CN108751815A - A kind of fiber reinforced cement-based composite material and preparation method thereof - Google Patents

A kind of fiber reinforced cement-based composite material and preparation method thereof Download PDF

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Publication number
CN108751815A
CN108751815A CN201810720118.XA CN201810720118A CN108751815A CN 108751815 A CN108751815 A CN 108751815A CN 201810720118 A CN201810720118 A CN 201810720118A CN 108751815 A CN108751815 A CN 108751815A
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China
Prior art keywords
parts
cement
water
composite material
based composite
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Pending
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CN201810720118.XA
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Chinese (zh)
Inventor
程华风
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Hefei Lian Sen Yu Teng New Material Technology Development Co Ltd
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Hefei Lian Sen Yu Teng New Material Technology Development Co Ltd
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Priority to CN201810720118.XA priority Critical patent/CN108751815A/en
Publication of CN108751815A publication Critical patent/CN108751815A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

A kind of fiber reinforced cement-based composite material, by weight, including following raw material:50~70 parts of cement, 10~20 parts of carbon fiber reinforcement, 2~4 parts of swelling agent, 20~30 parts of steel fibre, 10~30 parts of water, 1~3 part of water-reducing agent, 10~20 parts of ceramic powder, 8~16 parts of silica flour;Using fully dispersed ultra-fine silicon ash particle, it is filled in the gap of cement granules accumulation system, realize particle packing densification, high solidity particle packing system is formed by high efficiency water reducing agent again, so that fiber reinforced cement-based composite material has higher elasticity modulus, the very-high performances such as high tensile strength and compressive strength, stronger self-healing capability and hypotonicity, the addition of carbon fiber reinforcement and steel fibre, so that the structural strength higher of the finished product of fiber reinforced cement-based composite material, to keep the raising of the bearing capacity of fiber reinforced cement-based composite material reinforced steel concrete structure more obvious.

Description

A kind of fiber reinforced cement-based composite material and preparation method thereof
Technical field
The present invention relates to building material technical fields, and in particular to a kind of fiber reinforced cement-based composite material and its preparation Method.
Background technology
Construction material is the general designation of the material used in civil engineering and architectural engineering, can be divided into structural material, decoration material Material and certain proprietary materials.Structural material include timber, bamboo wood, stone material, cement, concrete, metal, brick and tile, ceramics, glass, Engineering plastics, composite material etc., ornament materials include various coating, paint, coating, veneer, assorted ceramic tile, have special-effect Glass etc.;Proprietary material refers to for waterproof, moisture-proof, anti-corrosion, fire prevention, fire-retardant, sound insulation, heat-insulated, heat preservation, sealing etc..
However traditional fiber reinforced cement-based composite material because the ratio of mud is larger etc. factors influence due to there is elasticity modulus In place of the deficiencies of relatively low, cause the bearing power increase of fiber reinforced cement-based composite material reinforced steel concrete structure and unknown It is aobvious.
Invention content
The purpose of the present invention is to provide a kind of fiber reinforced cement-based composite materials and preparation method thereof, above-mentioned to solve The problem of being proposed in background technology.
To achieve the above object, the present invention provides the following technical solutions:
A kind of fiber reinforced cement-based composite material, by weight, including following raw material:50~70 parts of cement, carbon fiber 10~20 parts of reinforcement, 2~4 parts of swelling agent, 20~30 parts of steel fibre, 10~30 parts of water, 1~3 part of water-reducing agent, ceramic powder 10~ 20 parts, 8~16 parts of silica flour.
It is as further technical solution of the invention:By weight, including following raw material:55~65 parts of cement, carbon fiber Tie up 13~17 parts of reinforcement, 2~4 parts of swelling agent, 23~27 parts of steel fibre, 15~25 parts of water, 1~3 part of water-reducing agent, ceramic powder 13 ~17 parts, 10~14 parts of silica flour.
It is as further technical solution of the invention:By weight, including following raw material:60 parts of cement, carbon fiber 15 parts of reinforcement, 3 parts of swelling agent, 25 parts of steel fibre, 20 parts of water, 2 parts of water-reducing agent, 15 parts of ceramic powder, 12 parts of silica flour.
It is as further technical solution of the invention:The cement is low-heat cement, and the swelling agent is sulphur aluminic acid Salt cement expansive material, the water-reducing agent are Polycarboxylic Superplasticizer or naphthalene series high-efficiency water-reducing agent.
It is as further technical solution of the invention:The mass percent of amorphous silica in the silica flour Content is more than or equal to 90%.
A kind of preparation method of fiber reinforced cement-based composite material, this approach includes the following steps:
(1) cement, ceramic powder and silica flour being put into blender 10~20min of stirring, the rotating speed of blender is 80~ 120r/min obtains the first mixture;
(2) swelling agent and water-reducing agent is added in the first mixture prepared into step (1), is then stirred by blender 10~20min obtains the second mixture;
(3) carbon fiber reinforcement, steel fibre and water is added in the second mixture prepared into step (2), then passes through Blender stirs 20~40min, obtains the first semi-finished product;
(4) the first semi-finished product for using packing machine to prepare step (3) pack and are sealed up for safekeeping, to obtain fiber reinforcement water Cement-based composite material.
The beneficial effects of the invention are as follows fully dispersed ultra-fine silicon ash particle is used, it is filled in cement granules accumulation system In gap, particle packing densification is realized, then high solidity particle packing system is formed by high efficiency water reducing agent so that fiber increases Strong cement-base composite material has very-high performances, the stronger self-healings such as higher elasticity modulus, high tensile strength and compressive strength Conjunction ability and hypotonicity, in addition, the addition of carbon fiber reinforcement and steel fibre so that fibre reinforced cement base composite wood The structural strength higher of the finished product of material, to make the bearing capacity of fiber reinforced cement-based composite material reinforced steel concrete structure Raising it is more obvious.
Specific implementation mode
In the following, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common The every other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1:
The fiber reinforced cement-based composite material of the present embodiment includes the weight of following component:50 parts of cement, carbon fiber increase Strong 10 parts of body, 2 parts of swelling agent, 20 parts of steel fibre, 10 parts of water, 1 part of water-reducing agent, 10 parts of ceramic powder, 8 parts of silica flour.
The specific preparation method of the above fiber reinforced cement-based composite material is as follows:
(1) cement, ceramic powder and silica flour are put into blender and stir 10min, the rotating speed of blender is 80r/min, is obtained To the first mixture;
(2) swelling agent and water-reducing agent is added in the first mixture prepared into step (1), is then stirred by blender 10min obtains the second mixture;
(3) carbon fiber reinforcement, steel fibre and water is added in the second mixture prepared into step (2), then passes through Blender stirs 20min, obtains the first semi-finished product;
(4) the first semi-finished product for using packing machine to prepare step (3) pack and are sealed up for safekeeping, to obtain fiber reinforcement water Cement-based composite material.
Embodiment 2:
The fiber reinforced cement-based composite material of the present embodiment includes the weight of following component:70 parts of cement, carbon fiber increase Strong 20 parts of body, 4 parts of swelling agent, 30 parts of steel fibre, 30 parts of water, 3 parts of water-reducing agent, 20 parts of ceramic powder, 16 parts of silica flour.
The specific preparation method of the above fiber reinforced cement-based composite material is as follows:
(1) cement, ceramic powder and silica flour are put into blender and stir 20min, the rotating speed of blender is 120r/min, is obtained To the first mixture;
(2) swelling agent and water-reducing agent is added in the first mixture prepared into step (1), is then stirred by blender 20min obtains the second mixture;
(3) carbon fiber reinforcement, steel fibre and water is added in the second mixture prepared into step (2), then passes through Blender stirs 40min, obtains the first semi-finished product;
(4) the first semi-finished product for using packing machine to prepare step (3) pack and are sealed up for safekeeping, to obtain fiber reinforcement water Cement-based composite material.
Embodiment 3:
The fiber reinforced cement-based composite material of the present embodiment includes the weight of following component:55 parts of cement, carbon fiber increase Strong 13 parts of body, 2 parts of swelling agent, 23 parts of steel fibre, 15 parts of water, 1 part of water-reducing agent, 13 parts of ceramic powder, 10 parts of silica flour.
The specific preparation method of the above fiber reinforced cement-based composite material is as follows:
(1) cement, ceramic powder and silica flour are put into blender and stir 13min, the rotating speed of blender is 90r/min, is obtained To the first mixture;
(2) swelling agent and water-reducing agent is added in the first mixture prepared into step (1), is then stirred by blender 13min obtains the second mixture;
(3) carbon fiber reinforcement, steel fibre and water is added in the second mixture prepared into step (2), then passes through Blender stirs 25min, obtains the first semi-finished product;
(4) the first semi-finished product for using packing machine to prepare step (3) pack and are sealed up for safekeeping, to obtain fiber reinforcement water Cement-based composite material.
Embodiment 4:
The fiber reinforced cement-based composite material of the present embodiment includes the weight of following component:65 parts of cement, carbon fiber increase Strong 17 parts of body, 4 parts of swelling agent, 27 parts of steel fibre, 25 parts of water, 3 parts of water-reducing agent, 17 parts of ceramic powder, 14 parts of silica flour.
The specific preparation method of the above fiber reinforced cement-based composite material is as follows:
(1) cement, ceramic powder and silica flour are put into blender and stir 17min, the rotating speed of blender is 110r/min, is obtained To the first mixture;
(2) swelling agent and water-reducing agent is added in the first mixture prepared into step (1), is then stirred by blender 17min obtains the second mixture;
(3) carbon fiber reinforcement, steel fibre and water is added in the second mixture prepared into step (2), then passes through Blender stirs 35min, obtains the first semi-finished product;
(4) the first semi-finished product for using packing machine to prepare step (3) pack and are sealed up for safekeeping, to obtain fiber reinforcement water Cement-based composite material.
Embodiment 5:
The fiber reinforced cement-based composite material of the present embodiment includes the weight of following component:60 parts of cement, carbon fiber increase Strong 15 parts of body, 3 parts of swelling agent, 25 parts of steel fibre, 20 parts of water, 2 parts of water-reducing agent, 15 parts of ceramic powder, 12 parts of silica flour.
The specific preparation method of the above fiber reinforced cement-based composite material is as follows:
(1) cement, ceramic powder and silica flour are put into blender and stir 15min, the rotating speed of blender is 100r/min, is obtained To the first mixture;
(2) swelling agent and water-reducing agent is added in the first mixture prepared into step (1), is then stirred by blender 15min obtains the second mixture;
(3) carbon fiber reinforcement, steel fibre and water is added in the second mixture prepared into step (2), then passes through Blender stirs 30min, obtains the first semi-finished product;
(4) the first semi-finished product for using packing machine to prepare step (3) pack and are sealed up for safekeeping, to obtain fiber reinforcement water Cement-based composite material.
Comparative example 1:
Except external without fibre reinforced, formula and preparation process are consistent with embodiment 5.
Comparative example 2:
In addition to without ceramic powder, formula and preparation process are consistent with embodiment 5.
After the fiber reinforced cement-based composite material that embodiment 1 to 5 and comparative example 1-2 is prepared, performance test knot Fruit is as shown in the table:
Compression strength (MPa) Tensile strength (MPa) Chlorion depth of invasion (mm)
Embodiment 1 89.3 5.4 4.5
Embodiment 2 91.2 7.0 2.2
Embodiment 3 98.6 6.2 2.1
Embodiment 4 99.2 7.4 1.8
Embodiment 5 102.5 7.8 1.5
Comparative example 1 86.2 5.3 4.6
Comparative example 2 84.6 5.1 4.8
As can be seen that passing through the composition material progress to fiber reinforced cement-based composite material from the comparison of three item datas The correlated performance of selection and proportioning, fiber reinforced cement-based composite material prepared by embodiment 5 is significantly higher than embodiment 1-4 and right Ratio 1-2.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (6)

1. a kind of fiber reinforced cement-based composite material, which is characterized in that by weight, including following raw material:Cement 50~70 Part, 10~20 parts of carbon fiber reinforcement, 2~4 parts of swelling agent, 20~30 parts of steel fibre, 10~30 parts of water, 1~3 part of water-reducing agent, 10~20 parts of ceramic powder, 8~16 parts of silica flour.
2. a kind of fiber reinforced cement-based composite material according to claim 1, which is characterized in that by weight, including Following raw material:55~65 parts of cement, 13~17 parts of carbon fiber reinforcement, 2~4 parts of swelling agent, 23~27 parts of steel fibre, water 15~ 25 parts, 1~3 part of water-reducing agent, 13~17 parts of ceramic powder, 10~14 parts of silica flour.
3. a kind of fiber reinforced cement-based composite material according to claim 1, which is characterized in that by weight, including Following raw material:60 parts of cement, 15 parts of carbon fiber reinforcement, 3 parts of swelling agent, 25 parts of steel fibre, 20 parts of water, 2 parts of water-reducing agent, ceramics 15 parts of powder, 12 parts of silica flour.
4. a kind of fiber reinforced cement-based composite material according to claim 1, which is characterized in that the cement is low-heat Cement, the swelling agent are aluminium sulfate class cement expansive material, and the water-reducing agent is Polycarboxylic Superplasticizer or naphthalene system High efficiency water reducing agent.
5. a kind of fiber reinforced cement-based composite material according to claim 1, which is characterized in that the nothing in the silica flour The mass percentage content of sizing silica is more than or equal to 90%.
6. a kind of preparation method of fiber reinforced cement-based composite material according to claim 1, which is characterized in that the party Method includes the following steps:
Cement, ceramic powder and silica flour are put into 10~20min of stirring in blender, the rotating speed of blender is 80~120r/min, Obtain the first mixture;
To step(1)Swelling agent and water-reducing agent are added in first mixture of middle preparation, then by blender stirring 10~ 20min obtains the second mixture;
To step(2)Carbon fiber reinforcement, steel fibre and water are added in second mixture of middle preparation, is then stirred by blender 20~40min is mixed, the first semi-finished product are obtained;
Using packing machine to step(3)The first semi-finished product prepared carry out pack and seal up for safekeeping, multiple to obtain fibre reinforced cement base Condensation material.
CN201810720118.XA 2018-07-03 2018-07-03 A kind of fiber reinforced cement-based composite material and preparation method thereof Pending CN108751815A (en)

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Application Number Priority Date Filing Date Title
CN201810720118.XA CN108751815A (en) 2018-07-03 2018-07-03 A kind of fiber reinforced cement-based composite material and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201810720118.XA CN108751815A (en) 2018-07-03 2018-07-03 A kind of fiber reinforced cement-based composite material and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115073093A (en) * 2022-06-24 2022-09-20 武汉工程大学 Low-shrinkage high-strength self-compacting recycled concrete and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817287A (en) * 2015-04-16 2015-08-05 华东交通大学 high-performance concrete admixture in use of waste ceramic powder and implementing method thereof
CN105198339A (en) * 2015-10-28 2015-12-30 上海罗洋新材料科技有限公司 Ultrahigh-performance cement-based composite material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817287A (en) * 2015-04-16 2015-08-05 华东交通大学 high-performance concrete admixture in use of waste ceramic powder and implementing method thereof
CN105198339A (en) * 2015-10-28 2015-12-30 上海罗洋新材料科技有限公司 Ultrahigh-performance cement-based composite material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115073093A (en) * 2022-06-24 2022-09-20 武汉工程大学 Low-shrinkage high-strength self-compacting recycled concrete and preparation method thereof

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Application publication date: 20181106

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