CN108751869A - A kind of permeable crystallization type self-repair concrete structure and preparation method thereof - Google Patents

A kind of permeable crystallization type self-repair concrete structure and preparation method thereof Download PDF

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Publication number
CN108751869A
CN108751869A CN201810819124.0A CN201810819124A CN108751869A CN 108751869 A CN108751869 A CN 108751869A CN 201810819124 A CN201810819124 A CN 201810819124A CN 108751869 A CN108751869 A CN 108751869A
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CN
China
Prior art keywords
sodium metasilicate
concrete
particle
crystalline material
renovation agent
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Pending
Application number
CN201810819124.0A
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Chinese (zh)
Inventor
吕宏鑫
李静
陈连佳
甘振先
陈万昕
李小雨
冯伟浩
高嘉欣
戚桠童
韦欣怡
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South China University of Technology SCUT
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South China University of Technology SCUT
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Priority to CN201810819124.0A priority Critical patent/CN108751869A/en
Publication of CN108751869A publication Critical patent/CN108751869A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1018Coating or impregnating with organic materials
    • C04B20/1029Macromolecular compounds
    • C04B20/1048Polysaccharides, e.g. cellulose, or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of permeable crystallization type self-repair concrete structure, including concrete component, penetrant crystalline material granule and sodium metasilicate renovation agent particle are evenly arranged in the concrete component, the sodium metasilicate renovation agent particle is in microcapsule structure.The present invention also provides a kind of production methods of permeable crystallization type self-repair concrete.The present invention can improve the mechanical property and water impermeability of concrete structure, and the ability for making it have damage self-repairing, to improve concrete structure safety, durability and economy.

Description

A kind of permeable crystallization type self-repair concrete structure and preparation method thereof
Technical field
The present invention relates to a kind of permeable crystallization type self-repair concrete structure and preparation method thereof, including concrete component, Belong to self-repair concrete and its similar building material field.
Background technology
Concrete is split during normal be on active service since the factors such as environment and fatigue damage inevitably result from Seam, these cracks provide the channel into inside concrete for extraneous harmful substance, and then accelerate the corrosion of internal reinforcing bar, Reduce safety and the durability of concrete structure.For fully developed macrocrack, we can easily use meat Outlook is other, and utilizes traditional means, i.e., structure reinforcing method, grouting method, completion method etc. carry out the reparation in later stage;And for small Crack is difficult to be detected accurately and in time under existing Detection Techniques, and repairing means using traditional crack at this time reaches Less than repairing effect, the micro crack for failing effectively to be repaired in time can not only influence normal use performance and the shortening of structure Service life, it is also possible to be further development of macrocrack and structural fragility is caused to be broken, generate serious catastrophic failure.More Important to be, conventional fracture repairing means cost is very high, expends a large amount of manpower and materials.Meanwhile for waterproof requirements such as tunnels Higher structure, concrete used are required have good water impermeability, with ensure the isostructural durability in tunnel and Safety.
Invention content
In view of this, the present invention caters to the actual needs of building materials Intellectualized Tendency, engineering safety and durability, one kind is provided Permeable crystallization type self-repair concrete structure and preparation method thereof.
The present invention is realized using following scheme:
A kind of permeable crystallization type self-repair concrete structure, including concrete component are evenly arranged in the concrete component Penetrant crystalline material granule and sodium metasilicate renovation agent particle, the sodium metasilicate renovation agent particle are in microcapsule structure.
Further, the core materials of the sodium metasilicate renovation agent particle are anhydrous sodium metasilicate, and cyst material is ethyl Cellulose.
Further, the penetrant crystalline material granule is activated silica penetrant crystalline masterbatch.
Further, the sodium metasilicate renovation agent particle is the sheet-like particle of a diameter of 5 ~ 6mm.
A kind of production method of such as self-repair concrete structure, including step:
Step 1:Make sodium metasilicate renovation agent particle;
Step 2:Concrete mix is designed, determines penetrant crystalline material granule and sodium metasilicate renovation agent particle volume, wherein institute It is 1.85% ~ 2.15% to state penetrant crystalline material granule substitution cement proportion, the sodium metasilicate renovation agent particle volume and body of cement Product is than being 4.0% ~ 4.5%;
Step 3:Concrete on casting concrete component, and conserve molding.
Further, the step 1 specifically includes:
Step 11:Ethyl alcohol is poured into a reservoir, then ethyl cellulose is poured into container, is mixed evenly, is made ethyl cellulose Dissolving;
Step 12:Anhydrous sodium metasilicate is poured into container again, stirring makes to be uniformly mixed;
Step 13:Heat container, accelerating alcohol volatilization, to obtain solid matter;
Step 14:Solid matter is broken into the sheet-like particle of a diameter of 5 ~ 6mm, the sodium metasilicate renovation agent as actually used Grain.
Further, in the step 2, when the strength grade of the concrete component is C40, its slump be 160 ~ When 200mm, cement consumption is 228 ~ 243 parts, fine aggregate dosage is 700 ~ 750 parts, coarse aggregate dosage is 1060 ~ 1100 parts, water Dosage is 156 ~ 160 parts, flyash dosage is 111 ~ 114 parts, 40 ~ 43 parts of water-reducing agent dosage.
Further, the cement is 42.5 Portland cements of PO;The flyash is to meet international GB/ II grade of fly ash in electric power plant of 2005 standards of T1506-;The lime stone rubble of 5 ~ 16mm of coarse aggregate continuous gradings;It is described Fine aggregate is sand in natural river sand and IIth area;The polycarboxylate water-reducer that the water-reducing agent water-reducing rate is 30% and solid content is 40%.
Further, the density of the penetrant crystalline material granule is 2000 ~ 2100kg/m 3
Further, in step 3, the sodium metasilicate renovation agent composite particles uniformly mix concrete in the form of aggregate In, it is mixed in concrete together with the penetrant crystalline material granule and cement, the concrete component uses self-compaction coagulation Soil, the without vibration in casting process.
Compared with prior art, the present invention improves the mechanical property and water impermeability of concrete structure, while also assigning The ability for having given concrete damage selfreparing has just carried out being directed to and effectively inhibit, greatly in the early stage of development of distress in concrete The big later stage for reducing crack repairs generated great number cost, greatly improves durability, the safety of concrete structure And economy.
Description of the drawings
Fig. 1 is the organigram of the self-repair concrete structure of the embodiment of the present invention.
Fig. 2 is the organigram of the sodium metasilicate renovation agent microcapsules of the embodiment of the present invention.
Figure label explanation:1- concrete components, 2- penetrant crystallines material, 3- sodium metasilicate renovation agents particle, 4- are without water silicon Sour sodium, 5- ethyl celluloses.
Specific implementation mode
To make the objectives, technical solutions, and advantages of the present invention more comprehensible, specific embodiment and phase will be passed through below Attached drawing is closed, invention is further described in detail.
Embodiment one
As shown in Figure 1 and 2, a kind of permeable crystallization type self-repair concrete structure, including concrete component 1, the concrete component Penetrant crystalline material granule 2 and sodium metasilicate renovation agent particle 3 are evenly arranged in 1, the sodium metasilicate renovation agent particle 3 is in micro- Capsule structure, wherein the core materials of the sodium metasilicate renovation agent particle 3 are anhydrous sodium metasilicate 4, and cyst material is that ethyl is fine Dimension element 5.The penetrant crystalline material granule 2 is activated silica penetrant crystalline masterbatch.The sodium metasilicate renovation agent particle 3 is a diameter of The sheet-like particle of 5 ~ 6mm.
Embodiment two
A kind of production method of such as self-repair concrete structure, including step:
Step 1:Make sodium metasilicate renovation agent particle 3;
Step 2:Concrete mix is designed, determines 3 volume of penetrant crystalline material granule 2 and sodium metasilicate renovation agent particle, wherein The penetrant crystalline material granule 2 replaces cement proportion to be 1.85% ~ 2.15%, 3 volume of sodium metasilicate renovation agent particle and water Mud volume ratio is 4.0% ~ 4.5%;
Step 3:Concrete on casting concrete component, and conserve molding.
In the present embodiment, the step 1 specifically includes:
Step 11:Ethyl alcohol is poured into a reservoir, then ethyl cellulose 5 is poured into container, is mixed evenly, is made ethyl cellulose 5 dissolvings;
Step 12:Anhydrous sodium metasilicate 4 is poured into container again, stirring makes to be uniformly mixed;
Step 13:Heat container, accelerating alcohol volatilization, to obtain solid matter;
Step 14:Solid matter is broken into the sheet-like particle of a diameter of 5 ~ 6mm, the sodium metasilicate renovation agent as actually used Grain 3.
In step 2 described in the present embodiment, when the strength grade of the concrete component 1 is C40, its slump be 160 ~ When 200mm, cement consumption is 228 ~ 243 parts, fine aggregate dosage is 700 ~ 750 parts, coarse aggregate dosage is 1060 ~ 1100 parts, water Dosage is 156 ~ 160 parts, flyash dosage is 111 ~ 114 parts, 40 ~ 43 parts of water-reducing agent dosage.
Specifically, in the present embodiment, the cement is 42.5 Portland cements of PO;The flyash is to meet state II grade of fly ash in electric power plant of the border standards of GB/ T1506-2005;The lime stone of 5 ~ 16mm of coarse aggregate continuous gradings is broken Stone;The fine aggregate is sand in natural river sand and IIth area;The polycarboxylic acids that the water-reducing agent water-reducing rate is 30% and solid content is 40% Water-reducing agent, 2 activated silica penetrant crystalline masterbatch of the penetrant crystalline material granule, density are 2000 ~ 2100kg/m 3
Step 3 pours in manufacturing process, and uniformly incorporation is mixed in the form of aggregate for the sodium metasilicate renovation agent composite particles 3 It in solidifying soil, is mixed in concrete together with the penetrant crystalline material granule 2 and cement, the concrete component 1 is used from close Real concrete, the without vibration in casting process.
The concrete component 1 of above-described embodiment exists due to mixing penetrant crystalline material granule 2, active chemistry therein Inside concrete reacts with unhydrated cement granules, generates insoluble crystalline material, be filled in distress in concrete or In gap, play the role of air-free concrete, improve intensity, that is, improves the impermeability and mechanical property of concrete.Meanwhile working as crack Split generate and through sodium metasilicate renovation agent composite particles 3 make anhydrous sodium metasilicate 4 expose, and then with the hydroxide in concrete substrate Calcium reaction generates the hydrated calcium silicate gel in filling crack, and then crack is made to be closed.
It should be noted that the foregoing is merely illustrative of the preferred embodiments of the present invention, be not intended to limit the invention, it is all Within the spirit and principles in the present invention, made by all any modification, equivalent and improvement etc., should be included in the protection of the present invention Range.

