CN108729211A - The graphene that graphene is modified the preparation method of anti-bacterial fibre and is prepared is modified anti-bacterial fibre and gauze - Google Patents
The graphene that graphene is modified the preparation method of anti-bacterial fibre and is prepared is modified anti-bacterial fibre and gauze Download PDFInfo
- Publication number
- CN108729211A CN108729211A CN201810749199.6A CN201810749199A CN108729211A CN 108729211 A CN108729211 A CN 108729211A CN 201810749199 A CN201810749199 A CN 201810749199A CN 108729211 A CN108729211 A CN 108729211A
- Authority
- CN
- China
- Prior art keywords
- graphene
- bacterial fibre
- preparation
- modified
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 93
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 59
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 57
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 31
- 238000001035 drying Methods 0.000 claims abstract description 24
- 238000012545 processing Methods 0.000 claims abstract description 23
- 239000011259 mixed solution Substances 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 16
- 238000012986 modification Methods 0.000 claims abstract description 14
- 230000004048 modification Effects 0.000 claims abstract description 14
- WIVXEZIMDUGYRW-UHFFFAOYSA-L copper(i) sulfate Chemical compound [Cu+].[Cu+].[O-]S([O-])(=O)=O WIVXEZIMDUGYRW-UHFFFAOYSA-L 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000011282 treatment Methods 0.000 claims abstract description 6
- 230000008569 process Effects 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000000465 moulding Methods 0.000 claims description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000001954 sterilising effect Effects 0.000 abstract description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 3
- 230000002421 anti-septic effect Effects 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920002101 Chitin Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000322338 Loeseliastrum Species 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 229920000914 Metallic fiber Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000037358 bacterial metabolism Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- -1 graphite Alkene Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229910021655 trace metal ion Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention discloses the graphenes that a kind of graphene is modified the preparation method of anti-bacterial fibre and is prepared to be modified anti-bacterial fibre and gauze, method is that graphene plantation is coated on fiber surface, it is modified anti-bacterial fibre to obtain graphene, is contained in the specific steps of method：S1：Graphene powder is added to the water and is ultrasonically treated with cuprous sulfate powder, mixed solution is obtained；S2：Pending fiber is soaked in mixed solution, and heats pressurized treatments for a period of time；S3：By treated, fiber takes out, and washes and obtains graphene modification anti-bacterial fibre after drying and processing.The invention enables the sterilization of the graphene being prepared modification anti-bacterial fibre, bacteriostasis property are fabulous and nontoxic, environmentally friendly, reusable.
Description
Technical field
The present invention relates to the graphenes that a kind of graphene is modified the preparation method of anti-bacterial fibre and is prepared to be modified antibacterial
Fiber and gauze, belong to field of material engineering technology.
Background technology
Currently, anti-bacterial fibre be it is a kind of have sterilization, bacteriostasis property functional fiber, wherein playing major antibacterial, antibacterial
Function is antiseptic.Main organic and inorganic two class of antiseptic currently used for textile.Organic antibacterial agent is usually logical
The negative electrical charge for crossing positive charge group and bacterium surface that active constituent carries attracts each other, and physically destroys the cell of bacterium
Film plays the function of bacteriostasis antibiosis；Inorganic antiseptic is the trace metal ion that is gradually dissolved out in allowing fiber into bacterial cell
Diffusion, causes bacterial metabolism obstacle and dead, such as metal ion (Ag, Cu, Zn) type antiseptic, oxide photocatalyst-type anti-biotic
Agent etc. (TiO2, ZnO, MgO etc.).
The difference of antiseptic addition manner, anti-bacterial fibre can be divided into following a few classes：
1, per se with the fiber of antibacterial functions, such as certain bast-fibres, chitin fiber and metallic fiber；
2, the textile arranged with antiseptic, this method simple processing, but washability is slightly poor；
3, antiseptic is added in fiber and manufactured anti-bacterial fibre in synthetic fiber spinning, this kind of fibre antibacterial, washability
It is good, it is easy to knit dye processing.
The research of antiseptic is concentrated mainly in metal ion type at present, this kind of antiseptic has high temperature resistant, persistence
The advantages that good, but poor dispersion in the fibre, and whether harmful there is also disputes to human body.
Invention content
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, it is fine to provide a kind of graphene modification antibacterial
The preparation method of dimension, it so that the graphene being prepared modification anti-bacterial fibre is sterilized, bacteriostasis property is fabulous and nontoxic, ring
It protects, is reusable.
In order to solve the above-mentioned technical problem, the technical scheme is that：A kind of graphene is modified the preparation of anti-bacterial fibre
Method, method are：
Graphene plantation is coated on fiber surface, anti-bacterial fibre is modified to obtain graphene.
Further, the fiber is Fypro.
Further provide it is a kind of how graphene being planted into the method for being coated on fiber surface, in the specific steps of method
Contain：
S1：Graphene powder is added to the water and is ultrasonically treated with cuprous sulfate powder, mixed solution is obtained；
S2：Pending fiber is soaked in mixed solution, and heats pressurized treatments for a period of time；
S3：By treated, fiber takes out, and washes and obtains graphene modification anti-bacterial fibre after drying and processing.
Further, in step sl, the mass ratio of graphene powder and cuprous sulfate powder is (1~3)：1, and/or it is mixed
It is 5/2/1000ths~thousand to close the Solute mass fraction in solution.
Further, in step sl, the time of supersound process is 1~2 hour, and supersound process frequency is 10~30KHz.
Further, in step s 2, it heats and contains in the parameter of pressurization：Heating temperature is 80 DEG C~100 DEG C and/or pressurization
Pressure is 0.5~1MPa and/or the processing time of heating pressurization is 8-12 hours.
Further, in step s 2, the volume ratio of fiber and mixed solution is 1：(2~3).
Further, in step s3, contain in the parameter of drying and processing：Drying temperature is 70 DEG C~90 DEG C and/or drying
Processing time is 1~2 hour.
The present invention also provides a kind of graphenes to be modified anti-bacterial fibre, it is prepared by the preparation method.
The present invention also provides a kind of gauzes, it is modified anti-bacterial fibre by graphene and is made.
After using above-mentioned technical proposal, compared to nano-metal antibacterial agent and other physics, chemical sterilization method, graphite
Alkene be modified anti-bacterial fibre advantage be：
1, the water body under room temperature, normal pressure and air environment all can be used.
2, Wet or dry condition also all can be used；
It 3, need not be by the energy and complex device or utensil；
4, without Environment release, without danger, such as explosion, the dangerous hidden danger of radiation etc.；
5, antibacterial, it is antibacterial efficiently and effectively；
6, environmentally safe, without discharge.
The graphene of the present invention is modified anti-bacterial fibre and preparation method thereof, and graphene is melted in fiber different from existing
The method being granulated in master batch, this programme is used is coated on the method for fiber surface to prepare graphene modification by graphene plantation
Anti-bacterial fibre, compared with prior art, this method have it is simple for process, of low cost, the features such as fiber surface is evenly distributed,
Meanwhile prepared graphene is modified anti-bacterial fibre with the advantageous characteristics such as nontoxic, environmentally friendly, reusable.
Description of the drawings
Fig. 1 is pristine fibre surface SEM photograph figure；
Fig. 2 is the surface SEM photograph figure that graphene is modified anti-bacterial fibre；
Fig. 3 is the surface SEM photograph figure of the graphene modification anti-bacterial fibre after 50 washings.
Specific implementation mode
In order that the present invention can be more clearly and readily understood, right below according to specific embodiment and in conjunction with attached drawing
The present invention is described in further detail.
Embodiment one
A kind of graphene is modified the preparation method of anti-bacterial fibre, contains in the specific steps of method：
S1：It takes 0.5g graphene powders to be placed in 1000ml beakers with 0.5g cuprous sulfate powder, 500ml distilled water is added
And be put into ultrasonic vibration instrument and be ultrasonically treated, obtain mixed solution；
S2：Pending fiber is soaked in mixed solution, and heats pressurized treatments for a period of time；
S3：By treated, fiber takes out, and washes and simultaneously obtains graphene modification antibacterial fibre after drying and processing in drying box
Dimension.
In step sl, the time of supersound process is 1 hour, and supersound process frequency is 30KHz.
In step s 2, it heats and contains in the parameter of pressurization：Heating temperature is 80 DEG C, moulding pressure is 0.5MPa and heating
The processing time of pressurization is 12 hours.
In step s 2, the volume ratio of fiber and mixed solution is 1：2.
In step s3, contain in the parameter of drying and processing：Drying temperature is 70 DEG C, the drying and processing time is 1 hour.
In the present embodiment, the fiber can be Fypro (polyamide fibre), and but not limited to this.Graphene is modified anti-
The preparation method of bacterium fiber is also not necessarily limited to apply in Fypro, can also be applied in other various fibers, at other
Adopting said method is also protected in fiber.
Embodiment two
A kind of graphene is modified the preparation method of anti-bacterial fibre, contains in the specific steps of method：
S1：It takes 1g graphene powders to be placed in 1000ml beakers with 0.5g cuprous sulfate powder, 500ml distilled water is added simultaneously
It is put into ultrasonic vibration instrument and is ultrasonically treated, obtain mixed solution；
S2：Pending fiber is soaked in mixed solution, and heats pressurized treatments for a period of time；
S3：By treated, fiber takes out, and washes and simultaneously obtains graphene modification antibacterial fibre after drying and processing in drying box
Dimension.
In step sl, the time of supersound process is 1 hour, and supersound process frequency is 30KHz.
In step s 2, it heats and contains in the parameter of pressurization：Heating temperature is 90 DEG C, moulding pressure is 0.5MPa and heating
The processing time of pressurization is 8 hours.
In step s 2, the volume ratio of fiber and mixed solution is 1：2.
In step s3, contain in the parameter of drying and processing：Drying temperature is 70 DEG C, the drying and processing time is 1 hour.
In the present embodiment, the fiber can be Fypro (polyamide fibre), and but not limited to this.
Embodiment three
A kind of graphene is modified the preparation method of anti-bacterial fibre, contains in the specific steps of method：
S1：It takes 1g graphene powders to be placed in 1000ml beakers with 0.5g cuprous sulfate powder, 500ml distilled water is added simultaneously
It is put into ultrasonic vibration instrument and is ultrasonically treated, obtain mixed solution；
S2：Pending fiber is soaked in mixed solution, and heats pressurized treatments for a period of time；
S3：By treated, fiber takes out, and washes and simultaneously obtains graphene modification antibacterial fibre after drying and processing in drying box
Dimension.
In step sl, the time of supersound process is 1 hour, and supersound process frequency is 30KHz.
In step s 2, it heats and contains in the parameter of pressurization：Heating temperature is 100 DEG C, moulding pressure is 1MPa and heating
The processing time of pressurization is 8 hours.
In step s 2, the volume ratio of fiber and mixed solution is 1：3.
In step s3, contain in the parameter of drying and processing：Drying temperature is 70 DEG C, the drying and processing time is 1 hour.
In the present embodiment, the fiber can be Fypro (polyamide fibre), and but not limited to this.
The graphene being prepared in embodiment one to three is modified the preparation method of anti-bacterial fibre, mainly by graphene kind
Plant is coated on fiber surface, and anti-bacterial fibre is modified to obtain graphene.
Also, the preparation method that embodiment one is modified anti-bacterial fibre to the graphene of embodiment three and the present invention is not limited to
It applies in Fypro, can also be applied in other various fibers, adopting said method is also protected in other fibers
Shield.
It is pristine fibre surface SEM photograph figure as shown in Figure 1, it is fine to be modified antibacterial to graphene prepared by embodiment one to three
Dimension carries out antibacterial and Surface testing, wherein Surface testing observes fiber surface using SEM, is illustrated in figure 2 the preparation of embodiment three
Obtained graphene is modified the surface SEM photograph figure of anti-bacterial fibre, is illustrated in figure 3 the graphene that embodiment three is prepared and changes
Property surface SEM photograph figure of the anti-bacterial fibre after 50 washings, the detection of antibacterial test is according to being GB/T 20944.2-
2007《The evaluation of antibacterial textile performance》Part 2：Absorption process, sample explanation：Control sample is standard cotton calico, according to mark
Quasi- regulation, is cut into 18mm × 18mm sizes by control sample, respectively weighs 0.4 gram, the graphene that embodiment one to three is prepared
Antibacterial testing result of the modified anti-bacterial fibre after 50 washings is as shown in the table.
The graphene that embodiment one to three is prepared is modified antibacterial testing result of the anti-bacterial fibre after 50 washings
Table
By above table as can be seen that the graphene modification anti-bacterial fibre that embodiment one to embodiment three is prepared resists
Bacterium, bacteriostasis are fabulous.
Particular embodiments described above, pair present invention solves the technical problem that, technical solution and advantageous effect carry out
It is further described, it should be understood that the above is only a specific embodiment of the present invention, is not limited to this
Invention, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in this hair
Within bright protection domain.
Claims (10)
1. a kind of graphene is modified the preparation method of anti-bacterial fibre, it is characterised in that method is：
Graphene plantation is coated on fiber surface, anti-bacterial fibre is modified to obtain graphene.
2. preparation method according to claim 1, it is characterised in that：The fiber is Fypro.
3. preparation method according to claim 1, it is characterised in that contain in the specific steps of method：
S1：Graphene powder is added to the water and is ultrasonically treated with cuprous sulfate powder, mixed solution is obtained；
S2：Pending fiber is soaked in mixed solution, and heats pressurized treatments for a period of time；
S3：By treated, fiber takes out, and washes and obtains graphene modification anti-bacterial fibre after drying and processing.
4. preparation method according to claim 3, it is characterised in that：In step sl, graphene powder and cuprous sulfate
The mass ratio of powder is（1~3）：1 and/or mixed solution in Solute mass fraction be 5/2/1000ths ~ thousand.
5. preparation method according to claim 3, it is characterised in that：In step sl, the time of supersound process is 1 ~ 2 small
When, supersound process frequency is 10 ~ 30KHz.
6. preparation method according to claim 3, it is characterised in that：In step s 2, it heats and contains in the parameter of pressurization：
Heating temperature is 80 DEG C ~ 100 DEG C and/or moulding pressure is 0.5 ~ 1MPa and/or the processing time of heating pressurization is 8-12 hours.
7. preparation method according to claim 3, it is characterised in that：In step s 2, the volume of fiber and mixed solution
Than being 1：（2~3）.
8. preparation method according to claim 3, it is characterised in that：In step s3, contain in the parameter of drying and processing：
Drying temperature is 70 DEG C ~ 90 DEG C and/or the drying and processing time is 1 ~ 2 hour.
9. a kind of graphene is modified anti-bacterial fibre, it is characterised in that：It is by preparation such as described in any item of the claim 1 to 8
Method is prepared.
10. a kind of gauze, it is characterised in that：It is modified anti-bacterial fibre by graphene as claimed in claim 9 and is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810749199.6A CN108729211B (en) | 2018-07-10 | 2018-07-10 | Preparation method of graphene modified antibacterial fiber and prepared graphene modified antibacterial fiber and gauze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810749199.6A CN108729211B (en) | 2018-07-10 | 2018-07-10 | Preparation method of graphene modified antibacterial fiber and prepared graphene modified antibacterial fiber and gauze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108729211A true CN108729211A (en) | 2018-11-02 |
| CN108729211B CN108729211B (en) | 2023-11-17 |
Family
ID=63926519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810749199.6A Active CN108729211B (en) | 2018-07-10 | 2018-07-10 | Preparation method of graphene modified antibacterial fiber and prepared graphene modified antibacterial fiber and gauze |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108729211B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111021050A (en) * | 2020-01-03 | 2020-04-17 | 深圳市寒暑科技新能源有限公司 | Antibacterial cotton fiber and preparation method thereof |
| CN111996793A (en) * | 2020-09-09 | 2020-11-27 | 宁波中冶电子科技有限公司 | Preparation method and application of graphene antibacterial cloth |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102839534A (en) * | 2012-08-30 | 2012-12-26 | 西北工业大学 | Surface modification method of carbon fiber by plasma treatment and coating of nano graphene |
| CN105002736A (en) * | 2015-07-07 | 2015-10-28 | 武汉纺织大学 | Graphene/polyvinyl alcohol modified nonwoven fabric production method |
| CN106367952A (en) * | 2015-07-23 | 2017-02-01 | 徐海波 | Surface treatment method for carbon fibers using oxidized graphene quantum dots as coating, and composite material |
| CN106930096A (en) * | 2017-03-15 | 2017-07-07 | 山东圣泉新材料股份有限公司 | A kind of modified fibre product, preparation method and its usage |
| CN106930098A (en) * | 2017-03-15 | 2017-07-07 | 山东圣泉新材料股份有限公司 | A kind of composite fibre, preparation method and its usage |
| CN106930097A (en) * | 2017-03-15 | 2017-07-07 | 山东圣泉新材料股份有限公司 | A kind of modified fibre product, preparation method and its usage |
| CN107006516A (en) * | 2017-04-14 | 2017-08-04 | 南通强生石墨烯科技有限公司 | Graphene antibiosis liquid and preparation method thereof |
| CN107237120A (en) * | 2017-07-10 | 2017-10-10 | 山东圣泉新材料股份有限公司 | A kind of fibre maceration extract, modified fibre product and preparation method |
-
2018
- 2018-07-10 CN CN201810749199.6A patent/CN108729211B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102839534A (en) * | 2012-08-30 | 2012-12-26 | 西北工业大学 | Surface modification method of carbon fiber by plasma treatment and coating of nano graphene |
| CN105002736A (en) * | 2015-07-07 | 2015-10-28 | 武汉纺织大学 | Graphene/polyvinyl alcohol modified nonwoven fabric production method |
| CN106367952A (en) * | 2015-07-23 | 2017-02-01 | 徐海波 | Surface treatment method for carbon fibers using oxidized graphene quantum dots as coating, and composite material |
| CN106930096A (en) * | 2017-03-15 | 2017-07-07 | 山东圣泉新材料股份有限公司 | A kind of modified fibre product, preparation method and its usage |
| CN106930098A (en) * | 2017-03-15 | 2017-07-07 | 山东圣泉新材料股份有限公司 | A kind of composite fibre, preparation method and its usage |
| CN106930097A (en) * | 2017-03-15 | 2017-07-07 | 山东圣泉新材料股份有限公司 | A kind of modified fibre product, preparation method and its usage |
| CN107006516A (en) * | 2017-04-14 | 2017-08-04 | 南通强生石墨烯科技有限公司 | Graphene antibiosis liquid and preparation method thereof |
| CN107237120A (en) * | 2017-07-10 | 2017-10-10 | 山东圣泉新材料股份有限公司 | A kind of fibre maceration extract, modified fibre product and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| 姜山等: "《纳米》", 30 September 2013, 科学普及出版社 * |
| 马世昌: "《化学物质辞典》", 30 April 1999, 陕西科学技术出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111021050A (en) * | 2020-01-03 | 2020-04-17 | 深圳市寒暑科技新能源有限公司 | Antibacterial cotton fiber and preparation method thereof |
| CN111996793A (en) * | 2020-09-09 | 2020-11-27 | 宁波中冶电子科技有限公司 | Preparation method and application of graphene antibacterial cloth |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108729211B (en) | 2023-11-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Fan et al. | Mussel-induced nano-silver antibacterial, self-healing, self-adhesive, anti-freezing, and moisturizing dual-network organohydrogel based on SA-PBA/PVA/CNTs as flexible wearable strain sensors | |
| Kumar et al. | Reusable MoS2-modified antibacterial fabrics with photothermal disinfection properties for repurposing of personal protective masks | |
| Liu et al. | Novel alginate-cellulose nanofiber-poly (vinyl alcohol) hydrogels for carrying and delivering nitrogen, phosphorus and potassium chemicals | |
| CN103614927B (en) | A kind of fiber textile containing cellulose antibiotic finishing method | |
| TWI359219B (en) | ||
| CN112760742B (en) | Traditional Chinese medicine composite antiviral multifunctional degradable polylactic acid fiber and preparation method thereof | |
| CN112941652A (en) | Chinese herbal compound anti-coronavirus and anti-influenza virus antibacterial degradable multifunctional fiber | |
| CN103705969A (en) | Method for preparing chitosan-based silver-loaded composite antimicrobial superfine fiber membrane | |
| CN108729211A (en) | The graphene that graphene is modified the preparation method of anti-bacterial fibre and is prepared is modified anti-bacterial fibre and gauze | |
| CN108621481B (en) | Antibacterial fabric containing silver ions and antibacterial textile | |
| CN105754136A (en) | Antibacterial aerogel with cellulose loaded with nano silver and preparation method and application thereof | |
| CN106012510B (en) | Have anti-bacterial fibre, antibacterial textile of washability and preparation method thereof | |
| CN107142720B (en) | A kind of preparation method of graphene exposure suit | |
| Erdogan | Textile finishing with chitosan and silver nanoparticles against Escherichia coli ATCC 8739 | |
| Ghiasi et al. | Electrospinning of wheat bran cellulose/TiO2/ZnO nanofibre and investigating the UV blocking and bactericidal properties | |
| CN108642872A (en) | A kind of anti-bacterial fibre and preparation process | |
| CN111549521B (en) | Preparation method of antibacterial fabric, antibacterial fabric and antibacterial product | |
| CN103147289A (en) | In-situ complexing method for preparing antibacterial fabric by simple steps | |
| Dat et al. | Surface modification of poly (propylene) fabric with graphene oxide‐based silver nanoparticles for antibacterial applications | |
| Liu et al. | Fabrication of antimicrobial viscose fibers containing silver nanoparticle@ catechol formaldehyde resin microspheres | |
| Riaz et al. | Recent advances in development of antimicrobial textiles | |
| Tang et al. | A review of cellulose-based catechol-containing functional materials for advanced applications | |
| CN103122581A (en) | Preparation method of antibacterial fibers with soft hand-feel by in-situ complexing method | |
| CN116084042B (en) | Manufacturing method of multifunctional Chinese mugwort herb fiber material | |
| Ramya et al. | Analysis of the antimicrobial efficacy of bamboo/cotton knitted fabric finished with the extracts of the Syzygium aromaticum buds |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |