CN108717824A - A kind of aluminium crystalline substance label and preparation method thereof - Google Patents
A kind of aluminium crystalline substance label and preparation method thereof Download PDFInfo
- Publication number
- CN108717824A CN108717824A CN201810357392.5A CN201810357392A CN108717824A CN 108717824 A CN108717824 A CN 108717824A CN 201810357392 A CN201810357392 A CN 201810357392A CN 108717824 A CN108717824 A CN 108717824A
- Authority
- CN
- China
- Prior art keywords
- layer
- crystalline substance
- paper layer
- label
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0257—Multilayer
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0272—Labels for containers
- G09F2003/0273—Labels for bottles, flasks
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to aluminium crystalline substance label technique fields more particularly to a kind of aluminium crystalline substance label and preparation method thereof.Aluminium crystalline substance label provided by the invention includes light oil reservoir, embossing brush layer, aluminizer paper layer and priming coat from top to bottom；The paper layer of aluminizing includes aluminum plated PET layer, rubberised layer, original paper layer and back coating from top to bottom；The aluminum plated PET layer is bonded with original paper layer by the rubberised layer without aluminium face；The aluminum plated PET layer is two-way thermal contraction PET vacuum plated aluminum films；The shrinking percentage of the two-way thermal contraction PET vacuum plated aluminum films is 50-70 DEG C, and longitudinal direction is 30%-45%, is laterally 55%-80%.Aluminium crystalline substance label provided by the invention has paper products label and plastic label advantage, has paper label individual continuous labeling function after printed label, need not replace labelling machine, can accomplish new old product exchange on assembly line labelling machine.It after labeling, is not bubbled wrinkle resistant, does not occur marking scratch mark, be a kind of more satisfactory middle and high end label, be particularly adapted to the beer company that southern moisture is waited.
Description
Technical field
The present invention relates to aluminium crystalline substance label technique fields more particularly to a kind of aluminium crystalline substance label and preparation method thereof.
Background technology
The processing space of Beer Brewage producer compares larger, can not ensure the humiture, particularly plum rains of production site
Season, outdoor and indoor humiture are consistent, so being easy to be bubbled after labeling, cause the out-of-flatness of mark face and existing defects.
The mode of sale and the storage of beer is varied, having that plastic crate fills, have packaging box installed, the general warehouse for storing beer close
It closes and Temperature and Humidity Control is all relatively backward, be easy to crumple after the beer label moisture absorption, the damage of label look image is bigger；Restaurant,
Bar, family have the meeting for liking drinking ice beer to be put into refrigerator or be directly placed into ice water cooling to have reached the refreshing pleasant sensation of ice, from
The label on beer that refrigerator-freezer is taken out is crumpled and mark grabs print and has apparent appearance, takes out that show light be mark in ice water
Grab print, crumple it is particularly evident, it is serious by mark grab print extension there is mark, presentation quality is severely damaged.
It is bubbled, crumples, marking these three problems of keeping the seal always present on beer label, earlier year Chinese beer industry is walked big
Majority is low side route, and attention drinking and selling wine is relatively weaker, and compatriots now want personation and exterior quality
Ask and be also continuously improved, thus bubbling on beer label, crumple, mark three persistent ailments of keeping the seal be damage appearance mortal wound it is necessary
It is renovated, earliest international top-brand is used PET to be processed into pressure sensitive adhesive product as label material and is attached on beer bottle, solves really
This three major issues, but new problem is also subsequently formed, and 1. prices are relatively high；2, labeling is slow.
Invention content
In order to solve the above technical problems, the present invention provides a kind of aluminium crystalline substance label, uses the beer bottle of the aluminium crystalline substance label
Recyclable reuse, canned speed per hour will be at 4.5 ten thousand bottles or more.
Aluminium crystalline substance label provided by the invention includes light oil reservoir, embossing brush layer, aluminizer paper layer and priming coat from top to bottom；
Appropriate primary coat liquid, has obstructed aluminium crystalline substance label before not pasting on beer bottle, to the sensibility of ambient temperature and humidity perfectly.
The aluminizer paper layer includes aluminum plated PET layer, rubberised layer, original paper layer and back coating from top to bottom；The aluminum plated PET
Layer is bonded with original paper layer by the rubberised layer without aluminium face；The aluminum plated PET layer is that two-way thermal contraction PET is vacuum aluminum-coated
Film；The shrinking percentage of the two-way thermal contraction PET vacuum plated aluminum films is 50-70 DEG C, and longitudinal direction is 30%-45%, is laterally 55%-
80%.Since beer bottle needs to reuse, canned speed per hour will at 4.5 ten thousand bottles or more, if directly use body paper as
Label material, the beer label moisture absorption (be put into refrigerator or be directly placed into ice water and cool down) are easy to crumple afterwards or directly fall off, mark
It is bigger to sign image appearance damage；But the adhesion of PET vacuum plated aluminum films and vial is bad, is susceptible to the bad of bubbling
The labeling requirement of middle and high end beer is not achieved in effect, therefore compound with original paper layer progress, and original paper layer is mutually pasted with glass, just
Solve the problems, such as that aluminium crystalline substance label is susceptible to bubbling corrugation.Compound if it is original paper layer and common PET vacuum plated aluminum film, that is very
The de- mark of hardly possible, cannot be satisfied the requirement of beer bottle recycling；It is answered if it is original paper layer and the unidirectional PET vacuum plated aluminum films that are heat-shrinked
It closes, label is easy to shorten a slender type into, float into beer bottle in demoulding, substantially reduces de- mark efficiency, cannot be satisfied beer
Factory's demand.
Wherein, the glue of the rubberised layer of the paper layer of aluminizing includes following components by weight percentage：Curing agent 8-12%,
Polyacrylic acid sodium salt 1-2%, phenolic resin 2-4%, ethyl acetate 40-50%, excess water.Due to two-way thermal contraction PET vacuum
The adhesion of aluminizer and high-end beer body paper layer material is all bad, therefore is hardly formed very stable composite layer.It is returning in this way
When receiving vial, composite layer is easy layering, and the organic efficiency of such vial can be very low.Glue provided by the invention is with poly-
Acrylic acid sodium salt can form good compoiste adhering performance as the wetting agent of glue with phenolic resin, and can be very good will be two-way
It is heat-shrinked together with PET vacuum plated aluminum films and high-end beer original paper layer Material cladding.
Wherein, the body paper layer material of the paper layer of aluminizing wet strong 25-35 grams of body paper in being；The wet drawing of the body paper layer material
Power is longitudinal direction >=8, laterally >=4.
Wherein, by weight the 1 of the material of the body paper layer material and aluminum plated PET layer of the aluminizer paper layer：0.9-1.1 is multiple
It closes.In view of cost and labeling speed, this is by weight 1：0.9-1.1 composite effects are best.
Wherein, the coating of the back coating includes following components by weight percentage：Carboxymethyl cellulose 1-8%, the third three
Alcohol 8-15%, lubrication humectant 0.3-0.8%, water 83-90%.It is more smooth that this back coating infiltrates the paper layer that makes to aluminize.
Wherein, the coating of the priming coat includes following components by weight percentage：Dihydric alcohol 2.1-3.2%, ethyl alcohol
1.9-2.8%, excess water.
The preparation method of above-mentioned aluminium crystalline substance label, includes the following steps：
(1) by the front coating 5-9g/m of the original paper layer2After glue, drying forms rubberised layer, the dry type on rubberised layer
Compound two-way thermal contraction PET vacuum plated aluminum films；
(2) paper layer of aluminizing is prepared：By the backsize back coating coating of the original paper layer, after drying, back coating is formed.
(3) aluminium crystalline substance label is prepared：It is coated with embossing brush layer, light oil reservoir successively on the pet layer of aluminizer paper layer, and is plating
On the back coating of aluminium film paper layer after painting bottom coating, drying printing layer, light oil reservoir and priming coat are to get to aluminium crystalline substance label.
Compared with prior art, the present invention has the advantages that：
The performance of the product；Paper products label and plastic label advantage are combined, is had after printed label made of paper
Individual continuous labeling function of label, need not replace labelling machine, can accomplish that new old product exchanges on assembly line labelling machine.With
Has the advantages of plastic label in water reaction, it is not in upper curling to be placed in water.Not by ambient humidity and timeliness shadow after labeling
Ring, be not bubbled it is wrinkle resistant, do not occur mark scratch mark.It is a kind of more satisfactory middle and high end label, is particularly adapted to southern moisture
The beer company of time.
It is compared with conventional labels, which has the practicability of paper label, also have the appearance of adhesive sticker plastic label
Effect, cost is less than adhesive label, slightly above common papery sticker price, but printing effect and patch bottle appearance are much higher than
Common paper label.
Specific implementation mode
It is that the present invention will be further described for specific implementation mode, but following implementation is only to this hair with lower part
Bright is explained further, and does not represent the scope of the present invention and is only limitted to this, the equivalence replacement that every thinking with the present invention is done,
In protection scope of the present invention.
