CN108727247A - A kind of antifoggant based on indole derivatives - Google Patents

A kind of antifoggant based on indole derivatives Download PDF

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Publication number
CN108727247A
CN108727247A CN201810726153.2A CN201810726153A CN108727247A CN 108727247 A CN108727247 A CN 108727247A CN 201810726153 A CN201810726153 A CN 201810726153A CN 108727247 A CN108727247 A CN 108727247A
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CN
China
Prior art keywords
antifoggant
indole derivatives
antifog
water
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810726153.2A
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Chinese (zh)
Inventor
王恩佳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xi'an Follow Heart Car Service Co Ltd
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Xi'an Follow Heart Car Service Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Xi'an Follow Heart Car Service Co Ltd filed Critical Xi'an Follow Heart Car Service Co Ltd
Priority to CN201810726153.2A priority Critical patent/CN108727247A/en
Publication of CN108727247A publication Critical patent/CN108727247A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D209/00Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04Indoles; Hydrogenated indoles
    • C07D209/30Indoles; Hydrogenated indoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to carbon atoms of the hetero ring
    • C07D209/42Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of antifoggant based on indole derivatives, including indole derivatives, assistance agent and solvent, shown in the structural formula such as formula (I) of the indole derivatives.Antifoggant construction proposed by the present invention based on indole derivatives is simple, easy to clean.In construction, it is only necessary to spray antifoggant or coated on glass, the problem of then being wiped with towel or paper handkerchief etc., be rubbed off there is no anti-fog coating in work progress, unlikely occur due to uneven caused glare problem.

Description

A kind of antifoggant based on indole derivatives
Technical field
The present invention relates to a kind of antifoggants, and in particular to a kind of antifoggant based on indole derivatives.
Background technology
Autumn and winter, water mist lead to blurred vision in interior surfaces of glass condensation, the visual field of household and office are influenced, such as in automobile It is even more to constitute to seriously threaten to vehicle safety travel if glass hazes.China's motor traffic accidents in 2015 is more than 30 ten thousand It rises, due to weather, traffic accident caused by the visual field is fuzzy accounts for about 1/3.Currently used antifoggant is surfactant type With two class of polymer electrolyte antifoggant, the former reduces the surface tension of water by surfactant so that water mist is flat in glass surface It spreads out, realizes preferable anti-fog effect, be the mainstream in market, but the antifog time only has 2~3 days.Existing antifoggant is to skill of constructing Art is more demanding:It if gently smeared, can cause to smear uneven, glare phenomenon is serious, will will if firmly smeared slightly Antifoggant is wiped, and anti-fog effect is lost.The above problem existing for existing antifoggant limits its promotion and application.There is an urgent need for anti-in market Fog effect is good, and the antifog time is long, easy high-performance long-acting antifoggant of constructing.
Invention content
The purpose of the present invention is to provide a kind of antifoggants based on indole derivatives, solve existing for existing antifoggant Problem, antifog time are up to 4 months or more, and it is extremely simple to construct.
In order to achieve the above-mentioned object of the invention, technical scheme is as follows:
A kind of antifoggant based on indole derivatives, including indole derivatives, assistance agent and solvent, the indoles derive Shown in the structural formula of object such as formula (I):
Indole derivatives contain amino, carboxylic group, contain allyl simultaneously.The double bond of allyl can under sunlight With spontaneous carry out polymerization film formation, the adhesive force of antifoggant is promoted, and then antifog persistence can be promoted.The amino introduced on indoles There is stronger hydrophily with carboxyl, anti-fog effect can be promoted.Indoles has the stronger ability for absorbing ultraviolet light simultaneously, can To promote the UV resistance of antifoggant, and then promote the stability of film layer.
It is preferred that the assistance agent is sodium carboxymethylcellulose.The antifoggant based on indole derivatives, use Assistance agent is sodium carboxymethylcellulose, and this auxiliary agent can prevent antifoggant liquid spontaneous polymerization during storage, is extended The resting period of antifoggant liquid itself.
When antifoggant is coated on glass, since double bond not yet polymerize at this time, it is very easy to coating uniformly, it will not There is the problem of glare.It after the completion of construction, irradiates in the sun, double-bond polymerization film forming, antifoggant realizes firm attachment.Due to anti- Contain a large amount of amino and carboxyl in mist agent, when water mist encounters antifog film, moment is absorbed, and is realized antifog.
It is preferred that the mass concentration of the indole derivatives is 0.1%~18%, the mass concentration of the assistance agent is 0.1%~5%.By experimental test, the content of indole derivatives is 0.1%~18%, and carboxymethylcellulosodium sodium content is When 0.1%~5%, anti-fog effect is best, can reach 4 months or more, and the duration of 2~3 days than existing antifoggant has The promotion of matter.
It is preferred that the one kind of the solvent in water, ethyl alcohol, methanol, propyl alcohol, acetone, ethyl acetate and petroleum ether.
In the present invention, the use concentration of the mass concentration of indole derivatives and the equal relative solvent of mass concentration of assistance agent For.
The present invention also protects the application of the antifoggant based on indole derivatives, is particularly applicable on glass.
The beneficial effects of the invention are as follows:
(1) the anti-fog effect of the present invention is quickly and efficiently.Indole derivatives contain amino, carboxylic group, contain allyl simultaneously Base, the double bond of allyl under sunlight can spontaneous carry out polymerization film formation, promote the adhesive force of antifoggant, and then can carry Rise antifog persistence;The amino and carboxyl introduced on indoles has stronger hydrophily, can promote anti-fog effect;Indoles simultaneously With the stronger ability for absorbing ultraviolet light, the UV resistance of antifoggant can be promoted, and then promote the stability of film layer;? It is irradiated under sunlight, double-bond polymerization film forming, antifoggant realizes firm attachment.Due to containing a large amount of amino and carboxyl in antifoggant, When water mist encounters antifog film, moment is absorbed, and is realized antifog.
(2) the present invention antifog time is long.The double bond of allyl under sunlight can spontaneous carry out polymerization film formation, promoted The adhesive force of antifoggant, and then antifog persistence can be promoted, therefore can be by antifog time lengthening to 4 months or more, than existing 2~3 days duration of antifoggant are improved.
(3) present invention construction is simple, easy to clean.In construction, it is only necessary to spray antifoggant or be coated on glass, so The problem of being wiped with towel or paper handkerchief etc., being rubbed off there is no anti-fog coating in work progress afterwards, unlikely goes out Now due to uneven caused glare problem.
In short, the present invention is easy to clean, pollution-free, construction is simple, good antifogging effect, antifog time length (up to 4 months with On), all more existing antifoggant has qualitative leap on anti-fog duration and construction, solves the defect of existing antifoggant, It can be promoted in fields such as building, automobiles.
Description of the drawings
Fig. 1 is the scanning electron microscope (SEM) photograph for the antifoggant that embodiment 2 is prepared.
Specific implementation mode
With reference to specific example, the present invention is furture elucidated.It should be understood that these embodiments are merely to illustrate this hair It is bright, rather than limit protection scope of the present invention.Technical staff is according to the improvement of the invention made and tune in practical applications It is whole, still fall within protection scope of the present invention.
Except special instruction, equipment and reagent that the present invention uses are the art regular market purchase product.
Embodiment 1
A kind of antifoggant based on indole derivatives, the indole derivatives 0.1wt% shown in formula (I), carboxymethyl cellulose Plain sodium 0.1wt% and water 99.8wt% compositions,
A kind of preparation method of the antifoggant based on indole derivatives:
(1) according to the component and dosage of above-mentioned antifoggant, indole derivatives, sodium carboxymethylcellulose and water are weighed;
(2) indole derivatives and sodium carboxymethylcellulose that step (1) weighs are sequentially added in water, is stirred It is even to get the antifoggant based on indole derivatives.
Embodiment 2
A kind of antifoggant based on indole derivatives, the indole derivatives 10wt% shown in formula (I), carboxymethyl cellulose Sodium 3wt% and water 87wt% compositions,
A kind of preparation method of the antifoggant based on boroxane derivative:
(1) according to the component and dosage of above-mentioned antifoggant, indole derivatives, sodium carboxymethylcellulose and water are weighed;
(2) indole derivatives and sodium carboxymethylcellulose that step (1) weighs are sequentially added in water, is stirred It is even to get the antifoggant based on indole derivatives.
Embodiment 3
A kind of antifoggant based on indole derivatives, the indole derivatives 18wt% shown in formula (I), carboxymethyl cellulose Sodium 5wt% and water 77wt% compositions,
A kind of preparation method of the antifoggant based on indole derivatives:
(1) according to the component and dosage of above-mentioned antifoggant, indole derivatives, sodium carboxymethylcellulose and water are weighed;
(2) indole derivatives and sodium carboxymethylcellulose that step (1) weighs are sequentially added in water, is stirred It is even to get the antifoggant based on boroxane derivative.
Test case:
Antifoggant and certain commercially available brand antifoggant that Examples 1 to 3 is obtained 1 carries out the antifog time as a comparison case Measurement.
The step of antifog time measures:Prepare 5 clean slides, Examples 1 to 3 is applied in the single side of 4 clean slides 1~4,1 sheet glass of test sample is obtained successively as blank sample with the antifoggant of comparative example 1, and test sample dries.By water 40 DEG C are heated to, makes to be coated with antifoggant that face face water surface, distance about 10cm, time contact every time with vapor is 5min, Then naturally dry.Judged with there is " number of occurrence " before atomization there are about 10% glass surface.1 day morning and evening is twice Alternation of wetting and drying, being calculated as a cycle i.e. antifog time twice is calculated as 1d, and obtained test result is as shown in table 1.
Table 1
Sample Blank 1 2 3 4
Antifog time (d) 0 120 152 125 3
It can be obtained by table 1, the antifog time longest of the antifoggant that embodiment 2~3 is prepared was up to 125~152 days.
It is verified repeatedly by inventor, the solvent replacement in Examples 1 to 3 is ethyl alcohol, methanol, propyl alcohol, acetone, acetic acid second The antifoggant that ester or petroleum ether are prepared remains to reach 4~5 months antifog time.
Above-listed detailed description is illustrating for possible embodiments of the present invention, which is not to limit this hair Bright the scope of the claims, all equivalence enforcements or change without departing from carried out by the present invention are intended to be limited solely by the scope of patent protection of this case In.

Claims (7)

1. a kind of antifoggant based on indole derivatives, which is characterized in that including indole derivatives, agent and solvent are assisted, it is described Indole derivatives structural formula such as formula (I) shown in:
2. the antifoggant according to claim 1 based on indole derivatives, which is characterized in that the assistance agent is carboxylic first Base sodium cellulosate.
3. the antifoggant according to claim 1 based on indole derivatives, which is characterized in that the indole derivatives Mass concentration is 0.1%~18%.
4. the antifoggant according to claim 1 based on indole derivatives, which is characterized in that the quality for assisting agent is dense Degree is 0.1%~5%.
5. the antifoggant according to claim 1 based on indole derivatives, which is characterized in that the solvent be selected from water, One kind in ethyl alcohol, methanol, propyl alcohol, acetone, ethyl acetate and petroleum ether.
6. the application of antifoggant of the Claims 1 to 5 any one of them based on indole derivatives.
7. the application of the antifoggant according to claim 6 based on indole derivatives, which is characterized in that apply in glass On.
CN201810726153.2A 2018-07-04 2018-07-04 A kind of antifoggant based on indole derivatives Pending CN108727247A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201810726153.2A CN108727247A (en) 2018-07-04 2018-07-04 A kind of antifoggant based on indole derivatives

Publications (1)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0339909A2 (en) * 1988-04-28 1989-11-02 Nippon Oil And Fats Company, Limited Anti-fogging resin film-forming composition
CN104845587A (en) * 2015-05-21 2015-08-19 青岛千帆高新技术有限公司 Antifogging agent for automobile glass
CN105238355A (en) * 2015-10-26 2016-01-13 陈麒雅 Long-acting glass antifog membrane and preparation method thereof
CN107384316A (en) * 2017-08-11 2017-11-24 陈奕安 A kind of glass antidimmer red based on pyrroles and its preparation method and application
CN107794000A (en) * 2017-08-11 2018-03-13 陈奕安 A kind of glass antidimmer based on primary cellulose acetate and its preparation method and application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0339909A2 (en) * 1988-04-28 1989-11-02 Nippon Oil And Fats Company, Limited Anti-fogging resin film-forming composition
CN104845587A (en) * 2015-05-21 2015-08-19 青岛千帆高新技术有限公司 Antifogging agent for automobile glass
CN105238355A (en) * 2015-10-26 2016-01-13 陈麒雅 Long-acting glass antifog membrane and preparation method thereof
CN107384316A (en) * 2017-08-11 2017-11-24 陈奕安 A kind of glass antidimmer red based on pyrroles and its preparation method and application
CN107794000A (en) * 2017-08-11 2018-03-13 陈奕安 A kind of glass antidimmer based on primary cellulose acetate and its preparation method and application

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Application publication date: 20181102

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