CN108719308A - 一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物 - Google Patents
一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物 Download PDFInfo
- Publication number
- CN108719308A CN108719308A CN201810944455.7A CN201810944455A CN108719308A CN 108719308 A CN108719308 A CN 108719308A CN 201810944455 A CN201810944455 A CN 201810944455A CN 108719308 A CN108719308 A CN 108719308A
- Authority
- CN
- China
- Prior art keywords
- adipic acid
- ethyl ketone
- acid copper
- pyrrole ethyl
- thiazole pyrrole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000282376 Panthera tigris Species 0.000 title claims abstract description 28
- 239000003292 glue Substances 0.000 title claims abstract description 28
- ZCXLQZOQWCXFNN-UHFFFAOYSA-N copper;hexanedioic acid Chemical compound [Cu].OC(=O)CCCCC(O)=O ZCXLQZOQWCXFNN-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 17
- IPPZJWGYHAMLAB-UHFFFAOYSA-N C(C)C(=O)CC.N1C=CC=C1.S1C=NC=C1 Chemical compound C(C)C(=O)CC.N1C=CC=C1.S1C=NC=C1 IPPZJWGYHAMLAB-UHFFFAOYSA-N 0.000 title claims abstract description 6
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 6
- 239000011737 fluorine Substances 0.000 title claims abstract description 6
- 125000001153 fluoro group Chemical group F* 0.000 title claims abstract description 5
- FXYOBYMJDLKKMF-UHFFFAOYSA-N C(C)C(=O)CC.N1C=CC=C1.S1C=NC=C1.[F] Chemical compound C(C)C(=O)CC.N1C=CC=C1.S1C=NC=C1.[F] FXYOBYMJDLKKMF-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000002360 preparation method Methods 0.000 claims description 17
- 230000000361 pesticidal effect Effects 0.000 claims description 13
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 239000004563 wettable powder Substances 0.000 claims description 3
- 239000002552 dosage form Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- 241000233679 Peronosporaceae Species 0.000 abstract description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 6
- 230000002265 prevention Effects 0.000 abstract description 6
- 206010059866 Drug resistance Diseases 0.000 abstract description 5
- 201000010099 disease Diseases 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 230000003111 delayed effect Effects 0.000 abstract 1
- 230000003641 microbiacidal effect Effects 0.000 abstract 1
