CN108752845A - A kind of wear-resisting ABS composite material of antibacterial and preparation method thereof - Google Patents
A kind of wear-resisting ABS composite material of antibacterial and preparation method thereof Download PDFInfo
- Publication number
- CN108752845A CN108752845A CN201810638214.XA CN201810638214A CN108752845A CN 108752845 A CN108752845 A CN 108752845A CN 201810638214 A CN201810638214 A CN 201810638214A CN 108752845 A CN108752845 A CN 108752845A
- Authority
- CN
- China
- Prior art keywords
- wear
- temperature
- composite material
- solution
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
It is composed of the following components by weight the present invention relates to wear-resisting ABS composite material of a kind of antibacterial and preparation method thereof：ABS is 80 parts -100 parts；Antiseptic is 4 parts -6 parts；Anti-wear agent is 6 parts -8 parts；Compatilizer is 0.1 part -0.3 part；Antioxidant is 0.1 part -0.5 part；The antiseptic is Cu/TiO2；The anti-wear agent is the compound of two selenizing niobiums and titanium carbide.TiO2Itself has certain antibiotic property, positively charged Cu2+It can attract each other with electronegative bacteria cell wall, copper ion by reacting with zymoprotein in cellular machinery, makes protein coagulating, play the role of sterilization again；The wearability of two selenizing niobiums is fine, is prepared for a kind of two selenizing niobiums/carbonization titanium compound anti-wear agent with it in the application, it is more preferably than single anti-wear agent titanium carbide wearability.
Description
Technical field
The invention belongs to technical field of polymer materials, a kind of wear-resisting ABS composite material of antibacterial and its preparation are particularly related to
Method.
Background technology
Acrylonitrile-butadiene-phenylethylene (ABS) becomes modern because its is cheap, have excellent performance, source is wide, easy processing
One of most widely used plastics.In some specific application fields, there is the requirement of anti-microbial property, wear-resisting property to ABS, commonly
ABS composite material cannot be satisfied requirement.
The present inventor has been made a kind of wear-resisting ABS composite material of antibacterial, can realize ABS material by making great efforts for many years
Antibiotic property and wearability, this material not yet see report so far, this has the use scope of extension ABS composite material
Very important realistic meaning.
Invention content
The object of the present invention is to provide wear-resisting ABS composite materials of a kind of antibacterial and preparation method thereof, to solve the prior art
The problem of fungus resistance energy and the wear-resisting property deficiency of ABS material.
The present invention is achieved by the following technical solutions：
A kind of wear-resisting ABS composite material of antibacterial, it is composed of the following components by weight：
The antiseptic is Cu/TiO2；
The anti-wear agent is the compound of two selenizing niobiums and titanium carbide.
The preparation method of the antiseptic, includes the following steps：
(1) a certain amount of nano-TiO is weighed2、Cu(NO3)2Solution, by nano-TiO2、Cu(NO3)2Solution is put into three mouthfuls of burnings
In bottle, 2-4h is reacted in the case of 60-80 DEG C, obtains solution A；
(2) a certain amount of glucose, potassium hydroxide solution are weighed, the glucose solution B of alkalinity is configured to；
(3) weigh a certain amount of solution A, solution B is put into three-necked flask, and 20-40min is reacted in the case of 70-90 DEG C, obtain
Solution C；
(4) solution C is filtered by vacuum, washed, the dry 2-4h in 50-70 DEG C of baking oven grinds broken rear sieving, obtains
Antiseptic Cu/TiO2。
Nano-TiO in step (1)2、Cu(NO3)2The mass ratio of solution is (20-30)：(120-160), and nano-TiO2
Grain size be 20-30nm.
Glucose, potassium hydroxide solution mass ratio in step (2) are (40-60)：(100-140).
The mass ratio of solution A, solution B in step (3) is (30-50)：(60-80).
The preparation method of the anti-wear agent, includes the following steps：
(1) a certain amount of two selenizings niobium and titanium carbide are weighed；
(2) two selenizing niobiums and titanium carbide are put into spheroidal graphite machine to be ground, are sieved, both obtain two selenizing niobium of anti-wear agent/carbonization
Titanium；
(3) two selenizing niobiums/titanium carbide powder in (2) is put into graphite grinding tool, 3- is sintered at a temperature of 600-800 DEG C
5h obtains two selenizing niobiums/titanium carbide, places into disintegrating apparatus and crush classification, and sieving obtains two selenizing niobiums/titanium carbide
Compound anti-wear agent.
The mass ratio of two selenizing niobiums and titanium carbide in step (1) is (60-80)：(30-40).
The antioxidant is three (2,4- di-t-butyl) phenyl-phosphites, four [β-(3,5- di-tert-butyl-hydroxy phenyl)
Propionic acid] pentaerythritol ester or 1,3,5- trimethyls -2,4, one kind or several in 6- (3,5- di-t-butyl -4- hydroxyphenylmethyls) benzene
The mixing of kind.
The preparation method of the wear-resisting ABS composite material of any of the above-described antibacterial, includes the following steps：
(1) weigh 80 parts -100 parts ABS, 4 parts of -6 parts of antiseptics, 6 parts of -8 parts of anti-wear agents, 0.1 part of -0.3 part of SEBS-g-
MAH, 0.1 part of -0.5 part of antioxidant are mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material.
Double screw extruder in the step (2) includes six humidity provinces sequentially arranged, area's temperature 190~210
DEG C, two 230~270 DEG C of area's temperature, three 230~270 DEG C of area's temperature, four 230~270 DEG C of area's temperature, five area's temperature 230~270
DEG C, six 230~270 DEG C of area's temperature, 230~270 DEG C of head temperature；200~260r/min of screw speed.
The method have the benefit that：
Antiseptic Cu/TiO2Reaction mechanism it is as follows：
Cu2++2OH-→Cu(OH)2
Cu(OH)2→CuO+H2O
C5H6(OH)5CHO+CuO→C5H6(OH)5COOH+Cu
Antiseptic Cu/TiO2Antibacterial Mechanism：①TiO2Itself has certain antibiotic property.2. positively charged Cu2+Energy
Enough to attract each other with electronegative bacteria cell wall, copper ion by reacting with zymoprotein in cellular machinery, makes albumen again
Matter solidifies, and plays the role of sterilization.
The wearability of two selenizing niobiums is fine, and it is wear-resisting with it to be prepared for a kind of two selenizing niobiums/carbonization titanium compound in the application
Agent, it is more preferably than single anti-wear agent titanium carbide wearability.
Specific implementation mode
Carry out the technical solution that the present invention will be described in detail by the following examples, embodiment below is merely exemplary, only
It can be used for explanation and illustration technical scheme of the present invention, and be not to be construed as the limitation to technical solution of the present invention.
Raw material is as follows used in the following embodiment of the application：
ABS (model AG15AB), Taiwan；Nano-TiO2, Liuzhou Ruo Si Nono-material Science & Technology Ltd.；Cu
(NO3)2Solution, Shenzhen Bo Linda Science and Technology Ltd.s；Glucose, Wujiang Xin Li Fine Chemical Co., Ltd；Potassium hydroxide is molten
Liquid, the clear Xingxin Material Co Science and Technology Ltd. in Chuzhou；Two selenizing niobiums, Sichuan Xin Longdiye scientific and technological developments limited liability company；Carbonization
Titanium, Anhui Ke Run nanosecond science and technology Co., Ltd；SEBS-g-MAH, Suzhou Asia match plasticizing Co., Ltd；Antioxidant (model
Irganox168, Irganox1010, Irganox1330), Switzerland's Ciba.
Test equipment used in the following embodiment of the application is as follows：
ZSK30 type double screw extruders, German W&P companies；JL-1000 type tensile testing machines, the wide just experiment instrument in Guangzhou
Device company produces；HTL900-T-5B type injection (mo(u)lding) machines, the production of Hai Tai plastics machineries Co., Ltd；XCJ-500 type shock-testings
Machine, the production of Chengde testing machine factory；QT-1196 type tester for elongation, Dongguan City Gao Tai detecting instruments Co., Ltd；QD-GJS-
B12K type homogenizers, Beijing perseverance Order instrument and meter Co., Ltd.
The application provides a kind of wear-resisting ABS composite material of antibacterial, composed of the following components by weight：
Antiseptic is Cu/TiO2；
Anti-wear agent is the compound of two selenizing niobiums and titanium carbide.
The preparation method of antiseptic, includes the following steps：
(1) a certain amount of nano-TiO is weighed2、Cu(NO3)2Solution, by nano-TiO2、Cu(NO3)2Solution is put into three mouthfuls of burnings
In bottle, 2-4h is reacted in the case of 60-80 DEG C, obtains solution A；Nano-TiO2、Cu(NO3)2The mass ratio of solution is (20-30)：
(120-160), and nano-TiO2Grain size be 20-30nm.
(2) a certain amount of glucose, potassium hydroxide solution are weighed, the glucose solution B of alkalinity is configured to；Glucose, hydrogen
Potassium oxide solution mass ratio is (40-60)：(100-140).
(3) weigh a certain amount of solution A, solution B is put into three-necked flask, and 20-40min is reacted in the case of 70-90 DEG C, obtain
Solution C；Solution A, solution B mass ratio be (30-50)：(60-80).
(4) solution C is filtered by vacuum, washed, the dry 2-4h in 50-70 DEG C of baking oven crosses 400 mesh after grinding is broken
Sieve, obtains antiseptic Cu/TiO2。
The preparation method of anti-wear agent, includes the following steps：
(1) a certain amount of two selenizings niobium and titanium carbide are weighed；The mass ratio of two selenizing niobiums and titanium carbide is (60-80)：
(30-40)。
(2) two selenizing niobiums and titanium carbide are put into spheroidal graphite machine to be ground, are sieved, both obtain two selenizing niobium of anti-wear agent/carbonization
Titanium.
(3) two selenizing niobiums/titanium carbide powder in (2) is put into graphite grinding tool, 3- is sintered at a temperature of 600-800 DEG C
5h obtains two selenizing niobiums/titanium carbide, places into disintegrating apparatus and crush classification, and sieving obtains two selenizing niobiums/titanium carbide
Compound anti-wear agent.
Compatilizer is SEBS-g-MAH.
Antioxidant is three (2,4- di-t-butyls) phenyl-phosphites (abbreviation Irganox168), the four [β-of BASF AG
(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester (abbreviation Irganox1010) or 1,3,5- trimethyls -2,4,
The mixing of one or more of 6- (3,5- di-t-butyl -4- hydroxyphenylmethyls) benzene (abbreviation Irganox1330).
The preparation method of the wear-resisting ABS composite material of any of the above-described antibacterial, includes the following steps：
(1) weigh 80 parts -100 parts ABS, 4 parts of -6 parts of antiseptics, 6 parts of -8 parts of anti-wear agents, 0.1 part of -0.3 part of SEBS-g-
MAH, 0.1 part of -0.5 part of antioxidant are mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material.
Double screw extruder in step (2) includes six humidity provinces sequentially arranged, 190~210 DEG C of area's temperature, and two
230~270 DEG C of area's temperature, three 230~270 DEG C of area's temperature, four 230~270 DEG C of area's temperature, five 230~270 DEG C of area's temperature, six
230~270 DEG C of area's temperature, 230~270 DEG C of head temperature；200~260r/min of screw speed.
Embodiment 1
(1) weigh 80 parts ABS, 4 parts of antiseptics, 6 parts of anti-wear agents, 0.1 part of SEBS-g-MAH, 0.1 part of Irganox168
It is mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material P1.
Each area's temperature of double screw extruder and screw speed wherein in step (2) are respectively；One 190 DEG C of area's temperature, two
230 DEG C of area's temperature, three 230 DEG C of area's temperature, four 230 DEG C of area's temperature, five 230 DEG C of area's temperature, six 230 DEG C of area's temperature, head temperature
230℃；Screw speed 200r/min.
Embodiment 2
(1) weigh 100 parts ABS, 6 parts of antiseptics, 8 parts of anti-wear agents, 0.3 part of SEBS-g-MAH, 0.1 part
Irganox168,0.2 part of Irganox1010,0.2 part of Irganox1330 are mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material P2.
Each area's temperature of double screw extruder and screw speed wherein in step (2) are respectively；One 210 DEG C of area's temperature, two
270 DEG C of area's temperature, three 270 DEG C of area's temperature, four 270 DEG C of area's temperature, five 270 DEG C of area's temperature, six 270 DEG C of area's temperature, head temperature
270℃；Screw speed 260r/min.
Embodiment 3
(1) weigh 90 parts ABS, 5 parts of antiseptics, 7 parts of anti-wear agents, 0.2 part of SEBS-g-MAH, 0.1 part of Irganox168,
0.2 part of Irganox1010 is mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material P3.
Each area's temperature of double screw extruder and screw speed wherein in step (2) are respectively；One 200 DEG C of area's temperature, two
250 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 250 DEG C of area's temperature, head temperature
250℃；Screw speed 230r/min.
Embodiment 4
(1) weigh 85 parts ABS, 4 parts of antiseptics, 8 parts of anti-wear agents, 0.1 part of SEBS-g-MAH, 0.1 part of Irganox168,
0.2 part of Irganox1330 is mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material P4.
Each area's temperature of double screw extruder and screw speed wherein in step (2) are respectively；One 195 DEG C of area's temperature, two
235 DEG C of area's temperature, three 235 DEG C of area's temperature, four 235 DEG C of area's temperature, five 235 DEG C of area's temperature, six 235 DEG C of area's temperature, head temperature
235℃；Screw speed 235r/min.
Embodiment 5
(1) weigh 95 parts ABS, 6 parts of antiseptics, 7 parts of anti-wear agents, 0.1 part of SEBS-g-MAH, 0.1 part of Irganox1010
It is mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material P5.
Each area's temperature of double screw extruder and screw speed wherein in step (2) are respectively；One 190 DEG C of area's temperature, two
230 DEG C of area's temperature, three 230 DEG C of area's temperature, four 230 DEG C of area's temperature, five 230 DEG C of area's temperature, six 230 DEG C of area's temperature, head temperature
230℃；Screw speed 200r/min.
Comparative example 1
(1) 80 parts of ABS, 0.1 part of Irganox1010,0.2 part of Irganox168 is weighed to be mixed and stirred for uniformly, being mixed
Close material；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material D1.
Each area's temperature of double screw extruder and screw speed wherein in step (2) are respectively；One 190 DEG C of area's temperature, two
230 DEG C of area's temperature, three 230 DEG C of area's temperature, four 230 DEG C of area's temperature, five 230 DEG C of area's temperature, six 230 DEG C of area's temperature, head temperature
230℃；Screw speed 200r/min.
Comparative example 2
(1) 90 parts of ABS, 8 parts of titanium carbides, 0.1 part of Irganox1010,0.1 part of Irganox168,0.2 part of SEBS- are weighed
G-MAH is mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material P5.
Preferably, the double screw extruder in step (2) includes six humidity provinces sequentially arranged, 195 DEG C of area's temperature,
Two 235 DEG C of area's temperature, three 235 DEG C of area's temperature, four 235 DEG C of area's temperature, five 235 DEG C of area's temperature, six 235 DEG C of area's temperature, head temperature
235 DEG C of degree；Screw speed 235r/min.
Performance test：
Batten test, test is made with injection molding machine in ABS composite material prepared by above-described embodiment 1-5 and comparative example 1-2
Data such as following table：
The antibacterial it can also be seen that embodiment 1-5 is can be seen that from table by the data of embodiment 1-5 and comparative example 1
Performance, wear-resisting property will be better than comparative example 1, this illustrates that ABS composite material anti-microbial property, wear-resisting property are all made from the application
It is better than common ABS composite material.
The wearability that can be seen that embodiment 1-5 by the data of embodiment 1-5 and comparative example 2 is better than comparative example 2,
This illustrates two selenizing niobium material of complex abrasion-proof agent/titanium carbide in the application more preferably than single anti-wear agent titanium carbide wear-resisting property.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And deformation, the scope of the present invention are extremely equally limited by appended claims.
Claims (10)
1. a kind of wear-resisting ABS composite material of antibacterial, which is characterized in that composed of the following components by weight：
The antiseptic is Cu/TiO2；
The anti-wear agent is the compound of two selenizing niobiums and titanium carbide.
2. the wear-resisting ABS composite material of antibacterial according to claim 1, which is characterized in that the preparation method of the antiseptic,
Include the following steps：
(1) a certain amount of nano-TiO is weighed2、Cu(NO3)2Solution, by nano-TiO2、Cu(NO3)2Solution is put into three-necked flask,
2-4h is reacted in the case of 60-80 DEG C, obtains solution A；
(2) a certain amount of glucose, potassium hydroxide solution are weighed, the glucose solution B of alkalinity is configured to；
(3) weigh a certain amount of solution A, solution B is put into three-necked flask, and 20-40min is reacted in the case of 70-90 DEG C, obtain solution
C；
(4) solution C is filtered by vacuum, washed, the dry 2-4h in 50-70 DEG C of baking oven grinds broken rear sieving, obtains antibacterial
Agent Cu/TiO2。
3. the wear-resisting ABS composite material of antibacterial according to claim 2, which is characterized in that the nano-TiO in step (1)2、Cu
(NO3)2The mass ratio of solution is (20-30)：(120-160), and nano-TiO2Grain size be 20-30nm.
4. the wear-resisting ABS composite material of antibacterial according to claim 2, which is characterized in that glucose, hydrogen in step (2)
Potassium oxide solution mass ratio is (40-60)：(100-140).
5. the wear-resisting ABS composite material of antibacterial according to claim 2, which is characterized in that solution A, solution in step (3)
The mass ratio of B is (30-50)：(60-80).
6. the wear-resisting ABS composite material of antibacterial according to claim 1, which is characterized in that the preparation method of the anti-wear agent,
Include the following steps：
(1) a certain amount of two selenizings niobium and titanium carbide are weighed；
(2) two selenizing niobiums and titanium carbide are put into spheroidal graphite machine to be ground, are sieved, both obtain two selenizing niobium of anti-wear agent/titanium carbide；
(3) two selenizing niobiums/titanium carbide powder in (2) is put into graphite grinding tool, 3-5h is sintered at a temperature of 600-800 DEG C,
Two selenizing niobiums/titanium carbide is obtained, places into disintegrating apparatus and crushes classification, is sieved, it is compound to obtain two selenizing niobiums/titanium carbide
Type anti-wear agent.
7. the wear-resisting ABS composite material of antibacterial according to claim 6, which is characterized in that two selenizing niobiums in step (1) with
The mass ratio of titanium carbide is (60-80)：(30-40).
8. the wear-resisting ABS composite material of antibacterial according to claim 1, which is characterized in that the antioxidant is three (2,4- bis-
Tertiary butyl) phenyl-phosphite, four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters or 1,3,5- front threes
Base -2,4, the mixing of one or more of 6- (3,5- di-t-butyl -4- hydroxyphenylmethyls) benzene.
9. the preparation method of the wear-resisting ABS composite material of any one of the claims 1 to 8 antibacterial, which is characterized in that including with
Lower step：
(1) weigh 80 parts -100 parts ABS, 4 parts of -6 parts of antiseptics, 6 parts of -8 parts of anti-wear agents, 0.1 part of -0.3 part of SEBS-g-MAH,
0.1 part of -0.5 part of antioxidant is mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to ABS composite material.
10. the preparation method of the wear-resisting ABS composite material of antibacterial according to claim 9, which is characterized in that the step
(2) double screw extruder in includes six humidity provinces sequentially arranged, 190~210 DEG C of area's temperature, and two area's temperature 230~
270 DEG C, three 230~270 DEG C of area's temperature, four 230~270 DEG C of area's temperature, five 230~270 DEG C of area's temperature, six area's temperature 230~
270 DEG C, 230~270 DEG C of head temperature；200~260r/min of screw speed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810638214.XA CN108752845A (en) | 2018-06-20 | 2018-06-20 | A kind of wear-resisting ABS composite material of antibacterial and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810638214.XA CN108752845A (en) | 2018-06-20 | 2018-06-20 | A kind of wear-resisting ABS composite material of antibacterial and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108752845A true CN108752845A (en) | 2018-11-06 |
Family
ID=63979552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810638214.XA Pending CN108752845A (en) | 2018-06-20 | 2018-06-20 | A kind of wear-resisting ABS composite material of antibacterial and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108752845A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111808396A (en) * | 2020-07-17 | 2020-10-23 | 浙江王氏科技有限公司 | Antibacterial plastic and preparation method thereof |
| CN112094476A (en) * | 2020-09-30 | 2020-12-18 | 深圳市鑫鹏宇塑胶有限公司 | Antibacterial wear-resistant ABS plastic and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101024180A (en) * | 2007-02-25 | 2007-08-29 | 广州门德纳米科技有限公司 | Photo-catalyst micro-particles and its preparing method, photocatalyst and preparing method and use |
| CN102675817A (en) * | 2012-05-31 | 2012-09-19 | 四川长虹电器股份有限公司 | Antibacterial plastic for household appliances and preparation method thereof |
| CN104804361A (en) * | 2014-01-28 | 2015-07-29 | 深圳齐心集团股份有限公司 | Antibacterial resin composite material and preparation method thereof |
| CN107226953A (en) * | 2016-03-23 | 2017-10-03 | 合肥杰事杰新材料股份有限公司 | A kind of scratch-resistant composite and preparation method thereof |
| CN107245190A (en) * | 2017-06-21 | 2017-10-13 | 安徽江淮汽车集团股份有限公司 | A kind of wear-resisting PP PA66 composites of antibacterial and preparation method thereof |
| CN107413169A (en) * | 2017-04-19 | 2017-12-01 | 苏州泰利三佳纳米科技有限公司 | A kind of formaldehyde absorbent of the doped nano titanium dioxide containing Ternary copper and preparation method thereof |
-
2018
- 2018-06-20 CN CN201810638214.XA patent/CN108752845A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101024180A (en) * | 2007-02-25 | 2007-08-29 | 广州门德纳米科技有限公司 | Photo-catalyst micro-particles and its preparing method, photocatalyst and preparing method and use |
| CN102675817A (en) * | 2012-05-31 | 2012-09-19 | 四川长虹电器股份有限公司 | Antibacterial plastic for household appliances and preparation method thereof |
| CN104804361A (en) * | 2014-01-28 | 2015-07-29 | 深圳齐心集团股份有限公司 | Antibacterial resin composite material and preparation method thereof |
| CN107226953A (en) * | 2016-03-23 | 2017-10-03 | 合肥杰事杰新材料股份有限公司 | A kind of scratch-resistant composite and preparation method thereof |
| CN107413169A (en) * | 2017-04-19 | 2017-12-01 | 苏州泰利三佳纳米科技有限公司 | A kind of formaldehyde absorbent of the doped nano titanium dioxide containing Ternary copper and preparation method thereof |
| CN107245190A (en) * | 2017-06-21 | 2017-10-13 | 安徽江淮汽车集团股份有限公司 | A kind of wear-resisting PP PA66 composites of antibacterial and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 王文广等: "《塑料配方设计》", 31 July 2004, 化学工业出版社 * |
| 王毓民等: "《润滑材料与润滑技术》", 31 January 2005, 化学工业出版社 * |
| 裴立宅: "《高技术陶瓷材料》", 30 June 2015, 合肥工业大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111808396A (en) * | 2020-07-17 | 2020-10-23 | 浙江王氏科技有限公司 | Antibacterial plastic and preparation method thereof |
| CN112094476A (en) * | 2020-09-30 | 2020-12-18 | 深圳市鑫鹏宇塑胶有限公司 | Antibacterial wear-resistant ABS plastic and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103450631B (en) | Polyether-ether-ketone cable material and preparation method thereof | |
| CN108752845A (en) | A kind of wear-resisting ABS composite material of antibacterial and preparation method thereof | |
| CN106633452A (en) | High-performance PS composite material and preparation method thereof | |
| CN108948614B (en) | Lignin/polyvinyl alcohol composite material and preparation method thereof | |
| CN107400343A (en) | A kind of fire-retardant scratch-resistant PBT composite and preparation method thereof | |
| CN100593828C (en) | Method for preparing NdFeB/PPS injection moulding particle material | |
| CN107573657A (en) | A kind of PET composite material and preparation method thereof | |
| CN112341786A (en) | Polyphenyl ether/polystyrene composition and preparation method and application thereof | |
| CN107418050A (en) | A kind of high-performance antibiosis PP PA6 composites and preparation method thereof | |
| CN109294155A (en) | A kind of low VOC flame-proof abrasion-resistant ABS composite material and preparation method thereof | |
| CN107118442A (en) | A kind of heat conduction antibacterial PP PS composites and preparation method thereof | |
| CN107189249A (en) | A kind of high-performance antibiosis PS composites and preparation method thereof | |
| CN103740102A (en) | Conductive nylon composite material and preparation method thereof | |
| CN106867146A (en) | Low temperature resistant PPE PVC composites of a kind of antibacterial and preparation method thereof | |
| CN108752832A (en) | A kind of AES-PVC composite material and preparation methods | |
| CN109135207A (en) | A kind of High Performance Shielding PBT composite and preparation method thereof | |
| CN107266844A (en) | A kind of bloom scratch-resistant flame retardant PS composites and preparation method thereof | |
| CN107236299A (en) | A kind of PA66 AES composite materials and preparation method thereof | |
| CN107383743A (en) | A kind of AES PMMA composites and preparation method thereof | |
| CN109021483A (en) | A kind of AES-PET composite material and preparation method of low VOC | |
| CN107163568B (en) | A kind of fire-retardant high-ductility PA6-ACS composite material and preparation method | |
| CN107216559A (en) | A kind of PS PC composites and preparation method thereof | |
| CN109096727B (en) | Metal-appearance-imitated antibacterial PC composite material | |
| CN107418075A (en) | A kind of PS composites and preparation method thereof | |
| CN107418082A (en) | A kind of wear-resisting heat conduction ACS composites and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 230601 No. 99 Ziyun Road, Hefei Economic and Technological Development Zone, Anhui Province Applicant after: Anhui Jianghuai Automobile Group Limited by Share Ltd Address before: 230601 No. 669 Shixin Road, Taohua Industrial Park, Hefei City, Anhui Province Applicant before: Anhui Jianghuai Automobile Group Limited by Share Ltd |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181106 |