CN108752783A - A kind of heat preservation and soundproof PVC sidings and preparation method thereof - Google Patents

A kind of heat preservation and soundproof PVC sidings and preparation method thereof Download PDF

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Publication number
CN108752783A
CN108752783A CN201810483614.8A CN201810483614A CN108752783A CN 108752783 A CN108752783 A CN 108752783A CN 201810483614 A CN201810483614 A CN 201810483614A CN 108752783 A CN108752783 A CN 108752783A
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pvc
soundproof
heat preservation
sidings
foam device
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陈新霞
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0028Use of organic additives containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • C08J9/0071Nanosized fillers, i.e. having at least one dimension below 100 nanometers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0095Mixtures of at least two compounding ingredients belonging to different one-dot groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/104Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof
    • C08J9/105Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/04N2 releasing, ex azodicarbonamide or nitroso compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04Polysiloxanes

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Abstract

A kind of heat preservation and soundproof PVC sidings of present invention offer and preparation method thereof, one of which heat preservation and soundproof PVC sidings are made of following material:PVC powder;Silicon rubber;Isocyanates;Ginger powder;Nano silver part;Graphene;Vitamin E;Foaming agent;Stabilizer.Heat preservation and soundproof PVC sidings provided by the invention have good heat-insulating property, mechanical property, thermal stability, elastic property, sterilization and bacteriostasis property.In addition, the heat preservation and soundproof PVC sidings that the preparation method in addition provided through the invention is prepared have layering porous structure, the sound wave of different frequency can effectively be completely cut off by being layered porous structure, to make siding provided by the invention that there is excellent soundproof effect.

Description

A kind of heat preservation and soundproof PVC sidings and preparation method thereof
Technical field
The present invention relates to siding field, more particularly to a kind of heat preservation and soundproof PVC sidings and preparation method thereof.
Background technology
Siding is mainly the revetment or decorative wall panel that people work it out according to the needs of wall.Skirting currently on the market Predominantly solid wood board, composite plate, based on ceramic tile, be widely used in fields such as building, fresh-keeping transport, submarine heat preservations.Porcelain plate Too transport is inconvenient again for quality, easy fragmentation, difficult to install;It is solid wood board and composite plate lighter weight, non-breakable, but solid wood board and Composite plate needs higher environment installation requirement;When environment temperature is excessively moist, such as bathroom environment, solid wood board and composite plate Surface is easy attachment organic matter, mould growth, and user needs often to clean, and could keep cleaning.
Invention content
To solve the problem of that siding is easy attachment organic matter mould growth in above-mentioned background technology, the present invention provides a kind of Heat preservation and soundproof PVC sidings and preparation method thereof, one of which heat preservation and soundproof PVC sidings, the material matched by following parts by weight It is made:
Further, the material that the siding is matched by following parts by weight is made:
Further, the stabilizer is calcium-zinc composite stabilizing agent.
Further, the foaming agent has at least two fineness;The blowing temperature of different fineness foaming agent is different.
Heat preservation and soundproof PVC sidings provided by the invention, by isocyanates, a small amount of vitamin E, stabilizer to PVC materials Material is modified, to improve mechanics and thermal stability;Inventor in silicon rubber it was unexpectedly observed that add a small amount of Vitamin E can solve the problems, such as silicon rubber anti-tensile force difference, bring unexpected effect.It is improved by graphene hydrophobic Performance, and by the sterilization and bacteriostasis effect of nano silver and ginger powder, to avoid the attachment and growth of mould.Pass through isocyanic acid The PVC foam body that ester and silicon rubber are modified, is greatly improved in terms of elastic property;When panel surfaces are by big pressure When (such as submarine, with the increase of submerged depth, the heat preservation siding of submarine side wall is necessarily by the pressure of bigger), can keep away Exempt from heat preservation siding and the problem of crushing occurs due to the increase of pressure in dive process.
The present invention additionally provides a kind of preparation method of heat preservation and soundproof PVC sidings, the method step is specific as follows;
Step 1 will uniformly mix in PVC powder, silicon rubber and graphene input layering foam device, and then layering is foamed Device is warming up to 150 DEG C of -200 DEG C of reaction 1h-2h;
The reaction temperature for being layered foam device is down to 70 DEG C -100 DEG C by step 2, input ginger powder, nano silver and Wei Sheng Plain E reacts 0.5h-1h;
The cavity upper layer temperature of the layering foam device is set as T1 by step 3;By the cavity of the layering foam device Lower layer's temperature is set as T2;
Step 4 continues input isocyanates, foaming agent and stabilizer foaming 11h-20h in layering foam device, is formed Foamed product;
Step 5, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
Further, the T1 in the step 4 is 150 DEG C -300 DEG C;T2 is 150 DEG C -300 DEG C;The T1 is more than or small In the T2.