- 229940124561 microbicide Drugs 0.000 abstract 1
- 239000002855 microbicide agent Substances 0.000 abstract 1
- 240000008067 Cucumis sativus Species 0.000 description 7
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- 231100000419 toxicity Toxicity 0.000 description 7
- 230000001988 toxicity Effects 0.000 description 7
- 239000003814 drug Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 244000052769 pathogen Species 0.000 description 3
- 230000001717 pathogenic effect Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 238000004382 potting Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 208000031968 Cadaver Diseases 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- AHJOLADQNBVHTL-UHFFFAOYSA-N O1N=CC=C1.N1(CCCCC1)C=1SC=CN1 Chemical class O1N=CC=C1.N1(CCCCC1)C=1SC=CN1 AHJOLADQNBVHTL-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical group C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 125000003971 isoxazolinyl group Chemical group 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000003226 pyrazolyl group Chemical group 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 210000004885 white matter Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
本发明公开了一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物，氟噻唑吡乙酮和琥胶肥酸铜的重量比是1:50‑50:1；该杀菌组合物可用于防治多种作物的病害，尤其用于霜霉病的防治。本发明杀菌剂组合物具有增效、对环境污染性小，可延缓病菌抗药性产生等优点。
Description
技术领域
本发明属于农药技术领域，具体涉及一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物。
背景技术
氟噻唑吡乙酮是美国杜邦公司2007年研发出的具有全新化学结构的新型植物病原卵菌抑制剂，其化学结构包括了吡唑环、噻唑环及异恶唑啉环，对霜霉病有特效，能显著加强对土豆、葡萄、蔬菜等特产农作物病害的防治。目前国际上杀菌剂抗药性行动委员会(FRAC)将这类杀菌剂命名为哌啶基噻唑异恶唑啉类化合。
琥胶肥酸铜(copper(succinate+glutarate+adipate))，是一种高效低毒广谱性的杀菌剂，其作用机理是铜离子与病原菌膜表面上的阳离子交换，使边缘菌细胞膜上的蛋白质凝固，同时部分铜离子渗透进入病原菌细胞内与某些酶结合，影响其活性。琥胶肥酸铜并对植物生长有刺激作用。
长期单一的使用杀菌剂会导致病菌抗药性的增加，用药量持续增加，对严重污染环境。增效杀菌组合物不仅可以大大提高防效，减少用药量，降低成本，同时还可以避免植物病原菌产生抗性和延缓抗性的产生速度，是解决当前农药单用时抗性和成本问题的一种有效方式。因此，开发对真菌病害有增效作用的杀菌组合物具有重要意义。
发明内容
为了克服上述单一杀菌剂存在的药剂用量大，对环境污染严重、病菌抗性产生速度快等缺点，本发明的目的在于提供一种组分合理，增效作用显著，杀菌效果好，用药成本低，不易产生抗药性、对作物安全的农用杀菌组合物。本发明提供的技术方案为：
一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物，其由氟噻唑吡乙酮和琥胶肥酸铜复配而成。
作为优选，所述的氟噻唑吡乙酮和琥胶肥酸铜的重量比是1:50-50:1。
作为优选，所述的氟噻唑吡乙酮和琥胶肥酸铜的重量比是1:12-12:1。
本发明还提供了一种包含所述的的杀菌组合物的农药制剂，所述的氟噻唑吡乙酮和琥胶肥酸铜的重量占农药制剂总重量的5-80％，余量为农药上可接受的辅助成分助剂、溶剂或填料。
