CN108715717A - A kind of radiation shielding coating - Google Patents
A kind of radiation shielding coating Download PDFInfo
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- CN108715717A CN108715717A CN201810568363.3A CN201810568363A CN108715717A CN 108715717 A CN108715717 A CN 108715717A CN 201810568363 A CN201810568363 A CN 201810568363A CN 108715717 A CN108715717 A CN 108715717A
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- raw material
- water
- rheological agents
- preservative
- auxiliary rheological
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of radiation shielding coating, is made of following raw material:Raw material A:Water, preservative, dispersant, propylene glycol, wetting agent, antifoaming agent, bentonite, auxiliary rheological agents, AMP95, lotion, raw material B:Titanium dioxide, blanc fixe, dicalcium powder, beech cellulose, preservative, water, raw material C:Lotion, preservative, coalescents, antifoaming agent, AMP95, raw material D:Auxiliary rheological agents, water, compared with prior art, the present invention have following advantageous effect:Under the external influence of sunlight, wind and rain, cold and hot etc., the disadvantages such as cracking, dusting will not occur easily for the coating that coating is formed, discoloration, blister, fall off, staiing, while have radiation-proof effect.
Description
Technical field
The present invention is a kind of radiation shielding coating, belongs to technical field of coatings.
Background technology
Coating belongs to organic chemical industry's macromolecular material, is formed by film and belongs to high-molecular compound type.According to the modern times
The classification of current chemical products, coating belong to fine chemical product.Modern coating is gradually becoming a kind of multi-functional
Engineering material, be an important industry in chemical industry.
Founding of New is over 60 years, and along with the development of national economy every profession and trade, the coatings industry mating as its is from one
A extremely unobtrusive small industry gradually develops into the essential important industry of all fields of national economy.By several generations
Struggle hard, pioneer and keep forging ahead, China has become second-biggest-in-the-world coating material production state and country of consumption, enters world's coating industry
The mainstream of development.
Coating in the prior art is greatly most without anti-radiation performance, so needing to provide a kind of painting with radiation proof function
Expect to meet the market demand.
Invention content
In view of the deficienciess of the prior art, it is an object of the present invention to provide a kind of radiation shielding coating, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the goals above, the present invention is to realize by the following technical solutions:A kind of radiation shielding coating, by with
Lower raw material is constituted:Raw material A:Water, preservative, dispersant, propylene glycol, wetting agent, antifoaming agent, bentonite, auxiliary rheological agents, AMP95,
Lotion, raw material B:Titanium dioxide, blanc fixe, dicalcium powder, beech cellulose, preservative, water, raw material C:Lotion, preservative, at
Film auxiliary agent, antifoaming agent, AMP95, raw material D:Auxiliary rheological agents, water.
Further, it is made of following raw material:Raw material A:Water, preservative, dispersant, propylene glycol, wetting agent, 7010 defoamings
Agent, bentonite, RF15 auxiliary rheological agents, AMP95,8162 lotions, raw material B:R606 titanium dioxides, blanc fixe, dicalcium powder, beech
Cellulose, BIT preservatives, water, raw material C:8016 lotions, preservative, coalescents, 7010 antifoaming agent, AMP95, raw material D:801
Auxiliary rheological agents, water, U902 auxiliary rheological agents, U601 auxiliary rheological agents.
Further, using the beech in Europe, it is first made into wood pulp, then the beech in raw material are processed by spinning technique
Lignose.
Further, the dispersant in raw material A is vinyl bis-stearamides, glyceryl monostearate and three stearic acid
One kind in glyceride.
Further, reaction is added in 1,2- dichloropropanes, water, sodium bicarbonate and hexadecyl tributyl phosphonium bromide together
In kettle, 18h is reacted in the case where 100 DEG C of carbon dioxide divide 1.0MPa, obtains the propylene glycol in raw material.
Further, barium sulfide solution is mixed with the saltcake solution being added after removing calcium, magnesium, is reacted in 80 DEG C,
Precipitation is generated, after suction filtration, washing and pickling, pH value 5~6 is adjusted, refilters, dry, pulverize the precipitated sulfur in obtained raw material
Sour barium.
Further, the coalescents in raw material C are one kind in propandiol butyl ether, propylene glycol methyl ether acetate.
Further, it is made of following steps:The water that input water 140g is first measured in stirring container, then in middle low speed
Put into successively under state preservative 0.5g, dispersant 5g, propylene glycol 5g, wetting agent 1g, 7010 antifoaming agent 2g, bentonite 2g,
RF15 auxiliary rheological agents 2g, then high speed be uniformly dispersed to no particle, then under middle lower-speed state be added AMP951g, 8162
Lotion 140g puts into R606 titanium dioxides 50g, blanc fixe 400g, again in order in the state of middle low speed after mixing
Calcium powder 200g, beech cellulose 1g, BIT preservative 0.5g, are scraped edge powder with scraper, with height behind water 5g cleaning containers side
Speed disperses 20 minutes to fineness 60um hereinafter, being sequentially added into 8016 lotion 20g, preservative 1.5g, film forming under middling speed state
Auxiliary agent 7g, 7010 antifoaming agent 2g, AMP951g, stir evenly, and 801 auxiliary rheological agents 3g, water are then added under high speed state
3g, U902 auxiliary rheological agents 3g, U601 auxiliary rheological agents 4.5g, last moderate-speed mixer form finished product in 10 minutes.
Beneficial effects of the present invention:A kind of radiation shielding coating of the present invention, in the external influence of sunlight, wind and rain, cold and hot etc.
Under, the disadvantages such as cracking, dusting will not occur easily for the coating that coating is formed, discoloration, blister, fall off, staiing, while have anti-spoke
Penetrate effect.
Specific implementation mode
To make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, with reference to
Specific implementation mode, the present invention is further explained.
The present invention provides a kind of technical solution:A kind of radiation shielding coating is made of following raw material:Raw material A:Water, preservative,
Dispersant, propylene glycol, wetting agent, antifoaming agent, bentonite, auxiliary rheological agents, AMP95, lotion, raw material B:Titanium dioxide, sulfate precipitate
Barium, dicalcium powder, beech cellulose, preservative, water, raw material C:Lotion, preservative, coalescents, antifoaming agent, AMP95, raw material D:
Auxiliary rheological agents, water.
As an embodiment of the present invention:It is made of following raw material:Raw material A:Water, preservative, dispersant, propylene glycol,
Wetting agent, 7010 antifoaming agent, bentonite, RF15 auxiliary rheological agents, AMP95,8162 lotions, raw material B:R606 titanium dioxides, precipitated sulfur
Sour barium, dicalcium powder, beech cellulose, BIT preservatives, water, raw material C:8016 lotions, preservative, coalescents, 7010 defoamings
Agent, AMP95, raw material D:801 auxiliary rheological agents, water, U902 auxiliary rheological agents, U601 auxiliary rheological agents.
As an embodiment of the present invention:Using the beech in Europe, it is first made into wood pulp, then add by spinning technique
Work is at the beech cellulose in raw material.
As an embodiment of the present invention:Dispersant in raw material A is vinyl bis-stearamides, stearic acid list glycerine
One kind in ester and glyceryl tristearate.
As an embodiment of the present invention:1,2- dichloropropanes, water, sodium bicarbonate and hexadecyl tributyl phosphonium
Phosphonium is added in reaction kettle together, reacts 18h in the case where 100 DEG C of carbon dioxide divide 1.0MPa, obtains the propylene glycol in raw material.
As an embodiment of the present invention:Barium sulfide solution is mixed with the saltcake solution being added after removing calcium, magnesium, in
80 DEG C are reacted, and precipitation is generated, and after suction filtration, washing and pickling, are adjusted pH value 5~6, are refiltered, dry, pulverize and original is made
Blanc fixe in material.
As an embodiment of the present invention:Coalescents in raw material C are propandiol butyl ether, propylene glycol methyl ether acetate
In one kind.
As an embodiment of the present invention:It is made of following steps:The first metering input water 140g in stirring container
Then water puts into preservative 0.5g, dispersant 5g, propylene glycol 5g, wetting agent 1g, 7010 antifoaming agent successively under middle lower-speed state
2g, bentonite 2g, RF15 auxiliary rheological agents 2g, then high speed be uniformly dispersed to no particle, be then added under middle lower-speed state
AMP951g, 8162 lotion 140g put into R606 titanium dioxides 50g, precipitation in order in the state of middle low speed after mixing
Barium sulfate 400g, dicalcium powder 200g, beech cellulose 1g, BIT preservative 0.5g, are scraped edge powder with scraper, with water 5g
High speed dispersion 20 minutes is to fineness 60um hereinafter, being sequentially added into 8016 lotion 20g, anti-under middling speed state behind cleaning container side
Rotten agent 1.5g, coalescents 7g, 7010 antifoaming agent 2g, AMP951g, stir evenly, and 801 streams are then added under high speed state
Become auxiliary agent 3g, water 3g, U902 auxiliary rheological agents 3g, U601 auxiliary rheological agents 4.5g, last moderate-speed mixer forms finished product in 10 minutes.
As an embodiment of the present invention:A kind of radiation shielding coating of the present invention, in the outer of sunlight, wind and rain, cold and hot etc.
Under boundary's effect, the disadvantages such as cracking, dusting will not occur easily for the coating that coating is formed, discoloration, blister, fall off, staiing, and have simultaneously
There is radiation-proof effect.
As an embodiment of the present invention:National chemical building material is sent by the finished product that above-described embodiment is made to survey
After examination center is detected, show that testing result is:
External Exposure Index(1Ra)
0.05
Outreach services(1r)
0.04
The inside and outside Irradiation index of the sample meets GB6566-2010 after testing《Radioactive material radionuclides limitation》Middle A classes dress
Repair the technical requirement of radionuclide limitation.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention, for this field skill
For art personnel, it is clear that invention is not limited to the details of the above exemplary embodiments, and without departing substantially from the present invention spirit or
In the case of essential characteristic, the present invention can be realized in other specific forms.Therefore, in all respects, should all incite somebody to action
Embodiment regards exemplary as, and is non-limiting, the scope of the present invention by appended claims rather than on state
Bright restriction, it is intended that including all changes that come within the meaning and range of equivalency of the claims in the present invention
It is interior.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (8)
1. a kind of radiation shielding coating, it is characterised in that:It is made of following raw material:Raw material A:Water, preservative, dispersant, propylene glycol,
Wetting agent, antifoaming agent, bentonite, auxiliary rheological agents, AMP95, lotion, raw material B:Titanium dioxide, blanc fixe, dicalcium powder, beech
Cellulose, preservative, water, raw material C:Lotion, preservative, coalescents, antifoaming agent, AMP95, raw material D:Auxiliary rheological agents, water.
2. a kind of radiation shielding coating according to claim 1, it is characterised in that:It is made of following raw material:Raw material A:Water is prevented
Rotten agent, dispersant, propylene glycol, wetting agent, 7010 antifoaming agent, bentonite, RF15 auxiliary rheological agents, AMP95,8162 lotions, raw material
B:R606 titanium dioxides, blanc fixe, dicalcium powder, beech cellulose, BIT preservatives, water, raw material C:8016 lotions, preservative,
Coalescents, 7010 antifoaming agent, AMP95, raw material D:801 auxiliary rheological agents, water, U902 auxiliary rheological agents, U601 auxiliary rheological agents.
3. a kind of radiation shielding coating according to claim 1, it is characterised in that:Using the beech in Europe, first it is made into
Wood pulp, then the beech cellulose that is processed by spinning technique in raw material.
4. a kind of radiation shielding coating according to claim 1, it is characterised in that:Dispersant in raw material A is that vinyl is double
One kind in stearmide, glyceryl monostearate and glyceryl tristearate.
5. a kind of radiation shielding coating according to claim 1, it is characterised in that:1,2- dichloropropanes, water, sodium bicarbonate
It is added in reaction kettle together with hexadecyl tributyl phosphonium bromide, reacts 18h in the case where 100 DEG C of carbon dioxide divide 1.0MPa, obtain
To the propylene glycol in raw material.
6. a kind of radiation shielding coating according to claim 1, it is characterised in that:Barium sulfide solution be added through remove calcium,
Saltcake solution mixing after magnesium, is reacted in 80 DEG C, generates precipitation, after suction filtration, washing and pickling, adjusts pH value 5~6,
It refilters, dry, pulverize the blanc fixe in obtained raw material.