Embodiment 1-4 prepares aluminium crystalline substance label aluminizer paper layer
The shrinking percentage of the two-way thermal contraction PET vacuum plated aluminum films is 50-70 DEG C, and longitudinal direction is 30%-45%, is laterally
55%-80%, 32g；Body paper layer material wet strong 32 grams of body paper in being；The wet tensile strength of the body paper layer material is longitudinal direction >=8, laterally
≥4；Curing agent is SY-03B.
The coating of back coating includes following components by weight percentage：Carboxymethyl cellulose 1-8%, glycerine 8-15%,
Lubrication humectant (number 060A01) 0.3-0.8%, water 83-90%.
The glue layer of rubberised layer in embodiment 1 includes following components by weight percentage：Curing agent 8%, polyacrylic acid
Sodium salt 1%, phenolic resin 2%, ethyl acetate 40%, excess water.
The glue layer of rubberised layer in embodiment 2 includes following components by weight percentage：Curing agent 12%, polyacrylic acid
Sodium salt 2%, phenolic resin 4%, ethyl acetate 50%, excess water.
The glue layer of rubberised layer in embodiment 3 includes following components by weight percentage：Curing agent 10%, polyacrylic acid
Sodium salt 1.5%, phenolic resin 3%, ethyl acetate 45%, excess water.
The glue layer of rubberised layer in embodiment 4 includes following components by weight percentage：Curing agent 10%, phenolic resin
3%, ethyl acetate 45%, excess water.
Comparative example 1：Prepare aluminium crystalline substance label aluminizer paper layer
PET vacuum plated aluminum films used are that the unidirectional shrinking percentage for being heat-shrinked PET vacuum plated aluminum films is unidirectional 50-70 DEG C,
55%-80%, 32g；Body paper layer material wet strong 25-35 grams of body paper in being；The wet tensile strength of the body paper layer material is longitudinal direction >=8,
Laterally >=4；Curing agent is SY-03B.
The coating of back coating includes following components by weight percentage：Carboxymethyl cellulose 1-8%, glycerine 8-15%,
Lubrication humectant (number 060A01) 0.3-0.8%, water 83-90%.
The glue layer of rubberised layer includes following components by weight percentage：Curing agent 10%, polyacrylic acid sodium salt 1.5%,
Phenolic resin 3%, ethyl acetate 45%, excess water.
The preparation method of embodiment 1-4 and comparative example 1 is：
(1) by the front coating 5-9g/m of the original paper layer2After glue, drying forms rubberised layer, the dry type on rubberised layer
Compound PET vacuum plated aluminum films；
(2) by the backsize back coating coating of the original paper layer, after drying, back coating is formed.
Embodiment 5-8 and comparative example 1 prepare aluminium crystalline substance label
Wherein the coating of priming coat includes following components by weight percentage：Dihydric alcohol 2.1-3.2%, ethyl alcohol 1.9-
2.8%, excess water.
Aluminizer paper layer prepared by embodiment 1-4 and comparative example 1 is corresponded to respectively and is prepared into embodiment 5-8 aluminium crystalline substance labels,
Preparation method is as follows：
It is coated with embossing brush layer, light oil reservoir successively on the pet layer of aluminizer paper layer, and in the back coating of aluminizer paper layer
After upper painting bottom coating, drying printing layer, light oil reservoir and priming coat are to get to aluminium crystalline substance label.
Test result：
De- mark time test method：It is 8cm × 8cm that the specimen page prepared in embodiment 5-8 and comparative example 2, which is cut into area,
Specimen page, and in its backside coating 5g casein glues, then specimen page is attached on clean vial, temperature be 25 ± 3 DEG C and
It is placed 7 days in the laboratory that relative humidity is 50~60%；Then the vial for posting specimen page is immersed into the matter that temperature is 85 DEG C
It measures in the NaOH solution that score is 2.5%, presses timer and start timing, the washing bottle under the stir speed (S.S.) of 300rpm after 1min
Son, terminates timing when specimen page is completely fallen off from vial, then obtains the de- mark time.
| De- mark speed | |
| Embodiment 5 | 187s |
| Embodiment 6 | 163s |
| Embodiment 7 | 154s |
| Embodiment 8 | 272s |
| Comparative example 2 | 265s |
Comparative example 2 has shrink label in de- mark the vial for having 10-15%.
