CN1087361C - Zinc-tin alloy plating solution and preparation process thereof - Google Patents
Zinc-tin alloy plating solution and preparation process thereof Download PDFInfo
- Publication number
- CN1087361C CN1087361C CN95112541A CN95112541A CN1087361C CN 1087361 C CN1087361 C CN 1087361C CN 95112541 A CN95112541 A CN 95112541A CN 95112541 A CN95112541 A CN 95112541A CN 1087361 C CN1087361 C CN 1087361C
- Authority
- CN
- China
- Prior art keywords
- grams per
- per liters
- follows
- deionized water
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000007747 plating Methods 0.000 title claims abstract description 7
- 238000002360 preparation method Methods 0.000 title claims description 8
- 229910001128 Sn alloy Inorganic materials 0.000 title description 3
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000008139 complexing agent Substances 0.000 claims abstract description 9
- 239000012153 distilled water Substances 0.000 claims abstract description 9
- 229910007610 Zn—Sn Inorganic materials 0.000 claims abstract description 7
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 7
- 239000000956 alloy Substances 0.000 claims abstract description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- 150000003751 zinc Chemical class 0.000 claims abstract description 6
- 230000000536 complexating effect Effects 0.000 claims abstract description 5
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims abstract description 4
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 4
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims abstract description 4
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 7
- 238000009713 electroplating Methods 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000003788 bath preparation Substances 0.000 claims 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract description 6
- 229910021626 Tin(II) chloride Inorganic materials 0.000 abstract description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 235000011150 stannous chloride Nutrition 0.000 abstract description 3
- 235000005074 zinc chloride Nutrition 0.000 abstract description 3
- 239000011592 zinc chloride Substances 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000001119 stannous chloride Substances 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Electroplating And Plating Baths Therefor (AREA)
Abstract
A Zn-Sn alloy plating liquid for plating on metal surface is prepared from zinc chloride and stannous chloride as main salts through respectively adding disodium ethylenediamine tetraacetate as zinc salt complexing agent and NH as tin salt complexing agent4F. Dissolving and complexing nitrilotriacetic acid and distilled water, and then mixing. The invention can be prepared and used at normal temperature, has stable performance, does not pollute the environment, has simple process and energy saving, can plate the inner surface and the outer surface of a workpiece, has bright and compact plating layer which is blue-white or silvery-white, and resists the corrosion of dilute acid and alkali. The application is wide.
Description
A kind of matallic surface layer Zinc-tin alloy solution and preparation technology thereof.
Conventional electro-galvanizing tin alloy solution contains prussiate, and is bigger to human body and environmental hazard.The service temperature height, energy consumption is big, and the many zinc of coating tin of acquisition are few, and cost is higher.
The purpose of this invention is to provide a kind of Zn-Sn alloy electroplating bath and preparation technology thereof, accomplish can to prepare and use under the normal temperature, save energy, free from environmental pollution.
The present invention is to be main salt with zinc chloride and tin protochloride, adds complexing agent and forms.The proportioning of each component is as above:
Zinc chloride ZnCl
220～45 grams per liters
Tin protochloride SnCl
22H
2O 5～20 grams per liters
Zinc salt complexing agent disodium ethylene diamine tetraacetate C
10H
14N
2O
8Na
22H
2O 20～40 grams per liters
Pink salt complexing agent NH
4F or NaF 5～25 grams per liters
Nitrilotriacetic acid(NTA) N (CH
2COOH)
35～10 grams per liters
All the other are distilled water or deionized water PH=2～55
Preparation technology of the present invention is as follows:
A, in plastic channel, pour into part distilled water or deionized water.Pei Zhi volume (as follows) adds zinc salt complexing agent disodium ethylene diamine tetraacetate by 20～40 grams per liters as required, constantly be stirred to dissolving fully after, go into zinc salt ZnCl by 20～45 grams per liters
2Dissolve complexing.