7. a kind of radiation shielding coating according to claim 1, it is characterised in that:Coalescents in raw material C are propylene glycol
One kind in butyl ether, propylene glycol methyl ether acetate.
8. a kind of radiation shielding coating according to claim 1, it is characterised in that:It is made of following steps:First hold in stirring
The water of metering input water 140g, then puts into preservative 0.5g, dispersant 5g, propylene glycol successively under middle lower-speed state in device
5g, wetting agent 1g, 7010 antifoaming agent 2g, bentonite 2g, RF15 auxiliary rheological agents 2g, then high speed be uniformly dispersed to no particle,
Then AMP951g, 8162 lotion 140g are added under middle lower-speed state, after mixing, in the state of middle low speed in order
R606 titanium dioxides 50g, blanc fixe 400g, dicalcium powder 200g, beech cellulose 1g, BIT preservative 0.5g are put into, scraper is used
Edge powder is scraped, with high speed dispersion behind water 5g cleaning containers side 20 minutes to fineness 60um hereinafter, being pressed under middling speed state
8016 lotion 20g, preservative 1.5g, coalescents 7g, 7010 antifoaming agent 2g, AMP951g are added in sequence, stir evenly, then
801 auxiliary rheological agents 3g, water 3g, U902 auxiliary rheological agents 3g, U601 auxiliary rheological agents 4.5g, last middling speed are added under high speed state
Stirring forms finished product in 10 minutes.
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CN201810568363.3A CN108715717A (en) | 2018-06-05 | 2018-06-05 | A kind of radiation shielding coating |
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CN201810568363.3A CN108715717A (en) | 2018-06-05 | 2018-06-05 | A kind of radiation shielding coating |
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CN108715717A true CN108715717A (en) | 2018-10-30 |
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Citations (7)
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CN103562164A (en) * | 2011-05-31 | 2014-02-05 | 陶氏环球技术有限责任公司 | Process for the production of chlorinated propenes |
CN104962148A (en) * | 2015-07-07 | 2015-10-07 | 饶烨 | Antibacterial flame-retardant paint and preparation method thereof |
CN105153753A (en) * | 2015-08-07 | 2015-12-16 | 李涛 | Precipitated barium sulfate and preparation method thereof |
CN105624863A (en) * | 2014-10-28 | 2016-06-01 | 江阴芗菲服饰有限公司 | Anti-radiation cool sense-offered semi-worsted yarn and spinning technology thereof |
CN106700797A (en) * | 2016-12-29 | 2017-05-24 | 三棵树涂料股份有限公司 | Ultrahigh-elasticity flat finishing paint and preparation method thereof |
CN107118627A (en) * | 2017-05-11 | 2017-09-01 | 东莞市金基环保科技有限公司 | Ultralow radiation removes formaldehyde low-carbon health coating |
CN107641386A (en) * | 2017-10-26 | 2018-01-30 | 河北晨阳工贸集团有限公司 | A kind of net taste radiation proof VAE interior wall coatings and preparation method thereof |
-
2018
- 2018-06-05 CN CN201810568363.3A patent/CN108715717A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103562164A (en) * | 2011-05-31 | 2014-02-05 | 陶氏环球技术有限责任公司 | Process for the production of chlorinated propenes |
CN105624863A (en) * | 2014-10-28 | 2016-06-01 | 江阴芗菲服饰有限公司 | Anti-radiation cool sense-offered semi-worsted yarn and spinning technology thereof |
CN104962148A (en) * | 2015-07-07 | 2015-10-07 | 饶烨 | Antibacterial flame-retardant paint and preparation method thereof |
CN105153753A (en) * | 2015-08-07 | 2015-12-16 | 李涛 | Precipitated barium sulfate and preparation method thereof |
CN106700797A (en) * | 2016-12-29 | 2017-05-24 | 三棵树涂料股份有限公司 | Ultrahigh-elasticity flat finishing paint and preparation method thereof |
CN107118627A (en) * | 2017-05-11 | 2017-09-01 | 东莞市金基环保科技有限公司 | Ultralow radiation removes formaldehyde low-carbon health coating |
CN107641386A (en) * | 2017-10-26 | 2018-01-30 | 河北晨阳工贸集团有限公司 | A kind of net taste radiation proof VAE interior wall coatings and preparation method thereof |
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