作为优选，所述的氟噻唑吡乙酮和琥胶肥酸铜的重量占农药制剂总重量的15-60％，余量为农药上可接受的辅助成分助剂、溶剂或填料。
作为优选，所述的农药制剂的剂型为可湿性粉剂、水分散粒剂、悬浮剂、颗粒剂或水乳剂等。
本发明的农药制剂中使用的助剂包括溶剂、分散剂、乳化剂、稳定剂、防冻剂、成膜剂、润湿剂等及其它有益于有效成分在制剂中稳定和药效发挥的已知物质，都是农药制剂中常用或允许使用的各种成分，并无特别限定，具体成分和用量根据配方要求通过简单试验确定。
本发明的杀菌组合物在防治水稻、小麦、蔬菜、果树的等作物上的多种病害中应用，尤其适用于防治霜霉病等。本发明的组合物亦可按普通的方法施用，如浇注、喷雾、散布，其施用量随天气条件或作物状态变化。
与现有技术相比，本发明具有如下有益效果：
本发明组分合理，杀菌效果好，用药成本低，且其杀菌效果不是各组分活性的简单叠加，而是有显著的增效作用，对作物安全性好，符合农药制剂的安全性要求。
本发明对农作物霜霉病具有很好的防治效果，可以减轻病害抗药性的产生，减少环境污染。
具体实施方式
下面结合实施例对本发明的具体实施方式进行详细描述，但应当理解本发明的保护范围并不受具体实施方式的限制。
实施例1氟噻唑吡乙酮和琥胶肥酸铜复配对黄瓜霜霉病的室内毒力测定
试验对象：黄瓜霜霉病菌
本试验采用黄瓜霜霉病盆栽测定法在预备试验的基础上，选择2片真叶期、长势一致瓜苗，用油性记号笔写上标签编号、插入盆栽黄瓜苗盆内，按序排放，采用叶面喷雾法，将药剂喷洒于瓜苗叶片上，喷雾处理后将试材在通风橱或温室中阴干24h后接种。在温室中培养7d调查防治效果，以病情指数计算防治效果，用DPS数据处理软件进行统计分析，计算各药剂的EC50，然后按孙云沛法计算共毒系数(CTC)。具体测定结果见表1。
当CTC≤80，则组合物表现为拮抗作用，当80＜CTC＜120，则组合物表现为相加作用，当CTC≥120，则组合物表现为增效作用。
实测毒力指数(ATI)＝(标准药剂EC50/供试药剂EC50)×100
理论毒力指数(TTI)＝A药剂毒力指数×混剂中A的百分含量+B药剂毒力指数×混剂中B的百分含量
共毒系数(CTC)＝[混剂实测毒力指数(ATI)/混剂理论毒力指数(TTI)]×100。
表1氟噻唑吡乙酮和琥胶肥酸铜对黄瓜霜霉病的毒力测定
由表1可知，氟噻唑吡乙酮和琥胶肥酸铜组合使用可有效用于黄瓜霜霉病的防治，特别是当氟噻唑吡乙酮和琥胶肥酸铜配比为1:50-50:1的范围内，组合物对黄瓜霜霉病表现增效作用，其CTC值大于120，增效作用显著。其他配比则表现相加作用。
实施例2制剂实施例
制剂1：30％氟噻唑吡乙酮·琥胶肥酸铜水乳剂
制剂2：28％氟噻唑吡乙酮·琥胶肥酸铜悬浮剂
制剂3：52％氟噻唑吡乙酮·琥胶肥酸铜可湿性粉剂
制剂4：56％氟噻唑吡乙酮·琥胶肥酸铜水分散粒剂
实施例3氟噻唑吡乙酮和琥胶肥酸铜对葡萄霜霉病的田间防效
Claims (5)
1.一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物，其特征在于：其由氟噻唑吡乙酮和琥胶肥酸铜复配而成，所述的氟噻唑吡乙酮和琥胶肥酸铜的重量比是1:50-50:1。
2.根据权利要求1所述的杀菌组合物，其特征在于：所述的氟噻唑吡乙酮和琥胶肥酸铜的重量比是1:12-12:1。
3.一种包含权利要求1至2任一所述的的杀菌组合物的农药制剂，其特征在于：所述的氟噻唑吡乙酮和琥胶肥酸铜的重量占农药制剂总重量的5-80％，余量为农药上可接受的辅助成分助剂、溶剂或填料。
4.根据权利要求3所述的农药制剂，其特征在于：所述的氟噻唑吡乙酮和琥胶肥酸铜的重量占农药制剂总重量的15-60％，余量为农药上可接受的辅助成分助剂、溶剂或填料。
5.根据权利要求4所述的农药制剂，其特征在于：所述农药制剂的剂型为可湿性粉剂、水分散粒剂、悬浮剂、颗粒剂或水乳剂等。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810944455.7A CN108719308A (zh) | 2018-08-19 | 2018-08-19 | 一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810944455.7A CN108719308A (zh) | 2018-08-19 | 2018-08-19 | 一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108719308A true CN108719308A (zh) | 2018-11-02 |
Family
ID=63942971
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810944455.7A Pending CN108719308A (zh) | 2018-08-19 | 2018-08-19 | 一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108719308A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111587889A (zh) * | 2020-07-01 | 2020-08-28 | 安徽省农业科学院植物保护与农产品质量安全研究所 | 一种含氟噻唑吡乙酮和萎锈灵的杀菌组合物 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105941426A (zh) * | 2016-07-25 | 2016-09-21 | 李祥英 | 一种含氟噻唑吡乙酮和琥胶肥酸铜的农药组合物 |
| CN105961406A (zh) * | 2016-08-03 | 2016-09-28 | 田文华 | 一种含氟噻唑吡乙酮和喹啉铜的农药组合物 |
| CN106212476A (zh) * | 2016-08-03 | 2016-12-14 | 田文华 | 一种含氟噻唑吡乙酮和松脂酸铜的杀菌组合物 |
| CN106719710A (zh) * | 2017-01-20 | 2017-05-31 | 广东中迅农科股份有限公司 | 一种含有氟噻唑吡乙酮的杀菌组合物 |
-
2018
- 2018-08-19 CN CN201810944455.7A patent/CN108719308A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105941426A (zh) * | 2016-07-25 | 2016-09-21 | 李祥英 | 一种含氟噻唑吡乙酮和琥胶肥酸铜的农药组合物 |
| CN105961406A (zh) * | 2016-08-03 | 2016-09-28 | 田文华 | 一种含氟噻唑吡乙酮和喹啉铜的农药组合物 |
| CN106212476A (zh) * | 2016-08-03 | 2016-12-14 | 田文华 | 一种含氟噻唑吡乙酮和松脂酸铜的杀菌组合物 |
| CN106719710A (zh) * | 2017-01-20 | 2017-05-31 | 广东中迅农科股份有限公司 | 一种含有氟噻唑吡乙酮的杀菌组合物 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111587889A (zh) * | 2020-07-01 | 2020-08-28 | 安徽省农业科学院植物保护与农产品质量安全研究所 | 一种含氟噻唑吡乙酮和萎锈灵的杀菌组合物 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102204550B (zh) | 一种含有精甲霜灵的杀菌组合物及其用途 | |
| CN101632364A (zh) | 杀菌组合物 | |
| CN107581189B (zh) | 一种含寡糖与吡啶类杀菌成分的组合物 | |
| CN103444728B (zh) | 一种含有双氟磺草胺和苯氧羧酸类除草剂的组合物 | |
| CN108719308A (zh) | 一种含氟噻唑吡乙酮和琥胶肥酸铜的杀菌组合物 | |
| CN104285956B (zh) | 一种含有嘧菌酯和丙烷脒的农药组合物 | |
| CN103329905B (zh) | 一种含氟唑菌苯胺和井冈霉素的杀菌组合物 | |
| CN105409992B (zh) | 一种杀菌组合物及其应用 | |
| CN107318865A (zh) | 克菌丹和呋吡菌胺复配的农药组合物 | |
| CN107372548A (zh) | 含有克菌丹和氟唑环菌胺的农药组合物及其用途 | |
| CN102919259A (zh) | 双胍三辛烷基苯磺酸盐和氟啶胺的农药组合物 | |
| CN105831132A (zh) | 一种含苯噻菌酯和氟醚菌酰胺的杀菌组合物 | |
| CN104957143A (zh) | 含有氟唑菌酰胺和咯菌腈的杀菌组合物 | |
| CN103155924A (zh) | 一种含有吡噻菌胺的杀菌组合物 | |
| CN104957148A (zh) | 含有氟唑菌酰胺和噻唑锌的杀菌组合物 | |
| CN104285989A (zh) | 一种含有吡唑醚菌酯和丙烷脒的农药组合物 | |
| CN106538540A (zh) | 一种含螺环菌胺的杀菌组合物 | |
| CN103598190B (zh) | 一种含噻呋酰胺和啶酰菌胺的杀菌组合物 | |
| CN109169711B (zh) | 一种含申嗪霉素和pyriofenone的杀菌组合物 | |
| CN107751210A (zh) | 一种含吡唑萘菌胺的抗菌组合物 | |
| CN104472490B (zh) | 一种含有啶氧菌酯和溴菌腈的杀菌组合物 | |
| CN108651482A (zh) | 一种含有溴硝醇和噻霉酮的农药组合物 | |
| CN108782579A (zh) | 一种包含克菌丹和联苯吡菌胺的杀菌组合物 | |
| CN107333771A (zh) | 一种含乙基多杀菌素和哒螨灵的杀虫农药组合物 | |
| CN107467036A (zh) | 含有丙硫菌唑和萜烯醇的农药组合物及其应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181102 |