B, be equipped with nitrilotriacetic acid(NTA) N (CH by 5～10 grams per liters
2COOH)
3, pack that another has in the water plastic tank and with strong aqua or sodium hydroxide and adjusts to PH=4～5 into, add pink salt complexing agent NH by 5～25 grams per liters then
4F or NaF are stirred to dissolving fully, add pink salt SnCl by 5～20 grams per liters
22H
2After O dissolves complexing.All pour in the plastic channel and mix.
C, adding distil water or deionized water and are adjusted to PH=2～5.5 with HCl or NaOH solution and are got final product to the volume that needs preparation in the plastic channel.
In order to make effect of the present invention better, also can in plating bath, add micro-sea-gull washing composition.
Using method of the present invention is as follows: at normal temperatures workpiece is put into plating bath, with the electrolysis zine plate of different table area and sheet tin as anode.Be negative electrode with the workpiece and pass to 0.1～1A/Dm
2Low-voltage DC, just can be on the workpiece outside surface be electroplated the fine and close coating of light.On pipe fitting or inner walls of deep holes, obtain coating if desired, can penetrate aluminium bar in the workpiece and be suspended on the negative electrode, just can make and all obtain coating on workpiece inwall and the outside surface.
Compared with the prior art, the present invention has following characteristics:
1, can prepare and use at normal temperatures, stable performance, no waste gas produces, and is free from environmental pollution, do not damage human body.
2, preparation technology and using method are simple, and energy consumption is few, and the cost that obtains coating is low.
3, both the workpiece outside surface can be plated, the workpiece inwall can be plated again.Fine and close blue or green light of amount of coating light or silvery white, anti-diluted acid caustic corrosion, of many uses.
Embodiment one
The operation steps of embodiment is the same with processing step recited above, repeats no more.Its difference is the proportioning difference of each component.The proportioning of embodiment one is as follows:
ZnCl 45 grams per liter SnCl
22H
2O 20 grams per liters
C
10H
14N
2O
8Na
22H
2O 40 grams per liters
NH
4F or NaF 25 grams per liters
N (CH
2COOH)
310 grams per liters
All the other are distilled water or deionized water PH=5.5
The proportioning of embodiment two each components is as follows:
ZnCl 20 grams per liter SnCl
22H
2O 5 grams per liters
C
10H
14N
2O
8Na
22H
2O 20 grams per liters
NH
4F or NaF 5 grams per liter N (CH
2COOH)
35 grams per liters
All the other are distilled water or deionized water PH=2
The best proportioning of embodiment three each components is as follows:
ZnCl 35 grams per liter SnCl
22H
2O 10 grams per liters
C
10H
14N
2O
8Na
22H
2O 30 grams per liters
NH
4F or NaF 10 grams per liter N (CH
2COOH)
35 grams per liters
All the other are distilled water or deionized water PH=4
Claims (4)
1, a kind of metallic surface coating Zn-Sn alloy electroplating bath preparation technology is characterized in that processing step is as follows:
A, pour into part distilled water or deionized water in plastic channel, Pei Zhi volume (as follows) adds zinc salt complexing agent disodium ethylene diamine tetraacetate by 20～40 grams per liters as required, constantly be stirred to dissolving fully after, add zinc salt ZnCl by 20～45 grams per liters
2, dissolve complexing;
B, be equipped with nitrilotriacetic acid(NTA) N (CH by 5～10 grams per liters
2COOH)
3, pack that another has in the water plastic tank and with strong aqua or sodium hydroxide and adjusts to PH=4～5 into, add pink salt complexing agent NH by 5～25 grams per liters then
4F or NaF are stirred to dissolving fully, add pink salt SnCl by 5～20 grams per liters
22H
2After O dissolves complexing, all pour in the plastic channel and mix;
C, adding distil water or deionized water and are adjusted to PH=2～2.5 with HCl or NaOH solution and are got final product to the volume that needs preparation in the plastic channel.
2, Zn-Sn alloy electroplating bath preparation technology according to claim 1 is characterized in that also can adding micro-sea-gull washing composition in plating bath.
