CN108711516A - The preparation method of Filamentous dye-sensitized solar cell anode - Google Patents
The preparation method of Filamentous dye-sensitized solar cell anode Download PDFInfo
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
- H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Abstract
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：Step 1：The titanium dioxide of 5.2g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol to isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed and obtains anode slurry, and the anode slurry configured is positioned in refrigerator and is stored for future use.
Description
Technical field
The present invention relates to a kind of preparation methods of Filamentous dye-sensitized solar cell anode.
Background technology
The preparation process of Filamentous dye-sensitized solar cell anode is sufficiently complex in the prior art, and holds in sintering process
Easily reunite, influences general effect.
Invention content
The present invention proposes a kind of preparation method of Filamentous dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.1g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
The ability that the Filamentous dye-sensitized solar cell anode being obtained by this method generates photoelectric current is strong, and performance is stablized,
The present invention is simple, easy to spread.
Specific implementation mode
Embodiment 1
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.1g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 2
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.2g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 3
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.3g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 4
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.4g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 5
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.5g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 6
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.6g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 7
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.7g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 8
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.8g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 9
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.9g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 10
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 6g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 11
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, Nml is added（It should
The volume percent of solution is that 10%, N chooses from following numerical value：3.1,3.2,3.3,3.4,3.5,3.6,3.7,3.8,3.9,
4.0）, M ml ethanol solution（The volume percent of the solution is that 15%, M chooses from following numerical value：3.1,3.2,3.3,
3.4,3.5,3.6,3.7,3.8,3.9,4.0）, 1 gram of polyethylene glycol to isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram
Polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, are uniformly mixed and obtain anode slurry, and the anode slurry configured is placed
It is stored for future use in refrigerator；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Claims (2)
1. a kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps：
Step 1：The titanium dioxide of 5.2g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
（The volume percent of the solution is 10%）, 2ml ethanol solution（The volume percent of the solution is 15%）, 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use；
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare；
Step 3：Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050；
Step 4：It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards；
Step 5：It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes；
Step 6：It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium（It is commonly called as N719 ruthenium dyes, molecular formula：C58H86N8O8RuS2）Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
2. the ability that the Filamentous dye-sensitized solar cell anode being obtained by this method generates photoelectric current is strong, and performance is steady
Fixed, the present invention is simple, easy to spread.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810542398.XA CN108711516A (en) | 2016-07-11 | 2016-07-11 | The preparation method of Filamentous dye-sensitized solar cell anode |
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| CN201610540349.3A CN106158388B (en) | 2016-07-11 | 2016-07-11 | The preparation method of Filamentous dye-sensitized solar cell anode |
| CN201810542398.XA CN108711516A (en) | 2016-07-11 | 2016-07-11 | The preparation method of Filamentous dye-sensitized solar cell anode |
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| CN201610540349.3A Active CN106158388B (en) | 2016-07-11 | 2016-07-11 | The preparation method of Filamentous dye-sensitized solar cell anode |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108711514A (en) * | 2016-07-11 | 2018-10-26 | 王瑞明 | The preparation method of Filamentous dye-sensitized solar cell anode |
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| CN102013340A (en) * | 2009-09-04 | 2011-04-13 | 华东理工大学 | Dye sensitized solar cell and preparation method thereof |
| US20130171502A1 (en) * | 2011-12-29 | 2013-07-04 | Guorong Chen | Hybrid electrode and surface-mediated cell-based super-hybrid energy storage device containing same |
| CN103700502A (en) * | 2013-12-30 | 2014-04-02 | 中国科学院上海硅酸盐研究所 | Method for preparing titanium dioxide photo-anode of DSSC (Dye-Sensitized Solar Cell) |
| CN104332311A (en) * | 2014-10-25 | 2015-02-04 | 陕西玉航电子有限公司 | Preparation method of flexible titanium-based titanium dioxide thin film photo-anode |
| CN108711514A (en) * | 2016-07-11 | 2018-10-26 | 王瑞明 | The preparation method of Filamentous dye-sensitized solar cell anode |
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2016
- 2016-07-11 CN CN201810526874.9A patent/CN108711514A/en not_active Withdrawn
- 2016-07-11 CN CN201610540349.3A patent/CN106158388B/en active Active
- 2016-07-11 CN CN201810542398.XA patent/CN108711516A/en not_active Withdrawn
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| CN102013340A (en) * | 2009-09-04 | 2011-04-13 | 华东理工大学 | Dye sensitized solar cell and preparation method thereof |
| US20130171502A1 (en) * | 2011-12-29 | 2013-07-04 | Guorong Chen | Hybrid electrode and surface-mediated cell-based super-hybrid energy storage device containing same |
| CN103700502A (en) * | 2013-12-30 | 2014-04-02 | 中国科学院上海硅酸盐研究所 | Method for preparing titanium dioxide photo-anode of DSSC (Dye-Sensitized Solar Cell) |
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|---|---|---|---|---|
| CN108711514A (en) * | 2016-07-11 | 2018-10-26 | 王瑞明 | The preparation method of Filamentous dye-sensitized solar cell anode |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106158388B (en) | 2019-09-27 |
| CN108711514A (en) | 2018-10-26 |
| CN106158388A (en) | 2016-11-23 |
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