CN108736018A - A kind of zinc and air cell - Google Patents

A kind of zinc and air cell Download PDF

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Publication number
CN108736018A
CN108736018A CN201710275129.7A CN201710275129A CN108736018A CN 108736018 A CN108736018 A CN 108736018A CN 201710275129 A CN201710275129 A CN 201710275129A CN 108736018 A CN108736018 A CN 108736018A
Authority
CN
China
Prior art keywords
zinc
air cell
electrode
shell
cell according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710275129.7A
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Chinese (zh)
Inventor
宋永江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou You Teke New Energy Technology Co Ltd
Original Assignee
Changzhou You Teke New Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou You Teke New Energy Technology Co Ltd filed Critical Changzhou You Teke New Energy Technology Co Ltd
Priority to CN201710275129.7A priority Critical patent/CN108736018A/en
Publication of CN108736018A publication Critical patent/CN108736018A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • H01M4/8621Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9016Oxides, hydroxides or oxygenated metallic salts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Inert Electrodes (AREA)
  • Hybrid Cells (AREA)

Abstract

The present invention relates to a kind of zinc and air cells, including shell, the shell both ends are equipped with air electrode, have zinc electrode in shell, two groups of diaphragms are respectively equipped with positioned at the both sides of zinc electrode, electrolyte is filled in the shell, the present invention zinc and air cell is safe, height ratio capacity, greatly reduce the probability of battery short circuit, the zinc and air cell of directly-chargeable, the energy storage capacity of zinc and air cell is improved, while the fields such as energy storage can be applied on a large scale.

Description

A kind of zinc and air cell
Technical field
The present invention relates to a kind of secondary cells, more particularly, to a kind of zinc and air cell.
Background technology
Zinc and air cell is a kind of novel energy to grow up nineteen sixties, its anode is with oxygen in air As active material, negative electrode active material is metal zinc, and electrolyte is KOH aqueous solutions.Battery can make dry charged type battery, Using preceding addition electrolyte, impregnates 15 minutes or so and can be used, normal power supply in several seconds.Zinc and air cell has than energy Height is currently practical using one of highest battery kind of battery specific energy.And voltage is steady, use temperature range is wide, work Time is long, pollution-free, will not generate pollution to human body and environment in use, the refuse battery used will not be to environment It pollutes.
Since the zinc electrode of zinc and air cell is metal zinc metal sheet, both it had been kirsite, and using such zinc electrode product had been made With inefficient.
Invention content
Present invention aim to address problems set forth above, and it is empty to provide a kind of a kind of zinc improving zinc and air cell utilization rate Battery.
Realizing the technical solution of the object of the invention is:A kind of zinc and air cell of the present invention, including shell, the shell both ends are set There is air electrode, there is zinc electrode in shell, is respectively equipped with two groups of diaphragms positioned at the both sides of zinc electrode, is filled in the shell There is electrolyte.
A kind of above-mentioned zinc and air cell, the zinc electrode have the micropore being evenly distributed.
A kind of above-mentioned zinc and air cell, the zinc electrode are made of zinc oxide and/or zinc powder, binder and collector.
A kind of above-mentioned zinc and air cell, the air electrode are divided into three layers, are waterproof ventilative layer, collector and close respectively The Catalytic Layer of the electrolyte.
A kind of above-mentioned zinc and air cell, the waterproof ventilative layer are made of carbon and polytetrafluoroethylene (PTFE), wherein shared quality The content of carbon is 40% than in, and the content of polytetrafluoroethylene (PTFE) is 60%.
A kind of above-mentioned zinc and air cell, the Catalytic Layer include polytetrafluoroethylene (PTFE), activated carbon, catalyst and carbon dust.
The mass ratio of a kind of above-mentioned zinc and air cell, the polytetrafluoroethylene (PTFE) is 30%, active carbon potential 20%, and carbon dust is 30%.
A kind of above-mentioned zinc and air cell, the catalyst are manganese oxide, silver, platinum or Ca-Ti ore type, spinel-type catalyst.
The present invention has the effect of positive:The present invention zinc and air cell is safe, height ratio capacity, greatly reduce battery The probability of short circuit, the zinc and air cell of directly-chargeable improve the energy storage capacity of zinc and air cell, while can apply on a large scale The fields such as energy storage.
Description of the drawings
In order that the present invention can be more clearly and readily understood, right below according to specific embodiment and in conjunction with attached drawing The present invention is described in further detail, wherein
Fig. 1 is the structural diagram of the present invention.
Specific implementation mode
As shown in Figure 1, there is the present invention a kind of zinc and air cell, including shell 1,1 both ends of the shell to be equipped with air electrode 2, shell 1 is interior to have zinc electrode 3, is respectively equipped with two groups of diaphragms 4 positioned at the both sides of zinc electrode 3, electricity is filled in the shell 1 Solve liquid 5.The zinc electrode 3 has the micropore being evenly distributed.The zinc electrode is by zinc oxide and/or zinc powder, binder sum aggregate Fluid forms.By charging, the zinc oxide in zinc electrode is substantially transitioned to the metallic zinc with charge capacity, and electric current passes through afflux Body exports, and anode is lost under the effect of the catalyst by hydroxyl is electronically generated oxygen evolution.It is three that the air electrode 2, which divides, Layer is waterproof ventilative layer, collector and the Catalytic Layer close to the electrolyte 5 respectively.The waterproof ventilative layer is by carbon and to gather Tetrafluoroethene forms, wherein the content of carbon is 40% in shared mass ratio, the content of polytetrafluoroethylene (PTFE) is 60%.The Catalytic Layer Including polytetrafluoroethylene (PTFE), activated carbon, catalyst and carbon dust.The mass ratio of the polytetrafluoroethylene (PTFE) is 30%, active carbon potential 20%, Carbon dust is 30%.The catalyst is manganese oxide, silver, platinum or Ca-Ti ore type, spinel-type catalyst.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical solution and advantageous effect It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the guarantor of the present invention Within the scope of shield.

Claims (8)

1. a kind of zinc and air cell, it is characterised in that:Including shell (1), shell (1) both ends are equipped with air electrode (2), outside There is zinc electrode (3), the both sides for being located at zinc electrode (3) are respectively equipped with two groups of diaphragms (4), are filled in the shell (1) in shell (1) There is electrolyte (5).
2. a kind of zinc and air cell according to claim 1, it is characterised in that:The zinc electrode (3), which has, to be evenly distributed Micropore.
3. a kind of zinc and air cell according to claim 2, it is characterised in that:The zinc electrode is by zinc oxide and/or zinc Powder, binder and collector composition.
4. a kind of zinc and air cell according to claim 3, it is characterised in that:The air electrode (2) is divided into three layers, respectively It is waterproof ventilative layer, collector and the Catalytic Layer close to the electrolyte (5).
5. a kind of zinc and air cell according to claim 4, it is characterised in that:The waterproof ventilative layer is by carbon and polytetrafluoro Ethylene forms, wherein the content of carbon is 40% in shared mass ratio, the content of polytetrafluoroethylene (PTFE) is 60%.
6. a kind of zinc and air cell according to claim 5, it is characterised in that:The Catalytic Layer includes polytetrafluoroethylene (PTFE), work Property carbon, catalyst and carbon dust.
7. a kind of zinc and air cell according to claim 6, it is characterised in that:The mass ratio of the polytetrafluoroethylene (PTFE) is 30%, active carbon potential 20%, carbon dust 30%.
8. a kind of zinc and air cell according to claim 7, it is characterised in that:The catalyst is manganese oxide, silver, platinum or calcium Titanium ore type, spinel-type catalyst.
CN201710275129.7A 2017-04-17 2017-04-17 A kind of zinc and air cell Pending CN108736018A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710275129.7A CN108736018A (en) 2017-04-17 2017-04-17 A kind of zinc and air cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710275129.7A CN108736018A (en) 2017-04-17 2017-04-17 A kind of zinc and air cell

Publications (1)

Publication Number Publication Date
CN108736018A true CN108736018A (en) 2018-11-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710275129.7A Pending CN108736018A (en) 2017-04-17 2017-04-17 A kind of zinc and air cell

Country Status (1)

Country Link
CN (1) CN108736018A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112751015A (en) * 2019-10-31 2021-05-04 青岛海尔智能技术研发有限公司 Zinc cathode and preparation method thereof, zinc-air battery and direct current water heater

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN200941417Y (en) * 2006-08-24 2007-08-29 比亚迪股份有限公司 Zn-air cell
CN105789552A (en) * 2014-12-15 2016-07-20 中国科学院大连化学物理研究所 Zinc positive electrode for zinc/air battery

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN200941417Y (en) * 2006-08-24 2007-08-29 比亚迪股份有限公司 Zn-air cell
CN105789552A (en) * 2014-12-15 2016-07-20 中国科学院大连化学物理研究所 Zinc positive electrode for zinc/air battery

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
你是个那谁: "1.锌空气电池的工作原理", 《百度文库,HTTPS://WENKU.BAIDU.COM/VIEW/5A3E636E5901020206409C4F.HTML》 *
夏柳刷天籁: "锌空气电池简介", 《百度文库,HTTPS://WENKU.BAIDU.COM/VIEW/8A71C7A151E79B896802263A.HTML》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112751015A (en) * 2019-10-31 2021-05-04 青岛海尔智能技术研发有限公司 Zinc cathode and preparation method thereof, zinc-air battery and direct current water heater
CN112751015B (en) * 2019-10-31 2022-07-26 青岛海尔智能技术研发有限公司 Zinc cathode and preparation method thereof, zinc-air battery and direct current water heater

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Application publication date: 20181102

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