3, a kind of metallic surface coating Zn-Sn alloy electroplating bath is characterized in that the proportioning of each component is as follows:
ZnCl
220～45 grams per liter SnCl
22H
2O 5～20 grams per liters
C
10H
14N
2O
8Na
22H
2O 20～40 grams per liters
NH
4F or NaF 5～25 grams per liters
N (CH
2COOH)
35～10 grams per liters
All the other are distilled water or deionized water PH=2～5.5
4, Zn-Sn alloy electroplating bath according to claim 3 is characterized in that the best proportioning of each component is as follows:
ZnCl
235 grams per liter SnCl
22H
2O 10 grams per liters
C
10H
14N
2O
8Na
22H
2O 30 grams per liters
NH
4F or NaF 10 grams per liter N (CH
2COOH)
35 grams per liters
All the other are distilled water or deionized water PH=4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95112541A CN1087361C (en) | 1995-11-14 | 1995-11-14 | Zinc-tin alloy plating solution and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95112541A CN1087361C (en) | 1995-11-14 | 1995-11-14 | Zinc-tin alloy plating solution and preparation process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1150183A CN1150183A (en) | 1997-05-21 |
| CN1087361C true CN1087361C (en) | 2002-07-10 |
Family
ID=5079604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95112541A Expired - Fee Related CN1087361C (en) | 1995-11-14 | 1995-11-14 | Zinc-tin alloy plating solution and preparation process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1087361C (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039629A (en) * | 1989-06-30 | 1990-02-14 | 天津通信广播公司 | A kind of bright tin plating-Zinc alloy electroplating solution |
-
1995
- 1995-11-14 CN CN95112541A patent/CN1087361C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039629A (en) * | 1989-06-30 | 1990-02-14 | 天津通信广播公司 | A kind of bright tin plating-Zinc alloy electroplating solution |
Non-Patent Citations (1)
| Title |
|---|
| 电镀合金原理与工艺 第一版 1993. 8. 1 屠振密 国防工业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1150183A (en) | 1997-05-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1170963C (en) | Cyanide-free monovalent copper eletroplating solutions | |
| CN101665962B (en) | Alkaline non-cyanide plating solution for copper-plating used on iron and steel base and preparation method thereof | |
| CN1804142A (en) | Addictive for electroplating tin and tin nickel alloy | |
| CN1292093C (en) | Trivalent chromium pearl opal passivator for galvanizing and manufacturing method thereof | |
| CN106065486A (en) | A kind of non-cyanide copper electroplating compound additive and production technology thereof | |
| CN102758228A (en) | Sulfonic acid type semi-bright pure tin electroplating solution | |
| CN1676673A (en) | Brightening agent for cyanogen-free silver-plating and its preparing method | |
| CN102220610B (en) | Non-cyanide copper-tin alloy plating solution | |
| JPH01298A (en) | Zinc-based composite plating metal materials and plating methods | |
| US5378346A (en) | Electroplating | |
| GB2120681A (en) | Zinc alloy plating baths with brighteners | |
| CN106835212A (en) | A kind of cyanideless electro-plating nanocrystalline copper electroplate liquid and its application method | |
| CN1051584C (en) | bronze plating solution and preparation method and application thereof | |
| CN1165639C (en) | Sn-In alloy electroplating liquid and its preparing method | |
| CN1087361C (en) | Zinc-tin alloy plating solution and preparation process thereof | |
| CN1058053A (en) | The method of electroplating bright nickel on Nd-Fe-B alloy | |
| CN111235607A (en) | Alkaline cyanide-free zinc plating additive and preparation method thereof | |
| CN1757798A (en) | Propanetriol non-cyanide bright copper plating liquid | |
| CN1046198A (en) | Process for producing cyanogenless continuous copper plating | |
| CN210420210U (en) | Coating structure sealed by cyanide-free cadmium-titanium alloy and graphene of aerospace fastener | |
| CN1056422C (en) | Brightener for chemical nickel plating | |
| CN109930183B (en) | Tin plating solution for aluminum alloy surface and application and method thereof | |
| CN1396303A (en) | Metallic plating liquid | |
| CN1321205A (en) | Aqueous solution for electrodepositing tin-zinc alloys | |
| CN1920104A (en) | Low slag discharging environmental protection nickel plating liquid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |