CN108744984A - A kind of wound membrane element - Google Patents

A kind of wound membrane element Download PDF

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Publication number
CN108744984A
CN108744984A CN201810506388.0A CN201810506388A CN108744984A CN 108744984 A CN108744984 A CN 108744984A CN 201810506388 A CN201810506388 A CN 201810506388A CN 108744984 A CN108744984 A CN 108744984A
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CN
China
Prior art keywords
water
water flow
guiding screen
production
center
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810506388.0A
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Chinese (zh)
Inventor
武少禹
刘星
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Co Ltd Royal Membrane Water Purification Materials Development
Original Assignee
Nanjing Co Ltd Royal Membrane Water Purification Materials Development
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Co Ltd Royal Membrane Water Purification Materials Development filed Critical Nanjing Co Ltd Royal Membrane Water Purification Materials Development
Priority to CN201810506388.0A priority Critical patent/CN108744984A/en
Publication of CN108744984A publication Critical patent/CN108744984A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08Flat membrane modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025Reverse osmosis; Hyperfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027Nanofiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/145Ultrafiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/04Specific sealing means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/08Flow guidance means within the module or the apparatus

Abstract

The invention discloses a kind of wound membrane elements, including center water producing pipe, and it is wrapped at least one set of water purification diaphragm group on the water producing pipe of center, the water purification diaphragm group includes a production water flow-guiding screen, two Separation membranes and a raw water flow-guiding screen, it is raw water runner between two Separation membrane inner surfaces, it is arranged in raw water runner for production water flow passage, the raw water flow-guiding screen between the outer surface of two Separation membranes, the production water flow-guiding screen is arranged in producing water flow passage.The more traditional wound membrane element of the present invention differ in membrane component raw water flow-guiding screen and production water flow-guiding screen carry out hydrophilic macromolecule it is coating modified, it increases raw water flow-guiding screen and produces the hydrophily of water flow-guiding screen, the effective water that improves is to the flushing effect of membrane surface and the water conservancy diversion speed of water purification, come reach improve membrane component salt rejection rate and flux, increase the purpose of the stain resistance of membrane component.

