CN108707912A - A kind of high anti-rust cleaning agent of metal - Google Patents
A kind of high anti-rust cleaning agent of metal Download PDFInfo
- Publication number
- CN108707912A CN108707912A CN201810321681.XA CN201810321681A CN108707912A CN 108707912 A CN108707912 A CN 108707912A CN 201810321681 A CN201810321681 A CN 201810321681A CN 108707912 A CN108707912 A CN 108707912A
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- high anti
- rust cleaning
- cleaning agent
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/16—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions using inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of high anti-rust cleaning agent of metal, raw material includes by weight：2.3-6 parts of maleic acid, 0.8-1.7 parts of sodium metasilicate, 3.5-9 parts of polyvinyl lactam, 4.5-8 parts of dimethyl silicone polymer, 3.6-8.4 parts of anhydrous trisodium phosphate, 4.2-5.6 parts of 2,6-di-tert-butyl p-cresol, 1.4-5.3 parts of antirust agent, 1.6-4.3 parts of n-Propyl Bromide, 2.6-4.8 parts of petroleum sodium sulfonate.Cleaning efficiency of the present invention is high, and cleaning speed is fast, and dirt-removing power is strong.
Description
Technical field
The present invention relates to cleaning agent fields, and in particular to a kind of high anti-rust cleaning agent of metal.
Background technology
Anti-rust cleaning agent can effectively remove various pollutants matter (cutting oil, the punching oil generated in metalworking procedures
And the oil etc. used when heat treatment), and there is no corrosivity to metal, there is good oil resistant performance, can disperse rapidly
Polluter is a kind of close environment water solubility degreasing anti-rust cleaning agent with can also embody good cleaning performance on a small quantity.
But with industrialized development, the requirement to cleaning agent also the next high, and is often needed to using traditional cleaning agent
Repeated multiple times cleaning, not only scavenging period is longer, and can not obtain satisfied cleaning performance.
Invention content
Technical problems based on background technology, the present invention propose a kind of high anti-rust cleaning agent of metal, cleaning effect
Rate is high, and cleaning speed is fast, and dirt-removing power is strong.
A kind of high anti-rust cleaning agent of metal proposed by the present invention, raw material include by weight：2.3-6 parts of maleic acid,
0.8-1.7 parts of sodium metasilicate, 3.5-9 parts of polyvinyl lactam, 4.5-8 parts of dimethyl silicone polymer, anhydrous trisodium phosphate 3.6-8.4
Part, 4.2-5.6 parts of 2,6-di-tert-butyl p-cresol, 1.4-5.3 parts of antirust agent, 1.6-4.3 parts of n-Propyl Bromide, petroleum sodium sulfonate
2.6-4.8 part.
Preferably, raw material includes by weight：3-5 parts of maleic acid, 0.9-1.3 parts of sodium metasilicate, polyvinyl lactam 5-7
Part, 5-7 parts of dimethyl silicone polymer, 4.2-6.8 parts of anhydrous trisodium phosphate, 4.8-5.3 parts of 2,6-di-tert-butyl p-cresol, antirust
2.4-4.3 parts of agent, 2.6-3.3 parts of n-Propyl Bromide, 3.6-4.5 parts of petroleum sodium sulfonate.
Preferably, the preparation method of the antirust agent is：Deionized water is added into aluminium triphosphate, is heated to 80-95
DEG C, insulated and stirred 15-25min sequentially adds calcium lignosulfonate and chitosan, is cooled to 50-60 DEG C, be stirred to react 1-3h, is filtered under diminished pressure,
It is dry at 90-100 DEG C, obtain antirust agent.
Preferably, the preparation method of the antirust agent is：Deionized water is added into aluminium triphosphate, is heated to 85 DEG C,
Insulated and stirred 20min, sequentially adds calcium lignosulfonate and chitosan, is cooled to 55 DEG C, is stirred to react 2h, is filtered under diminished pressure, and is done at 95 DEG C
It is dry, obtain antirust agent.
Preferably, aluminium triphosphate, deionized water weight ratio be 1：1.5-2.
Preferably, aluminium triphosphate, calcium lignosulfonate, the weight ratio of chitosan are 1-2：2-3：0.5-0.8.
The present invention can be prepared according to conventional method in the prior art.
A kind of high anti-rust cleaning agent of metal of the present invention, raw material include maleic acid, sodium metasilicate, polyvinyl lactam, gather
Dimethyl siloxane, anhydrous trisodium phosphate, 2,6-di-tert-butyl p-cresol, antirust agent, n-Propyl Bromide, petroleum sodium sulfonate, wherein
Add antirust agent, there is excellently rust-proof effect, and with dimethyl silicone polymer, anhydrous trisodium phosphate, 2,6- di-t-butyls pair
Make final cleaning agent that there is excellent antirust, decontamination and bactericidal effect after cresols compounding, while separation layer can be formed, delays again
The time of secondary corrosion reduces use cost.The present invention changes aluminium triphosphate with calcium lignosulfonate in the preparation process of antirust agent
Property, the rust-proof effect of aluminium triphosphate can be largely improved, addition chitosan can not only promote calcium ion and trimerization
The complexing power of phosphate anion makes to form the passivation protection film of complicated densification in metal surface, while can improve antirust agent
Dirt-removing power, and do not corrode metal parts itself.Cleaning efficiency of the present invention is high, and cleaning speed is fast, and dirt-removing power is strong；Safety
Can be good, it is free from environmental pollution；Energy saving, washing is at low cost.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of high anti-rust cleaning agent of metal, raw material include by weight：2.3 parts of maleic acid, gathers 1.7 parts of sodium metasilicate
3.5 parts of ethernamine, 3.6 parts of anhydrous trisodium phosphate, 5.6 parts of 2,6-di-tert-butyl p-cresol, is prevented 8 parts of dimethyl silicone polymer
Become rusty 1.4 parts of agent, 4.3 parts of n-Propyl Bromide, 2.6 parts of petroleum sodium sulfonate.
Embodiment 2
A kind of high anti-rust cleaning agent of metal, raw material include by weight：6 parts of maleic acid, 0.8 part of sodium metasilicate, poly- second
9 parts of acrylamide, 4.5 parts of dimethyl silicone polymer, 8.4 parts of anhydrous trisodium phosphate, 4.2 parts of 2,6-di-tert-butyl p-cresol, antirust
5.3 parts of agent, 1.6 parts of n-Propyl Bromide, 4.8 parts of petroleum sodium sulfonate；
Wherein, the preparation method of the antirust agent is：Deionized water is added into aluminium triphosphate, is heated to 95 DEG C, protects
Temperature stirring 15min, sequentially adds calcium lignosulfonate and chitosan, is cooled to 60 DEG C, is stirred to react 1h, be filtered under diminished pressure, done at 100 DEG C
It is dry, obtain antirust agent.
Embodiment 3
A kind of high anti-rust cleaning agent of metal, raw material include by weight：4 parts of maleic acid, 1 part of sodium metasilicate, polyethylene
6 parts of amide, 6 parts of dimethyl silicone polymer, 5.5 parts of anhydrous trisodium phosphate, 5 parts of 2,6-di-tert-butyl p-cresol, antirust agent 3.5
Part, 3 parts of n-Propyl Bromide, 4 parts of petroleum sodium sulfonate；
Wherein, the preparation method of the antirust agent is：Deionized water is added into aluminium triphosphate, is heated to 80 DEG C, protects
Temperature stirring 25min, sequentially adds calcium lignosulfonate and chitosan, is cooled to 50 DEG C, is stirred to react 3h, be filtered under diminished pressure, dry at 90 DEG C,
Obtain antirust agent；
Aluminium triphosphate, deionized water weight ratio be 1：1.5.
Embodiment 4
A kind of high anti-rust cleaning agent of metal, raw material include by weight：3 parts of maleic acid, 1.3 parts of sodium metasilicate, poly- second
5 parts of acrylamide, 7 parts of dimethyl silicone polymer, 4.2 parts of anhydrous trisodium phosphate, 5.3 parts of 2,6-di-tert-butyl p-cresol, antirust agent
2.4 parts, 3.3 parts of n-Propyl Bromide, 3.6 parts of petroleum sodium sulfonate；
Wherein, the preparation method of the antirust agent is：Deionized water is added into aluminium triphosphate, is heated to 85 DEG C, protects
Temperature stirring 20min, sequentially adds calcium lignosulfonate and chitosan, is cooled to 55 DEG C, is stirred to react 2h, be filtered under diminished pressure, dry at 95 DEG C,
Obtain antirust agent；
Aluminium triphosphate, deionized water weight ratio be 1：2；
Aluminium triphosphate, calcium lignosulfonate, the weight ratio of chitosan are 1：3：0.5.
Embodiment 5
A kind of high anti-rust cleaning agent of metal, raw material include by weight：5 parts of maleic acid, 0.9 part of sodium metasilicate, poly- second
7 parts of acrylamide, 5 parts of dimethyl silicone polymer, 6.8 parts of anhydrous trisodium phosphate, 4.8 parts of 2,6-di-tert-butyl p-cresol, antirust agent
4.3 parts, 2.6 parts of n-Propyl Bromide, 4.5 parts of petroleum sodium sulfonate；
Wherein, the preparation method of the antirust agent is：Deionized water is added into aluminium triphosphate, is heated to 90 DEG C, protects
Temperature stirring 22min, sequentially adds calcium lignosulfonate and chitosan, is cooled to 58 DEG C, is stirred to react 1.5h, be filtered under diminished pressure, done at 93 DEG C
It is dry, obtain antirust agent；
Aluminium triphosphate, deionized water weight ratio be 1：1.7；
Aluminium triphosphate, calcium lignosulfonate, the weight ratio of chitosan are 2：2：0.8.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of high anti-rust cleaning agent of metal, which is characterized in that its raw material includes by weight：2.3-6 parts of maleic acid, silicic acid
0.8-1.7 parts of sodium, 3.5-9 parts of polyvinyl lactam, 4.5-8 parts of dimethyl silicone polymer, 3.6-8.4 parts of anhydrous trisodium phosphate, 2,
4.2-5.6 parts of 6- di-tert-butyl p-cresol, 1.4-5.3 parts of antirust agent, 1.6-4.3 parts of n-Propyl Bromide, petroleum sodium sulfonate 2.6-4.8
Part.
2. the high anti-rust cleaning agent of metal according to claim 1, which is characterized in that its raw material includes by weight：Malaysia
3-5 parts sour, 0.9-1.3 parts of sodium metasilicate, 5-7 parts of polyvinyl lactam, 5-7 parts of dimethyl silicone polymer, anhydrous trisodium phosphate 4.2-
6.8 parts, 4.8-5.3 parts of 2,6-di-tert-butyl p-cresol, 2.4-4.3 parts of antirust agent, 2.6-3.3 parts of n-Propyl Bromide, mahogany acid
3.6-4.5 parts of sodium.
3. the high anti-rust cleaning agent of metal according to claim 1 or claim 2, which is characterized in that the preparation method of the antirust agent
For：Deionized water is added into aluminium triphosphate, is heated to 80-95 DEG C, insulated and stirred 15-25min sequentially adds calcium lignosulfonate and shell
Glycan is cooled to 50-60 DEG C, is stirred to react 1-3h, is filtered under diminished pressure, dry at 90-100 DEG C, obtains antirust agent.
4. the high anti-rust cleaning agent of metal according to claim 3, which is characterized in that the preparation method of the antirust agent is：
Deionized water is added into aluminium triphosphate, is heated to 85 DEG C, insulated and stirred 20min sequentially adds calcium lignosulfonate and chitosan, cooling
To 55 DEG C, it is stirred to react 2h, is filtered under diminished pressure, it is dry at 95 DEG C, obtain antirust agent.
5. according to the high anti-rust cleaning agent of the metal of claim 3 or 4, which is characterized in that aluminium triphosphate, deionized water
Weight ratio is 1：1.5-2.
6. according to the high anti-rust cleaning agent of any one of the claim 3-5 metals, which is characterized in that aluminium triphosphate, calcium lignosulfonate,
The weight ratio of chitosan is 1-2：2-3：0.5-0.8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810321681.XA CN108707912A (en) | 2018-04-11 | 2018-04-11 | A kind of high anti-rust cleaning agent of metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810321681.XA CN108707912A (en) | 2018-04-11 | 2018-04-11 | A kind of high anti-rust cleaning agent of metal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108707912A true CN108707912A (en) | 2018-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810321681.XA Withdrawn CN108707912A (en) | 2018-04-11 | 2018-04-11 | A kind of high anti-rust cleaning agent of metal |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112663067A (en) * | 2020-11-27 | 2021-04-16 | 刘凯琳 | Environment-friendly quick-drying water-based antirust agent and preparation method thereof |
-
2018
- 2018-04-11 CN CN201810321681.XA patent/CN108707912A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112663067A (en) * | 2020-11-27 | 2021-04-16 | 刘凯琳 | Environment-friendly quick-drying water-based antirust agent and preparation method thereof |
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| WW01 | Invention patent application withdrawn after publication | ||
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Application publication date: 20181026 |