CN108752809A - A kind of ageing-resistant cable jacket material - Google Patents
A kind of ageing-resistant cable jacket material Download PDFInfo
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- CN108752809A CN108752809A CN201810679602.2A CN201810679602A CN108752809A CN 108752809 A CN108752809 A CN 108752809A CN 201810679602 A CN201810679602 A CN 201810679602A CN 108752809 A CN108752809 A CN 108752809A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The invention discloses a kind of ageing-resistant cable jacket materials, are related to cable jacket technical field, including following raw material：Brucite fiber that SG-4 polyvinyl chloride, Dow EPDM, isoprene-styrene-methacrylate copolymer, the palygorskite powder that fineness is 200-300 mesh, chopped length are 800-1200 μm, phosphorous acid three (2,4- di-tert-butyl-phenyls) ester, 4,4 '-methyl diphenylene diisocyanates, pucherite, captax BSPT, composite flame-retardant agent, complex antiager, composite vulcanizing agent, composite coupler.The cable jacket material of the present invention is prepared simply, has excellent temperature tolerance, resistance to ag(e)ing, mechanical performance etc., useful life longevity is good, and application field occasion is extensive.
Description
Technical field
The present invention relates to cable jacket technical fields, and in particular to a kind of ageing-resistant cable jacket material.
Background technology
Electrical/optical cable is the carrier that power Transmission and information are transmitted, and sheath tube material is indispensable in above-mentioned cable
Layer structure part plays a part of protecting cable, ensures that electrical/optical signal transmission is smooth in cable, allows leading in electric wire
The media such as electric alloy/optical fiber and water, air completely cut off, it is avoided damage, interference exterior materials occur or by transfer function
The unfavorable phenomenons such as missing, prevent transmission performance from deteriorating.With the reinforcement of people's environmental consciousness, having ruthless multinational family in the world, oneself forbids
The harmful components such as leaded cadmium in sheath tube material, and along with social progress and the high speed development of line cable industry, cable
It is risen year by year with protecting pipe material utilization amount, cable overall performance is required to be also higher, is primarily due to residing for current cable
Working environment it is more severe changeable, especially outdoor cable, may suffer from being exposed to the sun, it is cold freeze, impregnate, burn into rolls, oxygen
The environmental influences such as change, if if the comprehensive performance of cable is not excellent enough, it will lead to its season cracking, service life drop
It is low, and then lead to different degrees of line fault, seriously affect people normally life and work.
The patent application of Publication No. CN108034097A discloses a kind of cable jacket material, according to following original
The parts by weight of material form：50-80 parts of carboxy nitrile rubber, 1-5 parts of anti-aging agent, 2-3 parts of fire retardant, increases 10-30 parts of silicones
Mould 3-6 parts of agent, 6-8 parts of furnace black, 1-6 parts of zinc oxide, 10-15 parts of raw rubber matrix, 15-30 parts of active calcium silicate, graphene
1-3 parts, 2-6 parts of acidified starch, 1-2 parts of silazane, 4-6 parts of Black Warrior mineral wool, 1-3 parts of compound stabilizer, modified quicklime 3-5
Part.This kind of sheath material good flame resistance, tensile strength are high, elongation is high, environmental-friendly characteristic, but its density is larger, no
Suitable for as long-distance sand transport cable material, and corrosion resistance is poor, needs to be improved.
The patent application for authorizing Publication No. CN106084421B discloses a kind of anti-electric-mark uvioresistant ADSS optical cables shield
Jacking, the protective cover material include the raw material of following weight parts：65-70 parts of high-density polyethylene resin, ethylene acrylic acid co polymer 15-
20 parts, polycthylene grafted material 9-10 parts, 5-6 parts of dimethyl silicone polymer, 15-20 parts of magnesium hydroxide, black masterbatch 5.0-5.5
Part, 0.5-1.0 parts of ultra-violet absorber, 0.5-1.0 parts of antioxidant；The resistance to electric trace of the anti-corona of the protective cover material, ultraviolet radiation resisting, tool
Standby superior physical mechanical property, but its water resistance is poor, needs to be improved.
Invention content
The purpose of the present invention is to provide a kind of ageing-resistant cable jacket material, this kind of protective cover material high comprehensive performance, applications
Durability is good.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of ageing-resistant cable jacket material, including following raw material by weight：
58-64 parts of SG-4 polyvinyl chloride；
EPDM25-33 parts of Dow；
Isoprene -8-14 parts of styrene-methacrylate copolymer；
Fineness is 10-15 parts of the palygorskite powder of 200-300 mesh；
2.5-4 parts of the brucite fiber that chopped length is 800-1200 μm；
1-2 parts of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -0.5-1 parts of methyl diphenylene diisocyanates；
1.5-2.5 parts of pucherite；
BSPT1-1.5 parts of captax；
1-1.6 parts of composite flame-retardant agent；
0.7-1.1 parts of complex antiager；
1-2 parts of composite vulcanizing agent；
0.3-0.5 parts of composite coupler；
Above-mentioned composite vulcanizing agent is made of zinc oxide, sulphur, dual-tert-butyl peroxy isopropyl base benzene；
Above-mentioned composite coupler is made of tin coupled SSBR, rare-earth coupling agent.
Further, above-mentioned protective cover material is made of following raw material by weight：
58 parts of SG-4 polyvinyl chloride；
EPDM25 parts of Dow；
Isoprene -8 parts of styrene-methacrylate copolymer；
Fineness is 10 parts of the palygorskite powder of 200 mesh；
2.5 parts of the brucite fiber that chopped length is 800 μm；
1 part of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -0.5 part of methyl diphenylene diisocyanates；
1.5 parts of pucherite；
BSPT1 parts of captax；
1 part of composite flame-retardant agent；
0.7 part of complex antiager；
1 part of composite vulcanizing agent；
0.3 part of composite coupler.
Further, above-mentioned protective cover material is made of following raw material by weight：
64 parts of SG-4 polyvinyl chloride；
EPDM33 parts of Dow；
Isoprene -4 parts of styrene-methacrylate copolymer 1；
Fineness is 15 parts of the palygorskite powder of 300 mesh；
4 parts of the brucite fiber that chopped length is 1200 μm；
2 parts of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -1 part of methyl diphenylene diisocyanates；
2.5 parts of pucherite；
BSPT1.5 parts of captax；
1.6 parts of composite flame-retardant agent；
1.1 parts of complex antiager；
2 parts of composite vulcanizing agent；
0.5 part of composite coupler.
Further, the preparation method of above-mentioned protective cover material is as follows：
Ⅰ：Kneading machine is preheated to 48 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenyl methanes two different
Cyanate, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 3min, the OPE waxes of weight of material 30% is added, then slowly
75 DEG C are warming up to, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 6min, then
Refining 15min is closed in persistently overheating to 115 DEG C pressurizations again, obtains batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 130 DEG C, captax BSPT and compound is added
Refining 100s is closed in anti-aging agent pressurization；When temperature reaches 140 DEG C, composite coupler pressurization is added and closes refining 55s；When temperature reaches 155
DEG C when, Dow EPDM pressurization is first added and closes refining 20min, adds palygorskite powder and refining 6min is closed in brucite fiber pressurization,
Obtain mixed material B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 150 DEG C refines 55min, before conjunction refining terminates
Composite vulcanizing agent is added when 52s, obtains mixed material；Mixed material is delivered in double screw extruder extruding pelletization i.e. later
It can.
Further, the preparation method of above-mentioned protective cover material is as follows：
Ⅰ：Kneading machine is preheated to 52 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenyl methanes two different
Cyanate, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 3min, the OPE waxes of weight of material 40% is added, then slowly
85 DEG C are warming up to, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 4min, then
Refining 10min is closed in persistently overheating to 125 DEG C pressurizations again, obtains batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 140 DEG C, captax BSPT and compound is added
Refining 80s is closed in anti-aging agent pressurization；When temperature reaches 150 DEG C, composite coupler pressurization is added and closes refining 45s；When temperature reaches 165 DEG C
When, Dow EPDM pressurizations are first added and close refining 16min, adds palygorskite powder and refining 4min is closed in brucite fiber pressurization, obtain
Mixed material B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 160 DEG C refines 45min, before conjunction refining terminates
Composite vulcanizing agent is added when 56s, obtains mixed material；Mixed material is delivered in double screw extruder extruding pelletization i.e. later
It can.
Further, above-mentioned composite flame-retardant agent is tricresyl phosphate (2,3- bis- chloropropyl) ester, phosphoric acid (2- ethylhexyls)-hexichol
Ester, zinc borate in mass ratio 1:1:2 are fully blended to obtain.
Further, above-mentioned complex antiager is antioxidant 4010NA, antioxidant MB in mass ratio 3:2 are fully blended
It arrives.
Further, above-mentioned composite vulcanizing agent is zinc oxide, sulphur, dual-tert-butyl peroxy isopropyl base benzene in mass ratio 1:1:
3 are fully blended to obtain.
Further, above-mentioned composite coupler is tin coupled SSBR, rare-earth coupling agent in mass ratio 2:1 is fully blended
It arrives.
Further, above-mentioned composite coupler is tin coupled SSBR, rare-earth coupling agent in mass ratio 2.5:1.5 are fully blended
It obtains.
The present invention has following advantageous effect：The sheath material of the present invention by ingenious selection to raw materials for production and its
The inventive improvements of preparation process, in raw material the collaboration of the compositions such as polyvinyl chloride, EPDM, brucite fiber, pucherite make mutually
With so that finished sheath pipe structure realizes compactness improvement, has reached better stereoscopic graticule formula molecular structure, has following
Characteristic and advantage：Compatibility performance is good between raw materials for production, and production efficiency is high；Good mechanical property has excellent tensile strength, breaks
Norminal strain value, elasticity modulus and notched Izod impact hit intensity are split, environmental stress cracking resistance is good, improves the tough and tensile of cable
Property；Heat resistance is excellent, and brittle temperature is low, freeze proof, thermal stress cracking performance is good；Ageing-resistant corrosion, flame-proof weather-resisting, insulating properties
It is good, it preferably ensure that the integrity degree and service life of finished sheath pipe, widened its use occasion and field, even if disliking
It can also be worked normally under bad, high intensity environmental stress conditions, ensure that the electric wire in finished sheath pipe, cable are conveying signal mistake
Stability, reliability in journey and safety, have a extensive future.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
It all raw materials in embodiment and its produces composition and can be obtained by disclosed commercially available channel；
Embodiment 1
The present embodiment is related to a kind of ageing-resistant cable jacket material and preparation method thereof, the CABLE MATERIALS by it is following by weight
Raw material composition：
58 parts of SG-4 polyvinyl chloride；
EPDM25 parts of Dow；
Isoprene -8 parts of styrene-methacrylate copolymer；
Fineness is 10 parts of the palygorskite powder of 200 mesh；
2.5 parts of the brucite fiber that chopped length is 800 μm；
1 part of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -0.5 part of methyl diphenylene diisocyanates；
1.5 parts of pucherite；
BSPT1 parts of captax；
1 part of composite flame-retardant agent；
0.7 part of complex antiager；
1 part of composite vulcanizing agent；
0.3 part of composite coupler.
Composite flame-retardant agent in the present embodiment, complex antiager, composite vulcanizing agent and composite coupler selection and produce
As shown in table 1 below：
Table 1
The preparation method of protective cover material is carried out according to following general steps in the present embodiment
Ⅰ：Kneading machine is preheated to 48 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenyl methanes two different
Cyanate, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 3min, the OPE waxes of weight of material 30% is added, then slowly
75 DEG C are warming up to, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 6min, then
Refining 15min is closed in persistently overheating to 115 DEG C pressurizations again, obtains batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 130 DEG C, captax BSPT and compound is added
Refining 100s is closed in anti-aging agent pressurization；When temperature reaches 140 DEG C, composite coupler pressurization is added and closes refining 55s；When temperature reaches 155
DEG C when, Dow EPDM pressurization is first added and closes refining 20min, adds palygorskite powder and refining 6min is closed in brucite fiber pressurization,
Obtain mixed material B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 150 DEG C refines 55min, before conjunction refining terminates
Composite vulcanizing agent is added when 52s, obtains mixed material；Mixed material is delivered in double screw extruder extruding pelletization i.e. later
It can.
Embodiment 2
The present embodiment is related to a kind of ageing-resistant cable jacket material and preparation method thereof, the CABLE MATERIALS by it is following by weight
Raw material composition：
60 parts of SG-4 polyvinyl chloride；
EPDM28 parts of Dow；
Isoprene -1 part of styrene-methacrylate copolymer 1；
Fineness is 12 parts of the palygorskite powder of 250 mesh；
3 parts of the brucite fiber that chopped length is 1000 μm；
1.3 parts of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -0.6 part of methyl diphenylene diisocyanates；
1.7 parts of pucherite；
BSPT1.1 parts of captax；
1.2 parts of composite flame-retardant agent；
0.8 part of complex antiager；
1.2 parts of composite vulcanizing agent；
0.35 part of composite coupler.
Composite flame-retardant agent in the present embodiment, complex antiager, composite vulcanizing agent and composite coupler selection and produce
As shown in table 2 below：
Table 2
The preparation method of protective cover material is carried out according to following general steps in the present embodiment
Ⅰ：Kneading machine is preheated to 49 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenyl methanes two different
Cyanate, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 3.5min, the OPE waxes of weight of material 32% is added, then delay
It is slow to be warming up to 78 DEG C, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 5.5min,
Then refining 14min is closed in persistently overheating to 118 DEG C pressurizations again, obtains batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 132 DEG C, captax BSPT and compound is added
Refining 95s is closed in anti-aging agent pressurization；When temperature reaches 142 DEG C, composite coupler pressurization is added and closes refining 52s；When temperature reaches 158 DEG C
When, Dow EPDM pressurizations are first added and close refining 19min, adds palygorskite powder and refining 5.5min is closed in brucite fiber pressurization,
Obtain mixed material B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 152 DEG C refines 52min, before conjunction refining terminates
Composite vulcanizing agent is added when 53s, obtains mixed material；Mixed material is delivered in double screw extruder extruding pelletization i.e. later
It can.
Embodiment 3
The present embodiment is related to a kind of ageing-resistant cable jacket material and preparation method thereof, the CABLE MATERIALS by it is following by weight
Raw material composition：
61 parts of SG-4 polyvinyl chloride；
EPDM30 parts of Dow；
Isoprene -2 parts of styrene-methacrylate copolymer 1；
Fineness is 13 parts of the palygorskite powder of 250 mesh；
3.3 parts of the brucite fiber that chopped length is 1000 μm；
1.5 parts of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -0.7 part of methyl diphenylene diisocyanates；
1.9 parts of pucherite；
BSPT1.2 parts of captax；
1.3 parts of composite flame-retardant agent；
0.9 part of complex antiager；
1.4 parts of composite vulcanizing agent；
0.4 part of composite coupler.
Composite flame-retardant agent in the present embodiment, complex antiager, composite vulcanizing agent and composite coupler selection and produce
As shown in table 3 below：
Table 3
The preparation method of protective cover material is carried out according to following general steps in the present embodiment
Ⅰ：Kneading machine is preheated to 50 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenyl methanes two different
Cyanate, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 4min, the OPE waxes of weight of material 35% is added, then slowly
80 DEG C are warming up to, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 5min, then
Refining 12.5min is closed in persistently overheating to 120 DEG C pressurizations again, obtains batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 135 DEG C, captax BSPT and compound is added
Refining 90s is closed in anti-aging agent pressurization；When temperature reaches 145 DEG C, composite coupler pressurization is added and closes refining 50s；When temperature reaches 160 DEG C
When, Dow EPDM pressurizations are first added and close refining 18min, adds palygorskite powder and refining 5min is closed in brucite fiber pressurization, obtain
Mixed material B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 155 DEG C refines 50min, before conjunction refining terminates
Composite vulcanizing agent is added when 54s, obtains mixed material；Mixed material is delivered in double screw extruder extruding pelletization i.e. later
It can.
Embodiment 4
The present embodiment is related to a kind of ageing-resistant cable jacket material and preparation method thereof, the CABLE MATERIALS by it is following by weight
Raw material composition：
62 parts of SG-4 polyvinyl chloride；
EPDM32 parts of Dow；
Isoprene -3 parts of styrene-methacrylate copolymer 1；
Fineness is 14 parts of the palygorskite powder of 250 mesh；
3.6 parts of the brucite fiber that chopped length is 1000 μm；
1.8 parts of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -0.8 part of methyl diphenylene diisocyanates；
2.1 parts of pucherite；
BSPT1.3 parts of captax；
1.4 parts of composite flame-retardant agent；
1.0 parts of complex antiager；
1.6 parts of composite vulcanizing agent；
0.45 part of composite coupler.
Composite flame-retardant agent in the present embodiment, complex antiager, composite vulcanizing agent and composite coupler selection and produce
As shown in table 4 below：
Table 4
The preparation method of protective cover material is carried out according to following general steps in the present embodiment
Ⅰ：Kneading machine is preheated to 51 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenyl methanes two different
Cyanate, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 4.5min, the OPE waxes of weight of material 38% is added, then delay
It is slow to be warming up to 82 DEG C, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 4.5min,
Then refining 11min is closed in persistently overheating to 123 DEG C pressurizations again, obtains batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 136 DEG C, captax BSPT and compound is added
Refining 85s is closed in anti-aging agent pressurization；When temperature reaches 148 DEG C, composite coupler pressurization is added and closes refining 47s；When temperature reaches 162 DEG C
When, Dow EPDM pressurizations are first added and close refining 17min, adds palygorskite powder and refining 4.5min is closed in brucite fiber pressurization,
Obtain mixed material B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 158 DEG C refines 49min, before conjunction refining terminates
Composite vulcanizing agent is added when 55s, obtains mixed material；Mixed material is delivered in double screw extruder extruding pelletization i.e. later
It can.
Embodiment 5
The present embodiment is related to a kind of ageing-resistant cable jacket material and preparation method thereof, the CABLE MATERIALS by it is following by weight
Raw material composition：
64 parts of SG-4 polyvinyl chloride；
EPDM33 parts of Dow；
Isoprene -4 parts of styrene-methacrylate copolymer 1；
Fineness is 15 parts of the palygorskite powder of 300 mesh；
4 parts of the brucite fiber that chopped length is 1200 μm；
2 parts of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -1 part of methyl diphenylene diisocyanates；
2.5 parts of pucherite；
BSPT1.5 parts of captax；
1.6 parts of composite flame-retardant agent；
1.1 parts of complex antiager；
2 parts of composite vulcanizing agent；
0.5 part of composite coupler.
Composite flame-retardant agent in the present embodiment, complex antiager, composite vulcanizing agent and composite coupler selection and produce
As shown in table 5 below：
Table 5
The preparation method of protective cover material is carried out according to following general steps in the present embodiment
Ⅰ：Kneading machine is preheated to 52 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenyl methanes two different
Cyanate, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 3min, the OPE waxes of weight of material 40% is added, then slowly
85 DEG C are warming up to, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 4min, then
Refining 10min is closed in persistently overheating to 125 DEG C pressurizations again, obtains batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 140 DEG C, captax BSPT and compound is added
Refining 80s is closed in anti-aging agent pressurization；When temperature reaches 150 DEG C, composite coupler pressurization is added and closes refining 45s；When temperature reaches 165 DEG C
When, Dow EPDM pressurizations are first added and close refining 16min, adds palygorskite powder and refining 4min is closed in brucite fiber pressurization, obtain
Mixed material B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 160 DEG C refines 45min, before conjunction refining terminates
Composite vulcanizing agent is added when 56s, obtains mixed material；Mixed material is delivered in double screw extruder extruding pelletization i.e. later
It can.
Comparative example 1
This comparative example is related to a kind of cable jacket material, and relative to embodiment 1, there is only the composition of fire retardant differences；
The fire retardant composition that this comparative example uses is zinc borate.
Comparative example 2
This comparative example is related to a kind of cable jacket material, and relative to embodiment 2, there is only the composition of anti-aging agent differences；
The fire retardant composition that this comparative example uses is antioxidant 4010NA.
Comparative example 3
This comparative example is related to a kind of cable jacket material, and relative to embodiment 3, there is only the composition of vulcanizing agent differences；
The fire retardant composition that this comparative example uses is sulphur.
Comparative example 4
This comparative example is related to a kind of cable jacket material, and relative to embodiment 4, there is only the composition of coupling agent differences；
The fire retardant composition that this comparative example uses is rare-earth coupling agent.
Comparative example 5
This comparative example is related to a kind of cable jacket material, and relative to embodiment 5, there is only the differences of preparation method；
The preparation method of this comparative example cable jacket material is as follows：
By except composite vulcanizing agent it is other it is all be added in kneading machine, heated up with the rate of 5 DEG C/min, in temperature
When reaching 85 DEG C, refining 10min is closed；When temperature reaches 120 DEG C, refining 25min is closed；When temperature reaches 155 DEG C, refining 80min is closed；Close refining
Composite vulcanizing agent is added in 56s before terminating, and closes refining and terminates to obtain mixed material, mixed material is delivered in double screw extruder later
Extruding pelletization.
Comparative example 6
This comparative example is related to a kind of commercially available common cable jacket material, including following raw material by weight：
65 parts of haloflex, 20 parts of nitrile rubber, 6 parts of EVA resin, 5 parts of dioctyl phthalate, calcium zinc stabilizer
2 parts, 1.5 parts of zinc stearate, 6 parts of high wear-resistant carbon black, 3 parts of aluminium hydroxide, 4 parts of sulfur sulfurizing agent, 3 parts of Vulcanization accelerator TMTD, silane
KH5501.5 parts of coupling agent.
Implementation result
To verify the advantageous effect of the present invention, cable jacket material test piece made from above-described embodiment 1-5 and comparative example 1-6 is taken
(embodiment 1-5 corresponds to the #1-#5 in table respectively, and comparative example 1-6 corresponds to the #6-#11 in table respectively) carries out such as the following table 6,7 institute of table
The index test shown.
Table 6：Embodiment is (in conjunction with reference to GB/T2951-2008《Cable and optical cable insulating sheath material GENERAL EXPERIMENTATION》)
Table 7：Comparative example is (in conjunction with reference to GB/T2951-2008《Cable and optical cable insulating sheath material GENERAL EXPERIMENTATION》)
By upper table 6 and the comparison of table 7 it is found that the comprehensive performance of cable jacket material made from the present embodiment is more excellent, application
Performance is more preferable, and useful life longevity is longer.
In conjunction with the excellent effect of the present invention, applicant is illustrated the constituent part and preparation method of the present invention：
(1) composite flame-retardant agent；Zinc borate is common inorganic combustion inhibitor, and originally, applicant singly utilizes it as the present invention's
When fire retardant, the effect that discovery obtains is not obvious, and finally by many experiments, is had been surprisingly found that organic matter tricresyl phosphate (2,3-
Two chloropropyls) ester, phosphoric acid (2- ethylhexyls)-diphenyl ester and zinc borate be according to mass ratio (1-2):(1-2):(2-3) combination profit
Fire retardant more conform to the present invention material system, and enable to finished sheath material have excellent heat-resisting quantity and
Anti-flammability；In development process, it is found for example that as other inorganic combustion inhibitors and above two organic matters such as aluminium hydroxide, iron oxide reds
The effect that the present invention is not achieved, the even change of organic matter and each component content is used in combination, and can not achieve this hair
Bright technique effect has unobviousness.
(2) complex antiager；Applicant has been surprisingly found that the association of antioxidant 4010NA and antioxidant MB in development process
With being used in combination, reaction system more is prepared suitable for the protective cover material of the present invention, uses above two composition according to mass ratio (3-
5):(2-3) is blended utilization, can significantly improve the inoxidizability, stability and service life of product；If this kind compound anti-
The content ratio of each composition changes in old agent, then can lead to the decline of protective cover material performance；If in this kind of complex antiager, will prevent
Old agent 4010NA or antioxidant MB are substituted for antioxidant 264, antioxidant 4020 etc., can cause beneficial effects of the present invention cannot
Preferably realize.
(3) composite vulcanizing agent；Zinc oxide, sulphur, dual-tert-butyl peroxy isopropyl base benzene are provided with certain cross-linking vulcanized work
With, but in order to adapt to the formation of reaction system of the invention, applicant dexterously uses above-mentioned composition according to mass ratio (1-2):
(1-3):(3-5) collaborative combination uses, and preferably makes to realize cross-linking reaction between raw material, and then reach space network, not only
The mechanical performance of protective cover material is significantly improved, the stability of product is also preferably improved, service life greatly prolongs；If should
The change of certain composition and its content, can influence the embodiment of advantageous effect of the present invention in kind composite vulcanizing agent.
(4) composite coupler：Silane series coupling agent is most common coupling agent in CABLE MATERIALS preparation process, is most being started
Research and development in, applicant is the coupling agent separately as the present invention by it, but obtained finished sheath material performance is not ideal enough,
It is difficult to reach beneficial effects of the present invention, then, applicant determines the composition for changing coupling agent, separately after considering various reasons
Ward off path, using rare-earth coupling agent as the coupling agent of the present invention because its not only Costco Wholesale is cheap, but also be particularly suitable for this hair
Bright reaction preparation system, it is possible to obtaining effect can get well than silane series coupling agent, however coupling agent improve after obtain at
The advantageous effect that product protective cover material obtains does not highlight, and later, applicant is again unexpected to expect tin coupled SSBR, by the way that tin to be coupled
Cleverly collaborative combination uses for SSBR and rare-earth coupling agent, obtains unexpected effect so that finished cable protective cover material exists
Have in mechanical properties and is obviously improved, and the combination of above-mentioned composition is non-obvious.
Certainly, because of the requirement of the mentality of designing and goal of the invention of cable jacket material of the present invention, remaining group sorting of the present invention
It selects and content selection is obviously also non-obvious, those skilled in the art combine the prior art that can readily occur in absolutely not.
This has further embodiment in the preparation method of protective cover material of the present invention, in conjunction with the embodiment of the present invention it can be seen that, the present invention
Preparation method designed using I-III three step, raw material is added by several times in batches, step is simple and orderly, rather than uses existing skill
Art is conventional to be added at one time, and this technique is adapted with the special proportioning of protective cover material raw materials for production component of the present invention, only
Have using this technique, just can guarantee the excellent specific property for the protective cover material finally prepared.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (10)
1. a kind of ageing-resistant cable jacket material, which is characterized in that including following raw material by weight：
58-64 parts of SG-4 polyvinyl chloride；
EPDM25-33 parts of Dow；
Isoprene -8-14 parts of styrene-methacrylate copolymer；
Fineness is 10-15 parts of the palygorskite powder of 200-300 mesh；
2.5-4 parts of the brucite fiber that chopped length is 800-1200 μm；
1-2 parts of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -0.5-1 parts of methyl diphenylene diisocyanates；
1.5-2.5 parts of pucherite；
BSPT1-1.5 parts of captax；
1-1.6 parts of composite flame-retardant agent；
0.7-1.1 parts of complex antiager；
1-2 parts of composite vulcanizing agent；
0.3-0.5 parts of composite coupler；
The composite vulcanizing agent is made of zinc oxide, sulphur, dual-tert-butyl peroxy isopropyl base benzene；
The composite coupler is made of tin coupled SSBR, rare-earth coupling agent.
2. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that by following original by weight
Material composition：
58 parts of SG-4 polyvinyl chloride；
EPDM25 parts of Dow；
Isoprene -8 parts of styrene-methacrylate copolymer；
Fineness is 10 parts of the palygorskite powder of 200 mesh；
2.5 parts of the brucite fiber that chopped length is 800 μm；
1 part of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -0.5 part of methyl diphenylene diisocyanates；
1.5 parts of pucherite；
BSPT1 parts of captax；
1 part of composite flame-retardant agent；
0.7 part of complex antiager；
1 part of composite vulcanizing agent；
0.3 part of composite coupler.
3. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that by following original by weight
Material composition：
64 parts of SG-4 polyvinyl chloride；
EPDM33 parts of Dow；
Isoprene -4 parts of styrene-methacrylate copolymer 1；
Fineness is 15 parts of the palygorskite powder of 300 mesh；
4 parts of the brucite fiber that chopped length is 1200 μm；
2 parts of phosphorous acid three (2,4- di-tert-butyl-phenyls) ester；
4,4 ' -1 part of methyl diphenylene diisocyanates；
2.5 parts of pucherite；
BSPT1.5 parts of captax；
1.6 parts of composite flame-retardant agent；
1.1 parts of complex antiager；
2 parts of composite vulcanizing agent；
0.5 part of composite coupler.
4. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that the preparation method of the protective cover material
It is as follows：
Ⅰ：Kneading machine is preheated to 48 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenylmethane diisocyanates
Ester, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 3min, and the OPE waxes of weight of material 30%, then slowly heating is added
To 75 DEG C, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 6min, then holds again
It is continuous to be warming up to 115 DEG C of pressurization conjunction refining 15min, obtain batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 130 DEG C, captax BSPT and compound anti-old is added
Refining 100s is closed in agent pressurization；When temperature reaches 140 DEG C, composite coupler pressurization is added and closes refining 55s；When temperature reaches 155 DEG C,
Dow EPDM pressurizations are first added and close refining 20min, adds palygorskite powder and refining 6min is closed in brucite fiber pressurization, obtain batch mixing
B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 150 DEG C refines 55min, when closing 52s before refining terminates
Composite vulcanizing agent is added, obtains mixed material；Mixed material is delivered to extruding pelletization in double screw extruder later.
5. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that the preparation method of the protective cover material
It is as follows：
Ⅰ：Kneading machine is preheated to 52 DEG C, takes phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, 4,4 '-diphenylmethane diisocyanates
Ester, pucherite, composite flame-retardant agent, which are added in kneading machine, closes refining 3min, and the OPE waxes of weight of material 40%, then slowly heating is added
To 85 DEG C, SG-4 polyvinyl chloride is added and isoprene-styrene-methacrylate copolymer closes refining 4min, then holds again
It is continuous to be warming up to 125 DEG C of pressurization conjunction refining 10min, obtain batch mixing A；
Ⅱ：Batch mixing A is slowly heated up in kneading machine, when temperature reaches 140 DEG C, captax BSPT and compound anti-old is added
Refining 80s is closed in agent pressurization；When temperature reaches 150 DEG C, composite coupler pressurization is added and closes refining 45s；When temperature reaches 165 DEG C,
Dow EPDM pressurizations are first added and close refining 16min, adds palygorskite powder and refining 4min is closed in brucite fiber pressurization, obtain batch mixing
B；
Ⅲ：Mixed material B is taken to be added in kneading machine, pressurization, which is closed, under the conditions of temperature is 160 DEG C refines 45min, when closing 56s before refining terminates
Composite vulcanizing agent is added, obtains mixed material；Mixed material is delivered to extruding pelletization in double screw extruder later.
6. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that the composite flame-retardant agent is phosphoric acid
Three (2,3- bis- chloropropyl) esters, phosphoric acid (2- ethylhexyls)-diphenyl ester, zinc borate in mass ratio 1:1:2 are fully blended to obtain.
7. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that the complex antiager is anti-old
Agent 4010NA, antioxidant MB in mass ratio 3:2 are fully blended to obtain.
8. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that the composite vulcanizing agent is oxidation
Zinc, sulphur, dual-tert-butyl peroxy isopropyl base benzene in mass ratio 1:1:3 are fully blended to obtain.
9. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that the composite coupler is that tin is even
Join SSBR, rare-earth coupling agent in mass ratio 2:1 is fully blended to obtain.
10. a kind of ageing-resistant cable jacket material according to claim 1, which is characterized in that the composite coupler is tin
It is coupled SSBR, rare-earth coupling agent in mass ratio 2.5:1.5 are fully blended to obtain.
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| CN201810679602.2A CN108752809A (en) | 2018-06-27 | 2018-06-27 | A kind of ageing-resistant cable jacket material |
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| CN201810679602.2A CN108752809A (en) | 2018-06-27 | 2018-06-27 | A kind of ageing-resistant cable jacket material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396255A (en) * | 2019-06-25 | 2019-11-01 | 安徽上华电缆有限公司 | A kind of anti-aging cable material of oil resistant and preparation method thereof |
| CN112126175A (en) * | 2020-09-25 | 2020-12-25 | 镇江市华银仪表电器有限公司 | Radiation-resistant rubber cable sheath material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107082968A (en) * | 2017-07-03 | 2017-08-22 | 合肥市大卓电力有限责任公司 | A kind of cable jacket material and preparation method thereof |
| CN108690297A (en) * | 2018-06-25 | 2018-10-23 | 合肥东恒锐电子科技有限公司 | A kind of thermal stress cracking cable protecting pipe material |
-
2018
- 2018-06-27 CN CN201810679602.2A patent/CN108752809A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107082968A (en) * | 2017-07-03 | 2017-08-22 | 合肥市大卓电力有限责任公司 | A kind of cable jacket material and preparation method thereof |
| CN108690297A (en) * | 2018-06-25 | 2018-10-23 | 合肥东恒锐电子科技有限公司 | A kind of thermal stress cracking cable protecting pipe material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396255A (en) * | 2019-06-25 | 2019-11-01 | 安徽上华电缆有限公司 | A kind of anti-aging cable material of oil resistant and preparation method thereof |
| CN112126175A (en) * | 2020-09-25 | 2020-12-25 | 镇江市华银仪表电器有限公司 | Radiation-resistant rubber cable sheath material |
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