Description

A kind of wound membrane element
Technical field
The present invention relates to a kind of membrane component, belong to filter technology field in purifier.
Background technology
The principle of membrane filtration is the process sieved using the pore size of film, is driving with the pressure difference of film both sides Power, using film as filter medium, stoste flows through film surface under pressure, and the micropore of film surface only allows water and small molecule object Matter by by become permeate, and in stoste grain size be more than film surface micropore substance be then trapped within film liquid feeding side become it is dense Contracting liquid realizes the separation and concentration of stoste.
For existing wound membrane element generally use plastic wire as aquaporin filter is given, the purpose is to provide one for water inlet As close possible to the access of turbulent flow, makes to be parallel to membrane component direction between rolling diaphragm into water and fully flow, and in production flow Using plastic wire as production aquaporin in road, production water flows into central tube along longitudinal circulation perpendicular to membrane component.It is more in the market Number wound membrane elements using producing the production water in water flow passage by the way of the vertical wraparound one-way flow of membrane component, produce water ring around Membrane component to flow to central tube and finally collect and be directed to the production water collection pipe outside membrane component by central tube, because This, the flux magnitude of membrane component is directly influenced to the material of the production aquaporin in aquaporin filter and production water flow passage.
With extensive utilization of the membrane component in industrial production and the water treatment procedure of daily life, people are for membrane component Performance requirement be also constantly to improve, be contemplated for high throughput, equipment with high desalinization, low consumption and the strong membrane component of stain resistance. And processing scheme conventional at present is so that membrane component is had equipment with high desalinization, low consumption and resistant by improving the performance of diaphragm The advantages that metachromia is strong, but these processing modes are with the continuous promotion of diaphragm performance itself, effect increasingly unobvious.
Invention content
In view of the problems of the existing technology, the present invention proposes a kind of wound membrane element effectively improving permeant flux.
The present invention solves the technical solution of the above technical problem:A kind of wound membrane element, including center water producing pipe, and twine At least one set of water purification diaphragm group being wound on the water producing pipe of center;The water purification diaphragm group include a production water flow-guiding screen, two points From diaphragm and a raw water flow-guiding screen;It is raw water runner between two Separation membrane inner surfaces, two Separation membranes It is production water flow passage between outer surface;The raw water flow-guiding screen is arranged in raw water runner;The production water flow-guiding screen setting is being produced In water flow passage;The center water producing pipe is equipped with axial endoporus, and tube wall is equipped with multiple limbers for being connected to its endoporus;It is described Endoporus one end of center water producing pipe is closed, and the other end is equipped with water purification outlet, and water purification outlet sealing ring is equipped at the water purification outlet.
Further, flow direction of the raw water in water purification diaphragm group is parallel with the axis of center water producing pipe.
Further, the production water flow passage in every group of water purification diaphragm group is connected to the limbers on the water producing pipe of center.
Further, a part for the production water flow-guiding screen of the water purification diaphragm group or production water flow passage is close to center production water Pipe, rectangular after the production water flow passage expansion, the limbers of rectangle connection center water producing pipe keeps clear on one side, excess-three While being closed by adhesive bond.
Further, two Separation membranes Yu center water producing pipe of every group of water purification diaphragm group are produced parallel and close to center The side of water pipe passes through adhesive bond.
Further, the Separation membrane of the water purification diaphragm group is reverse osmosis membrane or NF membrane or ultrafiltration membrane.
Further, the lateral surface of the water purification diaphragm group is wound with sealant tape, and the outside of the sealant tape is equipped with Y Type sealing collar.
Further, the raw water flow-guiding screen and production water flow-guiding screen are by the coating modified of water-soluble high-molecular material 's.Specifically comprise the steps of:
S1:A certain amount of water-soluble high-molecular material is added to heating in quantitative ultra-pure water to make it dissolve, after dissolving It is cooling;
S2:Raw water flow-guiding screen and production water flow-guiding screen are dipped into aqueous solution made from S1 and are taken out after a certain period of time, and is put Enter baking oven, is taken out after being heated under certain condition;
S3:It soaks in certain density crosslinking agent and catalyst, is heated under the conditions of certain temperature, obtain hydrophilic coating By raw water flow-guiding screen and production water flow-guiding screen.
Further, the water-soluble high-molecular material includes but not limited to polyvinyl alcohol (PVA), polyethylene glycol (PEG), Polyethylene pyrrole network alkanone (PVP), polyacrylic acid (PAA), polyethylene glycol oxide (PEO) etc..
Further, the water-soluble high-molecular material should have high temperature water-soluble, and room temperature is insoluble in water, crosslinkable Property.
Beneficial effects of the present invention:The more traditional wound membrane element of the present invention is differed to the original in membrane component Water flow-guiding screen and production water flow-guiding screen progress hydrophilic macromolecule are coating modified, increase raw water flow-guiding screen and produce the parent of water flow-guiding screen It is aqueous, the water conservancy diversion speed of the effective flushing effect and water purification for improving membrane surface water, to reach the desalination for improving membrane component Rate and flux increase the purpose of the stain resistance of membrane component.The present invention raw water flow-guiding screen has been carried out it is hydrophilically modified, to subtract Hydrophobic contaminant is lacked to adsorb in the deposition of raw water net and film surface, has increased flushing effect of the raw water to film surface, reduce The concentration of the brine on diaphragm surface layer, increases the salt rejection rate of membrane component, enhances stain resistance.Produce the hydrophily of water flow-guiding screen Increase can allow water purification to be more easy to pass through, and be conducive to promote pure water flux.
Description of the drawings
In order to be easier to understand technical scheme of the present invention and beneficial technique effect, by referring to what is be shown in the accompanying drawings The specific implementation mode of the present invention is described in detail the present invention.These attached drawings, which depict only the typical of the present invention, to be implemented Mode does not constitute the limitation to protection scope of the present invention, wherein:
Fig. 1 is the structure explanation of the embodiment of the present invention 1.
Fig. 2 is the appearance diagram of the embodiment of the present invention 1.
Fig. 3 is that the structure expansion of the embodiment of the present invention 1 and pure water flow to schematic diagram.
Fig. 4 is that the structure expansion of the embodiment of the present invention 1 and raw water flow to schematic diagram.
In Fig. 1~4:1. center water producing pipe;2. water purification diaphragm group;3. Separation membrane;4. raw water flow-guiding screen;5. producing water water conservancy diversion Net;6. limbers;7. binder;8. sealant tape;9.Y type sealing rings;10. water purification outlet sealing ring;11. producing water flow passage;12. Water purification outlet;13. raw water runner.
Specific implementation mode
Embodiment 1
As shown in Figures 1 to 4, the present embodiment provides a kind of wound membrane elements, including center water producing pipe 1, and are wrapped in At least one set of water purification diaphragm group 2 on the water producing pipe of center;The water purification diaphragm group 2 includes 5, two separation of a production water flow-guiding screen Diaphragm 3 and a raw water flow-guiding screen 4, the self-control diaphragm doubling that two Separation membranes 3 are long 1m wide 0.32m form;Described two It is raw water runner 13 between 3 inner surface of Separation membrane, is production water flow passage 11 between the outer surface of two Separation membranes 3;Institute It states raw water flow-guiding screen 4 to be arranged in raw water runner 13, thickness 0.5mm, length 51cm, width 0.32m;The production water is led Drift net 5 is arranged in producing water flow passage 11;The center water producing pipe 1 is equipped with axial endoporus, and tube wall is connected to it equipped with multiple The limbers 6 of endoporus;Endoporus one end of the center water producing pipe 1 is closed, and the other end is equipped with water purification outlet 12, the water purification outlet Water purification outlet sealing ring 10 is equipped at 12.
Flow direction of the raw water in the water purification diaphragm group 2 is parallel with the axis of the center water producing pipe 1.Every group of water purification Production water flow passage 11 in diaphragm group 2 is connected to the limbers 6 on center water producing pipe 1.The production water flow-guiding screen of the water purification diaphragm group 2 It 5 or produces the part of water flow passage 11 and is close to center water producing pipe, the production water flow passage 11 is rectangular after being unfolded, during which is connected to The limbers 6 of heart water producing pipe 1 keeps clear on one side, and excess-three side is bonded by binder 7 and closed.Every group of water purification diaphragm Side of two Separation membranes 3 of group 2 with center water producing pipe 1 parallel and close to center water producing pipe 1 is bonded by binder 7. The Separation membrane 3 of the water purification diaphragm group 2 is reverse osmosis membrane or NF membrane or ultrafiltration membrane.In this way, by water purification diaphragm described in five groups Group 2 is wound into center water producing pipe 1, and outside is sealed with sealant tape 8, and the outside of the sealant tape 8 is equipped with Y types sealing collar 9.Institute It is by the coating modified of water-soluble high-molecular material to state raw water flow-guiding screen 4 and production water flow-guiding screen 5.It include specifically following step Suddenly:
S1:The polyvinyl alcohol (PVA) for measuring 1kg alcoholysis degrees 98%, is added in the ultra-pure water of 50KG and is heated to 100 DEG C simultaneously It stirs to dissolve, dissolves postcooling;
S2:It will be taken out after 1h in the aqueous solution for the PVA that raw water flow-guiding screen and production water flow-guiding screen are dipped into preparation, and be put into baking Case is taken out after heating 1h under the conditions of 80 DEG C;
S3:After immersing 3% glutaraldehyde and 0.5% aqueous sulfuric acid 30s, 3min is heated under the conditions of 100 DEG C, obtains hydrophily Coating by raw water flow-guiding screen and production water flow-guiding screen.
The water-soluble high-molecular material includes but not limited to polyvinyl alcohol (PVA), polyethylene glycol (PEG), polyethylene pyrrole Network alkanone (PVP), polyacrylic acid (PAA), polyethylene glycol oxide (PEO).
The hydrophilic coating material should have high temperature water-soluble, and room temperature is insoluble in water, crosslinkable property.
The test situation of the wound membrane element of the present embodiment is as follows:
Use certain city municipal tap water straight as raw water the membrane component of the two panels 1812-50G rolled without coating treatment Test is connect, test result is under the conditions of 0.41MPa pressure, 20% rate of recovery:When 25 DEG C of normal temperatures, water flux 165mL/ Min, salt rejection rate 98%;The membrane component water flux of the two panels 1812-50G rolled by coating treatment is 190mL/min, desalination Rate 99%.Result is shown after follow-on test 180 days:Non-modified membrane component water flux declines 35%, salt rejection rate 95%;It applies The modified membrane component water flux of layer declines 5%, salt rejection rate 98%.Show that raw water flow-guiding screen and production water flow-guiding screen change through hydrophilic coating After property, water flux, salt rejection rate and the anti-pollution ability of film are improved in various degree.
Above specific embodiment has carried out further specifically the purpose of the present invention, technical solution and advantageous effect It is bright, it should be understood that these are only specific embodiments of the present invention, it is not intended to restrict the invention, it is all in the present invention Spirit and principle within, any modification, equivalent substitution, improvement and etc. done, should be included in protection scope of the present invention it It is interior.

Claims (4)

1. a kind of wound membrane element, including center water producing pipe, and at least one set of water purification diaphragm for being wrapped on the water producing pipe of center Group;The water purification diaphragm group includes a production water flow-guiding screen, two Separation membranes and a raw water flow-guiding screen;Two separation It is raw water runner between diaphragm inner surface, is production water flow passage between the outer surface of two Separation membranes;The raw water water conservancy diversion Net is arranged in raw water runner;The production water flow-guiding screen is arranged in producing water flow passage;The center water producing pipe is equipped with the interior of axial direction Hole, and tube wall is equipped with multiple limbers for being connected to its endoporus;Endoporus one end of the center water producing pipe is closed, and the other end is equipped with Water purification outlet is equipped with water purification outlet sealing ring at the water purification outlet.
Flow direction of the raw water in water purification diaphragm group is parallel with the axis of center water producing pipe.
Production water flow passage in every group of water purification diaphragm group is connected to the limbers on the water producing pipe of center.
The production water flow-guiding screen of the water purification diaphragm group or the part for producing water flow passage are close to center water producing pipe, the production water flow passage Rectangular after expansion, the limbers of rectangle connection center water producing pipe keeps clear on one side, and excess-three side is viscous by binder Close closing.
Two Separation membranes of every group of water purification diaphragm group are parallel with center water producing pipe, and equal close to the side of center water producing pipe Pass through adhesive bond.
The Separation membrane of the water purification diaphragm group is reverse osmosis membrane or NF membrane or ultrafiltration membrane.
The lateral surface of the water purification diaphragm group is wound with sealant tape, and the outside of the sealant tape is equipped with Y type sealing collars.
Wherein, the production water flow-guiding screen in every group of Separation membrane group has carried out hydrophilic coating;Every group of Separation membrane group In raw water flow-guiding screen carried out hydrophilic coating.
2. a kind of wound membrane element according to claim 1, which is characterized in that the raw water flow-guiding screen and production water flow-guiding screen It is by the coating modified of water-soluble high-molecular material.Specifically comprise the steps of:
S1:A certain amount of water-soluble high-molecular material is added to heating in quantitative ultra-pure water to make it dissolve, dissolves postcooling;
S2:Raw water flow-guiding screen and production water flow-guiding screen are dipped into aqueous solution made from S1 and are taken out after a certain period of time, and is put into baking Case takes out after heating under certain condition;
S3:It soaks in certain density crosslinking agent and catalyst, is heated under the conditions of certain temperature, obtain hydrophilic coating will be former Water flow-guiding screen and production water flow-guiding screen.
3. a kind of wound membrane element according to claim 2, which is characterized in that the water-soluble high-molecular material include but It is not limited to polyvinyl alcohol (PVA), polyethylene glycol (PEG), polyethylene pyrrole network alkanone (PVP), polyacrylic acid (PAA), polyoxyethylene Alkene (PEO) etc..
4. a kind of wound membrane element according to claim 2, it is characterised in that:The water-soluble high-molecular material should have High temperature is water-soluble, and room temperature is insoluble in water, crosslinkable property.
CN201810506388.0A 2018-05-16 2018-05-16 A kind of wound membrane element Pending CN108744984A (en)

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Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114082310A (en) * 2022-01-20 2022-02-25 湖南叶之能科技有限公司 Roll type membrane element and preparation method and application thereof
CN114713031A (en) * 2022-04-19 2022-07-08 杭州卧特松环保科技有限公司 Reverse osmosis membrane layer assembly and reverse osmosis membrane element resistant to high COD and impurity pollution
CN115430294A (en) * 2022-08-03 2022-12-06 宁波方太厨具有限公司 Roll type nanofiltration membrane element capable of efficiently removing trace heavy metals

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CN107050927A (en) * 2017-04-27 2017-08-18 苏州捷尔沃科技有限公司 Composite structured oil-water separation mesh film and preparation method thereof
CN208694721U (en) * 2018-05-16 2019-04-05 南京帝膜净水材料开发有限公司 A kind of wound membrane element

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CN86107568A (en) * 1985-11-01 1987-04-29 孟山都公司 Polymer surface modification and implementation method thereof
CN101306327A (en) * 2008-07-08 2008-11-19 大连理工大学 Spiral carbon membrane and preparation method thereof
CN104138714A (en) * 2014-08-22 2014-11-12 江苏正本净化节水科技实业有限公司 Spiral-wound film component
CN105195027A (en) * 2015-09-10 2015-12-30 中国海洋大学 Forward osmosis membrane based on interface hydrophilic modification and preparation method of forward osmosis membrane
CN107050927A (en) * 2017-04-27 2017-08-18 苏州捷尔沃科技有限公司 Composite structured oil-water separation mesh film and preparation method thereof
CN208694721U (en) * 2018-05-16 2019-04-05 南京帝膜净水材料开发有限公司 A kind of wound membrane element

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114082310A (en) * 2022-01-20 2022-02-25 湖南叶之能科技有限公司 Roll type membrane element and preparation method and application thereof
CN114082310B (en) * 2022-01-20 2022-04-19 湖南叶之能科技有限公司 Roll type membrane element and preparation method and application thereof
CN114713031A (en) * 2022-04-19 2022-07-08 杭州卧特松环保科技有限公司 Reverse osmosis membrane layer assembly and reverse osmosis membrane element resistant to high COD and impurity pollution
CN115430294A (en) * 2022-08-03 2022-12-06 宁波方太厨具有限公司 Roll type nanofiltration membrane element capable of efficiently removing trace heavy metals
CN115430294B (en) * 2022-08-03 2024-04-02 宁波方太厨具有限公司 Rolling nanofiltration membrane element capable of efficiently removing trace heavy metals

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