Claims (10)

1. a kind of permeable crystallization type self-repair concrete structure, including concrete component(1), it is characterised in that:The concrete It is evenly arranged with penetrant crystalline material granule in component (1)(2)And sodium metasilicate renovation agent particle(3), the sodium metasilicate reparation Agent particle(3)In microcapsule structure.
2. permeable crystallization type self-repair concrete structure according to claim 1, it is characterised in that:The sodium metasilicate is repaiied Multiple agent particle(3)Core materials be anhydrous sodium metasilicate(4), cyst material is ethyl cellulose(5).
3. permeable crystallization type self-repair concrete structure according to claim 1, it is characterised in that:The penetrant crystalline material Expect particle(2)For activated silica penetrant crystalline masterbatch.
4. permeable crystallization type self-repair concrete structure according to claim 1, it is characterised in that:The sodium metasilicate reparation Agent particle(3)For the sheet-like particle of a diameter of 5 ~ 6mm.
5. a kind of production method of the self-repair concrete structure as described in any one of claim 1-4, which is characterized in that including Step:
Step 1:Make sodium metasilicate renovation agent particle(3);
Step 2:Concrete mix is designed, determines penetrant crystalline material granule(2)With sodium metasilicate renovation agent particle(3)Volume, Wherein, the penetrant crystalline material granule(2)It is 1.85% ~ 2.15% to replace cement proportion, the sodium metasilicate renovation agent particle(3) Volume is 4.0% ~ 4.5% with cement volume ratio;
Step 3:Concrete on casting concrete component, and conserve molding.
6. production method according to claim 5, which is characterized in that the step 1 specifically includes:
Step 11:Pour into ethyl alcohol in a reservoir, then by ethyl cellulose(5)Container is poured into, is mixed evenly, ethyl cellulose is made Element(5)Dissolving;
Step 12:Again by anhydrous sodium metasilicate(4)Container is poured into, stirring makes to be uniformly mixed;
Step 13:Heat container, accelerating alcohol volatilization, to obtain solid matter;
Step 14:Solid matter is broken into the sheet-like particle of a diameter of 5 ~ 6mm, the sodium metasilicate renovation agent as actually used Grain(3).
7. production method according to claim 5, which is characterized in that in the step 2, when the concrete component (1)Strength grade be C40, when its slump is 160 ~ 200mm, cement consumption is 228 ~ 243 parts, fine aggregate dosage be 700 ~ 750 parts, coarse aggregate dosage be 1060 ~ 1100 parts, water consumption is 156 ~ 160 parts, flyash dosage is 111 ~ 114 parts, water-reducing agent 40 ~ 43 parts of dosage.
8. production method according to claim 7, which is characterized in that the cement is 42.5 Portland cements of PO; The flyash is II grade of fly ash in electric power plant for meeting the international standards of GB/ T1506-2005;5 ~ the 16mm of coarse aggregate The lime stone rubble of continuous grading;The fine aggregate is sand in natural river sand and IIth area;The water-reducing agent water-reducing rate is 30% and consolidates The polycarboxylate water-reducer that content is 40%.
9. production method according to claim 5, which is characterized in that the penetrant crystalline material granule(2)Density be 2000~2100kg/m 3
10. production method according to claim 5, which is characterized in that in step 3, compound of the sodium metasilicate renovation agent Grain(3)It is uniformly mixed in concrete in the form of aggregate, the penetrant crystalline material granule(2)With coagulation is mixed together with cement In soil, the concrete component (1) uses self-compacting concrete, the without vibration in casting process.
CN201810819124.0A 2018-07-24 2018-07-24 A kind of permeable crystallization type self-repair concrete structure and preparation method thereof Pending CN108751869A (en)

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CN110510910A (en) * 2019-09-26 2019-11-29 交通运输部公路科学研究所 A kind of thin micro crack microcapsules self-repair material of the concrete that cyst wall is degradable
WO2020173220A3 (en) * 2019-02-27 2020-10-22 詹仰东 Nano-modified silicate-based permeating and crystallizing material and method of using same
CN112456854A (en) * 2020-11-13 2021-03-09 华南理工大学 Sodium silicate composite self-repairing concrete structure and preparation method thereof
CN112456899A (en) * 2020-11-13 2021-03-09 华南理工大学 Permeable crystallization composite self-repairing concrete structure and manufacturing method thereof
CN113045283A (en) * 2021-03-24 2021-06-29 交通运输部公路科学研究所 Intelligent trigger type concrete micro-crack self-repairing microcapsule and preparation method thereof
CN113060978A (en) * 2021-03-05 2021-07-02 华南理工大学 Foam fiber self-repairing concrete and preparation method thereof
CN113773009A (en) * 2021-11-15 2021-12-10 交通运输部天津水运工程科学研究所 Repair material and repair method for improving toughness of port high-pile wharf structure
CN115536329A (en) * 2022-09-05 2022-12-30 山东大学 Self-repairing particles, self-repairing cement-based composite material and preparation method thereof

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020173220A3 (en) * 2019-02-27 2020-10-22 詹仰东 Nano-modified silicate-based permeating and crystallizing material and method of using same
CN110510910A (en) * 2019-09-26 2019-11-29 交通运输部公路科学研究所 A kind of thin micro crack microcapsules self-repair material of the concrete that cyst wall is degradable
CN112456854A (en) * 2020-11-13 2021-03-09 华南理工大学 Sodium silicate composite self-repairing concrete structure and preparation method thereof
CN112456899A (en) * 2020-11-13 2021-03-09 华南理工大学 Permeable crystallization composite self-repairing concrete structure and manufacturing method thereof
CN113060978A (en) * 2021-03-05 2021-07-02 华南理工大学 Foam fiber self-repairing concrete and preparation method thereof
CN113045283A (en) * 2021-03-24 2021-06-29 交通运输部公路科学研究所 Intelligent trigger type concrete micro-crack self-repairing microcapsule and preparation method thereof
CN113773009A (en) * 2021-11-15 2021-12-10 交通运输部天津水运工程科学研究所 Repair material and repair method for improving toughness of port high-pile wharf structure
CN115536329A (en) * 2022-09-05 2022-12-30 山东大学 Self-repairing particles, self-repairing cement-based composite material and preparation method thereof
CN115536329B (en) * 2022-09-05 2023-09-05 山东大学 Self-repairing particles, self-repairing cement-based composite material and preparation method thereof

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