in cyanogen amine-formaldehyde resin, benzoguanamine formaldehyde resin and hexamethoxymethyl melamine.
3. fluorine carbon-nano anti-pollution anti-scratch varnish as described in claim 1, which is characterized in that contain hydroxyl in the fluorine silicon resin
Solid content be 50~80%.
4. fluorine carbon-nano anti-pollution anti-scratch varnish as described in claim 1, which is characterized in that the solvent selects ethyl acetate, second
It is one or more in acid butyl ester, propylene glycol methyl ether acetate and nylon acid methyl esters.
5. fluorine carbon-nano anti-pollution anti-scratch varnish as described in claim 1, which is characterized in that the auxiliary agent is levelling agent.
6. fluorine carbon-nano anti-pollution anti-scratch varnish as claimed in claim 5, which is characterized in that the levelling agent is selected from polyether polyester
It is one or more in azo polyether polyeste, dimethyl siloxane and fluorine richness polyacrylate.
7. fluorine carbon-nano anti-pollution anti-scratch varnish as described in claim 1, which is characterized in that the auxiliary agent is ethers antifoaming agent.
8. fluorine carbon-nano anti-pollution anti-scratch varnish as claimed in claim 7, which is characterized in that the ethers antifoaming agent is selected from polyoxy
Ethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene
It is one or more in glycerin ether.
9. a kind of application of the fluorine carbon-nano anti-pollution anti-scratch varnish in plank as described in claim 1~8 any one.
10. the preparation method of the fluorine carbon-nano anti-pollution anti-scratch varnish as described in claim 1~8 any one, which is characterized in that
Including：
1) fluorocarbon resin and fluorine silicon resin is added according to proportioning in the reaction vessel and is stirred；
2) it sequentially adds containing amino resins and auxiliary agent, and stirs evenly during stirring；
3) solvent of recipe ratio is added in the reaction vessel, and stirred evenly.
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| CN201810548504.5A CN108753162A (en) | 2018-05-31 | 2018-05-31 | A kind of fluorine carbon-nano anti-pollution anti-scratch varnish and its preparation method and application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116855172A (en) * | 2023-07-13 | 2023-10-10 | 上海彩谷新材料科技有限公司 | Anti-graffiti anti-sticking protective paint and preparation method thereof |
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| CN104559611A (en) * | 2014-12-05 | 2015-04-29 | 东来涂料技术（上海）有限公司 | Easy-to-clean fluorocarbon paint and preparation method thereof |
| CN106833162A (en) * | 2017-01-17 | 2017-06-13 | 衢州市闻天化工有限公司 | A kind of fluorine silicon Nano waterproof paint and preparation method thereof |
| CN107446424A (en) * | 2017-08-21 | 2017-12-08 | 昆明理工大电力工程技术有限公司 | A kind of super-hydrophobic three-resistance coating and preparation method thereof and application method |
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2018
- 2018-05-31 CN CN201810548504.5A patent/CN108753162A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559611A (en) * | 2014-12-05 | 2015-04-29 | 东来涂料技术（上海）有限公司 | Easy-to-clean fluorocarbon paint and preparation method thereof |
| CN106833162A (en) * | 2017-01-17 | 2017-06-13 | 衢州市闻天化工有限公司 | A kind of fluorine silicon Nano waterproof paint and preparation method thereof |
| CN107446424A (en) * | 2017-08-21 | 2017-12-08 | 昆明理工大电力工程技术有限公司 | A kind of super-hydrophobic three-resistance coating and preparation method thereof and application method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116855172A (en) * | 2023-07-13 | 2023-10-10 | 上海彩谷新材料科技有限公司 | Anti-graffiti anti-sticking protective paint and preparation method thereof |
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Application publication date: 20181106 |