Further, the layering foam device includes capping and the back cover of cavity and its both ends connection;Wherein:
The cavity wall is by least two pieces of heating boards;The heating board, temperature lowering board, capping and back cover temperature in Centre control system controls respectively.
Further, at least one piece of heating board side wall is equipped with cooling chamber;The cooling chamber is connect with refrigerating plant.
The preparation method of heat preservation and soundproof PVC sidings provided by the invention, the thermal insulation separation prepared by being layered foam device Sound PVC sidings have layering porous structure, the pore size on every aspect different;It can be right by being layered porous structure siding The sound wave of different frequency is effectively completely cut off, to make siding provided by the invention have excellent soundproof effect.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is this hair Some bright embodiments for those of ordinary skill in the art without creative efforts, can be with root Other attached drawings are obtained according to these attached drawings.
Fig. 1 is one diagrammatic cross-section of layering foam device provided by the invention;
Fig. 2 is the layered structure schematic diagram of heat preservation and soundproof PVC sidings.
Reference numeral:
10 cavity, 11 first heating board, 12 second heating board
13 cooling chambers 20 cover 30 back covers
40 refrigerating plants
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention In attached drawing, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art The every other embodiment obtained without creative efforts, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that term "center", " longitudinal direction ", " transverse direction ", "upper", "lower", The orientation or positional relationship of the instructions such as "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside" is It is based on the orientation or positional relationship shown in the drawings, is merely for convenience of description of the present invention and simplification of the description, rather than instruction or dark Show that signified device or element must have a particular orientation, with specific azimuth configuration and operation, therefore should not be understood as pair The limitation of the present invention.In addition, term " first ", " second " and similar word are used for description purposes only, and should not be understood as Instruction implies relative importance." connection " the either similar word such as " connected " and non-limiting connection with physics or machinery, But may include electrical connection, light connects etc., either directly or indirectly.
The present invention provides embodiment as shown in Table 1:
Table 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
PVC powder 30 parts 35 parts 34 parts 36 parts 40 parts
Silicon rubber 15 parts 20 parts 23 parts 25 parts 30 parts
Isocyanates 22 parts 20 parts 24 parts 26 parts 30 parts
Ginger powder 0.8 part 1.5 part 2 parts 3 parts 1 part
Nano silver 0.1 part 0.2 part 0.3 part 0.5 part 0.4 part
Graphene 0.5 part 1 part 1.5 part 3 parts 2 parts
Vitamin E 0.1 part 0.3 part 0.2 part 0.4 part 0.5 part
Foaming agent 8 parts 10 parts 11 parts 12 parts 15 parts
Stabilizer 10 parts 13 parts 15 parts 17 parts 20 parts
Preferably, stabilizer is calcium-zinc composite stabilizing agent;
Preferably, the isocyanates is diisocyanate or polyisocyanates;
Preferably, the foaming agent has at least two fineness;The blowing temperature of different fineness foaming agent is different.
Preferably, the foaming agent is azodicarbonamide and benzene sulfonyl hydrazide;The azodicarbonamide, benzene sulfonyl hydrazide Fineness is different.The fineness of azodicarbonamide is 0.5 μm -1 μm, and the fineness of sulfohydrazide is 0.4 μm -0.8 μm.Azodicarbonamide It is different with the blowing temperature of benzene sulfonyl hydrazide;The proportioning of the azodicarbonamide and benzene sulfonyl hydrazide is 1:1.
The present invention provides the preparation method of heat preservation and soundproof PVC sidings, specific as follows:
Embodiment 1
Step 1 will uniformly mix in 30 parts of PVC powders, 15 parts of silicon rubber and 0.5 part of graphene input layering foam device, Then layering foam device is warming up to 150 DEG C of reaction 2h;
The reaction temperature for being layered foam device is down to 70 DEG C by step 2,0.8 part of ginger powder of input, 0.1 part of nano silver and 0.1 part of vitamin E reacts 1h;
The cavity upper layer temperature of the layering foam device is set as 150 DEG C by step 3;By the layering foam device Cavity lower layer temperature is set as 200 DEG C;
Step 4 continues 22 parts of isocyanates of input, 8 parts of foaming agents and 10 parts of stabilizer foaming in layering foam device 11h forms foamed product;
Step 5, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
Embodiment 2
Step 1 will uniformly mix in 35 parts of PVC powders, 20 parts of silicon rubber and 1 part of graphene input layering foam device, so Layering foam device is warming up to 200 DEG C of reaction 1h afterwards;
The reaction temperature for being layered foam device is down to 100 DEG C by step 2,1.5 parts of ginger powders of input, 0.2 part of nano silver and 0.3 part of vitamin E reacts 0.5h;
The cavity upper layer temperature of the layering foam device is set as 200 DEG C by step 3;By the layering foam device Cavity lower layer temperature is set as 300 DEG C;
Step 4 continues 20 parts of isocyanates of input, 10 parts of foaming agents and 13 parts of stabilizer foaming in layering foam device 20h forms foamed product;
Step 5, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
Embodiment 3
Step 1 will uniformly mix in 34 parts of PVC powders, 23 parts of silicon rubber and 1.5 parts of graphene input layering foam devices, Then layering foam device is warming up to 160 DEG C of reaction 1.5h;
The reaction temperature for being layered foam device is down to 80 DEG C by step 2,2 parts of ginger powders of input, 0.3 part of nano silver and 0.2 Part vitamin E reacts 0.8h;
The cavity upper layer temperature of the layering foam device is set as 150 DEG C by step 3;By the layering foam device Cavity lower layer temperature is set as 200 DEG C;
Step 4 continues input isocyanates, foaming agent and stabilizer foaming 15h in layering foam device, forms foaming Product;
Step 5, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
Embodiment 4
Step 1 will uniformly mix in 36 parts of PVC powders, 25 parts of silicon rubber and 3 parts of graphene input layering foam devices, so Layering foam device is warming up to 150 DEG C of reaction 2h afterwards;
The reaction temperature for being layered foam device is down to 100 DEG C by step 2,3 parts of ginger powders of input, 0.5 part of nano silver and 0.4 part of vitamin E reacts 0.5h;
The cavity upper layer temperature of the layering foam device is set as 300 DEG C by step 3;By the layering foam device Cavity lower layer temperature is set as 200 DEG C;
Step 4 continues 26 parts of isocyanates of input, 12 parts of foaming agents and 17 parts of stabilizer foaming in layering foam device 11h forms foamed product;
Step 5, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
Embodiment 5
Step 1 will uniformly mix in 40 parts of PVC powders, 30 parts of silicon rubber and 2 parts of graphene input layering foam devices, so Layering foam device is warming up to 200 DEG C of reaction 1h afterwards;
The reaction temperature for being layered foam device is down to 100 DEG C by step 2,1 part of ginger powder of input, 0.4 part of nano silver and 0.5 part of vitamin E reacts 0.5h;
The cavity upper layer temperature of the layering foam device is set as 230 DEG C by step 3;By the layering foam device Cavity lower layer temperature is set as 300 DEG C;
Step 4 continues 30 parts of isocyanates of input, 15 parts of foaming agents and 20 parts of stabilizer foaming in layering foam device 18h forms foamed product;
Step 5, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
To examine the application of heat preservation and soundproof PVC sidings provided by the invention in practice, respectively to embodiment 1, embodiment 2, the heat preservation and soundproof PVC sidings in embodiment 3, embodiment 4 and embodiment 5 are tested as follows, and with Shandong Zouping profit Believe that the PVC series insulating plates of Co., Ltd's production are comparative example 1.Test result is as shown in table 2:
Table 2
Soundproof effect test method is:Sound source decibel is detected by decibel detector with through the sound after thermal insulation board to divide Shellfish;Then the numerical value surveyed is subtracted each other to obtain the i.e. noise reduction decibel of the two, the more high then soundproof effect of noise reduction decibel is better.
Anti-mold effect test method is as follows:By the heat preservation in heat preservation and soundproof PVC sidings provided by the invention and comparative example 1 Plate is separately positioned in the environment that temperature is 25 DEG C, air humidity is 80%, and observes the mouldy of each thermal insulation board after 15 days Situation:Level-one is no Signs of Mould;The mouldy area of two level is 1%-20%;The mouldy area of three-level is 21%-40%;Level Four Mouldy area be 41%-70%;The mouldy area of Pyatyi is 71%-100%, and the lower anti-mold effect of series is better.
The testing standard of thermal coefficient is GBT 6343-2009.
The testing standard of compression strength is GB/T8813-1988.
As shown in Table 2, the soundproof effect of the embodiment of the present invention 1, embodiment 2, embodiment 3, embodiment 4 and embodiment 5 is equal Reach 41.6dB or more, and the soundproof effect in comparative example 1 is only 32.1dB;It can be seen that heat preservation and soundproof provided by the invention The soundproof effect of PVC sidings is apparent excellent in comparative example 1.Also, as shown in various embodiments of the present invention test result, the present invention is real Apply the 400KPa that the compression strength in example is above in comparative example 1, it is seen that the present invention is effectively improved by being modified to PVC Compression strength.
In addition, the thermal coefficient in the embodiment of the present invention 1, embodiment 2, embodiment 3, embodiment 4 and embodiment 5 is respectively 0.051w/m.k, 0.056w/m.k, 0.052w/m.k, 0.054w/m.k and 0.053w/m.k, respectively less than in comparative example 1 0.079w/m.k.It can be seen that the soundproof effect of heat preservation and soundproof PVC sidings provided by the invention is substantially better than the sound insulation effect of comparative example 1 Fruit.
Mould proof survey in 15 days and 30 days in the embodiment of the present invention 1, embodiment 2, embodiment 3, embodiment 4 and embodiment 5 It is level-one to try effect, without Signs of Mould;And there is Signs of Mould after testing 15 days in the siding in comparative example 1, and Signs of Mould aggravates after 30 days.It can be seen that heat preservation and soundproof PVC sidings provided by the invention, can effectively press down mycostatic production It is raw, to avoid the problem that siding is infected by mould and leads to reduced lifetime.
Heat preservation and soundproof PVC sidings provided by the invention, by isocyanates, a small amount of vitamin E, stabilizer to PVC materials Material is modified, to improve mechanics and thermal stability;Inventor in silicon rubber it was unexpectedly observed that add a small amount of Vitamin E can solve the problems, such as silicon rubber anti-tensile force difference, to improve the connection tension between hole;By connecting between hole The raising for connecing tension, greatly strengthens soundproof effect.Hydrophobic performance is improved by graphene, and passes through nano silver and ginger powder Sterilization and bacteriostasis effect, to avoid the attachment and growth of mould.The heat preservation that the present invention is prepared by being layered foam device Sound insulation PVC sidings have layering porous structure, the pore size on every aspect different;It can be to not by being layered porous structure The sound wave of same frequency is effectively completely cut off, to make siding provided by the invention have excellent soundproof effect.
Preferably, the heat preservation and soundproof PVC sidings further include the material of following parts by weight proportioning:
8 parts -12 parts of hyaluronic acid
2 parts -5 parts of apricot kernel oil.
The hyaluronic acid of following mass fraction and apricot kernel oil are separately added into each embodiment 1, embodiment 2, embodiment 3, reality It applies in example 4 and embodiment 5;
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Hyaluronic acid 8 parts 11 parts 10 parts 9 parts 12 parts
Apricot kernel oil 5 parts 3 parts 2.5 part 3.5 part 4 parts
The adding method of hyaluronic acid and apricot kernel oil is as follows:
Step 1 will uniformly mix in PVC powder, silicon rubber and graphene input layering foam device, and then layering is foamed Device is warming up to 150 DEG C of -200 DEG C of reaction 1h-2h;
The reaction temperature for being layered foam device is down to 70 DEG C -100 DEG C by step 2, input ginger powder, nano silver and Wei Sheng Plain E reacts 0.5h-1h;The reaction temperature for being layered foam device is down to 50 DEG C -80 DEG C, input hyaluronic acid reacts 0.5h-1h, Apricot kernel oil reaction 0.5h-1h is put into again;
The cavity upper layer temperature of the layering foam device is set as T1 by step 3;By the cavity of the layering foam device Lower layer's temperature is set as T2;
Step 4 continues input isocyanates, foaming agent and stabilizer foaming 11h-20h in layering foam device, is formed Foamed product;
Step 5, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
Shown by testing, ensureing soundproof effect, compression strength, thermal coefficient and anti-mold effect, under by hyaluronic acid Heat preservation and soundproof PVC sidings are modified with apricot kernel oil modification, the interlayer faults rate of heat preservation and soundproof PVC sidings is made to reduce 50%-57% effectively reduces the probability that the fracture of different pore size level occurs in process of production.Also, inventor has found, passes through The synergistic effect of hyaluronic acid and apricot kernel oil can delay the aging of heat preservation and soundproof PVC sidings;It is aobvious by accelerated ageing test Show, the siding of hyaluronic acid and apricot kernel oil is added in heat preservation and soundproof PVC sidings provided by the invention and is not added with hyaluronic acid It is compared with the siding of apricot kernel oil, average life increases 1 times -1.2 times, significantly improves making for high temperature acoustic PVC sidings Use the service life.
The present invention additionally provides a kind of preparation method of heat preservation and soundproof PVC sidings is specific as follows:
Step 1 will uniformly mix in PVC powder, silicon rubber and graphene input layering foam device, and then layering is foamed Device is warming up to 150 DEG C of -200 DEG C of reaction 1h-2h;
The reaction temperature for being layered foam device is down to 70 DEG C -100 DEG C by step 2, input ginger powder, nano silver and Wei Sheng Plain E reacts 0.5h-1h;The reaction temperature for being layered foam device is down to 50 DEG C -80 DEG C, input hyaluronic acid reacts 0.5h-1h, Apricot kernel oil reaction 0.5h-1h is put into again;
The cavity upper layer temperature of the layering foam device is set as T1 by step 3;By the cavity of the layering foam device Lower layer's temperature is set as T2;
Step 4, input isocyanates, foaming agent and stabilizer foaming 11h-20h, form foamed product;
Step 5, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
Before above-mentioned steps 1, installation environment frequency noise can be acquired by frequency collection device, and acquire siding position Sound insulation data;Wherein, installation environment frequency noise is acquired by frequency collection device, if the installation site of siding is bathroom When, then collected frequency is mainly the frequency of the bathing underwater sound and/or the sound frequency that closestool draws water;In addition, decibel detector Acquire the soundproof effect data of siding position;As siding be mounted on build a wall with bricks or alloy sheets on when, pass through decibel detector point Not Ce Liang sound source and through the sound decibel after masonry walls or alloy sheets, the two, which is subtracted each other, can export masonry walls or alloy sheets Soundproof effect;
Preferably, passing through frequency and/or soundproof effect under the various environment that the various sidings of acquisition are installed to establish big number According to library.In large database concept, corresponding frequency and/or soundproof effect data may bring up by input environment parameter, make data It obtains more simple and efficient.
Above-mentioned layering foam device is as shown in Figure 1, the capping 20 including cavity 10 and its both ends connection and back cover 30;Its In:
10 side wall of the cavity is made of at least two pieces of heating boards;Each heating board, the hair for covering 20 and back cover 30 Hot temperature is controlled respectively by central control system.
Preferably, 10 side wall of the cavity is made of the first heating board 11 and the first heating board 12 being arranged below;Institute The space for stating capping 20 and the formation of the first heating board 11 is the upper layer for being layered foam device, temperature T1;30 He of the back cover The space that second heating board 12 is formed is the lower layer for being layered foam device, temperature T2;First heating board 11, second is sent out Hot plate 12, capping 20 and back cover 30 are made of electrically conductive exothermic material, such as copper, iron and aluminium;First heating board 11, second Heating board 12, capping 20 and back cover 30 control control heating temperature by central control system;Central control system is computer visitor Family end or other intelligent operation clients.By being layered the foaming of foam device, make the hair of layering foam device the upper and lower It is different to steep temperature, to the different layered structure of the pore size for the every aspect that foams out (as shown in Figure 2).
Further, 12 side wall of the heating board is equipped with cooling chamber 13;The cooling chamber 13 is connect with refrigerating plant 40.Drop Warm chamber 13 is looped around on 12 side wall of heating board, and cooling chamber 13 is connect with 40 pipeline of refrigerating plant;Refrigerating plant 40 is controlled with center System communication connects;Refrigerating plant 40 is to prepare thermantidote, including but not limited to air-conditioning;The cold air that refrigerating plant 40 is prepared Entered in cooling chamber 13 by pipeline.When central control system controls temperature T2 sizes, central control system controls heating board 12 stop fever, and control refrigerating plant 40 and prepare cold air and be conducted in cooling chamber 13;By cold air come regulation heating plate 12 temperature, to carry out fast cooling adjusting to temperature T2.
The preparation method of heat preservation and soundproof PVC sidings provided by the invention is determined by the acquisition of environmental parameter, can make this It is more targeted to invent the heat preservation and soundproof PVC sidings prepared;The heat preservation and soundproof PVC walls prepared by being layered foam device Plate has layering porous structure, the pore size on every aspect different;It can be to different frequencies by being layered porous structure siding The sound wave of rate is effectively completely cut off, to make siding provided by the invention have excellent soundproof effect.
Although more herein used the terms such as cavity, heating board, capping and back cover, use is not precluded The possibility of other terms.The use of these items is only for more easily describe and explain the essence of the present invention;Them Any one of the additional limitations is construed to all to disagree with spirit of that invention.
Finally it should be noted that:The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that:Its according to So can with technical scheme described in the above embodiments is modified, either to which part or all technical features into Row equivalent replacement;And these modifications or replacements, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution The range of scheme.

Claims (8)

1. a kind of heat preservation and soundproof PVC sidings, it is characterised in that:The material that the siding is matched by following parts by weight is made:
2. heat preservation and soundproof PVC sidings according to claim 1, it is characterised in that:The siding is matched by following parts by weight The material of ratio is made:
3. heat preservation and soundproof PVC sidings according to claim 1, it is characterised in that:The stabilizer is stablized for Ca Zn composite Agent.
4. heat preservation and soundproof PVC sidings according to claim 1, it is characterised in that:The foaming agent is thin at least two Degree;The blowing temperature of different fineness foaming agent is different.
5. a kind of preparation method of heat preservation and soundproof PVC sidings, it is characterised in that:The method step is specific as follows;
Step 1 will uniformly mix in PVC powder, silicon rubber and graphene input layering foam device, then will be layered foam device It is warming up to 150 DEG C of -200 DEG C of reaction 1h-2h;
The reaction temperature for being layered foam device is down to 70 DEG C -100 DEG C by step 2, and input ginger powder, nano silver and vitamin E are anti- Answer 0.5h-1h;
The reaction temperature for being layered foam device is down to 50 DEG C -80 DEG C by step 3, and input hyaluronic acid reacts 0.5h-1h, then throws Enter apricot kernel oil reaction 0.5h-1h;
The cavity upper layer temperature of the layering foam device is set as T1 by step 4;By the cavity lower layer of the layering foam device Temperature is set as T2;
Step 5 continues input isocyanates, foaming agent and stabilizer foaming 11h-20h in layering foam device, forms foaming Product;
Step 6, the foamed product are squeezed out by extruder, form the heat preservation and soundproof PVC sidings.
6. the preparation method of heat preservation and soundproof PVC sidings according to claim 5, it is characterised in that:T1 in the step 4 It is 150 DEG C -300 DEG C;T2 is 150 DEG C -300 DEG C;The T1 is more than or less than the T2.
7. the preparation method of heat preservation and soundproof PVC sidings according to claim 6, it is characterised in that:The layering foaming dress Set the capping (20) including cavity (10) and its both ends connection and back cover (30);Wherein:
Cavity (10) side wall is by least two pieces of heating boards;The heating board, temperature lowering board, capping (20) and back cover (30) temperature Degree is controlled respectively by central control system.
8. the preparation method of heat preservation and soundproof PVC sidings according to claim 6, it is characterised in that:At least one piece of hair Hot plate side wall is equipped with cooling chamber (13);The cooling chamber (13) connect with refrigerating plant (40).
CN201810483614.8A 2018-05-19 2018-05-19 A kind of heat preservation and soundproof PVC sidings and preparation method thereof Pending CN108752783A (en)

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Publication number Priority date Publication date Assignee Title
CN101443395A (en) * 2005-11-30 2009-05-27 Lg化学株式会社 Microcellular foam of thermoplastic resin prepared with die having improved cooling property and method for preparing the same
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Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN101443395A (en) * 2005-11-30 2009-05-27 Lg化学株式会社 Microcellular foam of thermoplastic resin prepared with die having improved cooling property and method for preparing the same
CN108003405A (en) * 2017-11-29 2018-05-08 国网湖南省电力有限公司 Flexible sound-absorbing material and its preparation method and application

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Application publication date: 20181106