Claims (7)
1. a kind of aluminium crystalline substance label, which is characterized in that the aluminium crystalline substance label includes from top to bottom light oil reservoir, embossing brush layer, aluminizes
Film paper layer and priming coat；
The aluminizer paper layer includes aluminum plated PET layer, rubberised layer, original paper layer and back coating from top to bottom；The aluminum plated PET layer
No aluminium face is bonded with original paper layer by the rubberised layer；The aluminum plated PET layer is two-way thermal contraction PET vacuum plated aluminum films；
The shrinking percentage of the two-way thermal contraction PET vacuum plated aluminum films is 50-70 DEG C, and longitudinal direction is 30%-45%, is laterally 55%-80%.
2. aluminium crystalline substance label according to claim 1, which is characterized in that the glue of the rubberised layer of the aluminizer paper layer is by weight
It includes following components to measure percentage：Curing agent 8-12%, polyacrylic acid sodium salt 1-2%, phenolic resin 2-4%, ethyl acetate 40-
50%, excess water.
3. aluminium crystalline substance label according to claim 1, which is characterized in that the body paper layer material wet strong 25-35 grams of original in being
Paper；The wet tensile strength of the body paper layer material is longitudinal direction >=8, laterally >=4.
4. aluminium crystalline substance label according to claim 1, which is characterized in that the body paper layer material of the aluminizer paper layer and aluminize
By weight the 1 of the material of pet layer：1 is compound.
5. aluminium crystalline substance label according to claim 1, which is characterized in that the coating of the back coating of the paper layer of aluminizing is by weight
Percentage includes following components：Carboxymethyl cellulose 1-8%, glycerine 8-15%, lubrication humectant 0.3-0.8%, water 83-
90%.
6. aluminium crystalline substance label according to claim 1, which is characterized in that the coating of the priming coat includes by weight percentage
Following components：Dihydric alcohol 2.1-3.2%, ethyl alcohol 1.9-2.8%, excess water.
7. the preparation method of any type aluminium crystalline substance label according to claim 1-6, which is characterized in that including following step
Suddenly：
(1) by the front coating 5-9g/m of the original paper layer2After glue, drying forms rubberised layer, the dry type Composite Double on rubberised layer
To thermal contraction PET vacuum plated aluminum films；
(2) aluminizer paper layer is prepared：By the backsize back coating coating of the original paper layer, after drying, back coating is formed；
(3) aluminium crystalline substance label is prepared：It is coated with embossing brush layer, light oil reservoir successively on the pet layer of aluminizer paper layer, and in aluminizer
On the back coating of paper layer after painting bottom coating, drying printing layer, light oil reservoir and priming coat are to get to aluminium crystalline substance label.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810357392.5A CN108717824B (en) | 2018-04-20 | 2018-04-20 | Aluminum crystal label and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810357392.5A CN108717824B (en) | 2018-04-20 | 2018-04-20 | Aluminum crystal label and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108717824A true CN108717824A (en) | 2018-10-30 |
| CN108717824B CN108717824B (en) | 2021-04-20 |
Family
ID=63899246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810357392.5A Active CN108717824B (en) | 2018-04-20 | 2018-04-20 | Aluminum crystal label and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108717824B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109532302A (en) * | 2018-12-11 | 2019-03-29 | 嘉兴市豪能科技股份有限公司 | One kind can wash UV imitating metal stopped out printing beer label and preparation method thereof |
| CN111696424A (en) * | 2020-05-15 | 2020-09-22 | 广东万昌科艺材料有限公司 | Label and preparation method thereof |
| CN116536971A (en) * | 2023-05-15 | 2023-08-04 | 江苏三原色包装科技有限公司 | Aluminum foil paper and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1580161A (en) * | 2003-08-09 | 2005-02-16 | 易志龙 | Void-free coating |
| CN101531079A (en) * | 2009-03-10 | 2009-09-16 | 安徽国风塑业股份有限公司 | Polyester thermal contraction film with balanced thermal contraction performance and production method thereof |
| CN201721724U (en) * | 2009-12-29 | 2011-01-26 | 吴桂谦 | Container with in-mould label |
| CN102822251A (en) * | 2010-03-31 | 2012-12-12 | 可隆工业株式会社 | Heat-shrinkable polyester-based film and heat-shrinkable polyester-based label |
| CN203697603U (en) * | 2013-12-31 | 2014-07-09 | 嘉兴市豪能包装有限公司 | Washable aluminum plated film pressure-sensitive label |
| CN104594123A (en) * | 2014-12-27 | 2015-05-06 | 广东鑫瑞新材料科技有限公司 | Preparation method of aluminized paper for beer labels and aluminized paper obtained by preparation method |
| CN107254272A (en) * | 2017-06-27 | 2017-10-17 | 六安三创建筑材料有限公司 | A kind of environment-friendly plywood adhesive and preparation method thereof |
| CN107610585A (en) * | 2017-09-18 | 2018-01-19 | 江苏景宏新材料科技有限公司 | A kind of preparation for washing transparent thermal contraction type beer bottle label and its wash mark technique |
-
2018
- 2018-04-20 CN CN201810357392.5A patent/CN108717824B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1580161A (en) * | 2003-08-09 | 2005-02-16 | 易志龙 | Void-free coating |
| CN101531079A (en) * | 2009-03-10 | 2009-09-16 | 安徽国风塑业股份有限公司 | Polyester thermal contraction film with balanced thermal contraction performance and production method thereof |
| CN201721724U (en) * | 2009-12-29 | 2011-01-26 | 吴桂谦 | Container with in-mould label |
| CN102822251A (en) * | 2010-03-31 | 2012-12-12 | 可隆工业株式会社 | Heat-shrinkable polyester-based film and heat-shrinkable polyester-based label |
| CN203697603U (en) * | 2013-12-31 | 2014-07-09 | 嘉兴市豪能包装有限公司 | Washable aluminum plated film pressure-sensitive label |
| CN104594123A (en) * | 2014-12-27 | 2015-05-06 | 广东鑫瑞新材料科技有限公司 | Preparation method of aluminized paper for beer labels and aluminized paper obtained by preparation method |
| CN107254272A (en) * | 2017-06-27 | 2017-10-17 | 六安三创建筑材料有限公司 | A kind of environment-friendly plywood adhesive and preparation method thereof |
| CN107610585A (en) * | 2017-09-18 | 2018-01-19 | 江苏景宏新材料科技有限公司 | A kind of preparation for washing transparent thermal contraction type beer bottle label and its wash mark technique |
Non-Patent Citations (1)
| Title |
|---|
| 黎阳辉: "《标签印刷500问》", 31 January 2014, 印刷工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109532302A (en) * | 2018-12-11 | 2019-03-29 | 嘉兴市豪能科技股份有限公司 | One kind can wash UV imitating metal stopped out printing beer label and preparation method thereof |
| CN109532302B (en) * | 2018-12-11 | 2021-05-18 | 嘉兴市豪能科技股份有限公司 | Washable UV metal-like etching printing beer label and preparation method thereof |
| CN111696424A (en) * | 2020-05-15 | 2020-09-22 | 广东万昌科艺材料有限公司 | Label and preparation method thereof |
| CN116536971A (en) * | 2023-05-15 | 2023-08-04 | 江苏三原色包装科技有限公司 | Aluminum foil paper and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108717824B (en) | 2021-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108717824A (en) | A kind of aluminium crystalline substance label and preparation method thereof | |
| CN108656695A (en) | A kind of aluminium crystalline substance label aluminized paper and preparation method thereof | |
| CN206204688U (en) | A kind of not general color dumb light aluminized paper of paint film | |
| CN201172295Y (en) | Washable transparent compound film sticker label | |
| CN104616592A (en) | Edge defoaming anti-counterfeit label and anti-counterfeit packing material | |
| CN102261017A (en) | Manufacturing method of waterborne environmentally-friendly transparent laser transfer paper | |
| CN201148016Y (en) | Washable transparent film self-adhesive label | |
| CN208873395U (en) | A kind of adhesive label with waterproof | |
| CN203200598U (en) | Composite paper with aluminium-laminated film | |
| CN201183342Y (en) | Novel spray-drawing medium material with cold lamination film | |
| CN110484148A (en) | A kind of pressure-sensitive lacquer disk(-sc) mark of local positioning and its production technology | |
| CN210006356U (en) | dry battery label film without backing paper and adhesive sticker | |
| CN102350830B (en) | Solar cooker light reflecting film and fabricating method thereof | |
| CN216749082U (en) | 3D encircles label | |
| CN215068920U (en) | Label with metal feel | |
| CN219044913U (en) | Corrosion-resistant self-adhesive vehicle-mounted label | |
| CN208351815U (en) | A kind of grape wine label | |
| CN219695955U (en) | Reworkable adhesive residue prevention bright silver polypropylene adhesive label | |
| CN111469574A (en) | Gravure online printing structure and printing method of black high-brightness composite paper | |
| CN205827796U (en) | A kind of new Kind of Supermarket label paper | |
| CN201587922U (en) | Digital pre-coated film | |
| CN208315071U (en) | A kind of double-layer label | |
| CN109300415A (en) | Fluorescence indicating sticker | |
| CN220352516U (en) | High-gloss white paperboard | |
| CN205788868U (en) | A kind of novel metal effect adhesive label |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |